Professional Documents
Culture Documents
By
Mohammed Wael Abu Shaban
Supervised By
Dr. Mohammed Arafa
June 2012
ABSTRACT
The main goal of this research is to produce Ultra High Performance Self
Compacting Concrete (UHPSCC) in Gaza strip, using materials which are
available at the local markets. Different trial mixes were used to obtain the
acceptable fresh properties of Self compacting concrete with a compressive
strength exceeding 140 MPa. The research includes also the use of a recognized
manufacturer mineral admixture, basalt aggregate, quartz, and special type of
fine aggregate (quartz powder).
The elimination of vibration for compacting concrete during placing through the
use of Self Compacting Concrete leads to substantial advantages in terms of
better homogeneity, enhancement of working environment and improvement in
the productivity by increasing the speed of construction. The resulting concrete
is characterized in the fresh state by methods used for Self Compacted Concrete,
such as slump-flow, V-funnel and L- box tests.
The fresh and hardened mechanical properties of UHPSCC were studied, i.e.,
workability, viscosity, flowability, passing ability, self compacting, compressive
strength, split cylinder strength, and flexural strength. The effect of using
different superplasticizer and silica fume doses on these properties are obtained
within research work.
The effect of adding different amounts of basalt aggregate (150%, 160%, and
170%) by cement weight on the fresh and hardened properties of UHPSCC, i.e.,
workability, viscosity, flowability, passing ability, compressive strength, and
density is also investigated.
The results showed that the optimum mix is obtained by adding 160% basalt,
3% superplastisizer and 15.5% silica fume. The test results also revealed that it
is possible to produce UHPSCC in Gaza Strip with compressive strength in
excess of 140 MPa using (1%, 2%, and 3%) superplasticizer,10% to 16% silica
fume, and 15.5% silica fume, with water cement ratio less than 0.33.
ARABIC ABSTRACT
140 .
.
.
.
%150 %160 %170
15.5%, 3%,160% .
140 %1
%2 %3 %10 %16
%15.5 .0.33
II
DEDICATIONS
To my Father, Mother, Joan, Hamam, and Belal, to my wife Alaa.
To my friends, and to whom I belong.
III
ACKNOWLEDGMENT
I would like to express my sincere appreciation to Dr. Mohamed Arafa and Dr.
Mamoun Al Qedra - Department of Civil Engineering, Faculty of Engineering,
The Islamic University of Gaza- for their help and guidance in the preparation
and
development
of
this
work.
The
constant
encouragement,
support
and
IV
TABLE OF CONTENTS
ABSTRACT ..................................................................................................................................... I
ARABIC ABSTRACT .................................................................................................................... II
DEDICATIONS ............................................................................................................................ III
ACKNOWLEDGMENT ............................................................................................................... IV
TABLE OF CONTENTS ................................................................................................................ V
LIST OF TABLES ...................................................................................................................... VIII
LIST OF FIGURES ....................................................................................................................... IX
CHAPTER 1- INTRODUCTION ................................................................................................... 2
1.1 General Background .............................................................................................................. 2
1.2 Statement of the problem....................................................................................................... 3
1.3 Scope of work ........................................................................................................................ 4
1.4 Research objectives ............................................................................................................... 4
1.5 Methodology ......................................................................................................................... 5
1.6 Thesis Layout ........................................................................................................................ 5
CHAPTER 2- LITERATURE REVIEW ........................................................................................ 8
2.1 Definition of Ultra High Performance Self Compacting Concrete ....................................... 8
2.2 History of developing UHPSCC ........................................................................................... 8
2.3 Advantages of UHPSCC ....................................................................................................... 9
2.4 New structural design and construction system .................................................................. 11
2.5 UHPSCC large scale application ......................................................................................... 13
2.6 Materials of UHPSCC ......................................................................................................... 14
2.6.1 Powder .......................................................................................................................... 14
2.6.2 Portland cement ............................................................................................................ 14
2.6.3 Silica fume .................................................................................................................... 17
2.6.4 Micro fine aggregates ................................................................................................... 19
2.7 Concluding Remarks ........................................................................................................... 20
CHAPTER 3- CONSTITUENT MATERIALS AND EXPERIMENTAL PROGRAM .............. 23
3.1 Introduction ......................................................................................................................... 23
3.2 Characterizations of constituent Materials .......................................................................... 24
3.2.1 Cement.......................................................................................................................... 24
VI
VII
LIST OF TABLES
Table 2.1: History of developing UHPSCC .................................................................................... 9
Table 2.2: Advantages of UHPSCC .............................................................................................. 11
Table 3.1: cement characteristics according to the manufacturer sheets ....................................... 24
Table 3.2: Physical property of basalt aggregate........................................................................... 26
Table 3.3: Physical property of quartz sand .................................................................................. 26
Table 3.4: Water absorption of basalt aggregate ........................................................................... 27
Table 3.5: Water absorption of quartz sand................................................................................... 27
Table 3.6: The technical data for the "Sika ViscoCrete - 10" (source: from supplier) .................. 28
Table 3.7: The technical data for the "Sika - Fume" (source: from supplier)................................ 29
Table 3.8: Self Compacting Criteria .............................................................................................. 34
Table 3.9: Test program for compressive strength ........................................................................ 42
Table 4.1: Best mixture proportions of UHPSCC by weight of cement ....................................... 49
Table 4.2: One cubic meter components of UHPSCC mixture ..................................................... 50
Table 4.3: Changing in mixtures proportions per cement weight ................................................. 50
Table 4.4: Mixtures classification ................................................................................................. 51
Table 4.5: Mixtures mean density ................................................................................................. 56
Table 4.6: Mixtures mean compressive strength after 28 days ..................................................... 57
Table 4.7: Summary of compressive strength test results for first UHPSCC mix ........................ 60
Table 4.8: Summary of compressive strength test results for all mixes ........................................ 61
Table 4.9: Comparison of ratio of (fc)t /(fc )28 of UHPSCC with the prediction of ACI
Committee 209 of NSC ................................................................................................................. 63
Table 4.10: Summary of splitting tensile strength test results ....................................................... 65
Table 4.11: Summary of splitting strength test results for first UHPSCC mix ............................. 66
Table 4.12: Changing in mixtures proportions .............................................................................. 69
Table 4.13: Basalt different proportion mixes results ................................................................... 69
VIII
LIST OF FIGURES
Figure 2.1: Advantages of UHPSCC ............................................................................................. 10
Figure 2.2: New Construction system achieved by making full use of UHPSCC ........................ 12
Figure 2.3: Sandwich structure for immersed tunnel .................................................................... 12
Figure 2.4: Burj Khalifa ................................................................................................................ 13
Figure 2.5: Microstructure development in Portland cement pastes ............................................. 15
Figure 2.6: Effect of micro silica in densifying the concrete mix ................................................. 18
Figure 3.1: Aggregates used in mixture preparations .................................................................... 25
Figure 3.2: The chemical admixture (Superplasticizer) used in mixture preparation ................... 29
Figure 3.3: Sika Fume ................................................................................................................ 30
Figure 3.4: Mix design procedure ................................................................................................. 30
Figure 3.5: The drum mixer........................................................................................................... 32
Figure 3.6: Experimental program steps chart............................................................................... 33
Figure 3.7: Slump cone and base plate .......................................................................................... 35
Figure 3.8: Slump flow test ........................................................................................................... 36
Figure 3.9: The largest diameter of the flow spread ...................................................................... 36
Figure 3.10: V-funnel test.............................................................................................................. 38
Figure 3.11: General assembly of L-box ....................................................................................... 39
Figure 3.12: Dimensions and typical design of L-box .................................................................. 40
Figure 3.13: Compression test specimens (100x100x100mm) ..................................................... 41
Figure 3.14: Compressive strength test machine ........................................................................... 42
Figure 3.15: Split cylinder test setup for cylinder 150 x 300mm .................................................. 44
Figure 3.16: Crack in a split cylinder tensile specimen ................................................................. 45
Figure 3.17: Diagrammatic view for flexure test of concrete by center-point loading ................. 46
Figure 3.18: Flexural test specimens (100*100*500mm) ............................................................. 46
Figure 4.1: Effect of silica fume and superplasticizer on UHPSCC slump flow .......................... 52
Figure 4.2: Effect of silica fume and superplasticizer on UHPSCC V-Funnel time ..................... 53
Figure 4.3: Effect of silica fume and superplasticizer on UHPSCC L-Box test............................ 55
Figure 4.4: Effect of silica fume and superplasticizer on UHPSCC density ................................. 57
Figure 4.5: Effect of silica fume and superplasticizer on UHPSCC compressive strength ........... 58
Figure 4.6: Effect of silica fume dosage on compressive strength ................................................ 60
Figure 4.7: The variation of mean compressive strength with age for first UHPSCC mix ........... 61
Figure 4.8: Relation between the mean compressive strength and age for all mixes .................... 62
IX
Figure 4.9: Comparison of ratio of (fc)t /(fc )28 for UHPSCC and NSC at different ages ........... 63
Figure 4.10: Compressive strength gain as a function of time after casting.................................. 64
Figure 4.11: Effect of silica fume and superplasticizer on UHPSCC splitting strength................ 66
Figure 4.12: The variation of splitting strength with age for first UHPSCC mix.......................... 67
Figure 4.13: The ratio of fsp (t) to fsp (28days) with time for UHPSCC ...................................... 68
Figure 4.14: Effect of Basalt Content on UHPSCC Slump Flow .................................................. 70
Figure 4.15: Effect of Basalt Content on UHPSCC V-Funnel test................................................ 70
Figure 4.16: Effect of Basalt Content on UHPSCC Compressive Strength .................................. 71
Figure 4.17: Effect of Basalt Content on UHPSCC Splitting Tensile Strength ............................ 71
Figure 4.18: Effect of Basalt Content on UHPSCC Flexural Tensile Strength ............................. 72
CHAPTER 1
INTRODUCTION
CHAPTER 1
INTRODUCTION
CHAPTER 1
INTRODUCTION
CHAPTER 1- INTRODUCTION
1.1 General Background
Reinforced concrete is considered the most frequently used structural material,
not only because it has good mechanical proprieties after hardening, easy to use,
etc. but also its dominant advantage that it is considered as an economic
structural material.
Increasing the concrete strength is always one of the main desires of concrete
technology. Since more than 20 years, ultra high strength concretes with
compressive strength ranging from 50 MPa up to 130 MPa have been used
worldwide in tall buildings and bridges with long spans or buildings in
aggressive environments (Farhang and Arash,2008).
Building
elements
made
of
high
strength
concrete
are
usually
densely
reinforced. The small distance between reinforcing bars may lead to defects in
concrete. If ultra high performance concrete is a self-compacting, the production
of densely reinforced building element from ultra high performance concrete
with high homogeneity would be an easy work (Jianxin and Jorg, 2002).
More over in recent years, premature deterioration of reinforced concrete
structures has given a considerable cause for concern where large numbers of
existing structures are currently in need of either strengthening or rehabilitation
due to various reasons.
Ultra high performance self compacting concrete can solve the problem of
casting in densely confined areas, and areas which need a large thickness of the
concrete.
Self compacting concrete is a concrete that flows and compacts only under
gravity. It fills the whole mold completely without any defects. The usual selfcompacting concretes have a compressive strength in the range of 30-50 MPa
(European Guidelines,2005).
CHAPTER 1
INTRODUCTION
Due
to
large
rehabilitation
and
numbers
of
deteriorated
strengthening,
ultra
high
structures
strength
which
concrete
need
is
and
segregation,
if
high
strength
concrete
is
self-
CHAPTER 1
INTRODUCTION
the
mechanical
prosperities
of
(UHPSCC),
this
will
open
new
possibilities for the production of a new material, locally. This can be achieved
through the following objectives:
I.
Identify the possible concrete mixes to produce several strengths with several
self compacting concrete (SCC) properties.
II.
III.
CHAPTER 1
INTRODUCTION
1.5 Methodology
In general terms, the following methodology was followed to achieve the
research objectives.
1- To
conduct
comprehensive
literature
review
related
to
subject
of
UHPSCC.
2- Selection
of
suitable
ingredient
materials
required
for
producing
physical
and
mechanical
laboratory
tests
on
UHPSCC
CHAPTER 1
INTRODUCTION
concrete,
history
of
UHPSCC,
Advantages,
applications
and
materials.
chapter
reviews
the
materials
were
used
in
producing
ultra
high
chapter
includes
the
concluded
remarks,
main
conclusions
and
CHAPTER 2
LITERATURE REVIEW
CHAPTER 2
LITERATURE REVIEW
CHAPTER 2
LITERATURE REVIEW
CHAPTER 2
LITERATURE REVIEW
Year
1950
1960
1980
1985
UHPC - History
Year
1988
1993
The
prototype
of
selfcompacting concrete was first
completed
using
materials
already on the market
The SCC was used for the first
time in Europe in the civil works
More
Compressive strengths
recently approaching (120MPa) is used
SCC - History
More
recently
SCC
was
European
specification
and
guidelines were developed for
SCC
SCC is used commercially in
Japan, Europe, USA, etc.
2002-2008
Some researches takes place on matching the UHPC and SCC in one mix in order to
develop the UHPSCC, which is used recently in many special tall buildings and tunnels
CHAPTER 2
LITERATURE REVIEW
for many years and significant funds have been necessary to repair aging infrastructure.
UHPSCC possesses good durability properties and lower porosity and capillaries account
for its endurance. UHPSCC construction requires lower maintenance costs in its service
life than conventional concrete. UHPSCC has enhanced ductility, high temperature
performance and improved impact resistance.
Figure (2.1) and Table (2.2) shows the advantages of UHPC, SCC and UHPSCC as one
mixture respectively.
Advantages of UHPSCC
Advantages
of SCC
Advantages
of UHPC
High compressive
strength
Low porosity
Less sensitivity to
temp. change
Durable
Homogeneous &
Durable
Homogeneous
10
CHAPTER 2
LITERATURE REVIEW
Advantages of
UHPSCC
11
CHAPTER 2
LITERATURE REVIEW
Rational Construction
System
Rational Combination of
Concrete & Steel
Figure 2.2: New Construction system achieved by making full use of UHPSCC
One example of this is the so-called sandwich structure Figure (2.3), where concrete is
filled into a steel shell. Such a structure has already been completed in Kobe, and could
not have been achieved without development of UHPSCC.
12
CHAPTER 2
LITERATURE REVIEW
13
CHAPTER 2
LITERATURE REVIEW
The term powder used in UHPSCC refers to a blended mix of cement and filler
particles smaller than 0.125 mm. The filler increases the paste volume required to achieve
the desirable workability of UHPSCC. The addition of filler in an appropriate quantity
enhances both workability and durability without sacrificing early strength.
2.6.2 Portland cement
Portland cement concrete is foremost among the construction materials used in civil
engineering projects around the world. The reasons for its often use are varied, but among
the more important are the economic and widespread availability of its constituents, its
versatility, and adaptability, as evidenced by the many types of construction in which it is
used, and the minimal maintenance requirements during service life.
2.6.2.1 Hydration of Portland cement
When Portland cement is mixed with water, its constituent compounds undergo a series
of chemical reactions that are responsible for the eventual hardening of concrete.
Reactions with water are designated hydration, and the new solids formed on hydration
are collectively referred to as hydration products. Figure (2.5) shows schematically the
sequence of structure formation as hydration proceeds. This involves the replacement of
water that separates individual cement grains in the fluid paste Figure (2.5.a) with solid
hydration products that form a continuous matrix and bind the residual cement grains
together over a period of time, as illustrated in Figure (2.5):(b-d).The calcium silicates
provide most of the strength developed by Portland cement. C3S provides most of the
14
CHAPTER 2
LITERATURE REVIEW
early strength in the first three to four weeks and both C3S and C2S contribute equally to
ultimate strength (Mindess, Young and Darwin, 2002).
The hydration reactions of the two calcium silicates are very similar, differing only in the
amount of calcium hydroxide formed as seen in the following equations (Mindess, Young
and Darwin, 2002):
23
3 2 8
3
11
+
Tricalcium +
calcium hydroxide
Calcium silicate hydrate
silicate
22
3 2 8
9
+
Dicalcium +
calcium
hydroxide
CSH
silicate
C-S-H or C3S2H8 is called calcium silicate hydrate and is the principal hydration
product. The formula C3S2H8 is only approximate because the composition of this
hydrate is actually variable over quite a wide range. In Portland cement, the hydration of
15
CHAPTER 2
LITERATURE REVIEW
tricalcium aluminate C3A involves reactions with sulfate ions that are supplied by the
dissolution of gypsum, which is added to temper the strong initial reaction of C3A with
water that can lead to flash set. The primary initial reaction of C3A is as follows:
2
3 2
26
Tricalcium + Gypsum +
aluminate
6 3 32
Ettringite
Where S is equivalent to SO3 and ettringite is a stable hydration product only while there
is an ample supply of sulfate available.
2.6.2.2 Cement grains Size Distribution, Packing and Dispersion
Portland cements are ground to a rather narrow range of particle sizes; varying only from
about 1 m to about 80 m. Cements are ground slightly finer, but not much. The mean
size being of the order of 9 to 10 m. In visualizing the state of the flocculated mass of
cement grains in fresh Portland cement mixes, it appears that the variation in particle size
between larger and smaller cement particles does not result a dense packing. To a
considerable extent this is due to the flocculated character particles once bumped together
are "stuck" together by forces of attraction cannot readily slide to accommodate each
other better. However, even if they could, they are far too close to being of the same
order of size to be able to form dense local mixes. Water filled pockets of roughly the
same size as the cement particles exist throughout the mass (Neville, 1993).
It is obvious that what is needed is an admixture of much finer particles to pack into the
water filled pockets between the cement grains. Silica fume (or "micro silica") provides
such particles, the mean particle size of commercial silica fume being typically less than
0.2 m. When micro silica is added to ordinary cement paste a denser packing that may
be ensued. In order to get the desired state of dense particle packing, not only must the
fine particles be present, but must be effectively deflocculated during the mixing process.
Only then can the cement particle move around to incorporate the fine micro silica
particles. The fine micro silica particles must themselves be properly dispersed so that
they can separate from each other and pack individually between and around the cement
grains. Another requirement for best packing is that the mixing used be more effective
16
CHAPTER 2
LITERATURE REVIEW
than the relatively usual mixing done in ordinary concrete production. High shear mixers
of several kinds have been explored. Proper dispersion and incorporation of fine micro
silica particles thus can results in a dense local structure of fresh paste with little waterfilled space between the grains. When the cement hydrates, the overall structure produced
in the groundmass is denser, tighter, and stronger (Young and Menashi, 1993).
2.6.3 Silica fume
Silicon, ferrosilicon and other silicon alloys are produced by reducing quartz, with coal
and iron or other ores, at very high temperatures (2000C) in electric arc furnaces. Some
silicon gas or fume is produced in the process, which reaches the top of the furnace with
other combustion gases, where it becomes oxidized to silica in contact with the air and
then condenses as 0.1 m to 1 m spherical particles of amorphous silica. This material
is usually known as silica fume. It is also referred to as microsilica or more properly,
condensed silica fume (CSF). Silica fume is an ultra fine powder, with individual particle
sizes between 50 and 100 times finer than cement, comprising solid spherical glassy
particles of amorphous silica (85-96 percent SiO2). However, the spherical particles are
usually agglomerated so that the effective particle size is much coarser (ACI 548.6R-96).
2.6.3.1 The pozzolanic reactions
In the presence of hydrating Portland cement, silica fume will react as any finely divided
amorphous silica-rich constituent in the presence of (CH) the calcium ion combines with
the silica to form a calcium-silicate hydrate through the pozzolanic reaction. See Figure
(2.6).
(3 + 2 )
+
Portland cement
+ + ( )
The simplest form of such a reaction occurs in mixtures of amorphous silica and calcium
hydroxide solutions.
(Grutzeck and Roy, 1995) studied the reactivity of silica fume with calcium hydroxide in
water at 38 C. Silica fume to calcium hydroxide ratios (SF:CH) 2:1, 1:1 and 1:2.25 were
included. They found that a well-crystallized form of CSH was formed by 7 days of
17
CHAPTER 2
LITERATURE REVIEW
curing. For the 2:1 mixtures, all CH was consumed by 7 days; for the 1:1 mixtures, 28
days was required to consume the CH.
(Grutzeck and Roy, 1995) suggest a gel model of silica fume-cement hydration.
According to this model, silica fume contacts mixing water and forms a silica-rich gel,
absorbing most of the available water. Gel then agglomerates between the grains of
unhydrated cement, coating the grains in the process. Calcium hydroxide reacts with the
outer surface of this gel to form C-S-H. This silica-fume gel C-S-H forms in the voids of
the C-S-H produced by cement hydration, thus producing a very dense structure.
2.6.3.2 The physical effects
The strength at the Interfacial Transition Zone (ITZ) between cement paste and coarse
aggregate particles is lower than that of the bulk cement paste. The transition zone
contains more voids because of the accumulation of bleed water underneath the aggregate
particles and the difficulty of packing solid particles near a surface. Relatively more
calcium hydroxide (CH) forms in this region than elsewhere. Without silica fume, the CH
18
CHAPTER 2
LITERATURE REVIEW
crystals grow large and tend to be strongly oriented parallel to the aggregate particle
surface (Monteiro and Maso, 1985). CH is weaker than calcium silicate hydrate (C-SH), and when the crystals are large and strongly oriented parallel to the aggregate surface,
they are easily cleaved. a weak interfacial transition zone (ITZ) results from the
combination of high void content and large, strongly oriented CH crystals.
According to (Mindess, 1988), silica fume increases the strength of concrete largely
because it increases the strength of the bond between the cement paste and the aggregate
particles.
(Jiaxnin and Jorg, 2002) pointed out .The increased coherence (cohesiveness) will
benefit the hardened concrete structure in terms of reduced segregation and bleed water
pockets under reinforcing bars and coarse aggregate.
(Monteiro and Mehta,1990) stated that silica fume reduces the thickness of the
transition zone between cement paste and aggregate particles. One reason for this is the
reduction in bleeding. The presence of silica fume accelerates the hydration of cement
during the early stages.
(Buitelaar, 2004) showed that addition of silica fume could reduce water demand
because the silica-fume particles were occupying space otherwise occupied by water
between the cement grains. This reduction only applies for systems with enough
admixtures to reduce surface forces.
It is worth emphasizing here that all of these physical mechanisms depend on thorough
dispersion of the silica-fume particles in order to be effective. This requires the addition
of sufficient quantities of water-reducing admixtures to overcome the effects of surface
forces and ensure good packing of the solid particles. The proper sequence of addition of
materials to the mixer as well as thorough mixing is also essential.
2.6.4 Micro fine aggregates
19
CHAPTER 2
LITERATURE REVIEW
The micro fine aggregate is an important parameter for gaining the self compacting
properties and the rheological properties which improved with increasing the micro fine
aggregates ratio. If the aggregate content in a UHPSCC mixture exceeds a certain limit,
blockage would occur independently of the viscosity of the mortar. Superplasticizer and
water content then determined to ensure desired self compacting characteristics
(Okamura and Ozawa, 1995).
Although most materials smaller than sieve 75 m increase the water demand of the
concrete, some experimental results claim that these fine particles can act as a lubricant
and enhance workability without a significant increase in the water demand for a given
workability (Hudson, 2007). Fillers such as microfines can have a positive effect on
concretes, influencing both particle packing and physiochemical reactions in the interface
zone (Kronlof, 1994).
Some positive effects of including fine fillers in mixtures are: smaller water requirement
due to improved particle packing; increased strength due to smaller water requirement
and improved interaction between paste and aggregate; decreased porosity; and better
workability (Kronlof, 1994).
2.7 Concluding Remarks
Ultra High Performance Self Compacting Concrete (UHPSCC) is one of the latest
developments in concrete technology. UHPSCC refers to materials with a cement matrix
and a characteristic compressive strength in excess of 120MPa. The hardened concrete
matrix of Ultra High Performance Self Compacting Concrete (UHPSCC) shows
extraordinary strength and durability properties, and the fresh concrete matrix shows
extraordinary workability allow it to flow under its own weight and without the need of
vibration.
These features are the result of using very low amounts of water, high amounts of
cement, fine aggregates and micro fine powders. These materials are characterized by a
dense microstructure. The sufficient workability is obtained by using superplasticizer.
Silica fume is an essential ingredient of UHPSCC. This material comprises extremely
20
CHAPTER 2
LITERATURE REVIEW
fine particles and not only fills up the space between the cement grains, but also reacts
with the cement which increasing the bond between cement matrix and aggregate
particles.
As a result of its superior performance, UHPSCC has found application in the storage of
nuclear waste, bridges, tall buildings, immersed constructions.
21
CHAPTER 3
CHAPTER 3
CONSTITUENT MATERIALS
AND EXPERIMENTAL
PROGRAM
22
CHAPTER 3
23
CHAPTER 3
Cement paste is the binder in UHPSCC that holds the aggregate (coarse, fine, micron
fine) together and reacts with mineral materials in hardened mass. The property of
UHPSCC depends on the quantities and the quality of its constituents. Because cement is
the most active component of UHPSCC and usually has the greatest unit cost, its
selection and proper use is important in obtaining most economically the balance of
properties desired of UHPSCC mixture.
In this research ordinary Portland Cement CEM I 42.5R was used for the production of
Ultra High Performance Self Compacting Concrete (UHPSCC). The cement met the
requirements of ASTM C 150 specifications. The results of physical and mechanical
analyses of the cements are summarized in Table (3.1) along with the requirements of
relevant ASTM specifications for comparison purposes.
Table 3.1: cement characteristics according to the manufacturer sheets
Test type
Setting time
(Vicat test) hr min
Mortar Compressive Strength
(MPa)
Fineness (cm2/gm)
Water demand
Initial
Final
3 Days
7 Days
28
Days
24
Min. 2800
No limit
CHAPTER 3
Aggregate is relatively inexpensive and strong making material for concrete. It is treated
customarily as inert filler. The primary concerns of aggregate in mix design for Ultra
High Performance Self Compacting Concrete are gradation, maximum size, and strength.
Providing that concrete is self compacting, the large particles of aggregate are
undesirable for producing Ultra High Performance Self Compacting Concrete. For
producing UHPSCC, selection of very strong aggregate with rough texture is
significantly more important the crushed basalt (coarse aggregate). The nominal size
ranges from 2 to 5 mm, quartz sand (fine aggregate) in the range of 0.3 to 0.8 mm which
is locally available in Gaza markets as shown in Figure (3.1), and quartz powder (micro
fine aggregate) in the range of 0 to 10 m. In addition, it is important to ensure that the
aggregates are clean, since a layer of silt or clay will reduce the cement aggregate bond
strength, in addition to increasing the water demand.
25
CHAPTER 3
The density of the aggregate is required in mix proportions to establish weight volume
relationships. The density is expressed as the specific gravity which is dimensionless
relating the density of the aggregate to that of water. The determination of specific
gravity of basalt and quartz sand was done according to ASTM C127 and ASTM C128.
The specific gravity was calculated at two different conditions which are the dry
condition and the saturated surface dry condition (SSD). Table (3.2) and Table (3.3) show
the physical properties of basalt and quartz sand.
The unit weight or the bulk density of the aggregate is the weight of the aggregate per
unit volume. The unit weight is necessary to select concrete mixtures proportions in
UHPSCC .The determination of unit weight was done according to ASTM C556. Table
(3.2) and Table (3.3) illustrate the unit weight of basalt and quartz.
Table 3.2: Physical property of basalt aggregate
Aggregate
Size(mm)
5
4.75
2.3
2
Average
Specific
Gravity(dry)
Specific
Gravity(SSD)
3.06
3.08
3.11
3.15
3.1
Unit Weight
(kg/m3) (dry)
3053
3065
3085
3097
3075
Unit Weight
(kg/m3) (SSD)
3076
3092
3112
3120
3100
3.02
3.04
3.07
3.11
3.06
Specific
Gravity(SSD)
2.666
2.675
2.685
2.697
2.68
Unit Weight
(kg/m3) (dry)
1661
1662.15
1663.13
1663.95
1662.56
Unit Weight
(kg/m3) (SSD)
1671.614
1672.588
1673.416
1674.1
1672.93
Aggregate
Size(mm)
0.8
0.6
0.4
0.3
Average
Specific
Gravity(dry)
2.65
2.658
2.668
2.68
2.67
26
CHAPTER 3
The aggregate moisture is the percentage of the water present in the sample aggregate,
either inside pores or at the surface. Moisture content of the coarse and fine aggregate
was done according to ASTM C127 and ASTM C128, but the final moisture content was
zero because the coarse and fine aggregates were dried in an oven at temperature (110o
C5). Table (3.4) and Table (3.5) illustrate the absorption percentages of basalt and
quartz sand.
Table 3.4: Water absorption of basalt aggregate
Aggregate
Size(mm)
5
4.75
2.3
2
Average
Water Absorption
(%)
1.43
1.45
1.48
1.52
1.47
Aggregate
Size(mm)
0.8
0.6
0.4
0.3
Average
Water Absorption
(%)
0.61
0.619
0.628
0.639
0.62
From the previous results, it can be observed that the specific gravity of all aggregates
ranges from 3.02 to 3.1 for basalt, and from 2.65 to 2.68 for quartz sand. For aggregates,
the water absorption tends to increase with the size reduction. In addition, when the
aggregate size decreases, the unit weight of the aggregates increases.
27
CHAPTER 3
3.2.3 Water
Tap water was used in all concrete mixtures and in the curing all of the tests specimens.
The water source was used from the soil and material laboratory at IUG which is
considered safe to drink.
3.2.4 Admixture
Type
Appearance
Density
PH value
Toxicity
Property
Turbid liquid
1.08 kg/It. 0.005
7.5
Non-Toxic
28
CHAPTER 3
Silica fume is a byproduct resulting from the reduction of high-purity quartz with coal or
coke and wood chips in an electric arc furnace during the production of silicon metal or
ferrosilicon alloys. The silica fume which condenses from the gases escaping from the
furnaces has a very high content of amorphous silicon dioxide and consists of very fine
spherical particles (ACI 548.6R-96).
The silica fume was supplied by SIKA Company .It is known as "Sika -Fume". Figure
(3.3) shows the appearance of used silica fume, while Table (3.7) shows the technical
data, as supplied by the SIKA Company.
Table 3.7: The technical data for the "Sika - Fume" (source: from supplier)
Type
Appearance
Specific gravity
Chloride Content
Toxicity
Property
Grey powder
2.20
Nil
Non-Toxic
29
CHAPTER 3
Accordingly the mix design in this research were developed pursuant to the standard
design procedure starting with determining the amount of aggregates required using the
other parameters such as densities of fine and coarse aggregates in SSD condition,
volume ratio of fine aggregate to the total aggregate, then determination of the cement
content for a target design compressive strength.
30
CHAPTER 3
After that the filler and water content to be determined according to the selected
water/powder ratio and assumed air content, using the total absolute volume equation.
Then determination of the superplasticizer dosage based on the calculated total powder
content.
3.4 UHPSCC Preparation
The preparation of the UHPSCC specimens was made in the Soil and Material Lab at
IUG. After the required amounts of all constituent materials are weighed properly, the
next step is mixing them. The aim of mixing is that all aggregate particles should be
surrounded by the cement paste and silica fume, and all the materials should be
distributed homogeneously in the concrete mass. A power-driven tilting revolving drum
mixer is used in the mixing process (Figure 3.5). It has an arrangement of interior fixed
blades to ensure end-to-end exchange of material during mixing. Tilting drums have the
advantage of a quick and clean discharge.
The mixing procedure for UHPSCC included the following steps (Arafa et.al, 2010):
1) Adding 40 % of superplasticizer to the mixing water.
2) Placing all dry materials (cement, silica fume, crushed quartz and aggregate) in the
mixer pan, and mixing for 2 minutes.
3) Adding water (with 40% of superplasticizer) to the dry materials, slowly for 2 minutes.
4) Waiting 1 minute then adding the remaining superplasticizer to the dry materials for 30
seconds.
5) Continuation of mixing as the UHPSCC changes from a dry powder to a thick paste.
The time for this process will vary.
After final mixing, the mixer is stopped, turned up with its end right down, and the fresh
homogeneous concrete is poured into a clean plastic pan.
The casting of all UHPSCC specimens used in this research was completed within 20
minutes after being done with mixing. All specimens were cast and covered to prevent
evaporation.
31
CHAPTER 3
32
CHAPTER 3
33
CHAPTER 3
To ensure the self compacting properties of the UHPSCC many test methods have been
developed. So far no single method or combination of methods has achieved universal
approval and most of them have their adherents. Similarly no single method has been
found which characterizes all the relevant workability aspects. Each mix design should be
tested by more than one test method for the different workability parameters.
For the initial mix design of SCC, all three workability parameters (filling ability, passing
ability and segregation) need to be assessed to ensure that all aspects are fulfilled as per
mentioned in table (3.8). A full-scale test should be used to verify the self compacting
characteristics of the chosen design for a particular application. While for site quality
control, two test methods are generally sufficient to monitor production quality. Typical
combinations are Slump-flow and V-funnel. With consistent raw material quality, a
single test method operated by a trained and experienced technician may be sufficient
(EFNARC, 2005).
Method
Unit
mm
S
S
-
34
Minimum
Range
550
2
6
0.7
Maximum
Range
850
9
12
1.0
CHAPTER 3
The slump-flow and T500 time is a test to assess the flowability and the flow rate of selfcompacting concrete in the absence of obstructions. It is based on the slump test to
measure two parameters the flow speed and the flow time. The result is an indication of
the filling ability of self-compacting concrete. The T500 time is also a measure of the
speed of flow and hence the viscosity of the self-compacting concrete, also the test is not
suitable when the maximum size of the aggregate exceeds 40 mm.
The fresh concrete is poured into a cone as used for the normal slump test as shown in
figure (3.7). When the cone is withdrawn upwards the time from commencing upward
movement of the cone to when the concrete has flowed to a diameter of 500 mm is
measured; this is the T500 time, figure (3.8). The largest diameter of the flow spread of
the concrete and the diameter of the spread at right angles to it are then measured and the
mean is the slump-flow, figure (3.9).
35
CHAPTER 3
The detailed procedure of this test was as mentioned in the European guidelines for SCC,
(EFNARC, 2005). The first step is to prepare the cone and base plate then place the
cleaned base in a stable leveled position, fill the cone without any agitation or rodding,
and strike off surplus from the top of the cone. Allow the filled cone to stand for not more
than 30s; during this time remove any spilled concrete from the base plate and ensure the
base plate is damp all over but without any surplus water.
Lift the cone vertically in one movement without interfering with the flow of concrete. If
the T500 time has been requested, start the stop watch immediately the cone ceases to be
in contact with the base plate and record the time taken to the nearest 0,1 s for the
concrete to reach the 500 mm circle at any point. Without disturbing the base plate or
36
CHAPTER 3
concrete, measure the largest diameter of the flow spread and record it as dm to the
nearest 10 mm. Then measure the diameter of the flow spread at right angles to dm to the
nearest 10 mm and record as dr to the nearest 10 mm.
Check the concrete spread for segregation. The cement paste/mortar may segregate from
the coarse aggregate to give a ring of paste/mortar extending several millimeters beyond
the coarse aggregate. Segregated coarse aggregate may also be observed in the central
area. Report that segregation has occurred and that the test was therefore unsatisfactory.
Then the slump-flow is the mean of dm and dr expressed to the nearest 10 mm, and the
T500 time is reported to the nearest 0.1 s.
3.6.1.2 V-funnel test
The V-funnel test is used to assess the viscosity and filling ability of self-compacting
concrete with a maximum size aggregate of 20mm. A V shaped funnel see Figure (3.10)
is filled with fresh concrete and the time taken for the concrete to flow out of the funnel is
measured and recorded as the V-funnel flow time.
V-funnel, made to the dimensions (tolerance 1 mm), fitted with a quick release,
watertight gate at its base and supported so that the top of the funnel is horizontal. The Vfunnel shall be made from metal; the surfaces shall be smooth, and not be readily
attacked by cement paste or be liable to rusting. However container is needed to hold the
test sample and having a volume larger than the volume of the funnel and not less than 12
L.
37
CHAPTER 3
Clean the funnel and bottom gate, the dampen all the inside surface including the gate.
Then close the gate and pour the sample of concrete into the funnel, without any agitation
or rodding, then strike off the top with the straight edge so that the concrete is flush with
the top of the funnel. Place the container under the funnel in order to retain the concrete
to be passed. After a delay of (10 2) s from filling the funnel, open the gate and
measure the time tv, to 0,1 s, from opening the gate to when it is possible to see vertically
through the funnel into the container below for the first time. tv is the V-funnel flow time.
3.6.1.3 L-box test
The L-box test is used to assess the passing ability of self-compacting concrete to flow
through tight openings including spaces between reinforcing bars and other obstructions
without segregation or blocking. There are two variations; the two bar test and the three
bar test. The three bar test simulates more congested reinforcement.
The main concept of this test is to allow a measured volume of fresh concrete to flow
horizontally through the gaps between vertical, smooth reinforcing bars and the height of
the concrete beyond the reinforcement is measured.
L-box, have the general arrangement as shown in Figure (3.11) and the dimensions
(tolerance 1 mm) shown in Figure (3.12). The L-box shall be of rigid construction with
surfaces that are smooth, flat and not readily attacked by cement paste or be liable to
38
CHAPTER 3
rusting. The vertical hopper may be removable for ease of cleaning. With the gate closed,
the volume of the vertical hopper shall be (12,6 12,8) L when filled level with the top.
The assemblies holding the reinforcement bars shall have 2 smooth bars of 12 mm
diameter with a gap of 59 mm for the two bar test and 3 smooth bars of 12 mm diameter
with a gap of 41 mm for the three bar test. These assemblies shall be interchangeable and
locate the bars in the L -box so that they are vertical and equidistant across the width of
the box.
39
CHAPTER 3
Support the L-box on a level horizontal base and close the gate between the vertical and
horizontal sections. Pour the concrete from the container into the filling hopper of the Lbox and allow standing for (60 10) s. Record any segregation and then raise the gate so
that the concrete flows into the horizontal section of the box. When movement has
ceased, measure the vertical distance, at the end of the horizontal section of the L-box,
between the top of the concrete and the top of the horizontal section of the box at three
positions equally spaced across the width of the box. By difference with the height of the
horizontal section of the box, these three measurements are used to calculate the mean
depth of concrete as H2 mm. The same procedure is used to calculate the depth of
concrete immediately behind the gate as H1 mm. The passing ability PA is calculated
from the following equation.
=
2
1
40
CHAPTER 3
Cubes stored in water until the time of the test. Before the tests, the specimens were airdried for 10 to15 minutes and any loose sand grains or incrustations from the faces that
will be in contact with the bearing plat of the testing machine are removed. The cubes are
placed in the testing machine so that the load is applied to opposite sides as cast and not
to the top and bottom as cast. Therefore, the bearing faces of the specimen are
sufficiently plane as to require no capping. If there is appreciable curvature, the face is
grinded to plane surface because, much lower results than the true strength are obtained
by loading faces of the cube specimens that are not truly plane surfaces.
41
CHAPTER 3
The compressive strength machine in soil and material laboratory at the IUG was used for
determining the maximum compressive loads carried by concrete specimen cubes, as
shown in Figure (3.14).
The compressive strength of the specimen, comp (in MPa), is calculated by dividing the
maximum load carried by the cube specimen during the test by the cross sectional area of
the specimen.
comp =
The compressive strength was determined at different ages 7, 14, and 28 days. At least
three of these cubes were tested for each period the mean value of the specimens was
considered as the compressive strength of the experiment. The test program for
compressive strength of UHPSCC is outlined in Table (3.9):
Table 3.9: Test program for compressive strength
Number of days
7
14
28
3
3
3
42
CHAPTER 3
The splitting tensile strength of UHPSCC was measured based on ASTM C496(2004)
Standard test Method for Splitting Tensile Strength of Cylindrical Concrete Specimens.
This test often referred to as the split cylinder test, indirectly measures the tensile strength
of concrete by compressing a cylinder through a line load applied along its length.
The failure of concrete in tension is governed by micro-cracking, associated particularly
with the interfacial region between the aggregate particles and the cement, also called
interfacial transition zone (ITZ). The load applied (compressive force) on the cylindrical
concrete specimen induces tensile and shear stresses on the aggregate particles inside the
specimen, generating the bond failure between the aggregate particles and the cement
paste. Usually, splitting tensile strength test is used to evaluate the shear resistance
provided by concrete elements. However, the most important advantage is that, when
applying the splitting procedure, the tensile strengths are practically independent of either
the test specimen or of the test machine sizes, being only a function of the concrete
quality alone. Thus, much inconvenience is eliminated, particularly with respect to the
scale coefficient, which is involved in direct tensile tests. For this reason, this procedure
is considered to reproduce more exactly the real concrete tensile strength.
The tensile strength of concrete is most often is evaluated using a split cylinder test, in
which a cylindrical specimen is placed on its side and loaded in diametrical compression,
so to induce transverse tension. Practically, the load applied on the cylindrical concrete
specimen induces tensile stresses on the plane containing the load and relatively high
compressive stresses in the area immediately around it. When the cylinder is compressed
by the two plane-parallel faceplates, situated at two diametrically opposite points on the
cylinder surface then, along the diameter passing through the two points, as shown in
Figure (3.15), the major tensile stresses are developed which, at their limit, reach the
fracture strength value ASTM C496 indicates that the maximum fracture strength can be
calculated based on the following equation.
=
43
CHAPTER 3
Where: P is the fracture compression force acting along the cylinder, D is the cylinder
diameter; = 3.14, L is the cylinder length.
The load and stress distribution pattern across the cross section if it is assumed that the
load is concentrated at the tangent points then, over the cross section, only tensile stresses
would be developed. In practice, however, the load is distributed over a finite width
owing to material deformations. So, over the cross section, horizontal compressive
stresses are developed too, in the close vicinity of the contact point between the press
plates and the material. Since the compressive stresses only develop to a small depth in
the cross section, it may be assumed that the tensile stresses are distributed evenly along
the diameter where the splitting takes place, see Figure (3.16). This test can be completed
in a standard concrete compression testing machine, with only one special requirement:
the bearing plates that load the specimen. Split cylinder tests were conducted on 6 x 12
in. (150 x 300mm) cylinders, tensile stress in the cylinder and the maximum tensile stress
occur at the center of the cylinder.
Figure 3.15: Split cylinder test setup for cylinder 150 x 300mm
44
CHAPTER 3
All cylinder specimens were cast for testing at 28 days. Three of these cylinders were
tested for each period the mean values of the specimens were considered as split cylinder
strength of the experiment.
3.6.2.3 Flexural Test
The flexural strengths of concrete specimens are determined by the use of simple beam
with center point loading in accordance with (ASTM C293, 1994) as shown in figure
(3.17). The spacemen is a beam 100 x 100 x 500 mm. the mold is filled in one layer,
without any compacting or rodding, the beam casting and then immersing in water at
25C.
The cast beam specimens are tested turned on their sides with respect to their position as
molded. This should provide smooth, plane and parallel faces for loading if any loose
sand grains or incrustations are removed from the faces that will be in contact with the
bearing surfaces of the points of support and the load application. Because the flexural
strengths of the prisms are quickly affected by drying which produces skin tension, they
are tested immediately after they are removed from the curing basin as shown in Figure
(3.18).
45
CHAPTER 3
Figure 3.17: Diagrammatic view for flexure test of concrete by center-point loading
The pedestal on the base plate of the machine is centered directly below the center of the
upper spherical head, and the bearing plate and support edge assembly are placed on the
pedestal. The center loading device is attached to the spherical head. The test specimen is
turned on its side with respect to its position as molded and it is placed on the supports of
the testing device. This provides smooth, plane, and parallel faces for loading. The
longitudinal center line of the specimen is set directly above the midpoint of both
supports.
The center point loading device is adjusted so that its bearing edge is at exactly right
angles to the length of the beam and parallel to its top face as placed, with the center of
the bearing edge directly above the center line of the beam and at the center of the span
length. The load contacts with the surface of the specimen at the center. If full contact is
not obtained between the specimen and the load applying or the support blocks so that
there is a gap, the contact surfaces of the specimen are ground.
46
CHAPTER 3
The specimen is loaded continuously and without shock at until rupture occurs. Finally,
the maximum load indicated by the testing machine is recorded.
The flexural strength of the beam, Fr (in MPa), is calculated as follows:
=
3
22
Where: P = maximum applied load indicated by the testing machine, L = span length, B =
average width of specimen, at the point of fracture, D = average depth of specimen, at the
point of fracture).
The specimen beams tested after 28 days. At least three of these beams were tested for
each period and the mean values are determined.
3.6.2.4 Unit weight
In this research, the unit weight of the concrete cube specimen is the theoretical density.
The density is calculated by dividing the weight of each cube by the volume. The same
cube specimens which are used to determine the compressive strength was used to
determine the density and the tests were carried out according to ASTM C642, 2004.
47
CHAPTER 4
CHAPTER 4
TEST RESULTS AND
DISCUSSION
48
CHAPTER 4
Materials
Proportion
49
1.00
0.33
0.155
0.385
0.733
1.583
0.03
CHAPTER 4
Materials
Unit
Proportion
Kg/m
Kg/m3
Kg/m3
Kg/m3
Kg/m3
Kg/m3
Kg/m3
600
200
93
231
440
950
18
All mixtures were subjected to fresh and hardened tests in order to be classified as
UHPSCC, some mixing proportions were fixed and the other were varied such as the
silica fume per cement weight percentage and superplasticizer per cement weight
percentage, Table (4.3) summarizes the change in mixing proportion.
Table 4.3: Changing in mixtures proportions per cement weight
Mixtur
e#
Mix(1)
Mix(2)
Mix(3)
Mix(4)
Mix(5)
Mix(6)
Mix(7)
Mix(8)
Mix(9)
Mix(10)
Mix(11)
Mix(12)
Silica/C
10%
15.5%
20%
30%
10%
15.5%
20%
30%
10%
15.5%
20%
30%
Superplasti
cizer/C
1%
1%
1%
1%
2%
2%
2%
2%
3%
3%
3%
3%
W/C ratio
0.33
0.33
0.33
0.33
0.33
0.33
0.33
0.33
0.33
0.33
0.33
0.33
Quartz
Powder/C
36.6%
36.6%
36.6%
36.6%
36.6%
36.6%
36.6%
36.6%
36.6%
36.6%
36.6%
36.6%
Quartz /C
Basalt/C
69.84%
69.84%
69.84%
69.84%
69.84%
69.84%
69.84%
69.84%
69.84%
69.84%
69.84%
69.84%
150.79%
150.79%
150.79%
150.79%
150.79%
150.79%
150.79%
150.79%
150.79%
150.79%
150.79%
150.79%
50
CHAPTER 4
Slump flow(mm)
V-Funnel(Sec.)
L-Box(H2/H1)
Mixture
#
Result Classification Result Classification Result Classification
Mix(1)
Mix(2)
Mix(3)
Mix(4)
633
574
529
507
SF1
SF1
---
12.00
14.11
18.00
NA
VF2
VF2
---
0.76
0.75
0.61
0.53
PA2
PA2
---
Compressive
strength
(28)day(MPa)
Concrete
Classification
127.2
135.0
114.4
113.8
UHPSCC
UHPSCC
UHPC
UHPC
Compressive
strength
(28)day(MPa)
Concrete
Classification
119.3
138.5
115.8
114.3
UHPSCC
UHPSCC
UHPC
UHPC
Compressive
strength
(28)day(MPa)
Concrete
Classification
135.3
141.2
115.5
112.8
UHPSCC
UHPSCC
UHPC
UHPC
(2% Superplasticizer)
Slump flow(mm)
V-Funnel(Sec.)
L-Box(H2/H1)
Mixture
#
Result Classification Result Classification Result Classification
Mix(5)
Mix(6)
Mix(7)
Mix(8)
765
750
688
549
SF3
SF2
SF2
--
10.77
11.23
16.00
NA
VF2
VF2
---
0.75
0.76
0.73
0.70
PA2
PA2
PA2
PA2
(3% Superplasticizer)
Slump flow(mm)
V-Funnel(Sec.)
L-Box(H2/H1)
Mixture
#
Result Classification Result Classification Result Classification
Mix(9)
Mix(10)
Mix(11)
Mix(12)
769
758
723
590
SF3
SF2
SF2
SF1
9.82
10.36
15.2
21
VF2
VF2
---
0.77
0.79
0.72
0.71
51
PA2
PA2
PA2
PA2
CHAPTER 4
800
750
700
650
600
1%Superplasticizer
550
2%Superplasticizer
500
3%Superplasticizer
450
400
0
10
15
20
25
30
35
Figure 4.1: Effect of silica fume and superplasticizer on UHPSCC slump flow
52
CHAPTER 4
V-Funnel (Sec.)
20
15
1%Superplasticizer
10
2%Superplasticizer
3%Superplasticizer
0
5
10
15
20
25
30
35
Figure 4.2: Effect of silica fume and superplasticizer on UHPSCC V-Funnel time
53
CHAPTER 4
These results allow identifying the optimum percent of silica fume and superplasticizer
for a specific L- Box ratio.
54
CHAPTER 4
0.9
0.8
L-Box Ratio
0.7
0.6
1%Superplasticizer
0.5
2%Superplasticizer
0.4
3%Superplasticizer
0.3
0.2
0
10
15
20
25
30
35
Figure 4.3: Effect of silica fume and superplasticizer on UHPSCC L-Box test
55
CHAPTER 4
Table (4.5) shows the effect of silica fume and superplasticizer on the UHPSCC hardened
density.
Table 4.5: Mixtures mean density
Mixtur
e#
Mix(1)
Mix(2)
Mix(3)
Mix(4)
Mixtur
e#
Mix(5)
Mix(6)
Mix(7)
Mix(8)
Mixtur
e#
Mix(9)
Mix(10)
Mix(11)
Mix(12)
Superplasticizer/C = 1%
Density
Silica/C
Kg/m3
10%
2555
15.5%
2543
20%
2542
30%
2534
Superplasticizer/C = 2%
Silica/C
Density
Kg/m3
10%
2530
15.5%
2545
20%
2539
30%
2522
Superplasticizer/C = 3%
Silica/C
Density
Kg/m3
10%
2595
15.5%
2533
20%
2521
30%
2493
56
CHAPTER 4
2620
Superplasticizer
(1%(
2600
Density kg/m3
2580
Superplasticizer
(2%(
2560
Superplasticizer
(3%(
2540
2520
2500
2480
2460
2440
10
15.5
20
30
Figure (4.4) shows the effect of silica fume and superplasticizer on the UHPSCC density,
the results show that the density of concrete slightly decreases when increasing the silica
fume content, and also slightly decreases when the dosage of superplasticizer increases.
This can be justified according to the Pozzolanic reaction discussed in chapter 2 where
the rich gel of silica fume agglomerates between the grains of unhydrated cement and
produce a very dense and rigid structure.
4.7.2 Effect of silica fume and superplasticizer on UHPSCC compressive strength
Table (4.6) shows the effect of silica fume and superplasticizer on the UHPSCC
compressive strength after 28 days.
Mixtur
e#
Mix(1)
Mix(2)
Mix(3)
Mix(4)
Superplasticizer/C = 1%
Mean Compressive
Silica/C
Strength (MPa)
10%
127.2
15.5%
135
20%
114.4
30%
113.8
57
CHAPTER 4
Mixtur
e#
Mix(5)
Mix(6)
Mix(7)
Mix(8)
Mixtur
e#
Mix(9)
Mix(10)
Mix(11)
Mix(12)
Superplasticizer/C = 2%
Mean Compressive
Silica/C
Strength (MPa)
10%
119.3
15.5%
138.5
20%
115.8
30%
114.3
Superplasticizer/C = 3%
Mean Compressive
Silica/C
Strength (MPa)
10%
135.3
15.5%
141.2
20%
115.5
30%
112.8
145
Compressive Strength (MPa)
140
135
130
125
(1%Superplasticizer (
120
(2%Superplasticizer (
115
(3%Superplasticizer (
110
105
100
0
10
15
20
25
30
35
Figure 4.5: Effect of silica fume and superplasticizer on UHPSCC compressive strength
The results shown in Table (4.6) and Figure (4.5) demonstrate that it is possible to make
UHPSCC with different silica fume percent. For 10 %, 15.5%, 20%, 30% silica fume,
very high strength concrete with 135 MPa, 141 MPa, 116 MPa, 120 MPa respectively can
be achieved. A pronounced effect of the using silica fume was observed. The increase in
the silica fume content from 10% to 15.5% effectively increases the compressive strength
of concrete. But using silica fume from 20% to 30% decreases the compressive strength
58
CHAPTER 4
as shown in Figure (4.5). The maximum compressive strength of the concrete specimens
was achieved using 15.5 % silica fume replacement where a compressive strength up to
141 MPa, which met the target compressive strength for the UHPSCC, and met the
results obtained by (Arafa, et.al, 2010) study.
This can be explained according to what have been mentioned in EFNARC, that the silica
fume works in two levels, the pozzolanic reaction and the physical function. The
hydration of Portland cement produces many compounds; including calcium silicate
hydrates (CSH) and calcium hydroxide (CH). When silica fume is added to fresh
concrete, it chemically reacts with the CH to produce additional CSH which improve the
bond between the cement and the surface of the aggregate, more ever the silica fume
particle can fill the voids creates by free water in the matrix. This function is called
particle packing refines the microstructure of the concrete, thus creating a much denser
pore structure the benefit of this reacts is twofold; increasing compressive strength and
decreasing total pores volume (EFNARC, 2005).
But as mentioned in the previous figure it can be noticed that the EFNARC justification
can be applicable when the silica fume percent less than 20%, but when silica fume
percent reaches 30% the strength decreases, this can be explained that the silica fume can
react to a certain level, after that the silica fume did not participate in the hydration
reaction and remain inert in concrete as the weakest point.
Figure (4.6) shows the relationship between compressive strength of cube specimens and
dosage of silica fume, the following relation was derived.
Fc= 140.3e-0.00S
Where:
Fc = compressive strength of cube specimens in MPa.
S = percent of silica fume (10% S 30%)
59
CHAPTER 4
180
170
160
150
140
x0.007e-140.38
=y
0.3677= R
130
120
110
100
90
80
10
15
20
25
Silica Fume (%)
30
35
Table (4.7) and Figure (4.7) show the compressive strength results at several ages of the
concrete mix, as shown in Table (4.1) and Table (4.2).
Table 4.7: Summary of compressive strength test results for first UHPSCC mix
Age of cubes
(day)
7
14
28
No. of
specimens
3
3
3
Mean
compressive
strength (MPa)
101
126
141.2
60
Standard
deviation
3.56
2.99
4.1
CHAPTER 4
160
140
120
100
80
60
40
20
0
0
10
15
20
25
30
Figure 4.7: The variation of mean compressive strength with age for first UHPSCC mix
The results in Table (4.7) and Figure (4.7) shows that this mixture can achieve a mean
compressive strength of concrete specimens near 140 MPa at an age of 28 days. Where
the curing was done at 25 C by immersion in water without any heat treatment. The
standard deviation values for all concrete specimens at different ages were less than 4.1
MPa.
The full test results of all mixes are presented in Table (4.8) and Figure (4.8). The
average values and standard deviation were calculated for compressive strengths at 7, 14,
and 28 days.
Table 4.8: Summary of compressive strength test results for all mixes
Mixtur
e#
Silica/
C
Mix(1)
Mix(2)
Mix(3)
Mix(4)
Mix(5)
Mix(6)
Mix(7)
Mix(8)
Mix(9)
10%
15.5%
20%
30%
10%
15.5%
20%
30%
10%
Superpla
sticizer/
C
1%
1%
1%
1%
2%
2%
2%
2%
3%
Mean Compressive
Strength (MPa) -7d
Mean Compressive
Strength (MPa)-14d
Mean Compressive
Strength (MPa)-28d
91.5
96.2
82.2
86.8
85.8
99.2
81.2
82.2
95.5
109.6
111.9
92.8
101
98.7
119.3
97.2
94.8
116.1
127.2
135
114.4
113.8
119.3
138.5
115.8
114.3
135.3
61
CHAPTER 4
Mix(10)
Mix(11)
Mix(12)
15.5%
20%
30%
3%
3%
3%
101
83.7
81.5
126
95.7
97.7
141.2
115.5
112.8
160
140
(1Mix(
(2Mix(
120
(3Mix(
100
(4Mix(
(5Mix(
80
(6Mix(
(7Mix(
60
(8Mix(
40
(9Mix(
(10Mix(
20
(11Mix(
0
0
10
15
20
25
30
(12Mix(
Figure 4.8: Relation between the mean compressive strength and age for all mixes
ACI Committee 209, 2033 recommends the following expressions to predict the
compressive strength (fc) of Normal Strength Concrete (NSC) with strengths up 41 MPa
at any time
( ) =
+ 28
Where a = 4 (cement type I), = 0.85 (moist curing), fc28 = 28 days strength and t is the
age of concrete.
62
CHAPTER 4
The comparison of the ratios for compressive strengths at different ages of UHPSCC
concrete (fc)t (3,7,14, and 28 days) to the compressive strength of Normal Strength
Concrete (NSC), using the above mentioned equation are given in Table (4.9) and Figure
(4.9).
1
0.8
0.6
0.4
UHPSCC
0.2
NSC
0
3
14
28
Figure 4.9: Comparison of ratio of (fc)t /(fc )28 for UHPSCC and NSC at different ages
Table 4.9: Comparison of ratio of (fc)t /(fc )28 of UHPSCC with the prediction of ACI
Committee 209 of NSC
Age of cubes (day )
3
7
14
28
Figure (4.9) and Table (4.9 show that the average strength of specimens for UHPSCC
lower than the NSC at three days age, but it increases at seven days age. At 14 days age,
the strength achieved is about 88% of the 28 days strength. Because of the larger amount
of type I cement plus silica fume used in the UHPSCC mixtures along with a relatively
63
CHAPTER 4
low W/C ratio , the high percent of silica fume increases the Pozzolanic activity to form
more CSH gel of the concrete. This is similar to normal concrete strength.
A regression analysis was conducted with a 94.7 % confidence interval to fit a function to
the data presented in Figure (4.10). Approximating function is given as follow:
37.4 ()+ 5.874
(fc)t = ( )28
100
This equation accurately describes the compressive strength gain behavior of UHPSCC at
any time starting after 41 hours following the casting, (fc)t .This equation includes the
age of concrete, t, and the 28 days compressive strength fc28 in MPa.
200
Compressive Strength (MPa)
180
R = 0.947
160
140
120
100
80
60
40
20
0
0
10
15
20
25
30
Table (4.10) shows the splitting tensile strength test results for the twelve mixtures.
Figure (4.11) shows the effect of adding 10%, 15.5%, 20%, and 30% silica fume by
mass of cement- and 1%, 2%, and 3% superplasticizer on the UHPSCC splitting tensile
strength. It also shows that the mixtures suffer from losing its tensile strength when the
64
CHAPTER 4
silica fume percentage equal or above 20% with superplasticizer 1%, 2%, 3. This met
with the results obtained by (Farhang and Arash, 2008) in their study.
It can determined from Figure (4.10) the possible percentage of silica fume and
superplasticizer for a specific splitting tensile strength.
Mixture #
Silica/C
Mean Splitting
Strength (MPa)
Mix(1)
Mix(2)
Mix(3)
Mix(4)
10%
15.50%
20%
30%
7.1
7.5
7.2
6.9
Superplasticizer/C=2%
Mixture #
Silica/C
Mean Splitting
Strength (MPa)
Mix(5)
Mix(6)
Mix(7)
Mix(8)
10%
15.50%
20%
30%
6.9
7.6
7.3
7.1
Superplasticizer/C=3%
Mixture #
Silica/C
Mean Splitting
Strength (MPa)
Mix(9)
Mix(10)
Mix(11)
Mix(12)
10%
15.50%
20%
30%
7.6
8.3
7.8
7.4
65
CHAPTER 4
8.5
8
7.5
(1%Superplasticizer (
7
(2%Superplasticizer (
(3%Superplasticizer (
6.5
6
0
10
20
30
40
Figure 4.11: Effect of silica fume and superplasticizer on UHPSCC splitting strength
4.7.5 Splitting tensile strength Time relationship
Table (4.11) and Figure (4.12) show the splitting tensile strength results at several ages
for the initial prepared mix shown in Table (4.1) and Table (4.2). The average values,
standard deviation were calculated for splitting tensile strength at 7, 14, and 28 days.
It can be observed when using several superplasticizer contents that the optimum silica
content is between 15% to 15.5% by cement weight. This is due to the fact that the silica
content of 15% to 15.5% by cement weight is the optimum content at which an enough
amount of silica gel (calcium silicate hydrates (CSH) and calcium hydroxide (CH)) will
be produced. This amount of silica gel is enough to cover all cement particles and fill in
all porous, resulting in a higher strength. However, when silica content is less than 10%
with several superplasticier contents, the silica gel will not fill in all porous and will not
cover all reacted cement particles resulting weakness in strength. When the silica content
is higher than 20%, part of it will not react and remain as inert particles. This will weaken
the concrete compressive strength of the mixtures.
Table 4.11: Summary of splitting strength test results for first UHPSCC mix
Age of cubes
No. of
Mean
Standard
66
CHAPTER 4
(day)
specimens
7
14
28
3
3
3
compressive
strength (MPa)
6.6
7.2
8.3
deviation
1.02
0.56
0.75
9
Splitting strength (Mpa)
8
7
6
5
4
3
2
1
0
0
10
15
20
25
30
Figure 4.12: The variation of splitting strength with age for first UHPSCC mix
The results in Table (4.11) and Figure (4.12) showed that this mixture can achieve a
mean splitting tensile strength of concrete specimens near 8.3 MPa at an age of 28 days.
Curing was done at 25o C by immersion in water without heat treatment. The standard
deviation values for all concrete specimens at different ages were low.
At 7 and 14 days, the splitting cylinder strength achieved about 79 % and 87 % of the 28day respectively, as shown in Figure (4.13), because the higher content of silica fume of
20% increases the bond between the cement paste and the aggregate particles and reduces
the pores in cement paste, which usually tends to increase the early strength of concrete.
67
CHAPTER 4
9
8
100%
7
87%
6
5
79%
4
3
2
1
0
7
14
28
Figure 4.13: The ratio of fsp (t) to fsp (28days) with time for UHPSCC
Another series of tests were carried out to study the effect of basalt content on the
concrete cubes, cylinders, and beams by evaluating the fresh and hardened properties of
Ultra High Performance Self Compacting Concrete (UHPSCC). Three new mixes were
developed after choosing the best mixture from the twelve UHPSCC mixtures. Table
(4.2) and table (4.3) show the mixture proportions and one cubic meter components of
UHPSCC, hereby all test results of the new three mixes are presented in appendix (A).
All mixtures were subjected to fresh and hardened tests in order to be classified as
UHPSCC, some mixing proportions were fixed such as silica fume, quartz, and
superplasticizer and the Basalt content were varied, to study the effect of basalt content
on fresh and hardened concrete. The following Table (4.12) summarizes the change in
mixing proportion.
68
CHAPTER 4
Mixture #
Silica/C
Mix(10)
Mix(10-A)
Mix(10-B)
15.5%
15.5%
15.5%
Superplasticizer/
C
3%
3%
3%
Basalt content/C
160%
170%
150%
This section discusses the results obtained from the testing program. The results were
observed from the slump flow test and T500 test, V-funnel, L-box, unit weight,
compression test and indirect tensile tests. Table (4.13) shows the observed results.
Materials
Cement
Water
Silica fume
Silica fume per cement weight
Quartz powder(0-10)
Quartz
Basalt
Superplasticizer
Basalt per cement ratio
Superplasticizer per cement ratio
Unit
Mix
(10)
Mix (10A)
Mix (10B)
Kg/m3
Kg/m3
Kg/m3
%
Kg/m3
Kg/m3
Kg/m3
Kg/m3
%
%
600
200
93
15.5
231
440
950
18
160
3
580
200
89.9
15.5
231
440
986
17.4
170
3
620
200
96.1
15.5
231
440
930
18.6
150
3
758
5.35
10.36
0.79
2533
101
126.0
141.2
8.2
12.67
730
5.9
10.6
0.8
2555
96.4
117.5
133.8
8.18
13.13
763
5
8.6
0.8
2530
97.9
119.2
136.2
7.78
12.19
69
CHAPTER 4
Figure (4.14) shows the effect of adding 150,160 and 170% basalt aggregate by mass of
cement- on the UHPSCC fresh properties (slump flow). It shows that the mixtures suffer
from losing its flowability when the basalt percentage increases.
770
Slump Flow (mm)
760
750
740
730
720
710
150
160
170
Figure (4.15) shows the effect of adding 150,160, and 170% basalt aggregate by mass of
cement- on the UHPSCC fresh properties (V-Funnel test). It also shows that the mixtures
suffer from losing its viscosity when the basalt percentage increases.
12
V-Funnel (Sec)
10
8
6
4
2
0
150
160
170
Figure (4.16) describes the effect of adding 150,160, and 170% basalt aggregate by
mass of cement- on the UHPSCC hardened properties (compressive strength). It can be
70
CHAPTER 4
recognized that the optimum percent of basalt content is 160% which give us the highest
compression strength in the concrete different ages.
160
140
120
100
80
Days-7
60
Days-14
40
Days-28
20
0
150
160
170
Figure (4.17) describes the effect of adding 150,160 and 170% basalt aggregate by mass
of cement- on the UHPSCC hardened properties (splitting tensile strength). It shows that
the splitting tensile strength increases when the basalt amount increases
8.3
8.2
8.1
8
7.9
7.8
7.7
7.6
7.5
150
160
170
71
CHAPTER 4
Figure (4.18) shows the effect of adding 150,160 and 170% basalt aggregate by mass of
cement- on the UHPSCC flexural tensile strength. The result shows that increasing the
amount of basalt aggregate added to the UHPSCC increase the flexural and splitting
tensile strength.
13.4
13.2
13
12.8
12.6
12.4
12.2
12
11.8
11.6
150
160
170
From the previous figures it can be noticed that the optimized basalt content to be used to
produce UHPSCC is 160% by the cement mass, with 3% superplasticizer, 15.5% silica
fume and constant W/C ratio 0.33.
72
CHAPTER 5
CHAPTER 5
CONCLUSIONS AND
RECOMMENDATIONS
73
CHAPTER 5
5.2 Conclusions
5.2.1 Generals
Increasing silica fume percent from 10% to 15.5% and then to 20% leads to a
slight decrease in the slump flow and the filling ability of the UHPSCC, but
increasing silica fume doses from 20% to 30% largely reduce the slump flow and
74
CHAPTER 5
the filling ability of the mixtures and may affect the self compacting properties
which prevent achieving UHPSCC.
No influence was observed in the slump flow and filling ability of UHPSCC when
3% superplasticizer instead of 2% used for silica fume percent between 10% to
15.5%, so 2% of superplasticizer with 10% or 15.5% silica fume can be used to
gain the same filling ability as using 3% of superplasticizer.
Increasing silica fume percent from 10% to 30% results in increasing the Vfunnel time which results in decreasing the UHPSCC viscosity.
When silica fume percent equal or exceed 30% and superplasticizer varies from
1% to 2%, the concrete loses its self compactability, and become a normal
concrete.
Increasing silica fume percent results in decreasing the L-box ratio, and therefore
decreases the passing ability of the UHPSCC.
UHPSCC cannot be developed when using silica fume 20% and 1% of
superplasticizer.
The most UHPSCC passing ability can be developed and implemented by using
3% of superplasticizer with 15.5% silica fume, the optimum percentage.
In all mixtures there werent any noticeable segregation in the aggregate and there
was a homogenous concrete. Accordingly, in order to avoid any segregation the
W/C ratio has to be equal or less than 0.33.
Adding 150%,160%, and 170% basalt aggregate by cement mass- to the
UHPSCC, shows that the mixtures suffer from losing its flowability when the
basalt percentage increases, at 15.5% silica fume and 3%superplasticizer.
Adding 150%,160%, and 170% basalt aggregate, cement mass, to the UHPSCC
fresh properties, V-Funnel test, reflects that the mixtures suffer from losing its
viscosity when the basalt content increases, at 15.5% silica fume and 3%
superplasticizer.
When using a superplasticizing admixture with UHPSCC made with water
absorbing aggregates, such as basalt and quartz sand, adding 60 % of the
admixture to final stage of mixing consistently improves the properties of fresh
75
CHAPTER 5
and hardened concrete compared with the traditional practice of adding the
admixture to the mixing water.
5.2.2 Hardened properties
Because of a large amount of Type I cement plus silica fume used in the UHPC
concrete mixtures with a relatively low W/C ratio, the strength of the concretes
develops more rapidly at the first 7 days than predicted by the current
recommendation of ACI Committee 209 (1993a) for normal conventional
concrete. The subsequent rate of strength growth is greatly decreased and is
comparable to that predicted by the ACI method.
The densities of concrete decreases as silica fume content increases, while 2%,
and 3% superplasticizer dosage obtained.
It is possible to make UHPSCC with several silica fume contents. For 10 %,
15.5%, 20%, 30% silica fume, very high strength concrete with 135 MPa, 141
MPa, 116 MPa, 120 MPa respectively can be achieved. A pronounced effect of
using silica fume was observed. The increase in the silica fume content from 10%
to 15.5% effectively increases the compressive strength of concrete. Otherwise
using silica fume form 20% to 30% gives us low compressive strength.
The compressive strength increases as the superplasticizer increases. Results
indicate that the compressive strength of UHPSCC ranges from 135 to 142 MPa,
when the superplasticizer contents ranges from 1% to 3% while silica fume range
from 10% to 15.5%.
The approximating function Fc= 140.3e-0.00S was suggested to predict the
compressive strength of concrete using any silica fume percentage ranging from
10% to 30%.
37.4 ()+ 5.874
100
was suggested to
predict the compressive strength at any starting age after 41 hours of casting of
concrete mixes, where (t) means the age of concrete.
As the compressive strength increases the splitting cylinder strength also increases
at certain cases of contents for the UHPSCC and as known in the normal concrete.
76
CHAPTER 5
5.3 Recommendations
The following recommendations are proposed for further research.
5.3.1 The effect of Material
The effect of other concrete mix proportions such as ratio fine aggregate on the
mechanical properties of UHPSCC need to be studied.
The influences of cement type, aggregate shape and surface on the mechanical
property of UHPSCC need to be taken into consideration.
The effect of fibers (Steel, Carbon, propylene and Glass) and polymers (Epoxy,
SPR) addition on the mechanical properties of UHPSCC need to be taken into
consideration for further research.
The effect of using recycled aggregates on the fresh and hardened properties of
UHPSCC need to be investigated.
77
CHAPTER 5
Another superplasticizer and silica fume trade markets to be used to study the
fresh and hardened properties of UHPSCC.
5.3.2 Durability of UHPSCC
78
CHAPTER 5
Further testing and studies on short term mechanical properties of UHPSCC such as the
following, need to be carried out:
Drying Shrinkage and creep.
The stress strain behavior in compression.
The stress strain behavior in tension.
Static and dynamic modulus.
5.3.4 Using UHPSCC in the Rehabilitation Works
Further testing and studies needed to be carry out, to test the behavior of UHPSCC when
we use it as a repair material, and derive a proper equations when we use it to repair the
different deteriorated structural elements such as beams, columns, slabs, footings, shear
walls etc.
79
CHAPTER 6
REFERANCES
CHAPTER 6
REFERENCES
80
CHAPTER 6
REFERANCES
CHAPTER 6- REFERENCES
ACI 209R-92, 2003, "Prediction of creep, shrinkage, and temperature effect in concrete
structures",ACI Manual of Concrete Practice part 1.
ACI 548.6R-96, 2003,"Guide for the Use of Silica Fume in Concrete" ACI Manual of
Concrete Practice part 2.
ASTM C109, 2004, Standard Test Method for Compressive Strength of cube Concrete
Specimens, American Society for Testing and Materials Standard Practice C109,
Philadelphia, Pennsylvania.
ASTM C127, 2004, Standard Test Method for Specific gravity and absorption of coarse
aggregate, American Society for Testing and Materials Standard Practice C127,
Philadelphia, Pennsylvania.
ASTM C150, 2004, Standard specification of Portland cement American Society for
Testing and Materials Standard Practice C150, Philadelphia, Pennsylvania.
ASTM C28, 2004, Standard Test Method for Specific gravity and absorption of fine
aggregate, American Society for Testing and Materials Standard Practice C128,
Philadelphia, Pennsylvania.
ASTM C293, 1994, Standard Test Method for Flexural Strength of Concrete (Using
Simple Beam with center-Point Loading), American Society for Testing and Materials
Standard Practice C293, Philadelphia, Pennsylvania.
ASTM C496, 2004, Standard Test Method for Splitting Tensile Strength of Cylindrical
Concrete Specimens, American Society for Testing and Materials Standard Practice
C496, Philadelphia, Pennsylvania.
81
CHAPTER 6
REFERANCES
ASTM C566, 2004, Standard Test Method for Bulk density (" Unit weight") and Voids
in aggregate, American Society for Testing and Materials Standard Practice C566,
Philadelphia, Pennsylvania.
ASTM C642, 2004, Standard Test Method for density, absorption, and voids in
hardened concrete, American Society for Testing and Materials Standard Practice
C642, Philadelphia, Pennsylvania.
El-Dieb, A, 2009, Mechanical, durability and microstructural characteristics of ultrahigh-strength self-compacting concrete incorporating steel fibers, Materials and Design
30 (2009) 42864292, United Arab Emirates University.
Farhang, F and Arash, S, 2008, Properties of High Performance Self Compacting
Concrete In Fresh and Hardened State, The 4th National Conference on Civil
Engineering, University of Tehran.
82
CHAPTER 6
REFERANCES
Jianxin, M and Jorg, D, 2002, Ultra High Performance Self Compacting Concrete,
First Edition, Prentice Hall.
Kronlof, A, 1994, Effect of Very Fine Aggregate on Concrete Strength, Materials and
Structures , Vol. 27, pp. 15-25.
Mindess, S, Young, J and Darwin, D, 2002, Concrete, Second Edition, Prentice Hall.
Murali, T and Kandasamy, S, 2009, Mix Proportioning of High Performance SelfCompacting Concrete using Response Surface Methodology, The Open Civil
Engineering Journal, 2009, Journal of Civil Engineering (IEB).
83
CHAPTER 6
REFERANCES
Okamura, H and Ozawa, K, 1995, Mix design for self compacting concrete, Concrete
Library of JSCE.
Sekhar, T and Rao, P, 2008, Relationship between Compressive, Split Tensile, Flexural
Strength of Self Compacted Concrete,International Journal of Mechanics and Solids.
The European Guidelines for Self Compacting Concrete, 2005, Production and Use,
bibm, CEMBUREAU, EFCA, EFNARC, ERMCO.
Xie, Y, Liu, B, Yin, J and Zhou, S, 2002, Optimum mix parameters of high-strength
self-compacting concrete with ultrapulverized fly ash, Cement and Concrete Research.
Young, F and Menashi, J, 1993, "Teaching the Materials Science, Engineering, and
Field Aspects of Concrete Part 1.
84
CHAPTER 7
Appendixes
CHAPTER 7
APPENDIXES
85
CHAPTER 7
Appendixes
CHAPTER 7- APPENDIXES
-
APPENDIX I
APPENDIX II
APPENDIX III
: Results
: Sika Fume
: Visco crete
86
CHAPTER 7
APPENDIX I
Appendixes
: Results
87
CHAPTER 7
Appendixes
88
CHAPTER 7
APPENDIX II
Appendixes
: Sika Fume
89
Sika -Fume
Construction
Description
Uses
Characteristics /
Advantages
Storage Conditions /
Shelf life
When stored in unopened sealed bags, the products effectivity will last for
at least one (1) year.
1.
2.
3.
4.
5.
Technical Data
Form
Agglomerated particles
Appearance / Colour
Grey
Specific Gravity
2.20 (approximately)
Chloride Content
Nil
Dosage
Suitability
Packaging
20 kg/bag
n Sika-Fume may have some fine powder associated with agglomerated particles
n Wearing of dust mask may therefore be advisable when pouring the product
into the mixer.
n Under relevant health and safety codes, Sika-Fume is classified as non-toxic.
The information, and, in particular, the recommendations relating to the application and end-use of Sika
products, are given in good faith based on Sikas current knowledge and experience of the products when
properly stored, handled and applied under normal conditions in accordance with Sikas recommendations.
In practice, the differences in materials, substrates and actual site conditions are such that no warranty
in respect of merchantability or of fitness for a particular purpose, nor any liability arising out of any legal
relationship whatsoever, can be inferred either from this information, or from any written recommendations,
or from any other advice offered. The user of the product must test the products suitability for the intended
application and purpose. Sika reserves the right to change the properties of its products. The proprietary
rights of third parties must be observed. All orders are accepted subject to our current terms of sale and
delivery. Users must always refer to the most recent issue of the local Product Data Sheet for the product
concerned, copies of which will be supplied on request.
Construction
Legal Notice
Tel.no.
: 800 1818
Fax. no
: 806 2378
www.sika.com.ph
Sika Fume 2/2
CHAPTER 7
APPENDIX III
Appendixes
: Visco crete
90
Product
Description
Sika ViscoCrete -10 is a fourth generation super plasticizer for concrete and
mortar. It meets the requirements for super plasticizers according to SIA 162 (1989)
prEN 934-2 and ASTM -C-494 Types G and F .
Uses
Sika ViscoCrete -10 facilitates extreme water reduction, excellent owability at the
same time optimal cohesion and hightest self compacting behaviour.
Construction
Characteristics /
Advantages
Sika ViscoCrete -10 does not contain chloride or other ingredients promoting
corrosion of steel reinforcement. It is therefore suitable to be used without any
restrictions for reinforced and prestressed concrete production.
Technical Data
Base
Appearance / Colour
Turbid liquid
Density
Packaging
5 and 20 kg pails
200 kg drums
Bulk Tanks packing available upon request
Application Details
Construction
For owing and self compaction concrete (S.C.C.) 0.3 2 % litre by weight of
cement.
Addition
Sika ViscoCrete -10 is added to the gauging water or simultaneously with it poured
into the concrete mixer. For optimum utilisation of the high water reduction we
recommend through mixing at a minimal wet mixing time of 60 seconds.
The addion of the remaining gauging water to ne tune concrete consistency
may only be started after 2/3 of wet mixing time, to avoid surplus water in the
concrete.
Concrete Placing
With the use of Sika ViscoCrete -10 concrete of highest quality is being produced.
The standard rules of good concreting practice (production as well as placing) must
Compatibility
- Sika Pump
- Sikafume
- SikaRapid
- Sika Retader
Pre-trials trials are recommended if combinations with the above products are being
made. Please consult our technical service.
Important Flowing
concrete S.C.C
Sika ViscoCrete -10 is also used to produce owing and self compacting concrete
(S.C.C) For these, special mix designs are required, contact out Tec hnical Service
devision.
Safety Instructions
Safety Precautions
Ecology
Transport
Non-hazardous
Toxicity
Legal notes
The information, and, in particular, the recommendations relating to the application and end -use of
Sika products, are given in good faith based on Sika's current knowledge and experience of the products
when properly stored, handled and applied under normal conditions in accordance with
Sikas recommendations. In practice, the differences in materials, s ubstrates and actual site conditions are
such that no warranty in respect of merchantability or of tness for a particular purpose, nor any liability
arising out of any legal relationship whatsoever, can be inferred either from this information, or from a ny
written recommendations, or from any other advice offered. The user of the product must test the products
suitability for the intended application and purpose. Sika reserves the right to change the properties of its
products. The proprietary rights of third parties must be observed. All orders are accepted subject to our
current terms of sale and delivery. Users must always refer to the most recent issue of the local Product
Data Sheet for the product concerned, copies of which will be supplied on request.
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