Th.S.Nguyen Hien Hoang Gv.

HSP

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Chng 1: M AU PHAN TCH NH LNG

1.1.Tnh ng lng gam cua cac chat tham gia phan ng :
1) Trung hoa : NaOH, KHSO4, N2O5, K2O, Ba(OH)2, NH3
2) Oxi hoa-kh hoac ket tua sau :
a) MnSO4 + 2NaOH Mn(OH)2 + Na2SO4
b) 2FeCl3 + 3Ba(OH)2 2Fe(OH)3 + 3BaCl2
c) 2KMnO4+ 10FeSO4 + 8H2SO4 5Fe2(SO4)3 + 2MnSO4
+K2SO4 + 8H2O
d) I2 + 2Na2S2O3 2NaI + Na2S4O6
e) K2Cr2O7 + 6FeSO4 + 7H2SO4 3Fe2(SO4)3 + Cr2(SO4)3
+ K2SO4 + 7H2O
3) Cac phan ng trao oi:
a) CaCl2 + 2H3PO4 Ca(H2PO4)2 + 2HCl
b) 3CaCl2 + 2H3PO4 Ca3(PO4)2 +6HCl
c) CaCl2 + Na2HPO4 CaHPO4 + 2NaCl
1.2.Ngi ta lay 20,00 ml dung dch H3PO4 em chuan o bang NaOH
th het 25,00 ml. Biet rang dung dch NaOH nay c pha che t
0,4000 gam NaOH ran trong bnh nh mc 250 ml va gia s ta ch
chuan o en NaH2PO4. Tnh o chuan T cua H3PO4 ?
1.3.Tnh o chuan cua moi dung dch muoi kim loai sau (di dang so
gam hoac miligam kim loai trong 1 ml dung dch) :
a) CuSO4 0,1M
(Cu = 63,545)
b) FeNH4( SO4)2.12H2O 0,1M (Fe = 55,847)
c) KMnO4 0,1N (chuan o trong axit) (Mn = 54,938)
d) K2Cr2O7 0,1N (chuan o trong axit) (Cr = 51,996)
1.4.Tnh nong o ng lng cua dung dch chuan K4Fe(CN)6 0,0500
M dung e chuan o Zn2+ theo phan ng :
K2Zn3[Fe(CN)6]2
3Zn2+ + 2Fe(CN)64 + 2K+
1.5.Tnh o chuan cua dung dch KMnO4 theo Mn dung e xac nh
Mn trong hp kim, biet rang e xac nh o chuan o, ngi ta can
1,0000 gam hp kim chuan co ham lng Mn c biet chnh xac la

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2,15 %, sau khi hoa tan mau thanh dung dch, che hoa dung dch o
bang nhng thuoc th thch hp, e tien hanh chuan o Mn 2+ bang
dung dch chuan KMnO4 trong o san pham cua phan ng la
Mn(III), th het 35,50 ml dung dch KMnO4
1.6.Mot mau phan tch cha Fe dang Fe2O3. Thiet lap cong thc
tnh so gam Fe trong mau, suy ra % khoi lng Fe va % Fe 2O3 trong
mau phan tch tren. Biet khoi lng mau la a gam, hoa tan tha nh V1
ml dung dch, lay ra V0 ml dung dch e phan tch. Khi phan tch,
kh Fe3+ thanh Fe2+ roi chuan o bang dung dch chuan K2Cr2O7
trong moi trng axit, dung dch nay co o chuan theo Fe la
TK2Cr2O7/ Fe The tch dung dch K2Cr2O7 can thiet la V2 ml
1.7.a) Tnh so ml dung dch NH3 25% (D = 0,907 g/ml) can phai lay
e pha che thanh 0,5 lt dung dch NH3 co nong o 0,1M. (dung dch
A)
b) Neu lay 25,00 ml dung dch A em chuan o bang dung dch
H2SO4 0,1M th phai dung het 13,75 ml. Tnh nong o ung cua
dung dch A va pha che tren.
c) Muon pha che 1 lt dung dch NH3 co nong o 0,05M t dung
dch A th phai lam sao ?
Chng 2 : CHUAN O AXIT BAZ
2.1.Chuan o 25,00 ml dung dch NaOH 0,0500M bang dung dch HCl
0,0500M.
1) Tnh the tch dung dch HCl dung e chuan o en iem tng
ng.
2) Tnh bc nhay chuan o neu chap nhan sai so q = 0,1 %
3) Ve ng cong chuan o, chon ch th thch hp (trong so cac
ch thong dung), cho biet s oi mau va pT cua tng ch th.
4) Tnh sai so chuan o khi dung metyl da cam lam ch th cho
phep chuan o tren.
2.2.The nao la khoang chuyen mau cua ch th axit-baz ? Mot chat ch

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Th.S.Nguyen Hien Hoang Gv.HSP

th axit-baz la mot axit hu c yeu HIn co hang so axit K = 10 7,3,

dang HIn co mau vang, dang In co mau xanh. Mat thng co the
nhan biet mau cua dang axit khi nong o cua no ln hn nong o
cua dang baz 10 lan va nhan biet c mau cua dang baz khi nong
o cua no ln ln dang axit 2 lan. Tnh khoang chuyen mau cua ch
th o.
2.3.Dang axit cua ch th HIn co mau o, dang baz In co mau vang.

Ch th co mau o ro khi

[HIn]
[In]
= 8 va co mau vang ro khi
= 12.

[In ]
[HIn]

Cho biet pKHIn = 4,8. Tnh khoang chuyen mau cua ch th.
2.4. Tnh sai so chuan o trong phep chuan o 50,00 ml dung dch
HCl 0,0500 M bang dung dch NaOH 0,0100 M, neu chua n o en
xuat hien mau vang cua ch th Metyl da cam (pT = 4,4).
2.5.Tnh bc nhay chuan o trong phep chuan o dung dch Ba(OH) 2
2,00.10 3 M bang dung dch HCl 5,00.10 3 M. Chap nhan sai so
chuan o la q = 0,2%
2.6. Hoa tan 0,6106 gam axit benzoic C6H5-COOH va them nc en
500 ml. Chuan o 20,00 ml dung dch nay th het 4,00 ml dung dch

NaOH. Cho KAxit = 6,6010 5

1) Tnh pH cua dung dch trc khi chuan o va khi en iem
tng ng.
2) Tnh bc nhay chuan o neu chap nhan sai so q = 0,2 %
3) Neu chuan o en pH = 9, tnh sai so chuan o ?
2.7.Hay chng to ieu kien e co the chuan o c mot n axit yeu
(C0 mol/l) bang mot n baz manh (C mol/l) la Ka.C0 10 11. Biet
sai so chuan o cho phep la 0,2 %, vi K la hang so phan ly cua
n axit yeu ma ta can chuan o.
2.8.Hoa tan 1,2500 gam axit HA trong 50,00 ml nc. Can phai dung
41,20 ml NaOH 0,0900 M e chuan o het lng axit nay. Biet rang
sau khi them 8,24 ml dung dch NaOH noi tren th pH cua dung dch

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thu c la 4,3.
1) Tm khoi lng phan t va hang so phan ly cua axit HA.
2) Tnh pH tng ng cua phep chuan o.
2.9.Chuan o 25,00 ml dung dch axit fomic H-COOH 0,0500M bang
NaOH 0,1000M. Tnh pH cua dung dch trc khi chuan o va khi
a them 10,00 ml; 12,45 ml; 12,50 ml; 13,00 ml dung dch NaOH.
Cho hang so phan ly cua axit fomic la 103,75.
2.10.Them 20,00 ml dung dch NaOH vao 30,00 ml dung dch axit
axetic CH3-COOH th pH cua hon hp thu c bang 10,50. Neu
them vao hon hp tren 5,00 ml dung dch HCl 0,0100 M th pH
giam xuong bang 6,00. Hay tnh nong o mol/l cua dung dch NaOH
va CH3-COOH Cho hang so phan ly cua CH3-COOH la K = 10 4,76
2.11.Mot dung dch A gom HCl 0,0100M va NH4Cl 0,2000M
1) Tnh pH cua dung dch A. Cho KNH4+ = 109,26

2) Chuan o lng HCl trong 25,00 ml dung dch A bang dung

dch NaOH 0,0200M en mau vang ro cua metyl o (pT =
6,2). Tnh sai so chuan o. Neu chap nhan sai so la q = 0,1
% th bc nhay chuan o la bao nhieu ?
3) Them 50,00 ml dung dch NaOH 0,3000M vao 50,00 ml
dung dch A. un soi uoi het NH3, chuan o hon hp con
lai bang dung dch H2SO4 0,1000M th het bao nhieu ml dung
dch H2SO4 ?
2.12.Chuan o 25,00 ml dung dch NH3 0,0250M bang dung dch HCl
cung nong o. Tnh pH dung dch trc khi chuan o va sau khi a
them vao lan lt cac the tch dung dch HCl : 10,00 ml; 20,00 ml;

24,95 ml; 25,00 ml; 25,02 ml; 30,00 ml. Cho K NH4+ = 10 9,26
2.13.e chuan o 50,00 ml dung dch NH3 phai dung 30,00 ml dung
dch HCl 0,2500 M.
1).Tnh pH dung dch trc khi chuan o, chuan o c 50%
NH3 va chuan o en iem tng ng.

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2).Co the dung metyl da cam lam ch th c khong neu sai so

khong c vt qua 0,2 %. K NH4+ = 10 9,26

2.14. Chuan o 20,00 ml dung dch H3PO4 0,0100M bang dung dch
NaOH 0,0200M.
1).Tnh pH cua dung dch sau khi a them 10,00 ml dung dch
hoac 20,00 ml dung dch NaOH.
2).Tnh sai so chuan o neu ket thuc chuan o tai pH = 4,4
3).Tnh sai so chuan o en mau hong cua phenolptalein (pT=
9) Cho biet cac cong thc tnh sai so cac iem tng ng 1 va 2
C+C0
h2 K1K2
2
CC0
h + K1h + K1K2
h
C+2C0
h2 K2K3
W
q2=( h)
2
2CC0
2(h + K2h + K2K3)
h

lan lt la : q1 = (W h)

2.15.Chuan o 50,00 ml dung dch H2A 0,0400M. Neu them 20,00 ml

dung dch NaOH 0,0800M th pH cua dung dch bang 3. Neu them
30,00 ml dung dch NaOH na th pH cua dung dch bang 9. Hay
tnh cac hang so K1, K2 cua H2A (Cho biet K1 K2)
2.16.e xac nh nong o chuan cua NaOH, ngi ta can 1,2600 gam
axit oxalic tinh the H2C2O4.2H2O hoa tan trong bnh nh mc 250
ml va sau o lay 25,00 ml dung dch nay em chuan o vi dung
dch NaOH tren, dung phenoltalein lam ch th th het 12,50 ml dung
dch NaOH (en iem tng ng 2)
1). Co the chuan o rieng tng nac c khong, neu chap nhan
sai so q = 1 %. Tnh pH tai iem tng cua phep chuan o tren
2).Neu dung metyl o lam ch th en khi chuyen han sang
vang (pT= 6) th a chuan o c bao nhieu % axit oxalic t
HC2O4 en C2O42 ?
Cho biet ieu kien e chuan o rieng tng nac cua diaxit
la :

K1 1 q
2 . Axit oxalic co K1 = 10 1,25; K2 = 10 4,27
K2
q

2.17.Chuan o 25,00 ml hon hp axit axetic va axit H3PO4 en oi

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mau metyl da cam (pT= 4,4) th phai dung 20,00 ml NaOH 0,1000
M. Neu chuan o en oi mau phenolptalein (pT= 9) th phai dung
45,00 ml dung dch NaOH. Tnh nong o mol/l cua tng axit trong
hon hp.
2.18.Chuan o 50,00 ml dung dch Na2CO3 0,0100M bang dung dch
HCl 0,0200M:
1).Tnh pH dung dch sau khi them cham lan lt tng the tch
dung dch HCl sau : 20,00 ml; 25,00 ml; 30,00 ml; 50,00 ml.
2).Neu chuan o dung dch Na2CO3 0,0100M en mat mau
phenoltalein (pT = 8) bang dung dch HCl 0,0200M th sai so chuan
o se la bao nhieu ? Cho biet cong thc sai so iem tng ng
1:
C+C0
h2 K1K2
+ 2
h + K1h + K1K2
h CC0

q1 = (h W )

2.19.Mot mau hoa chat nang 1,200 gam gom NaOH + Na2CO3 va tap
chat tr, c hoa tan va em chuan o vi dung dch HCl
0,5000M. Vi phenolptalein lam ch th, dung dch se chuyen sang
khong mau khi them c 30,00 ml dung dch HCl. Them metyl da
cam va chuan o tiep th phai s dung 5,00 ml na th ch th mi
oi mau. Tnh % khoi lng NaOH va Na2CO3 trong mau ?
2.20.Hoa tan 3 gam mot mau NaHCO3 co lan Na2CO3 va tap chat tr,
roi pha loang thanh 100 ml (dung dch A). Chuan o 25,00 ml dung
dch nay (dung metyl da cam lam ch th) het 48,00 ml dung dch
HCl 0,2000 M. Mat khac them 50,00 ml dung dch NaOH (dung
dch B) vao 25,00 ml dung dch A va sau o them BaCl 2 d. Loc bo
ket tua, chuan o NaOH d trong phan nc loc het 25,00 ml dung
dch HCl 0,2000M. Biet rang e chuan o 25,00 ml dung dch B
phai dung 31,00 ml dung dch HCl 0,2000M.
1).Tnh % khoi lng Na2CO3 va NaHCO3.
2).Tnh pH cua dung dch A.
3).Neu chuan o 25,00 ml dung dch A bang HCl 0,2000M en
mat mau phenolptalein, tnh the tch dung dch HCl can dung ?

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2.21.Them 25,00 ml dung dch NaOH 0,1000 M vao 5,00 ml dung

dch cha H2SO4 va H3PO4 th pH = 7,21. Them tiep 5,00 ml dung
dch NaOH na th pH = 9,78.
1) Tnh nong o mol/l cua H2SO4 va H3PO4
2) Tnh the tch NaOH can e trung hoa hoan toan 5,00 ml
dung dch hon hp 2 axit tren.
Cho KHSO4=10 2 va H3PO4 co K1=102,23; K2 = 10 7,21; K3 = 10 12,32
2.22.Tron 25,00 ml dung dch H3PO4 0,4000 M vao 30 ml dung dch
Na3PO4 0,5000 M roi pha loang thanh 100,00 ml dung dch A Tnh
the tch dung dch HCl 0,1000 M hoac NaOH 0,1000 M can e
chuan o 25,00 ml dung dch A en khi bat au chuyen mau metyl
da cam hoac phenolptalein
Chng 3: CHUAN O OXI HOA-KH
3.1. 1) Ve ng cong chuan o dung dch FeSO 4 0,1000 M bang
dung dch KMnO4 0,1000 M trong moi trng axit H2SO4 1N. Cho
biet :
Eo MnO4- /Mn2+ = 1,51 volt EoFe3+/Fe2+ = 0,68 volt
2) Neu dng chuan o FeSO4 tai the ien cc Pt trong dung dch
la E = 830 mV, tnh sai so chuan o.

3.2.Chuan o 20,00 ml dung dch U4+ 0,1000 M bang dung dch Ce4+
0,1000 M theo phan ng :
2Ce3+ + UO22+ + 4H+
2Ce4+ + U4+ + 2H2O
Cho biet EoCe4+/Ce3+= 1,44 volt va EoUO22+/U4+ = 0,334 volt
1) Tnh the oxi hoa kh cua dung dch khi chuan o thieu 0,2
%, tai iem tng ng va khi chuan o tha 0,2 %.
2) Tnh the tch dung dch Ce4+ can dung e the oxi hoa kh
cua dung dch la 0,42 volt hoac 1,27 volt

3.3.Ngi ta tien hanh chuan o 20,00 ml dung dch Fe3+ 0,0500 M

bang dung dch TiCl3 0,0200 M vi pH = 0 khong oi, phan ng
chuan o xay ra nh sau :

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Th.S.Nguyen Hien Hoang Gv.HSP

3+

3+

2+

2+

Fe + TiO + 2H
Fe + Ti + H2O
1) Tnh hang so can bang cua phan ng chuan o.
2) Tnh nong o Fe3+ tai iem tng ng.
3) Tnh the tch cua dung dch TiCl3 a dung neu chuan o en
the ien cc Pt trong dung dch la 0,330 volt
Cho E0Fe3+/Fe2+ = 0,77 volt
E0TiO2+/Ti3+ = 0,10 volt

3.4.Hay chon chat ch th thch hp cho qua trnh chuan o Fe 2+

0,0500 M bang Ce4+ 0,1000 M trong dung dch H2SO4 1 M. Cho biet
trong dung dch H2SO4 1 M, the ien cc tieu chuan ieu kien cua
cac cap oxi hoa-kh :
EoCe4+/Ce3+= 1,44 volt va EoFe3+/Fe2+ = 0,68 volt
3.5.Chuan o dung dch Sn2+ 0,100 M bang Fe3+ 0,1000 M. Tnh the
ien cc Pt nhung vao dung dch, khi a chuan o c 50 %; 90 %;
100 %; 110 %. Biet E0Fe3+/Fe2+ = 0,77 volt
EOSn4+/Sn2+ = 0,15 volt
3.6.Mau hp kim A nang 0,1676 g cha Au va Cu c hoa tan trong
dung dch hon hp cng toan HCl + HNO3, sau o cho bay hi
HNO3 va HCl d bang H2SO4. Tiep theo trung hoa H2SO4 bang
NaOH, sau o cho 4 gam KI, nhan c I 3. Chuan o I3 bang dung
dch Na2S2O3 0,0761 N va het 32,70 ml. Tnh % vang trong mau
hp kim tren. Biet phan ng chuan o:
3I + S4O62
I3 + 2S2O32
3.7.Tnh % khoi lng cac cau t trong hon hp A gom axit oxalic
H2C2O4.2H2O va kali hidrooxalat KHC2O4.H2O (co lan mot t tap
chat tr). Biet rang 1,2000 gam A phan ng het vi 37,80 ml dung
dch NaOH 0,2500 M va 0,4000 gam phan ng het vi 43,10 ml
dung dch KMnO4 0,1250 N (trong moi trng H2SO4 ).
3.8.Hoa tan 2,000 gam quang co Crom trong axit, sau o dung
(NH4)2S2O8 e oxi hoa Cr3+ thanh Cr2O72 . un nong e phan huy
het (NH4)2S2O8 con d, e nguoi va chuyen dung dch vao bnh nh
mc 100 ml roi them nc en vach. e xac nh Crom, ngi ta

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lay 20,00 ml dung dch thu c, che hoa vi 25,00 ml dung dch
FeSO4 (dung dch A). Lng FeSO4 tha c chuan o bang dung
dch KMnO4 0,0090 M th het 15,00 ml. Tnh % Cr theo khoi lng
trong quang, biet rang a dung 35,00 ml KMnO4 0,0090 M e
chuan o va het 25,00 ml dung dch dung dch A tren.
3.9.Mot mau BaCO3 ky thuat nang 0,5120 gam c hoa tan trong
HNO3. Sau khi trung hoa lng axit d, ngi ta ieu chnh pH = 5
bang dung dch em va Ba2+ c ket tua hoan toan di dang
BaCrO4 bang K2Cr2O7. Tach ket tua va hoa tan bang HCl, them vao
2,0000 gam KI ran, hon hp c lac eu va chuan o vi dung
dch Na2S2O3 0,1013 M th dung het 38,68 ml. Tm % khoi lng Ba
trong mau.
3.10.Mot mau quang PbO, PbO2 (co tap chat tr) nang 1,2340 gam
c em che hoa vi 20,00 ml dung dch H2C2O4 0,2500 M e kh
PbO2 thanh Pb2+, sau o them NH3 e lam ket tua Pb2+ di dang
PbC2O4. Loc ket tua, chuan o phan nc loc (a c axit hoa) het
10,00 ml dung dch KMnO4 0,0400 M. Hoa tan ket tua PbC2O4 trong
axit va chuan o dung dch thu c het 30,00 ml dung dch KMnO 4
0,0400M th dung dch va co mau tm nhat. Xac nh % khoi lng
PbO va PbO2 trong mau quang tren.
3.11.Hoa tan 0,6000 gam mot mau phan tch co cha Pb2O3 va Pb3O4
trong axit roi lam ket tua ch di dang PbCrO4. Hoa tan ket tua
trong axit, khi co KI d. Chuan o I2 tao thanh can 35,04 ml dung
dch Na2S2O3 0,2000 M. Mat khac cho 0,6000 gam mau tac dung
vi HCl ac th lng kh Clor thoat ra c hap thu hoan toan bang
dung dch KI d. e chuan o lng I 2 giai phong ra phai dung 9,36
ml dung dch Na2S2O3 0,2000 M. Tnh % khoi lng Pb2O3 va Pb3O4
trong mau phan tch.
3.12.Chuan o 100,00 ml dung dch hon hp gom FeSO4 0,0100 M va
Fe2(SO4)3 0,0050 M bang dung dch Ce(SO4)2 0,0100 M trong moi
trng axit H2SO4 1 M. Hay tnh bc nhay chuan o neu xem sai

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Th.S.Nguyen Hien Hoang Gv.HSP

so chuan o q = 0,1 %. Cho the ien cc chuan ieu kien:
EoFe3+/Fe2+=0,68 volt; EoCe4+/Ce3+ = 1,44 volt

3.13.Hoa tan 0,5000 gam mot hp kim cha Fe va V trong axit e

chuyen Fe thanh Fe(III) va V thanh VO2+. Pha loang dung dch
thanh 200 ml. Cho 50,00 ml dung dch i qua cot kh Ag roi chuan
o het 8,86 ml Ce4+ 0,2000 N. Mat khac cho 50,00 ml dung dch
phan tch i qua cot kh nap hon hong kem, roi chuan o het 22,00
ml dung dch Ce4+ 0,2000 N. Tnh % khoi lng Fe va V trong mau
phan tch.
3.14.Tnh sai so chuan o khi chuan o 100,00 ml Fe2+ 0,1000 N bang
dung dch Cr2O72 0,1000 N trong moi trng co pH khong oi bang
0 va ket thuc chuan o khi E = 1,00 volt va E = 1,30 volt
EoFe3+/Fe2+= 0,68 volt; EoCr2O72 /Cr3+ = 1,33 volt
3.15.Chuan o mot chat kh A bang dung dch chuan cha chat oxi
hoa B. Phng trnh phan ng chuan o:
n2OxA + n1KhB
n2KhA + n1OxB
o

Thiet lap bieu thc tnh gia tr cc tieu E A EB (vi Eo la the

tieu chuan cac cap tng ng A, B 30oC) sao cho chat ch th oi

mau gan nh hoan toan trong khoang sai so chuan o cho phep q=
0,2 % Gia thiet EoIn= ET va khoang chuyen mau cua ch th c
tnh theo bieu thc : E = EoIn

0,06
n

Chng 4: CHUAN O KET TUA

4.1 1) Tm nong o ion CrO42 phai co trong dung dch e khi chuan
o ion Br bang AgNO3 th ket tua Ag2CrO4 xuat hien ung iem
tng ng. Neu dung K2CrO4 2,00 10 3 M lam ch th trong
phep chuan o KBr 0,0100 M bang AgNO3 0,0500 M th sai so
chuan o la bao nhieu neu ket thuc chuan o khi bat au xuat hien
ket tua Ag2CrO4 (lng ket tua nay khong ang ke).
2) Tnh bc nhay chuan o trong phep chuan o KBr 0,0100 M

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bang dung dch AgNO3 0,0500 M neu chap nhan sai so chuan o q
= 0,1 %. Cho TAgBr = 10 12,3; TAg2CrO4= 10 11,7 va H2CrO4 co hang
so ien ly K2 = 106,5.

4.2.Chuan o dung dch Pb2+ 0,0100 M bang dung dch K2CrO4 0,0500
M dung Ag+ lam ch th. Tai iem cuoi chuan o xuat hien ket tua
mau nau gach cua Ag2CrO4. Tnh nong o cua ion Ag+ phai co
trong dung dch e sai so cua phep chuan o trong khoang 0,1%.
Coi lng Ag2CrO4 tach ra khong ang ke.
Cho TAg2CrO4=10 12 va TPbCrO4=10 14
4.3.Chuan o 100,00 ml dung dch AgNO3 bang dung dch chuan
KSCN 0,0100 M, dung Fe3+ lam ch th th het 55,00 ml dung dch
KSCN. Qua trnh chuan o ket thuc khi dung dch xuat hien mau
hong cua phc FeSCN2+ ng vi nong o cua FeSCN2+ la 6 10 6
M, nong o ion Fe3+ tai iem cuoi chuan o la 5 10 3 M. Tnh sai
so chuan o. Cho TAgSCN = 10 12; FeSCN2+ = 103,03
4.4.Them 50,00 ml dung dch AgNO3 0,0210 M vao 100,00 ml dung
dch HCl 0,0090 M, them tiep 1 ml dung dch Fe3+ 1M va 12,00 ml
dung dch NH4SCN 0,0500 M. Co mau o cua phc FeSCN2+xuat
hien khong ? Biet rang khi C FeSCN2+ 6 10 6 iong/l th co mau
xuat hien.
4.5.Them 50,00 ml dung dch AgNO3 0,1000 N vao 50,00 ml dung
dch KIO3 co HNO3. Loc ket tua AgIO3, chuan o nc loc dung
Fe3+ (CFe3+ = 5.10 3 iong/l) lam ch th, het 30,00 ml dung dch
NH4SCN 0,1000M. Biet rang tai iem cuoi chuan o, nong o cua
FeSCN2+ la 6 10 6 iong/l. Tnh nong o KIO3 trong dung dch goc
va sai so chuan o.
4.6.e kiem tra nong o cua dung dch FeCl2 a e lau ngay trong
khong kh, ngi ta tien hanh 2 th nghiem sau:
1) Lay 25,00 ml dung dch phan tch, axit hoa bang H2SO4 roi

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Tr.12

chuan o bang dung dch K2Cr2O7 0,1000M th het 8,00 ml dung

dch K2Cr2O7 tren. Cho [H+] = 1M
2) Lay 25,00 ml dung dch phan tch em axit hoa bang HNO 3,
them vao 100,00 ml dung dch AgNO3 0,1600 M, sau o chuan o
hon hp thu c bang dung dch tieu chuan NH4SCN 0,1200 M th
het 25,00 ml.
a) Tnh nong o mol/l cua Fe2+ va Cl trong dung dch phan
tch
b) Xac nh % Fe2+ a b oxi hoa thanh Fe3+
c) Lap bieu thc tnh E tai iem tng ng cua phep chuan
o trong th nghiem 1)
4.7.Lay a gam hp chat co 60% khoi lng NaCl va 37% khoi lng
KCl (con lai la chat tr) em hoa tan thanh dung dch, sau o them
vao 25,00 ml dung dch AgNO3 0,1000 M. Chuan o lng AgNO3
tha het 5,00 ml dung dch NH4SCN. Tnh khoi lng mau phan
tch. Biet 1,00 ml dung dch NH4SCN tng ng vi 1,10 ml dung
dch AgNO3 tren.
4.8.e xac nh thanh phan cua dung dch em NH3 + NH4Cl, ngi
ta tien hanh 2 th nghiem sau ay:
TN 1: Lay 25,00 ml dung dch phan tch em chuan o bang
HCl 0,1000 M th het 15,00 ml. Cho KNH4+= 5,5 10 10
TN 2 : Them 60,00 ml dung dch AgNO3 0,1000 M vao hon
hp tao thanh sau phan ng chuan o TN 1 tren, loc ket tua tach
ra, axit hoa nc loc bang HNO3 roi chuan o bang dung dch
NH4SCN 0,2000 M th het 18,00 ml.
1) Giai thch noi dung cac th nghiem tren va tnh nong o
mol/l cua NH3 va NH4Cl trong dung dch em.
2) Tnh pH cua dung dch em trc khi chuan o.
3) Chon ch th thch hp e xac nh iem cuoi trong TN 1
(trong so cac ch th thong dung).

4.9.Mot mau phan tch A cha NaOH va NaCl a hut am. Ngi ta

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can 6,7000 gam A hoa tan trong bnh nh mc 250 ml, c dung
dch B roi thc hien 2 th nghiem sau:
TN 1: Chuan o 25,00 ml dung dch B bang dung dch HCl
0,5000M vi phenoltalein ch th th phai dung 22,00 ml.
TN 2: Lay 25,00 ml dung dch B, axit hoa bang HNO3 roi chuan
o ion Cl trong dung dch thu c bang phng phap Volthard.
Sau khi them 35,00 ml dung dch AgNO3 0,1100 M th can dung
4,70 ml dung dch KSCN 0,0950 M e chuan o AgNO3 d. Hay
tnh:
1) % khoi lng cac chat trong mau A va pH cua dung dch B
2) Sai so chuan o trong th nghiem 1, neu ket thu c chuan o
pH = 10
3) Co the xac nh trc tiep Cl trong dung dch B bang
phng phap Mohr c khong, giai thch tai sao ?
4.10.Hoa tan 3,5000 gam mot mau Na2CO3 co lan NaCl va tap chat
tr vao nc roi pha loang thanh 250 ml. Chuan o 25,00 ml dung
dch thu c, dung metyl da cam lam ch th (pT=4) het 20,50 ml
dung dch HCl 0,2000 M. sau o un soi e uoi het CO 2 roi chuan
o tiep tuc dung dch thu c dung K2CrO4 5 10 3 M lam ch th
het 30,50 ml AgNO3 0,2000 M.
1) Tnh % khoi lng cac chat trong hon hp.
2) Tnh sai so chuan o trong phep chuan o th hai neu xem
tai iem cuoi chuan o co 5,75 107 mol Ag2CrO4 tach ra.
Cho TAgCl = 1010 va TAg2CrO4= 1012; NaCl = 58,5; Na2CO3 =
106

4.11.Viec nh lng Cl bang phng phap Mohr can thc hien trong
khoang gia tr pH nhat nh sao cho ket tua Ag2CrO4 co o tan
khong tang nhieu qua (do qua trnh proton hoa CrO42 ) va Ag2O
khong ket tua. Hay xac nh khoang pH o, cho biet:
2Ag+ + 2OH co K= 4.1016
Can bang Ag2O + H2O
H2CrO4 co K2 = 3,2 107, chap nhan o tan Ag2CrO4 co the
tang toi a 1% so vi o tan cua no trong dung dch bao hoa.

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Chng 5: CHUAN O TAO PHC

5.1.Chuan o 50,00 ml dung dch SrCl2 0,0100 M bang EDTA 0,0200
M trong dung dch em pH = 10. Tnh pSr sau khi a them 24,90
ml; 25,00 ml; 25,10 ml dung dch EDTA.
Cho Sr2+ = 10 13,18; SrY = 108,63
EDTA co : K1= 10 2; K2= 10 2,67; K3= 106,16; K4 = 1010.26

5.2.Tnh sai so chuan o dung dch Ca2+ 10 2 M bang EDTA 10 2 M

dung ch th Ecriocrom en R (H2In) pH = 12,5 neu tai iem cuoi
chuan o 50 % lng chat ch th ton tai dang phc vi ion kim
loai.
Cho : Ca2+= 10 12,5; lg CaIn= 5,3; H2In co pK1=7,0 , pK2 =13,5
Va CaY= 1010,57

5.3.Chuan o Ca2+ 0,0100 M bang dung dch EDTA cung nong o,

dung dch c em e gi pH= 10, va dung chat ch th oi mau
khi t so cac nong o [CaInd]/[Ind*]=1. e chat ch th oi mau
ung iem tng ng th hang so ben ieu kien * cua phc
CaInd phai bang bao nhieu ? Cac hang so giong bai 5.2
5.4. Chuan o 100,00 ml dung dch MgCl2 phai dung 50,00 ml dung
dch EDTA 0,0200 M e lam oi mau ch th Ecrio T pH= 10. Biet
rang tai iem ket thuc chuan o, 90 % ch th dang khong tao
phc. Tnh sai so cua phep chuan o.
Cho MgY = 108,7; MgIn = 107; Mg = 10 11,7;
Ch th Ecrio T co K2 = 10 6,3; K3 = 10 11,6
EDTA co K1 = 102; K2 = 10 2,67; K3 = 106,16; K4 = 10 10,26
5.5.Chuan o dung dch ion kim loai M 2+ nong o 0,0100 M bang
dung dch chuan EDTA (Na2H2Y) cung nong o, pH cua dung dch
c gi khong thay oi bang 5 va ket thuc chuan o khi t so nong
o [MIn]/[In*]= 1. Tnh sai so chuan o. Biet MY = 1018; chat ch
H2In co pK1=2 va pK2=7 va phc MIn co MIn =6,25 1010. Bo qua
phc hidroxo va axetat cua kim loai.

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Th.S.Nguyen Hien Hoang Gv.HSP

2+

10 3

5.6.Ve ng cong chuan o 100,00ml dung dch Zn

M bang
EDTA 0,1000 M trong hon hp em NH3 0,1000M va NH4Cl 0,1820
M. Bo qua qua trnh tao phc hidroxo cua Zn2+. Cho ZnY= 1016,5;
phc cua Zn-NH3 co 1=102,27, 2 = 104,61, 3 = 107,01, 4 = 109,06 va
hang so phan li K NH4+ = 5,50 10 10.
5.7.Chuan o 100,00 ml dung dch MnSO4 0,0100 M pH = 9 bang
dung dch complexon III 0,0200 M.
1) Tnh cac the tch Complexon III phai dung e chuan o c
50 % MnSO4, chuan o en iem tng ng, va chuan o
en gia tr pMn = 5 hoac pMn = 9.
2) Tnh sai so chuan o neu tai iem cuoi chuan o co pMn = 5
3) Tnh pMn tai iem tng ng.
Cho lg MnY = 13,8. Bo qua phc hidroxo cua Mn2+
5.8.e chuan o Ga(III), ngi ta them 25,00 ml dung dch Magie
complexonat nong o 0,05942 M vao dung dch chuan o, c gi
pH khong oi bang 10 (bang dung dch em) va mot lng nho
ch th Ecriocrom T. Sau o chuan o bang dung dch EDTA 0,0701
M th het 5,91 ml EDTA. Tnh so mg Ga trong mau. Cho biet GaY
= 1020,3 va MgY2 = 10+8,7. Ga = 69,72

5.9.Lay 50,00 ml nc, em axit hoa bang HCl roi un dung dch e
uoi het CO2. Trung hoa dung dch bang NaOH sau o em dung
dch pH = 10, chuan o dung dch bang EDTA 0,01204 M va het
31,63 ml dung dch. Tnh o cng cua nc (theo mili ng lng
gam /l).
5.10.Lay mot lng a voi (cha CaCO3, MgCO3, mot t Al, Fe) co
khoi lng 0,5021 gam hoa tan hoan toan trong dung dch HCl, sau
o them dung dch NH3 vao e lam ket tua het Al3+ va Fe3+. Pha
loang nc loc thu c (sau khi tach bo ket tua) bang nc e
c 500 ml dung dch.
Khi chuan o 20,00 ml dung dch nay vi ch th Murexit trong

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moi trng kiem manh (pH = 11,5) th het 9,4 ml dung dch EDTA
0,0150 M
Khi chuan o 20,00 ml dung dch nay vi Ecriocrom en T
pH= 9,3 th het 13,50 ml dung dch EDTA 0,0150 M
Tnh % khoi lng CaCO3 va MgCO3 trong mau.
Cho CaCO3 = 100, MgCO3 = 84, TCa(OH)2= 10 5,26; TMg(OH)2 = 10 10,95
5.11.Lay 25,00 ml dung dch A cha Fe3+ va Al3+; ieu chnh dung
dch co pH= 2. Them 200 mg axit salixilic, lac en tan. Chuan o
dung dch bang EDTA cho en khi mat mau cua phc Fe-Salixilat
het 29,60 ml dung dch EDTA 0,0230 M. Them tiep 50,00 ml dung
dch EDTA vao hon hp, un soi e am bao Al 3+ a tao phc het
vi EDTA (sau khi a ieu chnh pH = 5). Chuan o EDTA d bang
dung dch Fe(NO3)3 cho en khi xuat hien mau o cua phc FeSalixilat th het 38,00 ml dung dch Fe(NO3)3 0,0160 M.
1) Tnh hang so can bang ieu kien cua phc Fe-EDTA va AlEDTA pH= 2 va pH = 5 (coi rang trong dung dch ch tao mot
loai phc hidroxo Fe(OH)2+ va Al(OH)2+
2) Tnh nong o cua Al3+ va Fe3+ trong dung dch A. Cho biet ta
ch co the chuan o c ion kim loai M n+ khi hang so *MY
>108
Cho Fe3+ =102,17; Al3+ = 10 5; FeY = 1025,1; AlY = 1016,13
5.12.Chuan o 100,00 ml dung dch CuSO4 bang dung dch EDTA
(Na2H2Y) 0,10M trong dung dch em NH3 0,38M + NH4+ 0,0026M.
Phep chuan o dung Murexit lam ch th va tai iem cuoi chuan o
phai dung 10,00 ml EDTA, biet co 10% lng chat ch th ton tai
dang khong tao phc. Tnh sai so cua phep chuan o.
Murexit H4In co pK2 = 8,7; pK3=10,28; pK4 13,5; pK5 =14
Cho logCu-In = 17,9; logCu-Y =18,8 va KNH4+ = 10 9,26
Phc Cu2+-NH3 co : log1 =3,99; log 2 =7,33; log 3 = 10,66;
log 4 =12,03
EDTA co : K1=10 2; K2 =10 2,67; K3 = 10 6,16; K4 = 10 10,26

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Th.S.Nguyen Hien Hoang Gv.HSP

Bo qua qua trnh tao phc hidroxo cua Cu

2+

Chng 6 : PHNG PHAP KHOI LNG

6.1.e nh lng Mg trong mot mau phan tch, ngi ta can 0,5000
gam mau hoa tan thanh dung dch, lam ket tua Mg2+ di dang
MgNH4PO4. Sau khi loc ra ket tua, nung en khoi lng khong oi
thu c 0,3515 gam Mg2P2O7. Tnh % khoi lng Mg trong mau
6.2.Khi phan tch 0,3563 gam mot mau silicat, ngi ta thu c hon
hp NaCl + KCl nang 0,1758 g. Sau o chuyen vao dung dch va
lam ket tua Cl di dang AgCl, can nang 0,4104 gam. Tnh % khoi
lng Na2O va K2O trong mau.
6.3.1) Tnh the tch dimetyl glyoxim (H2Dim) nong o 10 g/l can e
lam ket tua hoan toan Ni2+ t dung dch cha 50 mg Ni2+. Gia thiet
e lam ket tua hoan toan phai dung d 5% lng thuoc th so vi
lng can thiet tnh theo phng trnh phan ng.
2) e xac nh Ni trong thep.ngi ta lay 1,0860 gam mau, sau
khi hoa tan hoan toan va che hoa vi H2Dim, Ni2+ c ket tua di
dang Ni(HDim)2. Sau khi ra va say kho ket tua, em can nang
0,2136 gam. Tnh % khoi lng Ni trong mau thep. Cho Ni = 58,71
va khoi lng phan t cua H2Dim = 116,12
6.4.Hoa tan 0,6700 gam mot mau KCl co lan KI va tap chat tr trong
nc va cho d AgNO3. Loc ra va lam kho ket tua c 0,5240
gam. Sau o ot nong ket tua trong mot luong kh Cl 2 e chuyen
hoan toan AgI thanh AgCl roi can ket tua kho c 0,4200 gam.
Tnh % khoi lng AgCl va KI trong mau phan tch.
6.5.Hoa tan 0,6000 gam a voi trong dung dch HCl. Ket tua ion Ca 2+
trong dung dch di dang CaC2O4. Loc, nung ket tua en khoi
lng khong oi c 0,2820 gam CaO. Tnh % CaCO3 co trong a
voi.
6.7.Mot mau KBr co lan mot t KBrO3 va tap chat tr. Hoa tan 5,00
gam mau vao nc va pha loang thanh 250 ml (dung dch A). Them

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NaHSO3 va axit vao 50,00 ml dung dch A e kh BrO3 thanh Br,

roi them d AgNO3 th c 0,6500 gam AgBr kho. Mat khac, axit
hoa 50,00 ml dung dch A bang H2SO4, khi ay BrO3 b Br kh het
thanh Br2. un soi e uoi het Br2 va lam ket tua Br d bang
AgNO3 c 0,2050 gam AgBr. Viet cac phng trnh phan ng va
tnh % khoi lng KBr va KbrO3 trong mau.
Chng 7: X LY CAC SO LIEU THC NGHIEM
7.1.1) Co bao nhieu ch so co ngha trong cac so sau: 0,104 1,04
104
1,04.104
log 1,01 = 0,004
0,0607
2) Bieu dien ket qua vi ch so co ngha can thiet cua phep
toan :
a) 204,2 + 19,15 + 3,035 =
b) 90,173 + 8,21 + 1,1 =
c) 4,00.102 M + 0,555.102 M + 0,0001.102 M =
d)
e)

46,32 0,173
=
51,743
3,472 61,84
=
0,01621

7.2. Bieu dien ket qua vi cac ch so co ngha can thiet:

a) pH = log (3,8.106) =
b) pH = log (1.1012) =
c) pH = 2 [H+] =
d) pH = 1,698 [H+] =
e) pK = 2,39 K =
f) pK = 10,3 K =
7.2. Tnh ham lng % cua Cu trong quang t nhng d kien sau ay
vi cac ch so co ngha can thiet: Khoi lng quang em phan tch
la 1,000 gam, phng phap xac nh: phng phap chuan o iot, the
tch dung dch Na2S2O3 0,10000N can la 4,00 ml vi buret 50 ml,
Cho Cu = 63,54
7.3.Dung chuan Q e xet cac gia tr nghi ng trong loat cac gia tr sau

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(nen gi lai hay bo i) :

a) 55,95 56,00 56,04 56,08 56,23
b) 5,12 6,02 6,12 6,22 6,32 6,82
7.3.Dung chuan t e xac nh xem cac ket qua xac nh lu huynh
trong dau mo (theo %) co mac sai so he thong khong: 0,112 0,118
0,115 0,119. Cho biet ham lng thc lu huynh co trong dau mo
la 0,123%.
7.4.Ket qua phan tch ham lng sat trong mot mau phan tch vi 4
th nghiem cho ket qua sau : tr trung bnh
x = 15,3%; o lech chuan
s = 0,10; n = 4. Xac nh khoang gia tr ham lng % cua sat

7.5.Xac nh Na2CO3 co trong mau tro bang 2 phng phap cho ket
qua sau ay :
PP 1:
PP 2:

x 1= 42,34
x2 = 42,44
S1 = 0,10
S2 = 0,122
n1 = 5
n2 = 4
a) Cac gia tr S1 va S2 co thc s khac nhau khong ?
b) Vi xac suat 95% hai gia tr trung bnh co thc s khac nhau
khong ?
7.7.Trong thc nghiem ngi ta xac nh c khoi lng nguyen t
C nh sau: 12,0112; 12,0210; 12,0102; 12,0118; 12,0111;
12,0106; 12,0113; 12,0101; 12,0097; 12,0095; 12,0080.
a) Tm gia tr trung bnh
b) Tnh o lech chuan.
c) Bieu dien khoi lng nguyen t C vi gii han tin cay xac
suat 95%
d) Neu co them mot ket qua la 12,0138, th so lieu nen bo i
hay e lai ?
7.7.Tien hanh phan tch olomit e xac nh %CaO trong mau, thu
c ket qua sau: 29,22; 28,82; 28,94; 29,02; 29,56; 29,22;

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29,78. Xac nh gia tr trung bnh

x, o lech chuan s, phng sai s2,
khoang tin cay cua gia tr trung bnh.
7.8.o chuan cua KMnO4 c xac nh trong 2 day o. Trong day
th nhat, chat xac nh la natri asenit, trong day th hai chat xac
nh la axit oxalic:
Day 1:
0,05010; 0,05014; 0,05015; 0,05018; 0,05015; 0,05012;
0,05014
Day 2:
0,05011; 0,05010; 0,05012; 0,05012; 0,05010; 0,05011, 0,05010;
0,05012
Hay anh gia hai day d kien theo tieu chuan F

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Hng dan va ap so:

6.1. 1) NaOH = 40 gam; KHSO4 = 136 g; N2O5 = 54 g; K2O = 47 g
Ba(OH)2 = 85,5 g; NH3= 17 g
2) a) MnSO4 = 75,5 g; NaOH = 40 g
b) Fe(OH)3= 54,17 g; Ba(OH)2 = 85,5 g
c) KMnO4 = 31,6 g; FeSO4=152 g
d) I2 = 127 g; Na2S2O3 = 158 g
e) K2Cr2O7 = 49 g; FeSO4=152 g
3) a) CaCl2 = 55,55 g; H3PO4 = 98 g
b) CaCl2 = 55,55 g; H3PO4 = 32,67 g
c) CaCl2 = 55,55 g; Na2HPO4 = 71 g