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Typical Properties
These properties are typical but do not constitute specifications.
Appearance
48
pH
7.7 to 8.7
Brookfield viscosity, cP
200 to 500
8.8
0.1072
27
32
3-5
Typical Performance
The following characteristics of coatings based on RHOPLEX AC-3001 acrylic emulsion have been recommended in
our laboratories and at our exposure stations located around the world. These coatings were compared to coatings
based on PRIMAL E-357 emulsion, a similar widely used acrylic vehicle.
Figure 1
Clear Film Water Whitening
RHOPLEX AC-3001 VS PRIMAL E-357
Water-Whitening Resistance
Clear films of RHOPLEX AC-3001 emulsion display excellent resistance to water-whitening in comparison to
PRIMAL E-357 finishes, another widely used vehicle for cementitious coatings, as demonstrated in Figure 1. Not
only do clear films based on RHOPLEX AC-3001 show a minimal amount of whitening under both ambient (25C)
and elevated (45C) water soak temperatures, but they also completely recover to visually clear films when
removed from the water.
CIE Lab L* Scale: 0 (black) to 100 (white)
Each coalesced [15% EB (BOP)] clear latex was drawn down (5 mil opening) on several preweighed 3" x 4"
black Leneta panels, which were then air-dried for several minutes, and placed in a constant temperature
room (CTR) for 24 hours.
Each sample was dried at 60C for 64 hours, and placed in a CTR for 24 more hours.
The samples were weighed, initial L* values were recorded, and clear film water-whitening tests were then
initiated by placing the test samples in ambient temperature (25C) or 45C DI water.
Measurements for L* were taken at the indicated time intervals, and DL* values (measured L* value minus
initial value) were calculated.
Figure 2
Water Resistance of Clear Films
RHOPLEX AC-3001 VS PRIMAL E-357
Water Resistance
In addition to its other features RHOPLEX AC-3001 emulsion provides excellent early water resistance properties
(see Figure 2). As shown, RHOPLEX AC-3001 compares favorably to the much harder and very water resistant
PRIMAL E-357 polymer.
The same steps in sample preparation were taken as in steps 1 and 2 noted under Figure 1.
The samples were then weighed at the same time intervals used in measuring L* values.
The percent water absorbed (clear film water pickup) by the clear film was then calculated as: [(polymer
%
Coalescent*
Block
Resistance**
Print
Resistance**
RHOPLEX AC-3001
32
PRIMAL E-357
55
Binder
* Coalescent: Ethylene glycol monobutyl ether, % BOP required for 28C MFFT.
**Rating: 1 - 10 (10 best)
Substrate: Fiber cement
Conditions: 70C preheat
Face to face block test: 6 hrs/28 psi/50C platens.
Print test: Cheesecloth between samples, 6 hrs/28 psi/50C.
Exterior Durability
Coatings based on RHOPLEX AC-3001 acrylic emulsion provide comparable durability to those based on PRIMAL
E-357 in a variety of formulations (Tables 2-4). Black, brown and green paints at various pigment volume
concentrations (PVC), based on RHOPLEX AC-3001, applied to preheated fiber-cement panels, at various pigment
volume concentrations, compare favorably to PRIMAL E-357 in both accelerated weathering and standard outdoor
exposures.
Table 2
EXTERIOR DURABILITY OF 18 PVC BLACK PAINTS BASED ON
RHOPLEX AC-3001 AND PRIMAL E-357
%
Coalescent*
Appearance**
Efflorescence
Resistance**
Face Cracking**
RHOPLEX AC-3001
10
10
10
PRIMAL E-357
10
RHOPLEX AC-3001
10
10
10
PRIMAL E-357
10
Vehicle
Spring House, PA
Florida
Table 3
ACCELERATED EXPOSURE RESULTS OF RHOPLEX AC-3001 VS PRIMAL E-357
IN 15 PVC, 25 PVC, AND 35 PVC BROWN PAINTS
Accelerated Exposure Condition and Time: QUV ('A') 1000 hr/QUV ('A') 2000 hr
% Gloss Retention
PVC
Efflorence
Resistance*
Face
Cracking*
Color Fade
DE**
60
85
RHOPLEX AC-3001
15
10/10
10/10
0.2/2.7
100/86
98/94
PRIMAL E-357
15
10/10
6/5
0.7/0.6
86/81
98/65
RHOPLEX AC-3001
25
10/10
10/10
0.7/1.4
100/96
96/86
PRIMAL E-357
25
10/10
9/9
0.5/1.0
100/96
96/86
RHOPLEX AC-3001
35
10/10
10/10
1.0/1.3
100/97
86/68
PRIMAL E-357
35
10/10
10/10
0.8/1.2
100/92
93/81
Vehicle
Table 4
ACCELERATED EXPOSURE RESULTS OF RHOPLEX AC-3001 VS PRIMAL E-357
IN 20 PVC GREEN PAINTS
Accelerated Exposure Condition and Time: QUV ('A') 1000 hr/QUV ('A') 2000 hr
% Gloss Retention
PVC
Efflorence
Resistance*
Face
Cracking*
Color Fade
DE**
60
85
RHOPLEX AC-3001
20
10/10
10/10
0.3/0.5
100/100
100/100
PRIMAL E-357
20
10/10
8/8
0.3/0.3
100/100
95/95
Vehicle
Table 5
Moisture Vapor Transmission of Clear Films Based on
RHOPLEX AC-3001 VS PRIMAL E-357
Perm Units*
(grains/ft2/hr/in Hg)
Latex
RHOPLEX AC-3001
PRIMAL E-357
4.4
14.2
A formulation containing latex and coalescent [15% EB (BOP)] was drawn down (3 mils dry) on Teflon-
observed.
Perm values were calculated as grains of water lost per square foot of coating surface, per hour, per inch of
Pounds
95.21
Drew L-108
0.11
Butyl Cellosolve
4.55
Surfynol 104E
0.13
Total
100.00
FORMULATION BC-3001-W1
STARTING POINT 20 PVC WHITE BASECOAT FORMULATION
BASED ON RHOPLEX AC-3001 EMULSION
Materials
Pounds
Gallons
Water
68.2
8.19
QP-4400 (2.0%)
53.4
6.36
6.2
0.67
Triton CF-10
1.6
0.18
4.2
0.57
246.4
7.63
604.7
68.87
54.4
7.14
3.2
0.39
1042.3
100.00
Cowles Grind
Ti-Pure R-960
Letdown
RHOPLEX AC-3001 (48%)
Ethylene glycol monobutyl ether (80%)*
Surfynol 104E
Totals
Formulation Constants
PVC, %
20
Volume solids, %
38.8
Weight solids, %
51.9
approx. 9.0
20
15
VOC, g/L
119.8
VOC, lb/gal
1.0
Note, this level of coalescent is recommended for ambient drying conditions. Elevated
preheat or postheat temperatures would diminish or possibly eliminate the need for
coalescent.
FORMULATION TC-3001-BL1
18 PVC BLACK TOPCOAT FORMULATION
BASED ON RHOPLEX AC-3001 EMULSION
Materials
Pounds
Gallons
Cowles Grind
Water
121.8
14.62
Natrasol 250MR
1.1
0.10
Ammonia (28%)
0.5
0.07
12.1
1.31
3.8
0.51
174.5
4.55
48.3
2.06
605.1
68.92
43.6
5.81
3.2
0.41
Water
13.7
1.64
Totals
1027.7
100.00
Formulation Constants
PVC, %
18
Volume solids, %
37.9
Weight solids, %
50.0
approx. 9.0
18
15
VOC, g/L
119.8
VOC, lb/gal
1.0
Note, this level of coalescent is recommended for ambient drying conditions. Elevated
preheat or postheat temperatures would diminish or possibly eliminate the need for
coalescent.
FORMULATION TC-3001-BR1
15 PVC BROWN TOPCOAT FORMULATION
BASED ON RHOPLEX AC-3001 EMULSION
Materials
Pounds
Gallons
Cowles Grind
Water
84.2
10.11
Natrasol 250HHR
0.7
0.06
Ammonia (28%)
0.4
0.05
8.4
0.91
Nopco NXZ
2.1
0.28
Ti-Pure R-960
1.4
0.04
Bayferrox 318M
76.6
2.00
Bayferrox 130M
17.5
0.43
Bayferrox 3420
10.4
0.31
WG-325 Mica
62.6
2.67
620.5
70.67
43.8
5.83
0.9
0.09
Letdown
RHOPLEX AC-3001 (48%)
Ethylene glycol monobutyl ether*
ACRYSOL RM-825 (25%)
Water
54.6
6.55
Totals
984.1
100.00
Formulation Constants
PVC, %
15
Volume solids, %
37.5
Weight solids, %
47.5
approx. 9.0
20
15
VOC, g/L
119.8
VOC, lb/gal
1.0
Note, this level of coalescent is recommended for ambient drying conditions. Elevated
preheat or postheat temperatures would diminish or possibly eliminate the need for
coalescent.
FORMULATION TC-3001-BR2
25 PVC BROWN TOPCOAT FORMULATION
BASED ON RHOPLEX AC-3001 EMULSION
Materials
Pounds
Gallons
Cowles Grind
Water
133.5
16.03
Natrasol 250HHR
1.1
0.10
Ammonia (28%)
0.6
0.08
13.3
1.44
3.3
0.44
2.2
0.07
121.5
3.17
Bayferrox 130M
38.6
0.95
Bayferrox 3420
16.5
0.48
WG-325 Mica
99.4
4.24
523.3
59.51
25.1
5.01
1.3
0.14
Bayferrox 318M
Letdown
RHOPLEX AC-3001 (48%)
Ethylene glycol monobutyl ether*
ACRYSOL RM-825 (25%)
Water
82.2
8.34
Totals
1061.9
100.00
Formulation Constants
PVC, %
25
Volume solids, %
35.9
Weight solids, %
50.0
approx. 9.0
20
15
VOC, g/L
107.8
VOC, lb/gal
0.9
Note, this level of coalescent is recommended for ambient drying conditions. Elevated
preheat or postheat temperatures would diminish or possibly eliminate the need for
coalescent.
FORMULATION TC-3001-GR1
20 PVC GREEN TOPCOAT FORMULATION
BASED ON RHOPLEX AC-3001 EMULSION
Materials
Pounds
Gallons
Cowles Grind
Water
102.3
12.28
Natrasol 250HHR
0.9
0.08
Ammonia (28%)
0.5
0.07
11.2
1.22
2.8
0.37
121.8
3.77
16.4
0.38
Bayferrox 318M
1.9
0.05
Bayferrox 3420
4.7
0.14
84.3
3.59
608.2
69.27
43.8
5.83
Water
24.6
2.95
Totals
1023.4
100.00
WG-325 Mica
Letdown
RHOPLEX AC-3001 (48%)
Formulation Constants
PVC, %
20
Volume solids, %
39.3
Weight solids, %
51.0
approx. 9.0
17
15
VOC, g/L
119.8
VOC, lb/gal
1.0
Note, this level of coalescent is recommended for ambient drying conditions. Elevated
preheat or postheat temperatures would diminish or possibly eliminate the need for
coalescent.
Type
Supplier
ACRYSOL RM-825
Rheology modifier
Bayferrox 318M
Bayferrox 130M
Bayferrox 3420
Black pigment
Red pigment
Yellow pigment
Miles Inc.
Industrial Chemicals Div.
Pittsburgh, PA
Defoamer
Butyl Cellosolve
Coalescent
Green pigment
Dowanol PnB
Dowanol DPnB
Coalescents
Dow USA
Midland, MI
Drew L-108
Defoamer
Nopco NXZ
Defoamer
QP-4400
HEC Thickener
Natrasol 250HHR
Natrasol 250MR
HEC Thickeners
Hercules Inc.
Wilmington, DE
Surfynol 104E
Surfynol 104H
Surfactants
TAMOL 731
Dispersant
Ti-Pure R-960
Titanium dioxide
pigment
Triton CF-10
Wetting agent
WG-325 Mica
Extender
ACRYSOL, RHOPLEX, PRIMAL, and TAMOL are trademarks of Rohm and Haas Company, Philadelphia, or its subsidiaries or affiliates.
ACRYSOL, RHOPLEX, and TAMOL are intended to designate goods marketed in North and South America; the same goods may be marketed
in other countries, generally under other Company trademark designations.
Suggestions for use of our products are based on information we believe to be reliable. They are offered in good faith, but without
guarantee, as conditions and methods of use of our products are beyond our control. We recommend that the prospective user determine
the suitability of our materials and suggestions before adopting them on a commercial scale. None of these suggestions should be construed
as recommending use of our products in violation of any patent or as permission or license to use any patents of Rohm and Haas Company.
Rohm and Haas Company maintains Material Safety Data Sheets (MSDS) on all of its products described in this publication. As the MSDS
contain pertinent information that you may need to protect your employees and customers against any known health or safety hazards
associated with our products, we recommend that you obtain copies of these documents for each product before its use in your facilities. We
also suggest that you contact your suppliers of other materials recommended for use with our products for appropriate health and safety
precautions prior to their use.