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This booklet contains 24 printed pages. YZ PAPER - 1: MATHEMATICS, PHYSICS & CHEMISTRY peat Bhekdet Cade, Do not open this Test Booklet until you are asked to do so. Read carefully the Instructions on the Back Cover of this Test Booklet. Important Instructions : 1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use of pencil is strictly prohibited. 2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and fill in the particulars carefully. 3. The test is of 3 hours duration. 4, ‘The Test Booklet consists of 90 questions. The maximum marks are 360. 5. There are titree parts in the question paper A, B, C consisting of Mathematics, Physics and ‘Chemistry having 30 questions in each part of equal weightage. Fach question is allotted 4 (four) marks for correct response. 6. Candidates will te awarted marks as stated above in instruction No. 5 for correct response of each question. 4 (one fourth) marks will be deducted for indicating incorrect response ofeach question. No deduction from the total score will be made if no response is initicated for an item in the answer sheet, 7. There is only one correct response for each question, Filling up more than one response in any question will be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6 above. 8. Use Blue/Black Ball Point Pen only for writing particulars/ marking responses on Side-1 and Side-2 of the Answer Sheet. Use of pencil is strictly prohibited, 9, No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any electronic device, etc. except the Admit Card inside the examination hall/room. 10. Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is given at the bottom of each page and in 3 pages (Pages 21 - 23) at the end of the booklet. 11. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them. 12. The CODE for this Booklet is R. Make sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this booklet. In case of discrepancy, the candidate should immediately report the maiter to the Invigilator for replacement of both the Test Booklet and the Answer Sheet. 13. Do not fold or make any stray marks on the Answer Sheet. EAL PART A — MATHEMATICS Ifthe equations x2+2«+3=0 and ax* Fbx+o=0, a, bce R, have a common root then a:b :e is Q) 3:1:2 Qe 1:2:3 @ a22n (4) 1:3:2 are coplanar, then k can have : @) exactly three values Q) any value. G) exactly one value (2) exactly two values. Mx, yy 2 are in AP. and tan~'y, tan“ly and tan” tz are also in AP. , then: Q) 6r=4y=32 2) @) %r=3y=6z (4) bray 4 At present, a firm is manufacturing 2000 items. It is estimated that the rate of change of production P w.r.t. additional number of workers x is given by = 100- 12v¥ dx 25 more workers, then the new level of If the firm employs production of items is: (4500 @) 2500 @) 3000 (3500 St the foci of the ellipse — + 16 having centre at (0, 3) is: @) Pty -eyt5=0 oy @ @) tas HE P=|1 3. 3/is the adjoint of a3x3 [244 matrix A and |A| = 4, then wis equal to : ao Qa eo ays R/Page 2 SPACE FOR ROUGH WORK Consider Statement -1; (p © ~ q) a (~ pag) is a fallacy. Statement -IL: (p is a tautology. Mole q> ~p) (1) Statement - 1 is false; Statement - I * is irue Q) Statement-Tis true; Statement - His truc; Statement - II is a correct explanation for Statement - I @) Statement -Tis true; Statement ~ Lis true: Statement - II is nat a correct explanation for Statement - 1 (2) Statement - Lis trne; Statement - His false. 8 The coordinate of the incentre of the triangle that has the coordinates of mid points of its sides as (0, 1) (1, 1) and (1, 0) is GQ) 1-2 Q a4 @ aw G14 v2 9. ‘The real number f for which the equation, 2x) | 3r+k=0 has lwo distinct real roots in 0, 1] (1) does not exist. (2) lies between 7 and 2. (3) lies between 2 and 3. (4) lies between —1 and 0. 10. fred = Hx}, then J 8 f¢ is equal to: a) gle?) - fru(jax] +c a 2 Les8)- f2a)a]+c Puls) - 8 Jev(ejax +c @) 4 PE!) —fraejar ec 1. The number of values cf k, for which the system of equations (k+1)x +8y=4k k-1 ket (K-43), hhas no solution, is a 3 2) infinite @) 1 @ 2 12. Let T,, be the number of all possible triangles formed by joining vertices of an n-sided regular polygon. IFT, ,—T,,=10, then the value of nis : a) 8 Q) 7 @ 5 @ 10 R/Page 3 SPACE FOR ROUGH WORK 18. Given : A circle, 2x?+2y?—5 and a | 16. Statement -1! parabola, y2= 45x. % Statement An equation of a The value of the integral f 4% __ common tangent to these curves is a ie ji Halong gene ade ‘sequal to 7 Statement - IT: If the line, skeet lite = Bel : b 2 y= mx + => (m0) is their common fiese~ fp ane mae tangent, then m satisfies m—9m?-+2=0, 5 a (1) Statement - I is false; Statement - I (1) Statement - 1 is false ; Statement - II is true. as tue Q) Statement -Lis trae; Statement - 1 is (2), Sei nent - 1 bytrue Statement is true; Statement - Il is a correct true; Statement - I] is a correct oa eter fae coer explanation for Statement - 1 (3) Statement - is tras; Statement - Il is @) Statement -1 is true; Statement =I is ue SH tania 71 48 TRO OW truc; Statement - IL is not a correct explanation for Statement - I explanation for Statement - | (2) Statement Tis true; Statement - Is (4) Statement - Lis true; Statement - is false. false. + 17. Ify=sec(tan ty), then © atx=1 is equal 14. ‘The area (in square units) bounded by the oa curves y= Vr, 2y-x+3=0, x-axis, and a) Vz lying in the first quadrant ie 1 z 2 OF a f Q) 9 ee @) 36 a 4 @) 18 18. If z is a complex number of unit modulus Aer ne Geprtealoa A SRA and argument 6, then arg (143) cor tan can be written as suum (1) seca +cosecA / Oy way Q) sind cosA+1 Gi =e @) sec cosecA +1 @ (land teotA @ R/Page 4 SPACE FOR ROUGH WORK a) * FS eon . wt z Ae ** 19. All the students of a class performed poorly in Mathematics. The teacher decided to give grace marks of 10 to each of the students. Which of the following statistical measures will not change even after the grace marks were given ? ()- variance 2) mean @) median (4) mode 20. A ray of light along x + /3y ~ V3 gets reflected upon reaching x-axis, the equation of the reflected ray is : ) vBy= Statement Titus Sta eanent Souths. “They: heye'ecemmoromagned true, Statement -II is the correct equator and are separated by a distance Seplanation of Gisteniane “1 of 20.0 cm. The value of the resultant horizontal magnetic induction at the mid - point © Of the line joining their ue cae 3) Statement -1is true, Statement - is (Horizontal component of carth’s iushabement= Ia nokihe couse magnetic induction is 36% 10-5 Wb/m2) expan Bes beenient—[ @) 5.80% 10-+ Wb/m? Q) 3.6«1079 Wb/m2 (3) 256x104 Wb/m? (4) Statement - 1 is true, Statement - Il is (@ 350x10-* Wb/m? false R/Page 8 SPACE FOR ROUGH WORK, 37. An ideal gas enclosed in a vertical cylindrical container supports a freely moving piston of mass M. The piston and the cylinder have equal cross sectional area A. When the piston is in equilibrium, the volume of the gas is Vp and its pressure is Pp, The piston is slightly displaced from the equilibrium position and released. Assuming that the system is completely isolated from its surrounding, the piston executes a simple harmonic motion with frequency : 1 [MM 0 oe Yaar Arty @ ay YM 1 VoMPy © wan 38, Let [eq] denote the dimensional formula of the permittivity of vacuum. If M=mass, L=length, T=time and A=electric current, then : 0) td @ [el=IM* Ll [MT L2T-1 A] 3) [egl=IM~EL-3 Tt a2] @) fel=IM7t 1? T71 A~4) vy OG The above p-v diagram represents the thermodynamic cycle of an engine, operating with an ideal monoatomic gas, The amount of heat, extracted irom the source ina single cycle is : (1) 4P0¥9 Q) rove 1B) @) (Fev @ & po vo 40. A projectile is given an initial velocity of (? tai has, where jis along the ground and j is along the vertical, If g=10 m/s%, the equation of its trajectory (1) 4y=2x- 25? Q) y=x—5x2 @) y=2x—5x? (4) 4y=2x—5x? R/Page 9 SPACE FOR ROUGH WORK a os S we 41, A beam of unpolarised light of irtensity Iy is passed through a polaroid A and then through another polaroid B which is oriented so that its principal plane makes an angle of 45° xelative to that of A. The Intensity of the emergent light is + GQ) 1/8 2) Jy ©) ly2 @ 4 42, A diode detector is used to detect an amplitude modulated wave of 60% modulation by using a condenser of capacity 250 pica farad im parallel with a Find the maximum modulated frequency which could be detected by it load resistance 100 kilo ohm. Q) 531Ni Q) 1062 MHz @) 10.62 kHz (4) 5.31 Mil? 43, a4, ‘The supply voltage toa room is 120 Y. The resistance of the Iead wires is 60. AGO W bulb is alseady switched on decrease of voltage across the bulb, when What is the a 240 W heater is switched on in parallel to the bulb ? (1) 10.04 Volt Q) zero Volt @) 29 Volt (13.3 volt A metallic rod of length ‘Y is ted toa siring of length 21 and made to zetate with angular speed » ona horizontal table with I there is @ vertical magnetic lield "B’ in the region, the one end of the string fixed. ent, induced across the ends of the red is by @® R/Page 10 SPACE FOR ROUGH WORK 45. The magnetic field in a travelling electromagnetic wave has a peak value of 20,n7. ‘The peak value of electiic field strength is : @) 2 v/m (2) 3V/m @) bv/m @ 9V/m 46. A sonometer wite of length 1.5 m is made of steel The tension in it produces an What is the fundamental frequency of steel if density and clasticity of steel are 7.7109 kg/me) and 22x10! N/m? respectively ? elastic strain of 1%. Q) 701k (2) 1885 He (3) 178.2 Hz (4) 200.5 Lz 47. 48, has Statement 1 and Statement U. Of the four choices given afier the Statements, choose the one that heat describes the troo Statements Statement - 1 This question 2 A point particle of mass mm moving with speed rv collides with stationary point particle of mass M. Lf the maximum energy loss possible is given as ai) fom (ane ala Statement - I occurs when the particles get stuck logether as a result of the collision (1) Statement - | is false, Statement - Il is true. Maximum energy less Statement - is true, Statement - [is true, Statement - II is a correct explanation of Statement - | Cy (3) Statement -Tis true, Statement - His true, Statement - II is not a correct explanation of Statement - 1 (4) Slatement - Lis true, Statement - Ils false. A charge Q is uniformly disteibated over a long 10d AB of length 1. as shown in the figure. ‘The electric potential at the point O lying at a distance 1. from the end A is ° A COTTA, Qin? OO Grest Q 2) 8mesL 3Q @ Feb a (Gre, bind R/Page 11 SPACE FOR ROUGH WORK 49, A-uniform cylinder of length L. and mass | 1. A hoop of radius r and mass m rotating M having cross - sectional area A is with an angular velocity 9 is placed on a suspended, with its length vertical, from a rough horizontal surface. The initial xed point by a massless spring, such that velocity of the centre of the hoop is zero. itis half submerged ina liquid of density What will be the velocity of the centre of at equilibrium position. ‘The extension the hoop when it ceases to slip ? of the spring when it is in equilibrium is : Mg (1, LAg (1) toy a ata tu 3 Mg hae Or 5 Mg (,_ LAa i @ ABO- FE o 3 Mg Uae) Mg (,_ LAa aw oy ( oM. en a > (Here k is spring constant) 30. Two coherent point sources S, and S, are separated by asmall distance’d’ asshown, | §2. The amplitude of @ damped oscilletor The fringes obtained on the screen will decreases to 0.9 times its original be: magnitude in 5s, In another 10s it will decrease to «times its original magnitude, where a equals : Screen @ 06 (Q) concentric circles Q) 07 (2) points (@) 0.81 (3) straight lines (4) semi - circles (a) 0.729 R/Page 12 ‘SPACE FOR ROUGH WORK 53. Assume that a drop of liquid evaporates by dectease in its surface energy, 90 that its temperature remains unchanged. What Should be the minimum radius of the crop for this to be possible? The surface tension. is T, density of liquid is p and I is its latent heat of vaporization. (1) 2T/eL @ el/T @) JT/oL (4) Tek. 54, What is the minimum energy required to launch a satellite of mass m from the surface of a planet of mass M and radius R in a circular orbit at an altitude 55. In a hydrogen like atom elvetron makes transition from an energy level with quantum number nt another with quantum number (n=1). If n>>1, the frequency of radiation emilted is proportional to : @ Che @) @ 56. Two charges, each equal to q, are kept at aand x=a on the x-axis, A particle of mass mand charge w=4 is placed at of 2R? the origin. If charge qy is given a small Gisplacement (y << 2) along the y - axis, mM the net force acting on the perticle is Q aR proportional to ES 1 3GmM eal ( AL 2 aR ory QQ y 3) Ss @ -y GmM w | OY TR y R/Page 13 SPACE FOR ROUGH WORK 57. Ifa piece of metal is heated to temperature Gand thenallowed to cool ina room which is at temperature 0, the graph between the temperature T of the metal and time will be closest to: 1| ay Se a Q) (3) ¥ @) ‘Two capacitors C, and C, are charged to 120 V and 200 V respectively. It is found that by connecting them together the potential on each one can be made zero. ‘Then : (ay 59. 60. ’ ‘The I - V characteristic of an LED is : a) @) 8) (ay Diameter of a plano - convex lens is 6 em and thickness at the centre is 3 mm. If speed of light in material of lens is 2108 m/s, the focal length of the lens is : QQ) 10cm av ) 2) 15cm @) 3c (3) 20cm (4) 3, +8¢, (4) 30cm R/Page 14 SPACE FOR ROUGH WORK ee 7 os PART C ~ CHEMISTRY 61. Which of the following represents the correct order of increasing first ionization enthalpy for Ca, Ba, S, Se and Ar? (1) CamM>1>0 @Q) W>ivel> mr (@) 1>>m>Iv (4) m>1>n>1v 71. The molarity of a solution obtained by mixing 750 mL of 0.5(M)HCI with 250 mL of 2(M)HCI will be : (1) 0975 M Q) 0875 M @) (4) 175M 1.00 M 72. For gaseous state, if most probable speed is denoted by C*, average speed by © and mean square speed by C, then for a large number of molecules the ratios of these speeds are : Q) Ch: GC = 1: 1.225: 1128 QQ) Ch: SC = 1.225: 112821 (@) Ch: G:C = 1128:1.205:1 Che GC = 11.128: 1.295 R/Page 16 SPACE FOR ROUGH WORK 73. Which of the following is the wrong statement ? (1) Ozone is diamagnetic gas. (2) ONCI and ONO” are not isoelectronic. (3) Oy molecule is bent. (4) -Ozone is violet-black in solid state. 74. An organic compound A upon reacting with NH, gives B. On heating, B gives C. C in presence of KOH reacts with Bry to give CH,CH,NH). Ais: (1) CH,CH,COOH @) CH,COOH (3) CH,CH,CH,COOH (4) CH,—CH-COOH H CH, 75. Four successive members of the first row transition elements are listed below with atomic numbers. Which one of them is 0 expected to have the highest E? 4.5 specter we the highest Bla. os value ? (1) Co(z=27) Q) Cr(Z=24) @)-Mn(Z=25) (4) Fe(Z=26) 76. 77. 78. In which of the following pairs of molecules/ions, both the species are not likely to exist ? (Hy, Hey @ HY, Hey @) Hy, Hey (4) HEY, He, ‘The gas leaked from a storage tank of the Union Carbide plant in Bhopal gas tragedy was (1) Phosgene (2) Methylisocyanate (3) Methylamine (4) Ammonia Consider the following reaction : xMnO; + yC,0, + 2H" > xMn*! +2yCO; + 5 H,0 ‘The values of x, y and = in the reaction are, respectively (1) 5, 2and8 (2) 5 2and 16 @) 2% 5and8 (@) 2, 5and 16 SPACE FOR ROUGH WORK 79. 80. 81. Which of the following species is not expected to exhibit optical complex isomerism ? (1) [Co(en)(NH5), Cl ]" 2) [Colenis}** (3). [Colen}y Clo} (4) [Co(NHs, Is ls] How many litres of water must be added to 1 litre of an aqueous solution of HCl with a pH of 1 to create an aqueous solution with pH of 2? () 904 2) 01L 3) 09L (4) 20L ‘The rate of a reaction doubles when its temperature changes from 300 K to 310K. Activation energy of such a reaction will be : (R=8314 JK~! mol~! and log 2=0.301) (1) 60.5 kJ mol-" (2) 53.6 kj mol-! (3) 48.6 kj mol-7 (4) 585k] mol-! 82. 83. : The first ionisation potential of Na is 5.1eV. The value of electron gain enthalpy of Nat will be: (1) +255 ev QQ) -255 ev @) -51eV (4) -102 ev The coagulating power of electrolytes having ions Nat, Al’* and Ba?* for arsenic sulphide sol increases in the order : (1), APY 1> 0 Q) m>m>1 () mu>m>1 (@) I>n>m R/Page 18 SPACE FOR ROUGH WORK 85. Stability of the species Li, Liy and Lid increases in the order of : @) Lig

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