Safety Data Sheet

Under Regulation (EU) No.

453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

- BRAND :

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

MARMOLIT

1: IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY

1.1. Product identifier
Trading name:

SOLID STRAW

1.2. Relevant identified uses of the mixture and uses advised against
Use of the mixture:

Unsaturated polyester resin styrene solution;

Mastic for marble, granite, stone in general
SU3 - Industrial Uses
SU22 - Professional Use
PROC10

1.3. Details of the supplier of the safety data sheet

B-CHEM Snc
Via Enzo Ferrari, 68 - Industrial Area A
62012 CIVITANOVA MARCHE (MC) ITALY
tel. +39 0733 801444, fax +39 0733 801062
Competent person responsible for the safety data sheet e-mail: info@b-chem.net
1.4. Emergency telephone number
Office hours: 8.30/12.30 - 14.30/17.30

tel. +39 0733 801444

2. HAZARDS IDENTIFICATION
Classification of the mixture under Directive 1999/45/EC: HAZARDOUS
The mixture meets the requirements of Regulation No. 1907/06 (REACH - Article 31, paragraph 1)
and requires a safety data sheet under the Annex II of REACH Regulation.
Further information on risks to human health and/or the environment are given in sections 11 and
12 of this safety data sheet.
2.1 Classification of the substance or mixture
R 10 Flammable
R 20 Harmful by inhalation
R 36/38 Irritating to eyes and skin
Acute and chronic effects on organs and systems: symptoms
Acute effects dose-dependent
Skin: irritation, delipidization
Eyes: irritation
Nervous System: depression, dizziness, fatigue
Upper airways: irritation
Lungs: irritation, pulmonary edema

SOLID STRAW - Mastic for marble, granite

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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

Chronic effects
Skin: irritant contact dermatitis
Nervous System: organic psycosyndrome, peripheral neuropathy
Eyes: irritation, conjunctivitis
Lungs: irritation, chronic obstructive pulmonary disease
Liver: liver damage
Urogenital System: renal damage
The substance (styrene) is currently not classified for mutagenicity and reproductive toxicity.
No available data on mutagenicity and reproductive toxicity.
Environmental hazards:
not classified as dangerous for the environment
2.2. Label elements
EEC Labelling
Symbol (s) and indication (s) of danger

Xn - Harmful
Risk Phrases (R)
R 10 Flammable
R 20 Harmful by inhalation
R 36/38 Irritating to eyes and skin
Precautionary statements (S)
S 7 Keep container tightly closed.
S 9 Keep container in a well-ventilated place.
S 23 Do not breathe gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and gloves.
S 43 In case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water.
S 60 This material and its container must be disposed of as hazardous waste.
Other information
All product components are listed in EINECS or ELINCS, unless specifically exempted by the EEC
Directive 67/548.
2.3. Other hazards
None

3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture of unsaturated polyester resin containing styrene, colourant pigment and inert mineral
charges.
Dangerous substances (Directive 67/548/EEC)

SOLID STRAW - Mastic for marble, granite

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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

EC number

202-851-5

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

CAS

Registration

Chemical

Conc

number

number

name

(%w/w)

100-42-5

012119457861-32

Styrene

11 - 13

Classification

Risk
phrases

Xn, Xi

R10
R20
R36/38

Note
This section gives the classification of substance, including the letters corresponding to the hazard
symbols and codes related Risk Phrases (R) assigned according to their risks for safety, health
and environment. The meaning of each code of risk is given in section 16 (the most important Risk
Phrases used in section 2 and 3 of this safety data sheet).
Hazardous Substances (Regulation No. 1272/2008 - CLP)
Index
number

International
Chemical
Identification

EC No

CAS No

601-026-00-0

Styrene

202-851-5

100-42-5

Classification
Hazard
Hazard
Class and statement
Category
Code(s)
Code(s)
Flam. Liq. 3
Acute Tox. 4
(*)
Eye Irrit. 2
Skin Irrit. 2

H226
H332
H319
H315

Labelling
Pictogram,
Signal
Word
Code(s)
GHS02
GHS07
Warning

Note
This section gives the classification of substance, including the codes of class and hazard
category, indication of hazard statement and pictograms and warning codes assigned according to
their hazards for safety, health and environment. The meaning of each code is given in section 16.

4. FIRST AID MEASURES

4.1. Description of first aid measures
IF ON SKIN:
Gently wash with plenty of soap and water. If skin irritation occurs get
medical advice.
IF IN EYES:
Rinse cautiously with water for several minutes while holding eyelids
open. If eye irritation persists get medical advice.
IF INHALED:
Remove victim to fresh air and keep at rest in a position comfortable for
breathing; if you feel unwell get medical attention.
IF SWALLOWED:
Do NOT induce vomiting, show the safety data sheet. Never give
anything by mouth if the victim is unconscious.
4.2. Most important symptoms and effects, both acute and delayed
None known.
4.3. Indication of any immediate medical attention and special treatment needed
Information for physician: symptoms treatment.

SOLID STRAW - Mastic for marble, granite

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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

5. FIREFIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing
media:

Unsuitable extinguishing
media:
Special protective
equipment for fire-fighters:

Use the following media:

- carbon dioxide
- foams
- water spray
- dry chemical
High-pressure water jets
Wear:
- Gas mask with breathing apparatus
- Full equipment consisting of helmet with face shield and neck
protection, jacket and fireproof pants with bands around arms, legs
and waist.
Vapours may cause dizziness, fainting or suffocation.
Cool fire exposed containers with water.

Special exposure hazards:

Special procedures:
WARNING
5.2. Special hazards arising from the substance or mixture
The dispersion of the substance in the environment may cause pollution.
Containers may explode when subjected to heat flow.
The firefighters must take into account the risk of explosion; the personnel assigned to extinguish
fires should act from a secure location.
The substance forms explosive mixtures with air.
The vapours of the substance can go back to the source point and create flashbacks phenomena.
The fumes from liquefied gas are initially heavier than air and tend to disperse along the ground.
The substance is easily transported at high temperatures. The damaged containers should be
handled only by trained personnel.
Do not discharge contaminated water into drains, soil or surface waters. Take appropriate
measures to contain the extinguishing water.
Away individuals who are unprotected.
5.3. Advice for firefighters
Refer to Section 8 for the use of personal protective equipment.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions,
protective equipment and
emergency procedures
6.2. Environmental
precautions

Wear gloves, protective clothing, safety goggles, boots and a tool of

protection for the respiratory system (breathing apparatus). Refer to
protective measures listed in sections 7 and 8.
Use installation systems and operating procedures to avoid the
product reaches the sewerage system, drains or watercourses.
To limit evaporation and to minimize the area affected by the
spread of vapours, provide barriers to contain spilled substance.
Avoid placing the spilt in the closed sewers or collect in closed
containers to reduce the risk of confined explosion.
6.3. Methods and material Cover the leaks with inert absorbent material (clay, sand or other
for
containment
and non-combustible material), in order to reduce the vapours
cleaning up
development.
Wash the floor with water after collecting the shed.
Collect the spilled material with non-sparking equipment.
SOLID STRAW - Mastic for marble, granite

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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

Enter the material collected in clean and labeled containers.

Do not use acid to clean.
Do not use cleaning products made from strong oxidants.
The use of water spray reduces the development of vapours but
does not prevent the substance ignition in enclosed areas.

7. HANDLING AND STORAGE

7.1. Precautions for Work upwind if possible.
safe handling
Avoid:
- contact with skin and eyes;
- inhalation of vapours and fumes.
Handle in well ventilated areas.
Include the use of local exhaust ventilation.
Never reuse empty containers before they are subjected to industrial
cleaning or reconditioning.
Before carrying out hot work clean up lines and containers.
Before carrying out transfer operations make sure that the tank does not
contain residues of incompatible substances.
Ensure the grounding of tanks, containers and equipment.
Ensure the grounding of equipment during decanting and wear antistatic
footwear during the operation.
Make sure that the transmission lines and equipment are perfectly clean
and do not contain acids or oxidizing substances before using the
substance.
Do not wear contact lenses during the handling of the substance.
Contaminated work clothing should be changed.
For matters not provided here, refer to personal protective equipment
recommended in Section 8 of this sheet.
7.2. Conditions for
Protect containers from damage.
safe storage,
Provide the possibility of cool with water and other systems the product
including any
containers.
incompatibilities
Ventilate the storage area so they can be diluted leaks from containers.
Provide electrical equipment in accordance with local regulations on
electrical safety for places with fire and explosion hazard.
Store in a well ventilated, dry and cool area.
Store in tightly closed and labeled containers.
Protect from direct sunlight. Keep away from all possible sources of
ignition. No smoking.
Keep away from food, feed and beverages.
Avoid accumulation of static discharges, particularly when pouring off.
Keep only in original container.
Keep at temperature not exceeding 25 C.
Keep separate containers from strong oxidizers.
7.3. Specific end
No data available.
use(s)

SOLID STRAW - Mastic for marble, granite

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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters (ACGIH)
Substance
TLV-TWA
STEL
Styrene
20 ppm
40 ppm
Occupational Exposure Limit: BEI ACGIH
Mandelic acid with benzoylformic acid on urine, shift end: 400 mg/g creatinine
Styrene in blood, shift end: 0.2 mg / L
8.2 Exposure controls
8.2.1. Appropriate engineering controls
8.2.2. Individual protection measures, such as personal protective equipment
8.2.2.1 Respiratory protection
Mask with filter type A1 - Organic gases and vapours - (EN
141).
8.2.2.2 Hand protection
Gloves:
- PVA (permeability time> 6 hours)
- Teflon (permeability time> 4 hours)
(CEN: EN 420, EN 374-1-2-3).
Avoid gloves made of: PVC, Nitrile, Neoprene and Latex
8.2.2.3 Eye protection
Safety glasses, do not use contact lenses.
8.2.1.4 Skin protection
Protective clothing (CEN: EN 340; EN 368; EN 369; EN
467).
8.2.3 Environmental exposure
-----controls
Precautionary measures
Do not eat, drink or smoke during work.
Wash hands accurately with soap and water before eating
and take a shower after work shift.
Working clothes should be washed separately and stored
in a separate place.
Provide workplace facilities for washing (emergency
shower and eye showers).
Recommended engineering controls
------

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Physical state:
solid
Colour:
straw-coloured
Odor:
characteristic of styrene
Odour threshold:
0.3 ppm (styrene)
pH:
n.a.
Melting point / freezing point:
- 30.6 C (styrene)
Initial boiling point and boiling range:
145.2 C (styrene)
Flashpoint:
30C
Evaporation rate:
n.d.
Flammability (solid, gas):
flammable
Upper/lower flammability or explosive limits:
1.1 (lower); 6.1 (higher) (styrene)
Vapour pressure:
600 Pa at 20 C (styrene)
Vapour density:
3.6 (styrene)
Relative density:
0.906 g/cmc
Liquid density
1782,30 g/l
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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

Solubility in water:
Partition coefficient:
Ignition temperature:
Decomposition temperature:
Viscosity:
Explosive properties:
Oxidising properties:
V.O.C. value:

0.29 mg/l (styrene)

octanol / water 2.95 (styrene)
490C (styrene)
n.d.
> 2600 mPa*s-1
1.1 (lower); 6.1 (upper) (styrene)
n.a.
1,13% p/p - 0,634 g/l

9.2. Other information

Solid content:
Acid number:
Softening point:
Ignition temperature:
SADT:
Active oxygen content:

84.3%
6 mgKOH/gr
n.a.
n.d.
n.a.
n.a.

n.a not applicable

n.d. not determined

10. STABILITY AND REACTIVITY

10.1. Reactivity
10.2. Chemical stability
10.3. Possibility of
hazardous reactions
10.4. Conditions to avoid

10.5. Incompatible
materials
10.6. Hazardous
decomposition products

Spontaneous polymerization. Reaction with alkalis. Possible reaction

with acids and oxidizing substances (styrene).
The product is stable under normal conditions of use and storage.
(styrene).
Spontaneous polymerization. Keep away from oxidizing agents,
strong acids and alkalis in order to avoid exothermic reactions
(styrene).
Keep away from open flames. Avoid formation of static discharges.
The product is stable under recommended storage and handling
conditions (see paragraph 7).
Avoid exposing container to direct sunlight.
Peroxides. Keep away from oxidizing agents, strong acids and
alkalis.
The product is flammable: it can give rise to formation of
decomposition products after combustion.

11 - TOXICOLOGICAL INFORMATION
Toxicological data about mixture as a whole are not available. Note the concentration of each
substance in order to evaluate the toxicological effects from exposure. Toxicological information
relating the main substances in the mixture are shown below.
Acute toxicity
Acute toxicity by oral, dermal and inhalation:
oral LD-50 (rat): 5000 mg/kg
skin LD-50 (rabbit): not available
inhalation LC-50 - 4 hours (rat): 2770 ppm
Irritation
Styrene is irritating to eyes, skin and mucous membranes. May be nephrotoxic, hepatotoxic and
can depress the central nervous system. Main symptoms are nausea, fatigue, headache, loss of
SOLID STRAW - Mastic for marble, granite

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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

coordination, muscle weakness, feeling of drunkenness, dizziness and unconsciousness. May

cause pulmonary edema and peripheral neuropathy.
Corrosion
Exposure by inhalation to styrene results in irritation of mucous membranes.
There is hyperaemia of the conjunctiva and cornea moderate impairment, with return to normal in
48 hours.
In rats exposed by inhalation was noted a reduction in ciliary activity against the nasal mucosa
and morphological anomalies with vacuolation of epithelial cells, nuclear pyknosis and, sometimes,
breaking in the cytoplasm membrane.
Sensitization
In humans, styrene resulted in sensitization reactions.
Repeated dose toxicity
Chronic exposure to the substance may cause obstructive pulmonary syndromes, CNS depression
and peripheral neuropathy.
Exposures more than five years have brought hepatotoxicity and nephrotoxicity.
Carcinogenicity, mutagenicity and reproductive toxicity
There was no evidence of carcinogenic activity in a two-year study of B6C3F1 mice and Fischer
344 rats by administering styrene by the oral route.
Information about potential exposure pathways
The main potential exposure pathways are inhalation, ingestion and skin contact. Workers are
exposed by inhalation or percutaneous absorption. The population can be exposed by ingesting
contaminated water or food, inhalation in areas contaminated by industrial waste or inhalation of
cigarette smoke.
Symptoms related to the physical, chemical and toxicological properties.
Styrene depresses the central nervous system and causes peripheral neuropathy: the mechanism
of action of the substance has not yet been clarified.
Immediate, delayed and chronic effects from exposure to short and long-term
Styrene is metabolized in the liver by mixed function oxidase system of the endoplasmic reticulum.
Metabolic transformation of styrene in humans begins with his conversion to epoxide (styrene
oxide), more toxic metabolite.
Interactive effects
No data available

12. ECOLOGICAL INFORMATION

Any known ecological data for the mixture, we report those for the individual components.
The mixture is NOT classified as dangerous for the environment: the following data refers to
styrene.
EC50/48h, Daphnia magna: 4.7 mg/l
LC50/96h: = 9.1 mg/l (fish)
12.1. Toxicity
The substance is not classifiable ecotoxic, according to data gathered in literature.
12.2. Persistence and degradability
There is no hydrolysis in water.
Photochemical degradation in the atmosphere.
Biodegradation.
12.3. Bioaccumulative potential
The bioconcentration factor is not significant.
SOLID STRAW - Mastic for marble, granite

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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

12.4. Mobility in soil

Low mobility in soil.
12.5. Results of PBT and vPvB assessment
The mixture does not contain any substances classified as persistent, bioaccumulative and toxic
(PBT) or very persistent and very bioaccumulative (vPvB).
12.6. Other adverse effects
Following treatments for wastewater containing styrene were studied: biological, stripping and
extraction with solvents and activated carbon.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Product
Dispose of according to local and national regulation.
In Italy dispose of according to Legislative Decree 152/2006.
Contaminated packaging
Other information

Dispose of as chemical waste empty and uncleaned containers.

------------

14. TRANSPORT INFORMATION

14.1 UN number
14.2 UN proper shipping name
14.3 Transport hazard class
Hazard Label
14.4 Packing group
14.5 Environmental hazards
14.6 Special precautions for
user
14.7 Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code

Transport/shipping by
road, rail, inland
waterways
(ADR/RID/ADN)
UN 1866
RESIN SOLUTION

Maritime transport
(IMDG Code)

Transport by air
(ICAO T.I./IATA)

UN 1866
RESIN SOLUTION

UN 1866
RESIN SOLUTION

3
3
III
Not classified
(*)

3
3
III
Not classified
EmS : F-E, S-E
(*)

3
3
III
Not classified
(*)

Not applicable

Not applicable

Not applicable

(*) - Transport, including loading and unloading, must be carried out by people who received the
necessary training required by the modal regulations concerning the transport of dangerous
goods.
Additional information for transport:
When the product is delivered in conjunction with the hardener (peroxide), the UN number
becomes UN 3269, as indicated in Section 3.3.1 - Special Provision 236 of the IMDG Code
Amendment 34 - 2008 currently in force.
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Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Regulation (EC) No 2037/2000 on substances that deplete the ozone layer, Annex I
Not listed.
Regulation (EC) No 2037/2000 on substances that deplete the ozone layer, Annex II
Not listed.
Regulation (EC) No 850/2004 on Persistent Organic Pollutants, Annex I
Not listed.
Regulation (EC) No 689/2008 concerning the export and import of dangerous chemicals, Annex I,
Part 1
Not listed.
Regulation (EC) No 689/2008 concerning the export and import of dangerous chemicals, Annex I,
Part 2
Not listed.
Regulation (EC) No 689/2008 concerning the export and import of dangerous chemicals, Annex I,
Part 3
Not listed.
Regulation (EC) No 689/2008 concerning the export and import of dangerous chemicals, Annex V
Not listed.
Regulation (EC) No 1907/2006, Article 59 (1): candidate list
Not listed.
Organic volatile compounds contained in the mixture: 0,634 g/l - 1,13% p/p VOC Value.
15.2. Chemical safety assessment: not carried out.

16. OTHER INFORMATION

Date: 25/11/2010
Revision: All sections
According to Regulation (EU) No 453/2010, Annex I.
Most important risk phrases used in the sections 2 and 3 of this SDS
R 10 Flammable
R 20 Harmful by inhalation
R 36/38 Irritating to eyes and skin
Pictograms, signal word codes, class and hazard category codes and additional information
used in Section 3 of this SDS
Pictogram, signal word code(s)
GHS 02
GHS 07
WARNING
Hazard class and category code(s)
Hazard statement code(s)
Acute Tox. 4
H332: Harmful if inhaled.
Eye Irrit. 2
H319: Causes serious eye irritation.
Skin Irrit. 2
H315: Causes skin irritation.
Flam. Liq. 3
H226: Flammable liquid and vapour.
Supplementary hazard statement code(s)
---Other information
SOLID STRAW - Mastic for marble, granite

page 10 of 11

Safety Data Sheet

Under Regulation (EU) No.
453/2010, Annex I

CIVITANOVA MARCHE (MC) ITALY

Issue date: 16/05/2011

Revision date: 16/03/2012
Version: 03

----Safety Data Sheet based on:

- Directive 1999/45/EC and subsequent amendments;
- Legislative Decree 14/3/2003 No 65 and subsequent amendments;
- Decision 2000/532/EC and subsequent amendments;
- Directive 67/548/EEC and subsequent amendments;
- Regulation (EC) No 1907/2006 (REACH);
- Regulation (EC) No 1272/2008 (CLP);
- Regulation (EC) No 790/2009;
- Regulation (EC) No 453/2010.
Legislation and reference sources:
- Directive 67/548/EEC and subsequent amendments (Classification and labelling of dangerous
substances);
- Directive 1999/45/EC and subsequent amendments (Classification and labelling of dangerous
preparations);
- Legislative Decree 14/3/2003 No 65 (Classification and labelling of dangerous preparations);
- Regulation (EC) No 1272/2008 (Classification, labelling and packaging of substances and
mixtures);
- Legislative Decree No 152/2006 (Regulations on the environment) and subsequent amendments;
- ADR (European Agreement concerning the International Carriage of Dangerous Goods by Road);
- International Maritime Dangerous Goods Code (IMDG Code);
- International Air Transport Association (IATA);
- SAX'S Dangerous Properties of Industrial Materials.
Note:
n.a = not applicable
n.a = not determined
Additional information:
Data and information provided here are in good faith and based on our knowledge about the
product, at the date of issue of this sheet. Some data are still under review; the information
provided not guarantee specific product features and shall not establish a legal contract. The list of
legislation, regulations and administrative acts should not be considered complete. The recipient of
the product should refer to official documents concerning the use, storage and handling of the
product, activities for which is solely responsible. The user must also provide all the information
needed for job security, health and environmental protection to people who may come into contact
with the product (use, storage, cleaning of containers, different actions), by sending them a copy of
this Safety Data Sheet.

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