Professional Documents
Culture Documents
Wastewater Treatment
Secondary Treatment
Biological Removal of BOD
Ponds
Activated Sludge
High Rate Processes
lagoons
UASB
digesters
CHNG 3804
Fariba Dehghani
Nitrogen
Phosphorus
Microbial Metabolism
Continuous and sequential batch reactor (SBR)
Effluent
Influent
Sludge Management
Anaerobic Digestion
Composting
Process Microbiology
Pseudomonas
Zoogloea
Achromobactor
Flavobacterium
Nocardia
Bdellovibria
Mycobacterium
Nitrosomonas
Nitrobacter
Sphaerotilus
Beggiatoa
others
Waste Sludge
Complex compounds
+O2 +bacteria
CO2 + H2O +
more bacteria
Sludge
Draw
Fill
Add Substrate
Influent
effluent
Remove effluent
React
Idle
Reaction time
5
Settle
Waste sludge
3
Clarity
Trickling Filter
Trickling Filter
Rotating Distributor
Effluent
Influent
Design process, key parameter is surface hydraulic loading rate.
The volume is then calculated from BOD5 loading.
Trickling Filter
Trickling Filter
Low-rate
Intermediate
-rate
Highrate
Super highrate
Anaerobic
Roughing
50-190
Advantages
Produces CH4 gas
Lower sludge disposal costs
Disadvantages
Longer Start-up
Susceptible to failure
0.5-1.6
1.5-7.5
1-2
3-10
5-10
Production of hydrogen
sulfide
0-1
1-2
1-2
1-4
Elimination of off-gas
pollution (aeration strips
VOC)
80-90%
50-70%
65-85%
60-80%
40-65%
high
partial
low
low
none
Filter Media
Rock/Slag Rock/Slag
Rock
Plastic
Plastic/
Wood
Loading
(m3/m2/d)
1.2-3.5
3.5-9.4
9-38
12-70
BOD5
loading
(kg/m3/d)
0.08-0.4
0.25-0.5
0.5-1
Depth (m)
2-3
2-3
Recirculation 0
Rate
BOD5
removal
efficiency
Nitrification
Anaerobic Ponds
Maximum Aeration
Intensity (g/m3/h)
Energy Required
(kg O2/kWh)
200
1.5-3.6
Coarse Bubble
static diffuser
100
0.9-1.2
Vertical
Mechanical
Aerator
Horizontal
Mechanical
Aerator
125
1.5-2.2
pH needs to be 6.4-7.8
Excessive feeding causes pH to drop and Methane
formation to cease
Scum
100
Complex
compounds
1.2-2.4
methane
CO2 + H2
Sludge
Typical Values
Units
Load
300-600
kgBOD5/ha/d
Load
0.1-0.2
kgBOD5/m3/d
Temperature
25-35
oC
HRT
6-20
days
Influent COD
1000-3000
mg/L
Effluent COD
200-500
mg/L
Facultative Ponds
Shallower pond than anaerobic (1.5-4 m)
Two zone environment
Top section of pond is aerobic
Lower section is anaerobic
Typical Values
Oxidation/Aerobic Ponds
Natural Oxygenation
Units
Wind
Photosynthesis
Load (T>15oC)
40-140
kgBOD5/ha/d
Load (T<15oC)
20-40
kgBOD5/ha/d
HRT
5-30
days
Shallow, 1-1.5 m
Low organic loading, suitable for treating effluent
from anaerobic ponds
Must be careful not to overload and turn the
pond anaerobic
Which in turn causes odor problems
COD/m3/day
Load: 100kg
HRT: as low as 1-2 hrs
COD removal up to 85%
Advantages:
UASB
UASB
Methane
Hydrolysis
Treated
Effluent
Acidogenesis
Conversion of soluble compounds to short chain fatty
acids
Acetogenesis
Conversion of other acids into acetic acid
Methanogenesis
Gas is collected
below water level
to reduce
turbulence at the
overflow
Need uniform
distribution
Channeling is a
potential problem
Gas
Collectors
Sludge
Blanket
Loading 4-12 kg
HRT 4-12 hours
85% COD removal
Revision Questions
1.
2.
3.
5.
1.
Volume?
Area?
3.
4.
5.
2.
4.
Revision Questions
Volume?
Area?
rs =
m X
Y
S
(K s + S )
rX = m X
S
kd X
Ks + S
Kinetic Parameters
(Domestic Wastewater)
Coefficient
m
Range
0.1-0.5
hr-1
Typical
0.12 hr-1
Ks
25-100 mgBOD5/L
60 mgBOD5/L
0.4-0.8
mgVSS/mgBOD5
0.6 mgVSS/mgBOD5
kd
0.002-0.003hr-1
0.0025hr-1
The yield can include the effects of endogenous respiration, e.g. the cells consuming
dead cells, in which case it is called the observed yield. (see chapter 8 Metcalf and
Eddy)
Kinetic Parameters
(Industrial Wastewater)
Ks
kd
Basis
Textile
0.1-7
90
0.5-0.7
0.01-0.1
BOD5
Poultry
500
1.3
0.7
BOD5
Meat
0.9
150-300
0.3-0.4
0.03-1.0
COD
Skim
milk
2.5
100
0.5
0.04
BOD5
Influent
(1+)Q, Sa, Xa
(1-)Q, Se, Xe
Effluent
Aerobic Reactor
Volume V
Sr, Xr
Q
(+)Q
Q Waste Sludge
Assumptions
Steady-state
No biomass in influent (X0=0)
Assume no reaction occur in the clarifier
Influent
(1+)Q, Sa, Xa
(1-)Q, Se, Xe
Effluent
Aerobic Reactor
Volume V
Sr, Xr
Q
(+)Q
Q Waste Sludge
0 = (1 )QX e QX r + VX a rx
Out
Waste
Growth
SRT Range
(days)
1-2
Temperature
Conversion of particulate
organics
2-4
Temperature
1-2
Temperature
3-18
Temp/specific
population/compounds
Biological Phosphorous
Removal
2-4
Temp/specific
populations
Stabilisation of AS
20-40
Temp
Degradation of Xenobiotic
compounds
5-50
Temp/specific
population/compounds
Example 1
An activated sludge plant is processing 3,800
m3/d.
The COD of the influent is 100 mg/L and the
COD of the effluent is 30 mg/L.
The observed yield is 0.3 mg/mg (1 kg of Sludge
has a COD of 1.4 kg)
What is the daily rate of sludge production?
What is the rate of oxygen consumption?
O2 consumption = (1-Yobs)*(S0-Se)
Tertiary Treatment
Example (Continued)
3800 (m3/d) x 1000 (L/m3)x(100-30)/1000 (g/mg)/1000
(kg/g)=266 Kg COD removed
biomass produced from COD: 0.3 x 266 = 79.8 Kg
Adsorption Systems
Adsorption Equilibria
Is defined as follows:
qe =
(C o C )V
M
Where
qe : equilibrium contaminant concentration (mg contamination/g
adsorbent)
Co : initial contamination Conc. In solution (mg/L)
C: equilibrium contamination concentration in solution (mg/L)
M: Mass of adsorbent (g)
Batch
stirred tank with filtration/sedimentation
Low capacity
Continuous
Fluidized bed
Fixed bed in series
Others
Ion Exchange
Ion Exchange
Wetland Systems
influent
influent
Seal
Effluent
Filtration
Removal of solid residue and pathogens from effluent
after secondary treatment.
Solid is removed by straining, precipitation and
flocculation
Continuous or intermittent process can be used.
Most common is semi continuous, cleaning the filter by
reverse flow (back washing).
Seal
Effluent
Organic nitrogen
(protein, Urea)
O2
Nitrite (NO2-)
O2
Nitrate (NO3-)
Denitrification
Nitrification/Denitrification
Nitrification/Denitrification
Nitrogen can occur in many forms in wastewater
and undergo numerous transformations in waste
water treatment.
Ammonia-nitrogen convert to product such as
nitrogen gas.
Two principle mechanisms are assimilation and
nitrification-denitrification.
Nitrogen is nutrient and can be incorporated into
the cell mass.
Organic carbon
Nitrification
Nitrification
Nitrifiers are autotrophic bacteria.
They obtain their carbon, used for cell synthesis from CO2.
Organic nitrogen
(net growth)
Organic nitrogen
(Bacterial cells)
Ammonia nitrogen
Nitrification
Denitrification
The key factor affecting nitrogen removal include, pH, temperature, age of
sludge, dissolved oxygen, and feed composition.
10
Denitrification
Phosphorous Removal
BNR Metabolism
Heterotrophic carbon oxidation (aerobic)
Heterotrophic denitrification and carbon
oxidation (anoxic)
Autotrophic nitrification (aerobic)
Heterotrophic phosphate release and carbon
uptake (anaerobic)
Heterotrophic phosphate uptake and carbon
oxidation (anoxic)
Heterotrophic phosphate uptake and carbon
oxidation (aerobic)
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AlPO4 + nH+
Wastewater Treatment
Primary treatment
settling
removes BOD (COD or C)
Secondary treatment
COD removal (some N and P)
Tertiary treatment
biological nutrient removal (BNR)
removes C, N, P
polishing (wetlands, sand filtration, etc)
disinfection
Anoxic
NO3 => N2
Aerobic
NH3 => NO3
The recycle from the aerobic to the anoxic is large ~ 5-20 times the influent feed rate
Anaerobic
Aerobic
Aerobic conditions
utilise stored RBCOD and take up ortho-phosphates
in excess of what they released
12
Modified Bardenpho
Anaerobic Anoxic
Aerobic
Anoxic
Aerobic
Aerobic
Standard UCT
Anaerobic
Anoxic
Aerobic
Heuristics
13
V
HRT
=
WF
W
where :
W = wasting ratio (fraction of F)
Effect of SRT
Phosphorous removal capacity depends
on PAO density.
Nitrification depends on autotrophic nitrifier
density and denitrifier density.
Longer SRT more biomass more
nutrient removal.
Longer SRT accumulation of inert
particulates larger secondary settling
tank (longer settling time).
Sludge Management
Sludge - solids streams are a by-product
of many primary secondary and tertiary
treatment processes.
Organic sludges can be used for
Digestion
Soil amendment
Land spreading
Other Stages
At this point we have removed many
contaminants from the waste water stream
But we still have to deal with the sludge we are
producing
and
Disinfect the water before recovery/discharge
Sludge Management
Sludge - solids streams are a by-product of
many primary secondary and tertiary treatment
processes.
Organic sludges can be processed by digestion
or composting to reduce solid mass.
Soil amendment
Land spreading
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Sludge Management
Organic
Digestion
Soil amendment
Animal feed
Land spreading
Chemical
Reuse by another industry
Incineration
landfill
Digestion
The purpose of digestion is to remove volatile
solids from the sludge
The digestion can be aerobic or anaerobic
Anaerobic reactors tend to be the more popular
as they can generate methane and hence
energy
They are typically egg shaped and a portion of
the biogas produced is reinjected to mix the
contents.
Anaerobic Digestion
Anaerobic Digestion
solid organic
compounds
hydrolytic
enzymes
STAGE 1
soluble organic
compounds
acidogenic
bacteria
volatile aromatic
compounds, VFA
reduced nitrogen
and sulfur
compounds
acidogenic
bacteria
VOC
acidogenic
bacteria
acetic acid
STAGE 2
acidogenic
bacteria
CO2
H2
hydrogenutilising
methanogens
acetoclastic
methanogenic
bacteria
STAGE 3
methane
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Anaerobic Digestion
Note anaerobic digesters also produce a lot of
CO2, typically the biogas is 60-70% methane
and 30-40% CO2.
The production of this CO2 causes the pH to
drop, hence you need alkalinity.
This is of great importance due to methanogens
being inhibited below a pH of 6.8.
Sulfate Reducers
Sludge Drying
Sludge Composting
Sludge Composting
Windrow
The sludge is placed in an open pile and
mechanically turned to provide aeration.
Requires around 30 days
Static Pile
Air is supplied mechanically
Requires around 30 days
In-vessel
Compost is mechanically stirred and aerated
Higher capital cost, but lower labour and land costs,
odour problems less likely
16
Disinfection
http://www.sydneywater.com.au/EnsuringTheFuture/Biosolids/
Membranes in Wastewater
Membranes in Wastewater
Size of Plant
Cl2
ClO2
O3
All
Small/Med
Med/Large All
UV
Lime
Membrane
Med/Large Large
Cost
Capital
Low
Med
High
Low
High
High
Operating
Low
Med
High
Low
High
Med
Maintenance Low
Med
High
Low/Med
High
Med
Contact
Time
Long
Mod/Long
Mod/Long
Short
Very Short
Mod
Safety
Concern
High
Med
Low
None
Low
None
Kills
Bacteria
Good
Good
Good
Virus
Poor
Good
Good
Unknown
Good
Unknown
Fish Toxicity
Yes
Yes
Slight
No
Mod
No
Hazardous
Products
Yes
Yes
Unknown
Unknown
Sludge
Unknown
Residual
Time
Long
Mod
Short/no
None
Short
No
This table is adapted from IWES 2005, see Metcalf and Eddy p 1222 for original
Adapted from IWES workshop
17
Summary
This lecture we have looked at
Activated Sludge
Tertiary Treatment
Biological Nutrient Removal
Sludge Management
Disinfection
References
Wastewater Engineering, Treatment, Disposal and
Reuse by Metcalf and Eddy
http://www.geocities.com/RainForest/5161/water1.ht
m
http://www.geocities.com/RainForest/5161/wwtps.
htm
http://www.gocolumbiamo.com/PublicWorks/Sewer/w
wtppg_4.php
http://en.wikipedia.org/wiki/Sewage_treatment
http://ohioline.osu.edu/aex-fact/0768.html
http://www.mhhe.com/engcs/civil/metcalf/information/chapter1.p
df
18