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Colligative property: physical properties of solutions that are affected by the number
(but not the identity) of dissolved solute particles.
• Include vapor pressure lowering, boiling point elevation, freezing point
depression & osmotic pressure. (based on molal conc.)
The French chemist Francois Raoult discovered the law that mathematically describes
the vapor pressure lowering phenomenon. Raoult's law is given in :
Psolution= χsolvent Psolvent
Raoult's law states that the vapor pressure of a solution, Psolution, equals the mole
fraction of the solvent, χsolvent, multiplied by the vapor pressure of the pure solvent,
Psolvent.
• Boiling point elevation:
○ As you increase the concentration of a solution, the boiling point of the solution
increases.
○ The reason for this is that adding solute decreases the vapor pressure of a
solution because there are fewer molecules at the surface of the solution that
can vaporize. Because liquids boil when their vapor pressure is equal to the
ambient atmospheric pressure, you need to heat them more to make them boil.
∆Tb = Kbm
Where:
∆Tb is the change in boiling point
Kb is the ebullioscopic constant (0.520 C/m for water)
m is the effective molality of the solute
○ Sample problems:
• What is the boiling point of a 1.75 m solution of formaldehyde (H2CO) in
analine? 190.60 C
• What is the boiling point of a 1.75 m solution of Ca3(PO4)2? 104.550 C
• Freezing point depression:
○ Solutions melt at lower temperatures than pure liquids because the solute
molecules disturb the intermolecular forces between the solvent molecules. As
a result, less energy is needed to break up the solid.
○ The rules for determining effective molality are the same as for boiling point.
The only thing different is the constant used.
Example: What is the melting point of a 1.75 m solution of NaCl? -6.510
C
normal normal
solvent freezing kf boiling kb(°C/m)
point (°C/ point
(°C) m) (°C)
water 0.00 -1.86 100.00 0.52
aniline -6.1 -5.87 184.4 3.52
phenol 40.9 -7.27 181.8 3.56
camphor 178.40 -40.00
benzene, 5.48 -5.12 80.15 2.53
C6H6
ether -116.3 -1.79 34.42 2.02