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FIRE RETARDANT
ADDITIVES
FOR WIRE AND CABLE
NON-HALOGEN
FLAME RETARDANCE
SMOKE SUPPRESSION
ELECTRICAL PERFORMANCE
PHYSICAL PROPERTY ENHANCEMENT
F lames
and
S mo k e
D on t
Like
Us
Alumina trihydrate (ATH) and magnesium hydroxide (MDH) are widely used to
make low-smoke and/or halogen-free flame retardant wire and cable compounds
for a range of insulation and jacketing applications. ATH and MDH serve to
retard both flame and smoke via an endothermic reaction that releases water
when heated to decomposition. The metal oxide by-product from decomposed
ATH and MDH, Al2O3 and MgO respectively, also helps form a char on the
polymer, which insulates the polymer from heat and oxygen.
The chart below compares the decomposition characteristics of ATH and MDH. ATH
decomposes at about 220C while MDH decomposes at about 330C, thus, having
a higher thermal stability allowing for a wider window for compounding processing.
100
90
80
ATH
70
MDH
60
0
100
200
300
400
500
Temperature ( C)
Particle Size,
Microns
Product
Description
600
Property
ATH
The ATH or MDH particle properties directly affect compound performance. For your specific application, let Huber
assist110
you with a product recommendation based on our technical expertise. Physical Form
Powder
100
Hexagonal
platelet
Particle Morphology
gonal
Property
ATHpla
Weight Loss
(%)Loss (%)
Weight
Property
ATH
Powder
Physical
Form
90
80
Hexagonal
platelet
Particle Morphology
gonal pla
White
Color
ATH
80
2.42
Specific
70 Gravity, g/cm3
MDH
9-10
pH Value
ATH
2.5-3.5
Mohs Hardness
70
60
1.57
Refractive Index
100 MDH200
300
400
0
220C / 428F
Decomposition
Temperature
Heat
Temperature280
( C)
60of Decomposition, cal/g
34.6%
Theoretical
Loss
on
Ignition,
%
100
200
300
400
0
White
Powder
2.42
Hexagonal
platelet
gonal pla
9-10
White
2.5-3.5
2.42
1.57
9-10
220C / 428F
2.5-3.5
280
1.57
34.6%
220C / 428F
280
34.6%
Color
Physical Form
Specific Gravity, g/cm3
MDH Particle Morphology
pH Value
Color
Powder Mohs Hardness
Specific Gravity, g/cm3
Hexagonal platelet
Refractive Index
pH Value
White
Decomposition Temperature
Mohs Hardness
2.36
Heat of Decomposition, cal/g
Refractive Index
10-11
Theoretical Loss on Ignition, %
Decomposition Temperature
2.0-3.0
Heat of Decomposition, cal/g
1.58
Theoretical Loss on Ignition, %
600
330C / 626F
328
31.0%
600
500
500
Temperature ( C)
Product
2.1 Size,
Particle
1.5
Microns
TM
Performance Benefits
75%
0.005
0.007
55
65
75%
Product Description
TM
75%
5576 mg
291%
Product
TM
TM
6644 mg
1123 psi
1142 psi
MDH
d ATH
d ATH
MDH
TH, low electrolytes
TH, spray-dried bead
1
bution
Hubers Surface-Treated
ATH and
MDH Products
for Wire and Cable Applications
TM
100
0.8
Ultrafine particle size, very low electrolytes
Zerogen
e distribution
Hubers state-of-the-art
the untreated fire retardant
Type surface treatments
Polymerenhance
Systemthe performance
PerformanceofBenefits
ectrolytes additives listed above.
Surface
ST (Fatty Acid)
Polyolefins, PVC
Processability, dispersion
ery low electrolytes
Treatments SG
(Alkyl Silane) Polymer
Polyolefins,System
Elastomers Performance
Processability, dispersion,
Type
Benefitshydrophobicity
Brightness
Dissipation
SA (Aminosilane) Tensile
Polyamides,Elongation
Polyolefins Low
temperature
properties, Compounding
mechanical properties
Surface
ST (Fatty Acid)
Polyolefins, PVC
Processability, dispersion
Strength
Factor
Torque
SP
(Vinyl
Silane)
Polyolefins,
Elastomers
Mechanical
properties,
flame
retardant (FR)
Treatments SG (Alkyl Silane) Polyolefins, Elastomers Processability, dispersion, hydrophobicity
fits
PK (Polymeric)
Polyolefins, Elastomers Processability, FR
SA (Aminosilane) Polyamides, Polyolefins Low temperature properties, mechanical properties
on
SV (Polymeric)
Polyolefins
FR (lower smoke, higher limiting oxygen index [LOI])
SP (Vinyl Silane)
Polyolefins, Elastomers Mechanical properties, flame retardant (FR)
on, hydrophobicity
SF (Phenyl Silane) PVC
Dynamic thermal stability, hydrophobicity
PK (Polymeric)
Polyolefins, Elastomers Processability, FR
erties, mechanical properties
SV (Polymeric)
Polyolefins
FR (lower smoke, higher limiting oxygen index [LOI])
flame retardant (FR)
SF (Phenyl Silane) PVC
Dynamic thermal stability, hydrophobicity
Zerogen 1
291%
291%
1.1
2.1
1.1
1.5
2.7
1.1
1.5
1.1
1
2.7
0.8
5
1.
Zerogen 1
1123 psi 1123 psi
ATH
Micral
932
Product
Micral 1500
Hydral 710
Micral 932
Hydral PGA-SD
Micral 1500
Vertex 60
Hydral 710
Vertex 100
Hydral TMPGA-SD
Zerogen 50
Vertex 60
TM
100
Zerogen
Vertex 100
ZerogenTM 50
Product
Description
1142 psi 1142 psi
ATH
Particle Size,
Microns
Tensile
Strength
Elongation
Tensile
Strength
Elongation
34.6%
Weight Weight
Loss (%)Loss
s on Ignition, % 90
31.0%
Specific Morphology
Gravity, g/cm3
Particle
pH Value
Color
Mohs Hardness
Specific
Gravity, g/cm3
Refractive
pH Value Index
Decomposition
Mohs
Hardness Temperature
Heat of Decomposition,
cal/g
Refractive
Index
Theoretical
Loss
on
Ignition,
Decomposition Temperature%
2.42pla
Hexagonal
platelet
gonal
9-10
White
2.5-3.5
2.42
1.57
9-10
220C
/ 428F
2.5-3.5
280
1.57
34.6%
220C
/ 428F
280
34.6%
90
80
ATH
80
70
MDH
ATH
70
60
Temperature
C)
Zerogen 100SP
Zerogen ( 50SP
TM
TM
200
300
400
500
600
55
65
75%
0.005
Product
Description
Product
0.007
Particle Size,
Microns
291%
Temperature ( C)
5576 mg
100
1123 psi
1142 psi
6644 mg
60
TM
Zerogen 100
TM
291%
75%
291%
100
0.8
Ultrafine
particle
size, verydistribution
low electrolytes
Zerogen
5
Vertex
100
1.
Fine,
uniform
particle
are most critical. The
chart
above highlights
improved performance
for EVAsize
compounds made with
TM
TM size, low electrolytes
Zerogen
50
1
Fine
particle
silane-treated Zerogen 100SP versus a similarly treated Zerogen 50 additive. This Zerogen 100 grade
100
0.8
Ultrafine particle size, very low electrolytes
Zerogen
also provides enhanced
compounding
rheology
as shown.
Type
Polymer System
Performance Benefits
Zerogen 100
1142 psi 1142 psi
Micral
932
2.1 Size, Product
Fine particle size, ground ATH
Product
Particle
Microns
Description
Micral 1500
1.5
Fine particle size, ground ATH
64% of MDH in EVA
Tensile Hydral
Elongation
Brightness1.1 Dissipation Ultrafine
Compounding
710
precipitated
ATH,
low electrolytes
2.1 Factor Fine particle
size,
ground
ATH
ATH Strength Micral 932
(28%
VA, 2 MI)
Torque
PGA-SD
Hydral
1.1
Ultrafine
precipitated
ATH,
spray-dried bead
Micral 1500
1.5
Fine particle size, ground ATH
Vertex 60
2.7
Broad particle
size distribution
MDH
Hydral
710
1.1
Ultrafine
precipitated
ATH, low electrolytes
ZerogenTM 100 is aVertex
newline
of
MDH
products
introduced
to offerparticle
improved mechanical
property
1.5
Fine, uniform
Hydral 100
PGA-SD
1.1
Ultrafine
precipitated size
ATH,distribution
spray-dried bead
balance and enhanced
electrical
and
color
performance
benefits.
The
Zerogen
100
products
are
TM
Zerogen
17
Fine particle
electrolytes
Vertex
6050
2.
Broad
particlesize,
sizelow
distribution
MDH
ATH
TM
TM
Kemgard
Flame
Retardants
and Smoke
Suppressants
ST (Fatty
Acid)
Polyolefins,
PVC
Processability, dispersion
Surface
Hubers
KemgardType
are molybdate-based
flame retardants
anddispersion,
smoke suppressants
Treatments
Polymer
Performance
Benefits
SGproducts
(Alkyl Silane)
Polyolefins,System
Elastomers
Processability,
hydrophobicityused in
EVA and PVC wireSAand
cable
compounds.
When
the
compound
burns,
molybdates
chemically influence
(Aminosilane)
Polyamides, PVC
Polyolefins Processability,
Low temperature
properties, mechanical properties
(Fatty
Acid)
Polyolefins,
dispersion
the Surface
formation of ST
organic
char, effectively
insulating the polymer
from the
heat and oxygen source,
Treatments SP (Vinyl
Polyolefins, Elastomers
Elastomers Processability,
Mechanical properties,
flame
retardant (FR)
(AlkylSilane)
Silane)
dispersion,
hydrophobicity
thereby loweringSGsmoke
and
heatPolyolefins,
release. Kemgard grades
are manufactured
by patented proPK (Polymeric)
Polyolefins, Elastomers
Processability,
FR
SA
(Aminosilane)
Polyamides,
Polyolefins
temperature
mechanical
properties
cesses in which molybdates
are precipitated
on an inertLow
mineral
core. properties,
This coated
core approach
SV
(Polymeric)
Polyolefins
FR
(lower
smoke,
higher
limiting
oxygen
index
SP
(Vinyl
Silane)
Polyolefins,
Elastomers
Mechanical
properties,
flame
retardant
(FR)
makes more efficient use of the molybdate species by maximizing the active surface area, and[LOI])
at a
SFthan
(Phenyl
Silane)
PVC chemicals,
Dynamic
thermal
stability, hydrophobicity
(Polymeric)
Polyolefins,
Elastomers
FR
much lower costPK
pure
molybdate
such asProcessability,
ammonium
octamolybdate
(AOM).
SV (Polymeric)
Polyolefins
Compounders can utilize Kemgard products to replace AOM or partially replace antimony oxide
SF (Phenyl Silane) PVC
Dynamic thermal stability, hydrophobicity
to achieve desirable
smoke suppression performance while
reducing costs and minimizing regulatory
Product
Description
Performance
Benefits
Product
concerns
over antimony oxide use.
Kemgard 700Z
Product
Kemgard 911B
900Z
Kemgard 7
11C
Kemgard
Kemgard 9
1100
Kemgard
11B
Kemgard 911C
Kemgard HPSS
Kemgard 1100
Kemgard HPSS
Tensile
Strength
Elongation
Br
Kemgard products
are available
with hydrophobic,
treatments to reduce
40
42
178
210
2 phr Sb2O3
phr Sb2OHPSS
3
5 phr 4Kemgard
38
40
106
178
No Sb2O3
2 phr Sb2O3
10 phr Kemgard
HPSS
5 phr
Kemgard HPSS
LOI
38
106
moisture pick-up,
improve powder flow
properties and ensure
better dispersion in
the polymer matrix.
4 phr Sb2O3
210
Br
Cost-effective
High
efficiencysmoke
smokesuppressant
suppressant and char former
Cost-effective
thin
High
efficiencysmoke
smokesuppressant,
suppressant suitable
and charfor
former
gauge wire applications
Cost-effective smoke suppressant
Smoke suppressant and char former
Cost-effective smoke suppressant, suitable for thin
gauge wire applications
Smoke suppressant and char former
42
LOI
Elongation
non-functional surface
Tensile
Strength
Performance
Benefits
High efficiency smoke
suppressant and char former
Sb2O3 (D max)
NBS No
smoke
75%
TM
Technical Papers
Huber offers an array of technical papers offering guidance in using its fire retardant performance
additives in wire and cable applications. The following articles are available upon request:
Molybdate / Borate Complexes for Enhanced Cable Compound Fire Performance
60th International Wire and Cable Symposium, 2011
Fire Performance Synergies of Metal Hydroxides and Metal Molybdates in Antimony-Free
Flexible PVC
SPE Vinyltec, 2010
Flame Retardant (FR) Olefinic Polymers Containing Metal Hydroxides
Fire Performance vs. Other Properties Optimization by Surface Modification
2010 BCC Conference on Flame Retardant Polymeric Materials
Enhanced FR Performance Enabled by Magnesium Hydroxide with Metal Molybdates in
EVA Wire and Cable Compounds
Earned the Jack Spergel Memorial Award for Outstanding Technical Paper, 58th
International Wire and Cable Symposium, 2009
Synergies of Metal Hydroxides and Metal Molybdates in Low-Smoke Flexible PVC
57th International Wire and Cable Symposium, 2008
New Magnesium Hydroxides Enabling Low-Smoke Cable Compounds
Wire and Cable Technology International, January 2008
Non-Halogen Flame Retardant Polyolefin Compounds via Synergistic Blends of Metal
Hydroxides and Mineral Fillers
SPE International Polyolefins Conference, 2007
Low-Smoke Flexible PVC Compounds via Metal Hydroxides as Flame Retardants
SPE Vinyltec, 2006
Synergistic Benefits of Metal Hydroxides and Zinc Borate in Flame Retardant Wire and
Cable Performance Compounds
54th International Wire and Cable Symposium, 2005
Use of Surface-Modified Magnesium Hydroxide for Low-Smoke Flame Retardant
Thermoplastics Applications
Intertechs Conference on Functional Fillers for Plastics, 2005
Effects of Morphological and Surface Characteristics of Magnesium Hydroxide on
Performance of Flame Retardant Wire and Cable Compounds
53rd International Wire and Cable Symposium, 2004
Comparison of Ground vs. Precipitated Fine Aluminum Trihydrate for Flame Retardant
Wire and Cable Applications
52nd International Wire and Cable Symposium, 2003
FireRetardantAdditives/WC/RevisionV/Nov11