Professional Documents
Culture Documents
II
CHEMISTRY
EXPERIMENTAL SCIENCE
II.
CHEMISTRY
SLcmtion:
ILmrtJon:
CLAY, MANAOEB
H. K. LEWIS, 136
GOWER
STREET, W.C.
Toronto :
EXPERIMENTAL SCIENCE
II.J
CHEMISTRY
BY
S.
E.
BROWN,
Cambridge
PKEFACE
author claims to have been one of the
-I-
first
to put
The path
and discovery was opened to many a boy and
girl who would otherwise have trodden the damp and
muddy ways of test-tube analysis.
The short time available and the ever-changing classes
render strict adherence to the "heuristic" method impracother than Science thinking and experimenting.
of adventure
ticable,
while
which make
many
it
tedious
"historic" method.
The
is
It should
very
little
systematically set
and exacted
for
home-work.
vi
Preface
The
first
Much
teacher.
fully explained.
Cam-
Examinations
Science),
and
Mr W.
June 1912.
BROWN.
CONTENTS
PAGE
CHAP.
I.
II.
10
III.
IV.
Separation
V.
and
crystallizing
VI.
VII.
VIII.
Solution
and
may
Oxygen
and Hydrochloric
Salts.
Water
Alkalies) and
Bases
(including
Crystallization
XIV.
XV.
XVI.
XVII.
XVIII.
XIX.
19
...
...
...
.... ...
Sulphuric, Nitric
XII.
filtering,
Problems on burning
Acids
XIII.
15
dissolving,
distilling
IX.
XI.
by
purifying
....
51
57
67
79
86
.103
.118
110
.
Atomic Theory.
tions.
KEVISION QUESTIONS
39
47
94
.
28
33
of
25
.134
.138
139
EXPEKIMENTAL CHEMISTRY
CHAPTER
I.
burner.
'
Unscrew the tube of your 'Bunsen'; you will notice a small jet
Connect the burner to the gas supply and
attached to the stand.
Turn
set a light to the jet.
long ordinary gas flame is seen.
Then close the holes at the
out the flame and screw on the tube.
bottom of the tube and light the gas at the top, again an ordinary
luminous flame appears. Open the holes and observe that the
flame is now smaller, non-luminous and hotter.
Blowpipe flame.
pipe on the edge of the tube and blow through the luminous
It is obvious that mixing air with coal gas conflame (Fig. 1).
centrates the flame
and renders
it
Fish-tail burner.
This gives a broad luminous flame suitable for softening glass tubing in order to bend it.
*Exp. Use the piece of thin iron wire supplied to find which flame
and which part of the name is the hottest. You can judge by the colour of
the heated wire.
for the
B. E. SO,
Experimental Chemistry
2.
It
is
[on. i
we
if
we
Fig. 1.
by the Bunsen
heat suitable
for
rise
flame.
evaporating purposes
A water bath
is
is
steady
obtained.
flow
of
above 100 C.
useful
when
it is
liquids as well as
A drying cone
is
Laboratory Methods
2-3]
rises
A desiccator
is
a glass
vessel,
precipitates
Fig. 3.
Fig. 2.
and
lid,
Fig. 4.
3.
To cut a
piece of
When
the glass
is
soft
ifc
may
12
[OH. I
Experimental Chemistry
it.
to cool before
removing
the lamp-black.
Fig. 5.
To draw out
it
out while
it is
The more
the hands are drawn
in the
flame.
rapidly
apart the finer the tube will be
(capillary tubing).
To
seal
a bulb,
flame.
Its
sharp
edges
they
gradually
close
to-
If a bulb is
gether (Fig. 6 B).
required (Fig. 6 c), continue the
is
a small
down
(!)
Laboratory Methods
3-7]
4.
liquid.
glass.
How to bore
5.
larger than
a hole in a cork.
Roll
it fits
required.
the flask or tube. Select a brass or steel cork borer rather smaller
is
it
if it
and boring down on to a soft piece of wood. Wet the glass tubing
before working it into the hole in the cork.
To bore a hole in a rubber cork dip the borer in caustic potash
solution before using.
To
6.
test
tight, close
all
is air-
is air-tight.
Fold a round
7.
Filtering.
press
it
To
corked
it
makes
first*
filter
into
the latter
is
rapidly, the
filter
funnel
is
flask
with
Fig. 7.
Experimental Chemistry
The
pressure
is
Fig. 8.
8).
Fig. 9.
Parallax error.
8.
[CH. 1
Care
position
is
B is
not.
is
from
To
collect a gas
(a)
by means
of-
filled
a pneumatic
jars,
which, after
ground glass
Fig. 10.
10).
by means of an
'
'
Laboratory Methods
7-9J
fill
the gas.
"
I I 8- 11
surface of the displaced water.
and
has
ceased
the
When reaction
apparatus is at the temperature of the room, adjust the level of the water in the cylinder
The volume of the
to that in the aspirator and close the tap.
-
water collected
9.
now
Corrections of
Volume of Gases
for
Tempera-
is
the volume at
V
E.g. 100c.c. is
C.
273 x
and
P mm.
at
C.
in the
12
water at
Experimental Chemistry
[OH.
11.
Fig> 12 '
it
See that the weights are correct before and after use and that they
Never put on or remove anything from the pans when the balance
swing and never leave it swinging.
is free to
3.
First see that the balance is correctly adjusted and then always put
the substance to be weighed in the left-hand pan.
4.
possibly help
if
you can
it.
5.
Always begin with a weight that is too great and continue to add
weights in the same order, downwards.
Never weigh anything hot or wet or likely to stick to the pan.
6.
7.
With the left hand, raise the lever gently, and only turn
when a balance is nearly obtained.
it
com-
pletely over
8.
Count the weights both by the number on the pan and by the vacant
13.
(a)
Weighing by difference.
An empty beaker or dish may
be
first
weighed and
Laboratory Methods
10-14]
(6)
substance
afterwards some of
it
the tube and remainder are again weighed and the weight of
what has been tipped out is found by difference/
14. To enter notes on observations and results.
*
Practical Exercises.
With the
Fig. 12 A.
Fig. 12 B.
QUESTIONS ON CHAPTER
Give reasons why
Weighing in 12.
1.
2.
Why
3.
Draw up a
is it
it is
I.
'
necessary to avoid 'Parallax Error ?
set of rules
CHAPTEE
II.
We
What
is
Chemistry?
substances
gases
left
which
free
Bxp.
tell
wax
have taken part in the burning and that other things are
formed as the candle disappears. To make clear the
inner meaning of these changes
is
the
work
of the
chemist.
Fig. 13.
we try to find
how they are
15-17]
built
up
16.
is
place
when they
formed as a
Physical changes.
We
interact
11
what are
result.
there are very complicated changes going on around us, as, for
instance, the conversion of food into flesh, bones, skin and hair.
But, are
all
is it
possible to classify
them?
Ponds and puddles dry up. The clouds and
Water.
(i)
Down come the rain, hail and
mist form out of a clear sky.
snow. The pond freezes and we skate on the floating ice. The
ice melts
(ii)
it
Its
*Exp.
glows.
Exp.
Repeat, substituting a
lump
burned quicklime,
Again no permanent change
of freshly
*Exp. These two steel pens do not attract each other. Weigh
(iv)
them. Then, taking them together by the points, rub them several times in
one direction only along a bar magnet. Try whether their ends attract or
The steel is now magnetized. Heat the pens red-hot.
repel each other.
They have lost their magnetism, although they are still steel pens and their
weight has not altered.
is
accom-
panied by:
17.
*Exp.
(a)
(6)
(c)
no alteration in composition,
(d)
no alteration in weight.
Water
To
may be
reversed,
illustrate
12
Experimental Chemistry
[CH. ii
By a thermometer T, we can read the temperaand steam. Taste the distillate D and evaporate a little
Notice there is no residue. Freeze some of
to dryness on a watch glass.
the distilled water in a test tube by surrounding the tube with a mixture of
is
Fig. 14.
[Liebig's Condenser is
tube
is
\MCo/.o WATER
Fig. 15.
18.
Further Experiments to
illustrate physical
change.
i.
Heat very gradually in test tubes small separate quantities of
Sulphur, (&) Iodine, (c) Mercury. Observe and record all the changes
both on heating and on cooling.
*Exp.
(a)
*Exp. ii. Eub Ebonite with Flannel and notice the attraction between
the electrified ebonite and light objects such as paper. Notice there is no
change in weight of both ebonite and flannel.
17-20]
13
by suspending
it
to a spring balance.
19.
When we
match to
its original
condition.
Exp.
Iron
(iii)
rusts,
and rust
is
It was shown in our first experiment ( 15) that air was neshall find later that the match,
cessary in burning a candle.
the magnesium and the iron, as they burn or rust, gain in weight
from the air and that the air loses an equal weight.
We
Chemical changes
new
the formation of
(6)
(c)
(d)
Add water
to the
Mix together a
(ii)
substances,
^Experiments to
20.
(i)
then involve:
(a)
lump
little
illustrate
Chemical Change.
of Quicklime used in
16,
iii.
(iii)
(iv)
Heat on
of Copper
(v)
(foil),
Warm
part.
in a test tube,
turnings.
Describe carefully
all
14
Experimental Chemistry
QUESTIONS ON CHAPTER
What
1.
(a)
[CH. 11
II.
a Physical Change,
(6)
Chemical Change ?
Heat
2.
(c)
Charcoal,
is
Sulphur,
(d)
3.
in air
4.
(b)
(a)
Mercury,
(6)
when the
Magnesium,
which
(a)
(c)
CHAPTER
III.
Mixtures.
sea-shore
is
a mixture.
You have
how
to separate
by means of solution in
16
Experimental Chemistry
22.
Compounds.
evaporated slowly,
each grain
we
If
find
bounded by
is
some
of
[CH.
the solution of
in
salt
is
23.
Elements.
bodies.
Exp.
chlorine.
Fig. 16.
salt
Note.
as follows.
sodium chloride
a chemical compound
is
formed.
(see Fig.
22-24]
Sodium converted to
i
$oc/ivm Chloride
Fig. 17.
24.
ditions
(a)
definite
(6)
it
is
composed.
(d)
change of temperature accompanies its formation.
Contrast these with the corresponding properties of mixtures.
Then refer to your experiments on chemical change, 20, some
of
equations
Elements
Compounds
Phosphorus Iodide
= 412 parts by weight
Iron Sulphide
= 88 parts by weight
= 95
Copper Sulphide
parts by weight
You must
by
direct
B. E. so.
18
Experimental Chemistry
[CH.
in-
definite proportions
by weight.
Name
elements and
1.
What
is
2.
What
3.
You
an element ?
State
you proceed?
4.
is
a definite chemical
five
compounds.
compounds ?
found underground
prove,
five
compound
of
your experiments to
(o. J.)
What
is
cal mixture ?
5.
State
salt/rom
its
(a)
decompose
CHAPTER
IV.
SEPARATION
25.
Separation by dissolving.
We
have
already
not a compound.
Gunpowder contains
(1)
nitre
(saltpetre)
Sulphur
To
is
is not.
to the gunpowder, in a
beaker. After warming and stirring the solution, the nitre will dissolve.
Filtering will give us a clear solution of nitre which may be evaporated until
Exp.
crystals
form on cooling.
To
The
filter
j,.
filter
to
in the draught-place.
22
'
'
dry
20
[en. iv
Experimental Chemistry
*Exp.
To
mixture are placed. Weigh the mixture in the beaker. Then add about 20 c.c.
of water (distilled) warm to dissolve the yellow chromate. The chalk is not
dissolved.
Balance two filter papers and prepare a filter by folding them
Filter the
together so that the chalk will be caught on one of the papers.
mixture into a weighed evaporating dish. Let the filter empty itself. Using
as little water as possible, rinse the beaker so that all the chalk is washed
on to the filter paper. Again allow the filter to empty itself. Pour a few
;
down
filter
coming
through is no longer yellow. (1) Carefully evaporate the liquid in the dish
to dryness and find the weight of the potassium chromate.
Dry the
(2)
counterpoised filter papers on the cone, separate them, place one in each
scale pan and weigh the chalk.
Calculate the percentage composition of the
mixture.
Further *Exps.
mixtures :
Sand and
(i)
26.
Terms and
Solvent
Water
salt,
(ii)
Definitions.
is
carbon bi-sulphide
for sulphur.
Saturated solution
saturated solution,
Filtrate
Residue
Solubility
by the number
the solid
remaining on the
filter
filter.
paper.
measured
grams
of
Mother liquor
is
Solution
25-28]
27.
Solubility
and
and
21
Distillation
Solubility Curves.
To
dish.
made.
saturated solution into the dish. Weigh again. Then evaporate to dryness
on the sand bath, but beware of over-heating. Weigh when cold. The loss
of weight is the weight of water which can dissolve the amount of nitre
remaining in the dish after evaporation. Heat again very gently and weigh.
Repeat until the weight is constant. Calculate the weight of nitre which
100 grams of water can dissolve, at the specified temperature.
By making
it is
similar experiments.
possible to obtain the solubility by somewhat
Results may be tabulated as follows :
Nitre.
At
C. 100
grams
20 C.
40 0.
of water dissolved 13
grams
31
64
132
>,
-
70 0.
28.
(Frac-
tional Crystallization.)
Exp.
water).
C.
(both soluble in
=5.
soluble substance is
isolated
by
this
removed from
method.
solution.
The
salts of
22
[OH. iv
Experimental Chemistry
Exp.
Similarly separate
(a)
(6) salt
from alum.
==
20
30'
60
60
80
90
0*
Take
for
example
differ-
and
Solution
28-29]
23
Distillation
shall
have
obtained, which
flask
practically pure.
*Exp.
flask in a
Distil a
water bath.
84.
distilling
Ke-distil this
a lump of quicklime
What
is distillation?
in practical chemistry?
2.
is
soluble in water?
4.
Calculate percentage of (a) sand and nitre,
chromate present in a mixture from the following
(6)
Weight of
filter
,,
=
=
paper
,,
,,
,,
,,
and mixture
dry sand
evaporating dish
,,
and dry
salt
(a)
(6)
-895
-78
gm.
4-275 gm.
= 1-425 gm.
= 27'35 gm.
=30-2
gm.
gm.
3-52 gm.
3-27 gm.
49'75 gm.
50-0 gm.
'
5.
'
'
of salt?
6.
(a)
6'8
gm.
24
c.c.
evaporation.
(6)
What
is
gm.
of dry nitre,
[CH. IY
Experimental Chemistry
8.
Weight
of evaporating dish
,,
,,
empty
and solution
= 44-32
= 48-97
gm.
gm.
dry nitre = 45-14 gm.
10.
If
Draw
following data
Temperature
CHAPTER
V.
MAY BE ACCOMPANIED BY
SOLUTION
CHEMICAL CHANGE.
30. When we make effervescing drinks, as for instance
when we pour water on to sherbet, fruit salts or Seidlitz
powders, we meet with instances of chemical change accompanyThe fact that a gas is set free gives us sufficient
ing solution.
proof of this, for
is
it is
produced when
*Exp. i. Make up a mixture of chalk and water and add a few drops of
hydrochloric acid. The solid chalk suspended in the water is dissolved and
a gas (carbon di-oxide) is set free. This gas puts out a burning taper.
*Exp.
vitriol) in
ii.
Drop thin shavings of zinc into dilute sulphuric acid
a test tube fitted with a cork and
delivery tube.
The
zinc
dissolves
(oil
of
and an
ment
if
Exp.
iii.
Exp.
warm
iv.
and
(6)
magnesium
Drop aluminium
for zinc.
foil
into a
Hydrogen
Fig. 20.
is liberated.
In
all
these cases
by chemical change.
it is
is
accompanied
26
Experimental Chemistry
31.
There
is
[CH.
nature
of Chemical Change.
between the weight of zinc
the weight of acid required and the weight
Quantitative
a definite relation
dissolved,
of gas liberated.
*Exp. i. Weigh out exactly a gram of zinc foil, and put it into a small
Having placed about 50 c.c. of dilute sulphuric acid in a small flask,
suspend the tube containing zinc in the flask by a thread and connect the
tube.
Fig. 21.
flask to
and pressure
of the
room.
If care is
taken
all
the
members
obtain, within one per cent., the same volume and therefore the same weight
of gas. (See Physics weight of 1 litre of gas.)
It
is difficult
(a)
and that
(b)
to
formed in solution.
However, approximate
(A)
zinc.
is
given
off.
Carefully remove,
Each
of
31]
27
Evaporate the two solutions to an equal bulk and let them stand for
Collect the crystals (zinc sulphate) and dry them separately.
Approximately equal weights are obtained.
(B)
a few hours.
results.
QUESTIONS ON CHAPTER V.
1.
dissolves
Salt
'
in water
zinc
'
dissolves
'
Compare the two processes. How would you prove that in the second case
a definite amount of sulphuric acid is required for the solution of a definite
amount of zinc? (o. J.)
2.
When
hydrogen are
evidence
is
collected.
a mixture of sand, salt and chalk were given you how would you
proceed in order to obtain from it all the sand arid all the salt which it
contains ? (o. j.)
3.
If
4.
10 c.c. and 20 c.c. of acid of the same strength are placed in separate
beakers and the same weight of magnesium ribbon is placed in each. When
all chemical action is over the metal remaining in each beaker is dried and
CHAPTER VL
THE ATMOSPHERE AND COMBUSTION IN
Air
32.
is
a mixture.
We
AIR.
Physics that the air has weight, that it is elastic (i.e. if compressed, it shrinks, but expands when the pressure is relaxed) and
that its volume is affected by heat and cold.
we
cool it or compress
further ice
air
press
is
until
obtained which
it,
water
is
formed
if
we
formed.
Similarly
it is
just as
boils
away
first,
different in density
comes
off as
The
196
C.), it is
quite
183
C.).
higher
is
NITROGEN.
OXYGEN.
else.
32-34]
29
which
and
air is formed.
We have now
two
But we
be
Discovery of Oxygen.
33.
Having
accidentally by Priestley, an Englishman, in 1774.
filled a glass jar with mercury in a pneumatic trough, he put
the substance on which he wished to experiment inside the jar,
and there, as it floated on the mercury, he heated it with the
rays of the sun concentrated by a powerful 'burning-glass.'
He heated the calx or ash of mercury (red precipitate) among
experiments
30
Experimental Chemistry
II.
(360
[OH. vi
0.),
Fig. 23.
Fig. 24.
shrinkage in the first experiment (Fig. 24). This gas was added
to the residual air of the first experiment, when ordinary air was
again produced. Moreover the mercury obtained by heating the
at the beginning.
the air
inert);
destroyed.
Lavoisier afterwards
34-37]
31
35.
in
burning!
Effect of Heat on Magnesium. Weigh a crucible and lid.
about a gram of magnesium turnings or ribbon. Weigh again.
Heat, raising the lid slightly from time to time to admit air, until all the
metal is burned. Weigh, when the crucible is cold, and calculate the
*Exp.
Place in
i.
it
to its
36.
air.
it
rusts.
Again iron
place.
"
are heated to expel any moisture present and are afterwards weighed, there
is found to be a considerable gain in weight.
if air is excluded.
That water alone does not
be shown by boiling together, in a round-bottomed
flask for some minutes, water and iron nails. Cork or seal up the flask while
the water is boiling, i.e. when the flask is full of steam. Another method is
to pour paraffin on the surface of the water immediately after removing the
source of heat. Air is thus excluded and no rusting occurs even after many
days have elapsed.
cause iron
to rust
may
[Note. That moisture and air alone do not cause iron to rust if
carbonic acid gas is absent is proved by suspending bright iron in a closed
flask containing a little potash solution, which absorbs carbonic acid gas.]
37.
It
is
probable that in
1727 oxygen was first isolated by heating red lead (minium) but
it was not recognized as a new element.
In 1774, Scheele, a
Swedish chemist, discovered oxygen independently of and possibly
earlier than Priestley.
He first obtained it by heating nitre.
He also found that, by varying the conditions and the temperature, lead yields
two
calxes, the
32
[en. vi
Experimental Chemistry
If the temperature
is
raised to a
bright red heat the red lead loses weight and yields oxygen, at
the same time reverting to litharge.
*Exp. Weigh a test tube containing about 10 grams of red lead. Heat
strongly and test the gas evolved with a glowing splinter. Oxygen (' active
air ') is liberated and on weighing again a loss of weight is observed. Break
open the
test
38.
We have now
As a commercial process
yields oxygen.
temperature constant.
method
1.
(6)
The
2.
and cooling
(a)
32).
not an element,
(o. J.)
cases lighter, in others heavier, than the original substances. Give one
instance of each kind. Describe experiments for investigating the action in
therefrom,
3.
when
(c. J.)
4.
What
5.
How
may
be
made
was oxygen
first
to investigate
what occurs
(c. J.)
obtained
is
indestructible?
Weight
of crucible
,,
,,
,,
7.
One gram
If 2 gm.
must be heated?
heated.
= 14-775 gm.
and magnesium = 14-805 gm.
,,
magn. oxide = 14-825 gm.
CHAPTER YIL
NITROGEN FROM AIR.
PROBLEMS ON BURNING.
Exp.
A small
and note
trough until the levels inside and outside the jar are the
same, and make a rough estimate of the diminution in
the volume of the air.
Wait until the solid white oxide
25
j.-
'
(Nitrogen).
up the apparatus as shown in Fig. 26. One of the two
which are of equal size, is filled with water. The two aspirators
are connected by their shorter tubes to a piece of combustion tubing loosely
Exp.
Set
aspirators,
B. E. SC.
34
Experimental Chemistry
[CH.
vn
a few minutes the phosphorus goes out and will not burn again even if heat
Stop the siphoning when one of the aspirators is full of water.
applied.
It will then be seen that the other aspirator is no longer empty but contains
is
Phosphorus
Fig. 26.
its volume of water which represents the volume of active air
absorbed by the phosphorus, the remaining $ being nitrogen. Close the taps
and keep this nitrogen for further experiments. Weigh the central tube and
notice the increase, in weight.
N.B. Copper turnings heated to redness may be substituted for phos-
about 4 of
41.
To compare
is slower.
Exp.
fill
two gas
jar
35
Problems on Burning
40-42]
Now
1
Fig. 27.
Take another gas cylinder full of air; moisten the sides and sprinkle
(6)
iron filings inside as before.
Invert this by the side of the jar containing
iron in nitrogen.
Attach two pieces of yellow phosphorus to two pieces of wire [Danger.
under water] and put the phosphorus into (c) a jar of nitrogen, (d) a jar
(2)
Do
this
of air.
No change
is
42.
The
air loses as
34)
is
much
The
Exp. To show that the total weight of air and phosphorus remains unchanged in burning. Cut a small piece of yellow phosphorus. [Danger. Cut it
32
36
Experimental Chemistry
[CH.
vn
catches
ment.
'
level the water,' and insert the cork.
Measurement will show
water,
that again th of the air has been absorbed by the phosphorus to form
oxide of phosphorus.
43.
44.
The
is
a gain in weight.
air.
45.
To
Problems on Burning
42-45]
37
To prepare nitrogen
several others.
15 grams of
ammonium
warming the mixture in the flask gently, pure nitrogen is set free
and may be collected in cylinders by the pneumatic trough
method.
Caustic
Soda
Quick Lime- ^
Wire Gauze
four-fifths of its
2.
much
How
that,
when a substance
38
Experimental Chemistry
3.
Some moist
[CH.
vn
and some
more
in a jar of air.
After being left for some days a lighted taper is
introduced into each jar. State and explain what happens, and whether
How
is
Nitrogen obtained?
How
its
What
properties ?
(c. J.)
could you prove that only one of the two chief constituents of
the atmosphere
is
CHAPTER
VIII
OXYGEN.
46. We have found that Oxygen may be obtained indirectly
from the air by means of the metals mercury and lead. We
must consider a more convenient method of preparing the gas
in the laboratory.
*Exp. ii.
heating one
of oxygen obtained
chlorate.
Weigh
11).
rately
'by
the
chlorate
difference.'
accu-
Get ready
an aspirator
(
8) and connect the
test tube to it (Fig. 31).
Heat the
and afterwards
gently
strongly until no more oxygen is
set free.
Allow the tube to cool.
chlorate
placed,
Fig- 31.
by
40
Experimental Chemistry
[en.
vm
of
Weight
=22-84 gram
=23-56 gram
0-72
=216
Vol. of water displaced = vol. of oxygen
Pressure of atmosphere = 740
Temperature = 15 C.
gram
c.c.
mm.
= 12 mm.
Pressure of aqueous vapour at 15 C.
Weight of tube + potassium chloride (after heating) = 23-28 gram
= 0-28 gram
/.weight of oxygen displaced
Volume
9)
760 x 288
For the answers required, divide the last two results by 0'72.
47.
Preparation of Oxygen.
Considerable heat
is
*Exp.
i.
test tube.
Heat
slowly so as to melt the potassium chlorate without decomposing it. Test that
no oxygen is given off. Now add a few grains of black oxide of manganese ;
oxygen
is
liberated rapidly.
by
and
oxygen
32
1
+ oxygen.
These substances, although they may change during the process, are
found to be unaltered after the reaction is completed. They are called
catalytic agents or catalysts, i.e. 'breakers down.'
41
Oxygen
46-48]
constant
stream of
In Chap,
xii
we
we
shall learn
gills
or other
how
to collect
48.
Combustions in Oxygen.
Indicators.
In order
to study
what
is
elements
named
litmus
(a solution
is
completed,
neutral
**
42
Experimental Chemistry
[OH.
vm
50.
43
Oxygen
49-51]
We
Metals.
line.
it
The
solutions of metallic oxides are alkaThe oxide of iron does not dissolve in water and therefore
lime-water.
derivation
it
means
was an
We
that there are some acids which contain no oxygen and also that
oxides of metals, far from being acid-forming, can remove the
acid properties from acids, whether they are soluble in water or
not.
51.
Common
thoroughly with
Oxides.
many
often recurring in
58 and
of the
60.)
if
possible.
We
should examine
44
Experimental Chemistry
Table of
Non-metallic
Elements
Common
Oxides.
[OH.
vin
Table of
Metallic
Elements
45
Oxygen
51]
Common
Oxides
(cont.).
46
Experimental Chemistry
[OH.
vm
6.
What is an oxide? Describe the appearance of the oxides of
magnesium, phosphorus, sulphur, calcium.
7.
What
is
(i)
(ii)
c.c.
way do
litre of
(a)
the metallic
46).
hydrogen
(S.T.P.)
density of air =
1,
CHAPTER
ACIDS
52.
IX.
We
We
The three
is
Acids.'
48
Experimental Chemistry
Sulphuric Acid 1
53.
[CH. ix
*Exp. ii. Make a thick syrup with a few lumps of sugar and a little
water at the bottom of a large beaker. Pour a few c.c. of cone, sulphuric
acid on the syrup and make a note of what you observe.
The old-fashioned
blacking is made in this way, chalk being added to remove excess of acid.
'
*Exp. iii. Write your name on a piece of paper, with the dilute
sulphuric acid prepared in Exp. i, using a glass rod dipped in the solution.
Gently evaporate off the water by warming the paper over the flame. Notice
the charring of the paper and compare the result with Exp. ii, where carbon
was
also liberated.
iv.
Pour dilute sulphuric acid on the metals zinc, iron and
copper (in test tubes). Notice that zinc and iron dissolve and that an
inflammable gas (hydrogen] is set free. Copper is not dissolved.
*Exp.
Exp.
v.
Warm, very carefully,
sulphuric acid with the three
metals named in Exp. iv, and notice
Carbon
strong
^a
dride) is liberated.
Fig. 34.
54.
Nitric Acid
is
*Exp.
i.
crystals to the
1
Danger.
53-55]
49
in Fig. 35.
Fig. 35.
the fumes change from red to white. Eemove the flask containing nitric
acid, allow the retort to cool, then taking it by the stem carefully empty the
Notice
liquid remaining in the retort into a porcelain evaporating dish.
Wash
these
away
[Danger.]
substances.
*Exp. ii. Pour a little nitric acid on copper in a test tube. Notice that
copper dissolves, that reddish fumes are set free, and that a blue solution is
formed. Try other metals such as iron, zinc, tin and lead, and record what
you observe in your note-book.
*Exp.
iii.
Add
washing soda,
(b)
chalk,
Notice that an
*Exp.
ii.
acid^gas
*Exp.
effect of
iii.
is liberated
Exp.
As in the case
iv,
solution.
and copper.
Compare the
53.
of sulphuric acid
B. E. SO.
from the
zinc, iron
(a)
and
washing soda,
(6)
chalk.
50
[CH. ix
Experimental Chemistry
General properties of Acids.
(a)
(b)
(c)
Later we
salt is
formed
(cf.
Exp.
31).
ii,
"What
tests
What
acid on copper
4.
What
and
dilute sulphuric
is
is
How may
CHAPTER
X.
soluble
members
of a larger class
metallic oxides are soft or soapy to the touch, turn red litmus
blue and destroy acids. They are called alkalies and are said
Because they are combined with
to be alkaline in reaction.
water (Greek
'hudor')
hydroxides.
Sodium
hydrate are caustic, i.e. they burn or corrode the skin and flesh,
consequently they are frequently called caustic soda and caustic
potash respectively.
Another common
of the gas
57.
ammonia
alkali,
its
ammonium
hydrate,
is
a solution
in water.
Preparation of Ammonia.
upward
delivery tube
42
52
Experimental Chemistry
[en.
Warm the mixture gently, keeping the flame moving, and collect
(Fig. 36).
two cylinders of the gas by 'upward displacement.'
Plunge one cylinder mouth downwards into a basin of water. The
(1)
C. one volume of water
water rushes up and nearly fills the jar. At
dissolves 1100 volumes of ammonia.
Ammonia
Fig. 37.
Fig. 86.
Turn the delivery tube so that it points downwards and fit a funnel
Pass ammonia into water, keeping the funnel's mouth just below the
surface of the water (Fig. 37).
The solution obtained is strongly alkaline
and is lighter than water. The specific gravity of a saturated solution, of
(3)
to
it.
ammonia
is -880.
sal
58.
lies.
We have
quantity of acid at a certain strength will always dissolve the same weight of metal ( 31,
It is probable therefore that acids
Exp. ii).
*Bxp.
Fill
is so.
two burettes
(Fig.
38),
57-59]
53
dilute caustic soda solution (sodium hydrate), the other with dilute hydrochloric acid (spirits of salt).
Adjust the levels to zero in your burettes.
Run about
with acid,
which
is
i.e.
54
Experimental Chemistry
[CH.
Metallic
60.
dissolve in acids
oxides,
and form
insoluble
salts.
in
We
water,
may
and whether a
salt is
formed in
solution.
is
*Exp.
ii.
*Exp. iii. Heat strongly dry crystals of copper sulphate in a hard glass
Black oxide of copper is recovered and sulphurous fumes are given off.
*Exp. iv. Heat dry crystals of lead nitrate. Litharge is recovered and
nitrous fumes as well as oxygen are liberated.
tube.
salt to
The
soluble bases
Water of Crystallization
59-61]
55
Bases, therefore, are metallic oxides, whether soluble or insoluble in water, which combine with acids to form salts.
Copper oxide then dissolved in acids will produce copper
salts;
dissolved in
salts.
nitrates,
Hydrochloric acid
chlorides.
61.
sulphate crystals
was given
crystalline
off.
Exp.
60,
Water
iii)
we probably
heated copper
composition of
anhydrous
(= without water)
salt.
*Bxp.
many
salts.
i.
(c)
test tubes,
(a)
copper
washing soda.
QUESTIONS ON CHAPTER X.
1.
What
are the
characteristics of alkalies?
2.
How
(a) is lighter
than
air, (b) is
Describe
How
how
mentioned in
56.
56
Experimental Chemistry
Describe the substances obtained
5.
What
6.
7.
may
litharge.
(o. J.)
how a
jar of dry
'
Weight
(a) dilute
upon
acid?
nature of the body formed,
nitric
when
[CH.
of crucible
ammonia
gas
(A)
(B)
Barium
Copper
Chloride
Sulphate
empty
22
22-5
25-6
22-425 gm.
24-2
gm.
21-8 gm.
CHAPTER XL
HYDROGEN AND WATER.
62.
describing
by the action
of
We
acids on metals.
shall
Air' (Hydrogen)
find later that
i.
in
granulated zinc.
down
on
to
first cylinder
that hydrogen
the light
extinguished.
Fig. 41.
58
Experimental Chemistry
Exp.
Using a second
[CH. xi
Hydrogen
is
used to
fill
balloons
and
dirigibles.
Water
is
air.
On
formed.
*Exp. ii. First remove water vapour from the hydrogen by inserting
a drying tube containing calcium chloride 1 or pumice stone saturated with
1
Light the dry hydrogen issuing from the delivery
strong sulphuric acid
tube and let the flame impinge against the side of a flask, kept cool by a
stream of water as in Fig. 43. Very slowly a liquid condenses. Bear in
.
Fig. 43.
1
62-64]
59
mind
gram
boils at 100
and that
it
64.
leaves nothing
on evaporation
it is
tasteless
and
is
metallic oxides.
Reduction.
(See also
colourless
water.
in
some
Chapter xvi.)
/VOf^
Lead oxide
-* Hydrogen
drying"
tube
Water condensed
Fig. 44.
'
In each case the metallic oxide is turned or led back again (reduced) to
The lead may be recognized by its malleability, its softness (it marks
metal.
paper) and its readiness to melt and tarnish on being heated in air. The
powdery iron is attracted by a magnet and dissolves in sulphuric acid with
'
We may
hydrogen and
oxygen,
(2)
60
[CH. xi
Experimental Chemistry
65.
*Exp. Again use the same flask and drying tube for preparing hydrogen
but insert a second drying tube to remove any traces of moisture. Black
oxide of copper carefully dried is placed in a porcelain 'boat and the weight
obtained [ = (say) 8-12 grams]. The 'boat' and oxide A are then placed in
a piece of hard glass tubing drawn out so as to fit into a small flask or bulb
with a calcium chloride tube (see Fig. 45) which prevents loss
(B) connected
'
of water vapour.
Dry Hydrogen
Fig. 45.
flask, cork and calcinm chloride tube B are weighed together
= (say) 49-52 grams). The hard-glass tube is now fitted to the small flask
[
and dry hydrogen is then passed slowly through the apparatus. Begin
The small
heating the copper oxide near the bend so that all moisture is carried over
into B. After reduction seems complete, stop heating but continue to pass
hydrogen until the copper is cold. Then detach the hydrogen generating
flask
of dry air from an aspirator. Weigh the boat and reduced copper A [
(say)
6'92 grams]. Weigh the flask and U tube B again [ = (say) 50 '87 grams].
'
The weight
grams
of water
= 1-20 grams
of
oxygen
lost
by
4 = 8'12-6-92
of oxygen,
*.
1'35
66.
1-20
~~
of hydrogen,
~~
0-15
The metals
65-66]
61
when
an alkaline
Exp.
is
soluble in water
i.
and therefore
its
solution gives
solution.
of
Magnesium
*Exp.
iv.
the
fire
is
as
1
The
safest
and most
striking
method
of show-
hydroxide
is
Fig. 47.
62
Experimental Chemistry
[OH. xi
Hydrogen
burning
A reversible change.
Fig. 48.
Iron heated
to redness
in steam provided that the hydrogen set free is swept away by the current of
Otherwise the reaction tries to reverse itself, for we have seen
steam.
already that hydrogen reduces oxide of iron back to iron with the formation
of water at the same time.
Exp. v. Pass a current of steam through a red-hot iron tube containing iron nails and collect the liberated hydrogen in a pneumatic trough.
When sufficient hydrogen has been collected, reverse the process
(Fig. 49.)
Fig. 49.
by passing dry hydrogen through the heated tube and condense the steam
that is formed in a cooled U tube (Fig. 50).
heated
reduced to
IRON
below
Hydroqer
Fig. 50.
66-68]
may
63
+ iron
~^_
Electrolysis of
67.
Water
The
passes
split up.
is
easily
The reason
brought about.
circuit
Now
sity of
in the proportion 1 to 8
68.
(cf.
65).
Synthesis of Water.
together.'
hydrogen and oxygen are 'placed together' in
a strong vessel in the proportions of 2 to 1 by volume no change
If
[CH. xi
Experimental Chemistry
Then
occurs until a spark or flame is brought into the mixture.
a violent explosion takes place and the two gases combine with
The Hon. Henry Cavendish, the
great heat to form water.
discoverer of 'inflammable
air,'
He made
use
with
with
sufficient
hydrogen to combine
all
volume
of
taking part in
the
explosions
is
52
glass,
limb.
The
level is
two
end
wires,
and
of the
68-70]
65
If the conditions of
(gaseous water) is formed after explosion.
temperature and pressure are unaltered during the experiment,
it is found that two volumes of hydrogen combine with one volume
of oxygen to form two volumes of steam.
'
69.
us
still
Sufficient experiments
Water
(a)
is
[See
24.]
Hydrogen
(b)
metal.
is
(c)
chosen
70.
an
(a)
by dissolving a metal
the only
in the acid,
(b)
difference
first
case hydrogen is
however
is
66
[OH. xi
Experimental Chemistry
current of an acid gas, we can pass it over a dry metallic oxide and
show that water is formed as well as a salt. [93 (4).]
QUESTIONS ON CHAPTER
1.
XL
Describe
apparatus.
a sketch of
2.
How would you prove that when hydrogen is passed over heated iron
oxide or lead oxide metallic iron or lead is obtained and water formed ?
how
3.
Describe fully
4.
a 'reversible change'?
5.
6.
What
be synthesised.
and
what
State
found.
calcium on water
7.
may
may be
Give an example.
is
meant by
'electrolysis'
and describe in
detail
the
electrolysis of water.
8.
If 15 c.c. of
in a eudiometer
9.
gen
If 9
gm.
hydrogen and 10
how much
c.c. of
of water are
How would
hydrogen
11.
is
Name
CHAPTER
XII.
71.
Carbon
first
terms
chemical
dioxide.
is
stances.
Carbon
gas was
first
known
Carbonates.
Calcium Oxide
(quicklime)
the metal
lime water
Calcium oxide, a metallic oxide,
is a base and will neutralize acids to form salts, as we have seen
above, where, with the weak carbonic acid it yielded calcium
we know
to be a
weak
alkali.
carbonate.
52
68
Experimental Chemistry
Calcium Carbonate
in great abundance
[OH.
XH
and in many
varieties.
Chalk, limestone,
marble, calc-spar, sea-shells, coral, egg-shells, all are more or
The chalk cliffs and hills of the
less pure calcium carbonate.
calcium carbonate, a
it
into its
(a)
Will heat cause the basic oxide and acid oxide to part
(b)
company
72.
*?
Lime
used in large
quantities for
and
mortar.
cement
making
In many parts
'lime burning'
of
is
the
country
carried on
in
coal
red-hot.
nearly
The
half
its
limestone
weight
loses
and
white substance called quicklime (calcium oxide) remains. Quicklime combines with nearly one-third of its weight of water in
being converted to slaked lime.
71-72]
Add
Gas
69
there
is
Exp.
ii.
of an aspirator.
gas
is
liberated
lime water.
Calc Spar
Lime Water
Fig. 54.
sufficient
been
(synthesis) of its
70
Experimental Chemistry
73.
is
composed
xn
[CH.
of a base
The
and a weak
acid oxide suggests that probably one of the stronger acids will
decompose it by combining with the base to form a salt, at the
is
set free.
We
have already found that mineral acids cause an effervescence of gas when poured on the carbonates of soda, potash and
lime (53). Let us now proceed to find whether the various forms of
calcium carbonate lose the same percentage by weight (44 / o see
72, Exp. i) when an acid is added as they did when strongly
,
heated.
74.
To
measure
to calcium carbonate.
calc-spar
weighed
powdered
fitted
up as in Fig.
about 20
c.c.
acid and an
55.
The
flask contains
of concentrated hydrochloric
equal volume of water. The
a stopper.
The larger tube is packed
with cotton wool or calcium chloride.
The apparatus shown in Fig. 55 is carefully
1
weighed and then fitted to the aspirator
.
The
flask
is
now
tilted
73-74]
71
We
composition.
is
all
by weight
of calcium oxide
of 'calc-spar
of
15
C.
/.
at
12
mm.
S.T.P.
240
9)
.'.
222
c.c.
1000
0-44 x 1000
c.c.
gram
= 1-98 gram.
Density of a gas
Wt. of a given volume of gas
_
Wt. of same volume of hydrogen (under same
.".
Wt.
1-98
0-09
of
1000
gram
gram
c.c.
hydrogen
S.T.P.
S.T.P
conditions)'
72
Experimental Chemistry
75.
Preparation
Acid
of Carbonic
[OH.
Gas
xn
and
Calcium Chloride.
*Exp. i. Fit up the same apparatus as was used in the preparation of
hydrogen. Small lumps of marble are placed in the flask and are covered
Pour a little strong hydrochloric acid down the funnel.
with water.
Collect four cylinders full of the carbon dioxide set free then pass the gas
through about 60 c.c. of lime water in a boiling tube. Notice that a white
Allow the gas to
precipitate (calcium carbonate) is formed (cf. 72, Exp. ii).
bubble through the milky liquid for several minutes.
;
*Exp.
the taper
ii.
is
*Exp.
extinguished.
iii.
ment
*Exp.
iv.
Plunge a piece of burning magnesium
ribbon into a jar of the gas *. Notice that magnesium
oxide is formed and that black specks of carbon are
'
~".'"
*Exp.
v.
Pour
76.
has
some minutes and probably the precipitate of calcium carbonate has dissolved. The clear solution is called Temporarily
Hard Water and contains a substance, calcium bi-carbonate,
for
This
result
is
better
magnesium powder
larger
Hardness of Water
75-77]
73
which will not lather with soap. Divide the 60 c.c. of hard
water into three equal parts in separate small flasks a, b and c.
*Exp.
i.
until there is
To the
(a)
first
formed.
(b)
Small Flask
-i
-I
(Fig. 57).
* lg< 57'
Set up a burette filled with
in
a solution of Castille soap
methylated spirit and run the soap solution
into the three flasks containing respectively (a) hard water to which lime
*Exp.
ii.
water has been added ; (6) hard water, boiled ; (c) the temporarily hard water,
untouched. Kecord your readings when you have added sufficient soap solution to produce, after shaking well, a lather covering the surface of the
It will be found that much less soap is required to
liquid for one minute.
We
(a)
by
first
and second
flasks
adding
lime,
(b)
by
Hence
boiling.
is
softened
the
term
77.
by
boiling.
is
not softened by
Calcium bi-carbonate
is
i.
The solution in the generating flask ( 75) contains calcium
To a few drops of this solution add washing soda (sodium carbonate)
74
Experimental Chemistry
solution.
and
xn
[CH.
A white
test (with
1
Filter
precipitate of solid calcium carbonate is formed .
whether
the
filtrate
is
soft.'
Pour
few drops
a
soap solution)
'
filter
it is
a carbonate.
*Exp.
ii.
78.
common
Double Decomposition.
in chemistry.
Thus in Exp. i
Calcium Chloride +}
(Soluble)
Sodium Chloride +
((Soluble)
^
Sodium Carbonate
interact.
precipitated.
In Exp. ii.
(Soluble) Calcium Chloride +]
L
Sodium Stearate
yield
J
,
Sodium Chloride +
[(Soluble)
S
((Insoluble) Calcium Stearate
precipitated.
79.
Calcium Chloride
obtained
from
the
solution
of
Marble in Hydrochloric Acid. When the liquid in the generating flask ( 75) no longer causes an effervescence with marble, filter
about 15 c.c. into a porcelain dish and evaporate to dry ness.
The white solid is calcium chloride. It is chiefly used as a
drying reagent.
Weigh the dish containing dry calcium chloride and put it aside
a few hours and weigh again. If the air is very damp the calcium
chloride may have absorbed so much moisture as to be in a state of solution.
*Bxp.
for
80.
way
is
said to deliquesce.
The
qualita-
and
1
synthesis.
is
the
Natural Waters
77-81]
(i)
filings of
75
the metallic element
Ca/c/w/j.
Lime Water
Fig. 59.
(iii)
The
(1)
(2)
(3)
81.
A.
reactions are
= calcium
Natural Waters.
Rain Water is the purest
it is
76
Experimental Chemistry
[OH.
XH
solution the gases present in the atmosphere, viz. oxygen, nitrogen, carbonic acid gas.
is
solids in solution
in suspension
brought
mud, con-
remains.
E.
and
down
is
The
going
on
is
Atlantic.
Baltic
magnesium
Natural Waters
81-82]
77
and calcium.
is
82.
*Exp.
i.
cork,
with one hole, is fitted to a long delivery tube so that the end of the tube
is flush with the cork.
The tube is now filled with water and the cork
the apparatus is then connected to a pneumatic
inserted in the flask
trough (Fig. 60). Boil the water and collect any gases driven off in a
:
narrow tube.
Fig. 60.
To analyse
Exp.
(1) push up into the tube a
small stick of yellow phosphorus attached to a wire.
[Danger.] Oxygen
will be slowly absorbed.
(2) Keplace the phosphorus with a stick of caustic
The remaining gas will be
soda, carbonic acid gas will be absorbed.
(3)
ii.
nitrogen.
An
gas, 50
nitrogen.
oxygen, 25
carbonic acid
is
dioxide in chalk
3.
0-74 gram of chalk on being heated yielded -415 gm. of quicklime.
Calculate percentage composition of chalk.
4.
determined
5.
in 100
gm.
of calc-spar be
78
Experimental Chemistry
carbon dioxide
If the density of
6.
is
22 what
is
[OH.
the weight of 5
xn
litres
of
the gas ?
How
which
contains?
it
8.
When carbon dioxide is passed into lime water a milky precipitate ia
obtained which disappears as more gas passes in. On boiling the clear
How do you account for this ?
solution the precipitate, reappears.
How
9.
What
10.
How may
is
it
be
softened?
To what
11.
is
cause
soap to be wasted?
12.
How may
13.
the
hardness
'
'
of water be determined ?
when carbon
dioxide
is
calcium.
How would
14.
water?
15.
Water
16.
From
turbid
of
mean ?
(o. j.)
What
when
boiled for
some time ?
(o. j.
From
is stated to
litre
18.
Separate quantities of 20 c.c. of distilled water, tap-water, rainwater and distilled water through which carbon dioxide has been bubbled for
some time, have soap solution added till a lather is obtained. Should the
amount of soap solution required be the same in each case? Give reasons.
CHAPTER
XIII.
*Exp. i. Heat about two grams of sugar in a test tube keeping the tube
nearly horizontal so that the water liberated does not run down on the hot
glass. Notice that an inflammable gas is given off as well as steam and that
finally a black substance, which is almost pure carbon, remains.
*Exp. ii. Transfer the carbon to a piece of hard glass tubing connected
with a wash bottle containing lime water, and leading to an aspirator (see
Burn the carbon in a current of air. Notice that chalk (calcium
Fig. 54).
carbonate) is precipitated in the lime water and that finally no residue is left.
Evidently the carbon burns in oxygen to form carbonic acid gas (carbon
See Chap. xn. )
(
dioxide) .
Fig. 61.
oxygen, free
therefore,
80
Experimental Chemistry
[OH.
xm
black-lead) and
burn completely in oxygen and form carbon
We therefore
dioxide, in the proportions obtained in Exp. iii.
must conclude that these substances are different forms of the
same element carbon. Such forms of an element are said to be
allotropic, i.e. the same from a chemical standpoint but differing
in physical properties.
Sulphur and phosphorus also exhibit
diamond
all
1
allotropic forms .
84.
is
also
the
called
Law
of Constant or Definite
Proportions.
Carbonic Oxide.
85.
oxide
is
Carbon
1
di- oxide
Fig. 62.
Carbonic Oxide
83-87]
81
and
is
oxidized to carbon
dioxide which
may
iii,
83.)
86.
The Law
of Multiple Proportions.
(See
Compare
87.
8:4 = 2:1).
hot Fire.
We have noticed
that on
Air
82
Experimental Chemistry
[CH.
xm
At CC
dioxide.
85).
88.
If
we
*Exp.
ii.
Breathe
is
*Exp.
iv.
To
stances.
test
87-89]
83
vapours which
Copper Oxide
Lime Water
Fig. 65.
naphtJi alent , starch, toasted bread,
and hydrogen.
Nearly
all
The blood
oxygen to
human being
In a healthy
is produced.
the normal temperature is
When
98*4 F.
rapidly, or
all
lions,
tigers,
eagles, vultures
and
life.
The bullock
jvig.
66.
The
grass
contains carbon, the bullock's flesh contains carbon,
and both
62
84
tiger
The
Experimental Chemistry
[CH.
xni
and bullock breathe out carbonic acid gas into the air.
air, for we can grow
is
Fig. 67.
its
89]
85
until
sufficient gas is
In Fig. 66 green water
obtained to show the test for oxygen.
weeds are put into a large flask filled with 'soda' water and
Pure country
is
shown graphically
in Fig. 67.
What
1.
do you mean by
'
Mention any
state for
2.
4.
5.
6.
By what means
8.
State
way do
9.
what
is
'
'
What
portions of
its
it
absorb
them?
(o. J.)
11.
could
How
you prove
oxygen? (o. j.)
CHAPTEE
SALT,
Rock
90.
XIV.
of the world
where
the salt
is
down one
of
which water
in
solubility
is
given in
28.
(1)
(2)
Preparation.
(3)
(4)
(5)
sodium oxide
sodium hydroxide
sodium carbonate
preparation of
salts.
93).
(93).
(59).
(73).
'
neutral,' the
Hydrochloric Acid
90-92]
solution
87
suitable indicator
91.
58 and
and
59).
C.
c.c.
Fig. 68.
a cylinder of the gas by downward displacement (Density = 18) and show that a taper will not burn iu
The reaction
is
Sodium Chloride +
Sodium Sulphate +
Hydrogen Sulphate]
Hydrogen chloride
92.
To show
it.
Gas.
*Exp. i. Fill a dry round-bottomed flask with the gas by downward
displacement. Fit a rubber cork, through which a tube drawn out to a jet
passes into the flask and invert the tube in a beaker of water coloured blue
with litmus. Cool the flask by pouring a little ether over it. The water runs
'
'
up the tube and dissolves the hydrochloric acid gas, thus producing a partial
vacuum. Record all you observe and give your reasons for what takes place.
The solubility may be similarly shown by filling a tube with the gas,
covering the end with the thumb and inverting it in water. On removing
the
thumb water
fills
the tube.
88
Experimental Chemistry
[OH.
xiv
*Exp. ii. Make a solution of the gas by passing it into water through a
wide funnel just dipping below the surface of the water (Fig.
Weigh
70).
Fig. 69.
Fig. 70.
The
density of concentrated
back to
refer
Tests.
recognized
Hydrochloric acid
is
55.
by the following
(1)
(2)
(3)
(4)
ammonia gas
57),
(solid)
with
Hydrochloric Acid
92-93]
(5)
precipitate,
which turns
a white
curdy
violet in sunlight,
93.
By synthesis.
1.
volume
If
of chlorine (prepared
Heated
Water
Metallic Oxide
condensed
converted to
Chloride
Excess of
Hyd. Chi
absorbed
in ff&ter
Fig. 71.
2.
If a jet of hydrogen is burned in chlorine gas acid fumes
hydrogen chloride ara produced ( 95).
3.
By analysis. If dry hydrochloric acid gas is passed
over heated sodium, calcium, zinc or magnesium, hydrogen gas is
liberated and the chloride of the metal is formed.
Exp.
4.
warmed
If dry
is
90
Experimental Chemistry
when an
is
-.</.,
Zinc Oxide +
Zinc Chloride +
Hydrogen Chloride
a
xiv
also produced,
5.
[CH.
salt)
and water
Fig. 72.
Hydrogen Chloride,
94.
Water + Chlorine +
still
farther oxidized or an
91
Chlorine
93-95]
The
metallic peroxide on hydrogen chloride (hydrochloric acid).
*
peroxide has been written oxide of the metallic oxide to indicate
that there is more oxygen available than is necessary to form a
salt and water according to the usual action of an acid on a base.
'
is set free
(Deacon's
Process).
Chlorine.
in
the laboratory
strong hydrochloric acid slowly from a tapfunnel on to the strong oxidizing agent
potassium permanganate
(crystals).
(Sec
Fig. 17.)
Pyrolusite +
Hydrochloric
Chtorino
Acid
many
elements; bleaches.
95.
jars of chlorine
Having collected
and having covered them with greased plates,
92
Experimental Chemistry
Put
(a)
piece
xiv
Observations.
Experiment.
1.
[OH.
of
dried
a dried en-
(a)
little
Very
change
dry
Next add a
(6)
little
water and
shake.
(&)
The
mark
post-
is not.
free carbon
and
Drop
powdered
antimony
is
chloride of
formed.
antimony
3.
Pour a few drops of turpentine
(containing carbon and hydrogen) on
a filter paper, previously warmed,
and drop
4.
it
Burn
taining
are formed
and carbon
is set free.
Carbon liberated,
ride (acid) formed.
hydrogen chlo-
chlorine.
5.
Burn a
chlorine.
jet
of
hydrogen in
(Fig. 74.)
Hydrochloric
formed.
Bleaching Powder.
chlorine
is
for
bleaching.
acid
The
If
fumes
are
chief use of
chlorine
is
to
Jet of Hydrogen or
Coat Gas burning m
Chlorine
Fig. 74.
all acid.
95]
93
1.
2.
salt
By what
3.
tests
is
6.
How may
6.
chlorine be prepared?
How
8.
Give an instance of
when dry
this.
is
extremely soluble
in water?
9.
state
on what
their
action depends.
10.
What
when a
a well-water in a limestone
(a)
added
(6)
(c)
to
district,
dioxide?
(o. J.)
CHAPTER
XV.
96.
of
density
is
bisulphide
It
is
soluble in carbon
25).
We have already
found that
a
yellow liquid which
18), forming
very thick treacle at about 180 C. On
it
reaches the
We
noticed
obtained at
120 C.
we pour
hours.
If
tropic forms
(see
83).
Sulphur and
96-97]
Metallic Sulphides.
burn in sulphur vapour
its
Oxides
95
We
97.
Sulphur dioxide.
We are well
ing,
formed.
anhydride.
current of
It
This gas
also
is
is sulphur dioxide
or sulphurous
produced when iron pyrites is roasted in a
air.
zinc
copper,
sulphuric acid
53).
Preparation
of Sulphur
dioxide.
Exp. The experiment should be
per-
tube,
Pour about 40
acid
c.c.
of strong sulphuric
gently.
by 'down-
Fig. 75.
70).
Exp.
is
extinguished.
The gas
dissolves,
forming an acid.
96
Experimental Chemistry
Bxp.
Show
iii.
[CH.
xv
Bxp.
iv.
find
(a)
(&)
solution
repeat
(c)
(6),
still
acid?
1); at 15
Its density
32 (hy0. one vol. of water dissolves about 50 vols.
If a
Composition.
in a current of
98.
is
solid,
crystallizing out
(Oil
of
Vitriol)
described in
52.
or Hydrogen
It
was
first
ob-
*Exp.
i.
Heat
crystallization has
finely
Sulphuric Acid
97-99]
97
without water) residue to a test tube and heat until a red powder, a red
oxide of iron (jeweller's rouge), is obtained. At the same time notice that
strongly acid fumes, which
may be
off.
named
Sulphur
substances.
Sulphur
Waste
dioxide
Copper +
Steel Cylinder
Containing Oxygen
under pressure
Nitric
Add
Sulphuric
Acid formed
Pig. 76.
pass (1) oxygen and sulphur dioxide produced by burning sulphur in excess of
oxygen, (2) steam, (3) the nitric fumes formed by pouring nitric acid on copper.
Sulphuric acid condenses in the bolt-head, which corresponds to the 'leaden
chamber,' and any uncombined gases are carried away to the draught-place.
Cylinder of
Liquid
Sulphur dioxide
Oxygen
Mercury
safety
v&lve.
Sulphuric
Anhydride
Fig. 77.
Exp.
iii.
process of preparing
is
as follows:
98
Experimental Chemistry
[CH.
xv
containing strong sulphuric acid to dry the gases, sulphur dioxide (from a
siphon) and oxygen (from a steel cylinder) are passed in the proportions
of 2 to 1 by volume.
The mixed gases are conducted over warmed spongy
platinum and combine to form the anhydride (lit. without water ') of sulphuric acid. Silky crystals of the anhydride may be obtained by condensing
the fumes in an ice-cooled tube or sulphuric acid may be formed directly
by passing the fumes into water through a wide funnel.
'
100.
is
barium sulphate.
Boil the liquid, in which the presence of sulphuric acid is suspected, with hydrochloric acid, filter if necessary, and add a solution of a
barium salt. A white precipitate indicates the presence of barium sulphate
*Exp.
and therefore
Practical Exercise.
Show
bichromate,
101.
(c)
it
with
(a)
is
converted to
(6)
potassium
potassium permanganate.
By double
= Iron
*Exp.
hydrogen
is
obvious.
The presence
of the gas
may
Hydrogen Sulphide
99-102]
that
it
blackens
filter
salt
the
alkalies.
of
the gas.
The
Liquid acting on
100
Experimental Chemistry
[CH.
xv
the tube and forces the acid out of the hole at the bottom, thus
stopping the production of gas.
Fig. 79.
101
Hydrogen Sulphide
102]
Show
that the gas burns, forming sulphur dioxide and water. If the
is limited by surrounding the flame with a gas cylinder, sulphur
supply of air
is set free.
Show that the gas is slightly acid and that it combines with ammonia,
forming a salt (ammonium sulphide) in solution.
Pass the gas into separate solutions of (a) copper sulphate, (b) ferrous
A precipitate
sulphate, to which a little hydrochloric acid has been added.
of copper sulphide is obtained in (a) but no reaction is visible in (b). Now
make
is
(b)
alkaline
by adding ammonia.
seen.
(See
104.)
XV.
QUESTIONS ON CHAPTER
By what
1.
purposes
is
For what
sulphur used?
2.
Describe
3.
What
all
when sulphur
is
State
heated.
be
4.
How
5.
how
copper pyrites.
How may
the gas
may
place when
dioxide ? (o.
J.)
7.
8.
How may
identify
9.
when green
the
vitriol is heated.
By what means
could you
it ?
sulphuric acid.
10.
If
filings, nitric
acid
Sketch the
102
Experimental Chemistry
[CH.
xv
11.
of sulphuretted hydrogen.
similar kind of apparatus.
12.
quantities?
13.
is
it
used in large
(o. j.)
What
is
burnt
in air?
14.
Four gas jars are supposed to contain sulphuretted hydrogen.
Describe four experiments which could be made with them to prove that
they do actually contain it. (o. J.)
15.
another ?
(a)
17.
Suggest some means for proving that sulphuretted hydrogen conand (b) sulphur but nothing else.
dioxide ?
By what
tests
(a)
sulphuric acid,
(b)
sulphur
CHAPTER
XVI.
If
we
refer to Ch. xi
we
shall
On
iron.
reducing agent,
it
'
Hydrogen + oxide
Here oxide
of iron
= oxide
(water)
of
hydrogen
-f
iron.
of
iron
is
reduced, i.e.
the reducing agent.
is
An
oxidizing agent
is
oxygen
is
liberated.
A reducing
agent 1
it is
We
sufficient to take
them
at present
104
Experimental Chemistry
[CH.
xvi
104:.
we
85.)
Oxidizing agents.
the metals, potassium nitrate, potassium chlorate, potassium bichromate, sodium permanganate (Condy's fluid) and chlorine are
common
oxidizers.
*Exp. i. Drop a piece of red-hot charcoal into a few drops of nitric acid
in a test tube, keeping your hands away from the tube.
The carbon is
oxidized to carbon dioxide.
*Exp.
ii.
*Exp. iii. Try which of the above-named oxidizing agents will convert
sulphurous acid to sulphuric acid or sodium sulphite to sodium sulphate
(
100).
Oxidizing agents are often good disinfectants and deodorizers. They convert the carbon and hydrogen of decaying
animal and vegetable matter into carbon dioxide and water;
103-106]
105.
105
and
the
Reducing agents
must be
them
to metal, at the
Carbon alone
Sulphur
and
Sulphurous
agents
(
dioxide
to
acid
act
form
as
reducing
sulphuric
acid.
100.)
*Exp.
the oxide
ii.
is
*Exp.
iii.
106.
shown
(b)
We
have already
To
liberate
Exp.
of nitric
liberated.
oxygen from
nitric acid.
i.
Heat a
little
106
Experimental Chemistry
[CH.
xvi
it is
oxygen.
Fig. 80.
nitric acid.
water) on magnesium
collect the gas liberated in a test tube by water displacement: prove that it
is hydrogen.
This experiment requires considerable care to obtain the right
conditions 1 .
Nitric oxide
107.
It
is
We must suppose
'
'
an
Nitric Oxide
106-109]
108.
To
and
Nitrates
107
in the flask that you used for preparing hydrogen, place about
Exp.
15 grams of copper, with about 20 c.e. of water
connect to the pneumatic trough. Pour gradually
strong nitric acid through the funnel on to the
i.
become
colourless,
copper dissolves.
Exp.
ii.
Show
that
a lighted taper
is
ex-
tion
is acid.
To prove
We
The blue
109.
We have
108
[CH. xvi
Experimental Chemistry
Exp.
warm
Carefully
The
nitrates of silver
and
of
heat.
HO.
Oxidation of
current of
Ammonia.
through a 'tower'
If
dried by passing
i- 82.
menfc
filled
Explain what
is
sulphur dioxide
is
Give reasons.
3.
How
is
present.
4.
Some parts of a gas flame exert an oxidizing action and other parts a
reducing action on substances placed in them. Explain as clearly as you can
what
5.
(6)
this
means and
How
can
it
(o. j.)
contains
(a)
hydrogen,
oxygen?
6.
In what way do you account for the fact that when copper
nitric acid hydrogen is not evolved?
upon by
is
acted
109-110]
109
7.
Why do
9.
may
many ways
as you can
how
lead oxide
and a
be prepared.
10.
How
CHAPTER XVII
PETROLEUM, COAL GAS AND FLAME.
Petroleum (Rock
111.
oil)
is
found
in
the
more
above.
It
is
by the
release of
marsh
gas.
compounds
of carbon
and hydrogen.
Petrol and oil engines depend for their motive power on the expansion
caused by the heating of gases produced by exploding the vapour of the petrol
or oil with air. The petrol or oil is introduced into the cylinder of the engine,
where the explosion takes place, in the form of vapour, the liquid being converted into gas by means of the carburetter. The mode of ignition is usually
by the
electric spark.
Coal Gas
111-112]
Coal Gas.
112.
Coal
is
111
another
product of ancient
'
Exp.
distillation
'
'
"*
"Litre
Gasometer
Purifier"
Ammonia
CoalTa,
L iqaor
Carbon
dioxide
&
Sulphur
Compounds
Fig. 83.
Coal tar
is
many
Germany.
112
Experimental Chemistry
xvn
[OH.
retorts
impurity,
Wood
present.
distilling sawdust in an
apparatus somewhat similar to that shown in Fig. 83, but without
the scrubber and lime purifier.'
'
'
Wood tar is
acetic acid
damp'
is
explosive
dangerous because
monoxide.
it
and forms
Explosions
Flame
113.
is
is
taking
We
and lamps.
Heat must be
The
tem-
perature of ignition.
Show
Exp.
114.
Exp.
i.
Mutual combination
in flame.
from a
glass jet held vertically and connected with an aspirator containing the gas
into which water is running from the tap. Over this jet bring a jar containing
Flame
112-115]
burning
(Fig.
hydrogen.
The oxygen
is
seen
113
burning
in
the
hydrogen.
84.)
Exp. ii. If our atmosphere were coal gas, we could produce a flame by
leading in air or oxygen through the gas pipes. Let us show this in
Air or
Oxygen
'burning
in
Hydrogen
Wile
Hydrogen
burning
Air
Air
gen
Fig. 84.
Fig. 85.
miniature. In Fig. 85 we have a lamp glass filled with coal gas. The tap at
the top is first closed and the gas is lit at the bottom as it issues into the air.
115.
is
flame of
light lantern.
of oxygen is blown
hydrogen
is lit
in the air
114
Experimental Chemistry
[CH.
xvn
'
off.'
Almost
.OUTER MANTLE
ouJttr
should be
seen only when
.7
A / is
the air hole
partially closed
'
(This
offiame.
LOWER
OXIDISING FLAME
(excess of
>
^-ZONE OF LOWEST TE
Fig. 86.
'
Flame
115]
115
shown in Fig. 86. Try to 'tap off' and burn some of the
'candle gas' from the inmost cone.
When you 'blow out' the candle, you cool the gases below their
temperature of ignition. The flame may be extinguished by surrounding
the wick with a small coil of copper wire which cools the flame by conducting
of the flame
away
This experiment
may
Bunsen flame.
Fig. 87.
*Exp. (i) Bring a piece of wire gauze of fine mesh on to the top of the
Bunsen flame (Fig. 87, B). The heat is conducted away by the gauze and unburnt gases, cooled below their ignition point, issue through
be lit above the gauze.
(ii)
tube.
it.
These
may
Turn off the gas and place the wire gauze on the top of the
Turn on the gas and light it above the gauze (Fig. 87, c). Baise the
is
Explain
this.
of miner's
made
of wire
gauze.
the lamp.
Exp. Lower a
4
c.c. of
82
116
Experimental Chemistry
xvn
[CH.
mixture with air. The ether vapour is seen burning inside the lamp but the
flame cannot penetrate the wire gauze. Often the lamp is extinguished by
the carbon dioxide and steam formed by the burning ether.
by introducing
(a)
incandescence,
solid
e.g.
a mantle of thorium
by introducing
(b)
benzene or
such as
petrol.
by cooling
rod of copper
(b)
pro-
is
if
a cold
or carbon dioxide
How
1.
What
is
2.
What
coal is burnt in
works?
3.
collect
'
'
petrol ?
an open
employed
and when
What becomes
it is distilled
of
them when
in a retort as in gas
(o. j.)
What
fire
is it
How
their nature
may
be proved,
Sketch an apparatus to
gas burns in air
jet of coal
(o. j.)
115-116]
5.
What
are
'
water gas,'
'
'
fire-damp,'
'
after-damp
6.
Sketch and describe the Davy safety lamp, and
and disadvantages.
7.
What
is
9.
when
How may
What
(a)
of heat,
and
if
not,
why not?
(o. j.)
lighted candle.
Bunsen burner?
the same amount
8.
117
'
'
?
is
CHAPTER
XVIII.
EQUIVALENTS.
The
Chemical Properties.
In
oxides of metals are basic, i.e. they neutralize acids to form salts.
Solutions of metallic oxides are alkaline.
Metals, which dissolve
in
an
We
salt.
118.
*Bxp.
trom azurite.
iii,
105,
Metals
117-118]
The
Blast Furnace.
is
Jj'ig.
furnace of
(let
i.e.
fire
119
88.
The
ore
which
will
air is
pumped
120
Experimental Chemistry
of the furnace.
The iron
[CH.
xvm
'
Electric Furnaces.
'
Fig. 89.
in Fig. 89),
which
powerful dynamo.
is
The
119.
Refer to
Electrolysis.
obtained
where
we
67,
hydrogen
and oxygen by passing a current of
heated
electricity
in
a platinum
dish
Fig. 90.
sulphuric acid.
Sir Humphry Davy, in 1807, using
a platinum dish as negative electrode
118-120]
121
Electrolysis
120.
Bxp.
i.
Copper Sulphate.
Exp.
Nitrate,
Connect
ii.
(4)
'
in series
'
with
ELECTROLYSIS OF
(I)
dilute
(2)
Sulphuric
Acid
(5)
Copper
Sodium
Chloride
Sulphate
SOLUTI ONS
Fig. 91.
(5).
elapsed and the solutions are thoroughly saturated, equal volumes of chlorine
anode in cells (4) and (5) and half this volume of
at
(1), (2)
and
(3).
and
(1)
In
oxygen
(4) where
cells (2)
it is
kathode;
kathode in
The
latter
may
be detected by
its
action on
122
121.
Experimental Chemistry
Equivalents.
By
xvm
[CH.
we can weigh
careful experiment
and
We
The
chlorine
=
=
=
copper
=31-5,
silver
then
Now
oxygen
1,
8,
35 '5,
108.
The chemical
is
the
Revision Exercises.
Ex. 1. We already know how to collect and measure the volume of
hydrogen displaced when a known weight of metal dissolves in acid devise
an experiment to show that the equivalent of magnesium=12. Use the
aspirator and remember that 1000 c.c. of hydrogen (S.T.P.) weigh -09 gram.
Ex. 2. Confirm this result by showing that magnesium combines with
;
of 12
8.
123
Equivalents
121-122]
Ex.
5.
122.
another metal.
We
in the proportions of
tatively, the metals replacing each other
their equivalent weights.
'
filter
the
through two balanced filter papers ( 25). Wash all the copper on to
with hot water and finally rinse the filter paper with rectified spirit.
filter
filter over the cone; separate the papers and weigh the copper.
Calculate the weight of iron which would displace 31-5 grams of copper.
[Eq. Wt. Iron =28.]
Dry the
i.
[Eq.
(2
Wt.
grams
of crystals in
50
of
to
c.c. of water).
Silver = 108.]
means
of the
blast furnace.
2.
Give a sketch of an
3.
Define 'electrolysis.'
electric furnace
What
is
and explain
the effect of
(a)
its
action.
passing an electric
platinum electrodes,
124
4.
How
first
[CH.
xvm
isolated?
What
5.
(a)
Experimental Chemistry
of
If excess of
hydrogen
sulphuric acid
will be evolved?
is
added
to 13
grams
of zinc
what weight
CHAPTER XIX
DALTON
1
.
123.
Law
a piece of silver
particle
is
i.e.
an
atom
The weight
of
an atom of an element
is
weight.
The
But there
equivalent weights of elements would be the same.
are reasons to suppose that molecules of elements generally
contain more than one atom. Thus the smallest particles of
oxygen in the
air
are called
molecules of oxygen;
each
is
be
For
made
fuller
to
126
Experimental Chemistry
[CH.
xix
form
Hydrogen
We
know
127
123]
particle
compound.
If the atomic weight of hydrogen
then
its
molecular weight
=
=
1,
2.
made up
atom
of
two atoms
of
oxygen
Valency.
of
hydrogen
(2 x 1)
(16).
of chlorine is
35 -5.
Its
lent weight,
weight.
combining value or valency of a single equivathe atomic weight of chlorine = 1 x its equivalent
atom of chlorine can combine with one atom of
i.e.
An
hydrogen and is said to have a valency of one and to be monovalent (Greek monos = one).
The equivalent weight of oxygen is 8. Its atomic weight = 16.
The atomic weight of oxygen = 2 x its equivalent weight, and
therefore the atom of oxygen weighing 16 can combine with
1
-^-
is
said to be 2.
Oxygen is cfo'valent.
The equivalent weight of nitrogen is 4-67. Its atomic
weight = 14. The atomic weight of nitrogen = 3 x its equivalent
weight, and therefore the atom of nitrogen weighing 14 can
combine with
nitrogen
3.
14
= 3 atoms
Nitrogen
is
of
hydrogen
bivalent.
128
Experimental Chemistry
[CH.
xix
The Valency
have
elements
weight
x specific
the
,*.
r^
specific
heat
This value
we can
Aluminium.
Specific
Heat = -21.
/
..
- = 28'5,
Valency of Aluminium =
..
..
124.
=3
^y
(approx.).
Symbols.
Each element
is
represented by a symbol,
atom
of the element.
Thus
01=
chlorine
35 '5,
Ca=
calcium
40,
carbon
12.
C=
125.
1,
O=
Formulae.
A molecule
16,
of an element or
may
compound
be represented by
123-127]
(1)
molecule of water
hydrogen and
(2)
of
oxygen;
HO
2
its total
molecule of calcium
and
129
consists of 2
molecular weight
atoms of
18 1
consists of
atom
Two
(3)
126.
[40 + 12 + (16 x
oxygen
=2
3)]
x 100
= 200.
Equations.
The formation
(1)
= 2CaCOs
=2
123)
may be
of water
2H + O = 2H O,
+16x2 = 2 [(1 x2) +
2
2(1
x 2)
by combination
represented as follows
2
of
hydrogen and
16],
4 + 32 = 36 parts by weight.
(2)
The action
(3)
of hydrochloric acid
on marble, similarly
Calculations.
127.
weights of
sary to
of the
Weight.
If
we
know
it is
neces-
CaCO 3 = CaO + C0 2
is
obtained by heating
.B.
E. SO.
130
Experimental Chemistry
.
[CH.
xix
marble yields
ton quicklime,
z-^
1 ton
..
..
1UO
=14
tons quicklime.
Sodium = Na = 23.
NaOH + HCl=rNaCl + H 5 0,
+ 16 + 1) + (1 + 35-5) = (23 + 35-5) + (HT2 + 16)
40 + 36-5 = 58-5 + 18 (by weight)
Equation.
(23
and produce
Qg
OD'O
Volume. The
occupies 22-2 litres
Thus
OO'D
Question
dissolving 7
i.
What volume
grams
of zinc
Zn + H2 S04 = ZnS0 4 + H2
65 grams of zinc displace 2 grams or 22-2
.
gram
of zinc displaces
litres of
hydrogen ;
22*2
litres of
OO.O y 7
.-.
by
hydrogen
= 2-39 litres
of
S.T.P.,
hydrogen
S.T.P.
The
corresponding
2Na + Cl 2 = 2NaCL
23.
.
35.
37.
34.
2Mg + O =2MgO.
6PbO + O 2 5:2Pb O4
(i)
JJ
(ii)
2Hg + O 2 ^: 2HgO.
O2 = 2CuO.
2Cu +
38.
46.
48.
54.
57.
58.
59.
131
Equations
127-128]
2KC10 8 =
S + O 2 = S0 2
10
(ii)
= KHSO 4 + HNO 3
2NH 4C1 + CaO = CaCl 2 + H 2O+2NH3
NaOH + HC1 = NaCl + H 2O.
(i)
P4 +5O = P4
2
KN0
3 +
H S0
2
(iii)
(ii)
(iii)
60.
(i)
75.
76.
(ii)
62.
66.
72.
(i)
CaH (CO
2
77.
(i)
85.
C02 +C = 2
88.
(a)
91.
93.
94.
97.
99.
100.
101.
3) 2
+ Ca(OH) 2 = 2CaCO 3 +
2H O.
2
H O.
2
104.
108.
109.
110.
122.
(i)
92
132
Experimental Chemistry
129.
sities,
[CH.
xix
&c., of Elements.
133
129]
1.
weight,'
'chemical symbol'?
2.
it
explains the
3.
If
What
is
formed?
5.
What volume
will be
at S.T.P.?
6.
What volume of sulphur dioxide will be produced
sulphur are burnt in oxygen?
7.
If
if
4 grams of
obtained ?
8.
What
if
556
c.c. of
carbon dioxide
93
charcoal and a
2.
How
vapour,
3.
(b)
lump
of lead.
carbon dioxide,
air of
a room of
(a)
water
solid particles?
(c)
What volume
of
What
to ascertain the
heated?
5.
acid?
What
Describe
hydrogen.
6.
Describe the appearance of roll sulphur.
What other forms of
sulphur are known? Describe experiments to show that sulphur dioxide,
sulphuretted hydrogen, and sulphuric acid all contain sulphur.
Some metals
7.
silver;
you
would not expect
8.
Describe
to find free
how you
(b)
from a solution
of caustic soda,
(c)
from
dilute
Examination Questions
PAPER
1.
three
13o
B.
common
2.
Describe three simple experiments by which it can be shown that
more than one substance is present in the atmosphere. Name the four chief
substances which are present and say what you know of their amounts.
3.
How
4.
is
By what
reactions
used?
In what forms are the metals potassium, tin, aluminium, and copper
7.
most commonly met with in nature? Describe how you would obtain any
one of the metals mentioned from a compound containing it.
What
takes place when (a) phosphorus, (6) sodium, (c) iron is exposed
Will the substances formed dissolve in water? If so, what are
the properties of the solutions thereby obtained?
8.
to the air?
PAPER
C.
oxygen
3.
How
is
and not a mixture of hydrogen and oxygen. What happens when water
added to (a) sodium metal, (b) strong sulphuric acid, (c) quicklime?
4.
dioxide
is
136
Experimental Chemistry
How
5.
chlorine prepared?
is
What
are
its
properties?
6.
Describe some of the properties of either nitric acid or hydrochloric
acid or sulphuric acid, showing how to distinguish the acid you select from
the other acids.
When
7.
a gas
is
given
off.
cases.
is
8.
for deciding
whether the
What
heated in air:
(d) sugar,
(e)
changes occur
(a)
State in each case whether the substance gains or loses in weight, and in
the case of (a), (b), (c) the effect of moistening the residue with water.
PAPER D.
1.
Give the names of eight different metals, and roughly classify them
according to the ease with which they (a) undergo oxidation in air, (b) dissolve
in dilute acids.
2.
Give three examples showing that when substances combine chemido so in definite proportions by weight, and three other examples
cally they
definite
and simple
proportions by volume.
are
is
and
of hydrochloric acid.
What
is
Examination Questions
7.
What
137
for
and why?
8.
strongly heated,
(&)
an oxidizing agent,
turpentine burns.
(d)
PAPER E.
1.
(a)
By what
water,
2.
sulphur,
(&)
How would
(c)
sand,
(d)
oxygen?
What happens
4.
lime water?
If
the
What two gases are commonly used for bleaching purposes? Explain
5.
in each case the chemical nature of the changes occurring and state why the
presence of water
affect
is
necessary.
how
mixed ?
What
are the chief bodies present in coal gas? What are the
substances formed when it is burnt in the ordinary gas flame? How would
6.
you demonstrate
7.
A solid
their presence ?
substance
when heated
By what
experiments
ANSWERS.
Ch. IV.
4.
(a)
6.
7.
36 gm. 25-5C.
29-54 gm.
(a)
8.
21-4
Ch. VI.
6.
66-6
Ch. VIII.
3.
25-51
Ch. X.
8.
415%.
Ch. XII.
3.
56 -08% quicklime.
6.
9-9
3.
4.
58| gm..
25 gm. carb.
5.
5560
7.
2471c.c.
(b)
Ch.XIX.
(6)
36-24 gm.
9,
19-42 gm.
gm.
.
7.
27 gm.
gm.
4.
4-864 gm.
36-84
43-92%
carbon dioxide,
gm.
c.c.
2780
8.
2'5gm.
c.c.
INDEX.
The Numbers
Chlorine, 90
Acids, 47, 50
Air a mixture, 28
,,
Combustion in
dissolved in water, 77
Alkalies, 51
oxidation
of,
28
oxygen, 41, 42
Compounds, 16, 17
Cork boring, 5
108
Dalton, 125
Animals
Atmosphere, 28
Atomic theory, 125
Avogadro, 126
Balance rules, 8
Bases, 54
Basic oxides with acids, 65
Blast furnace, 119
Bleaching powder, 92
Bunsen burner,
air,
,,
,,
refer to pages.
salts, 121
Elements, 16
Equations, 129, 130, 131
Equivalents, 122
Eudiometer, 64
flame, 114
Filtering, 5
Fire, chemistry of, 81
Calcium carbonate, 68
with
,,
,,
acid, 70
,,
chloride, 74
Calculations, 129, 130
,,
,,
,,
composition
Carbonic oxide, 80
Catalytic agents, 40
Caustic alkalies, 51
Chalk, 67
Chemical changes, 13
Chemistry, definition of, 10
of,
80
116
Formulae, 128
luminosity
of,
Fractional distillation, 22
by
Gas collecting, 6
Glass blowing, 3
Hardness
of water, 72, 73
Hydrochloric acid, 49
Index
140
Hydrogen, 57
burnt in air, 58
,,
from water, 60
Physical changes, 16
,,
experiments, 12
,,
constants, 132
,,
Indicators, 41
Quantitative nature
change, 26
chemical
of
Lime, 67
Reduction, 59
Eeversible change, 62
Eock salt, 87
Eusting of iron, 31
Lavoisier's
work on combustion, 29
,,
, ,
Salts, 51
Molecules, 125
, ,
ing, 34
Mineral acids, 47
Mixtures, 15
of,
81
preparation of, 86
from metallic oxides, 54
,,
,,
Natural waters, 75
Neutral salt, preparation of, 53
Neutralizing acids, 52
Nitrates, effect of heat on, 107
Separation by dissolving, 19
Nitric acid, 48
Solubility, 21
,,
,,
,,
difference
of solubility, 21
chloride, 86
Sodium
reduction, 105
,,
Nitric oxide, 107
Sulphur, 94
Sulphides, 95
Sulphur dioxide, 95
trioxide, 96
,,
Sulphuretted hydrogen, 98
Sulphuric acid, 48
Oxides, 43
,,
potassium
39, 40
solubility, 41
preparation, 96
Brin's process, 32
from
,,
Symbols, 128
chlorate,
Volume, at
S.T.P.,
Parallax error, 6
,,
,,
Petroleum, 110
of crystallization, 55
35, 36
31,
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