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SECOND PUC PREPARATORY EXAMINATION -2,016
Max Marks:70
Time: 3-15 hours
No.of Pages: O2
General Instructions:
cHEMISTRY
(a+)
i] The questlon paper has four pafis A, B, C, and D. All_ the parts are compulsory
question
iit p"rt.A carriei tb *u.ir, Each question carries one mark. Part-B caries 10 marks , Each
35
carries
Part-D
carries two marks. part-'C canies 15 marks. Each question carries three marks.
marks . Each question caries five marks.
iii] write balanced chemical equations and draw diagrams wherever necessary.
iv]us" logtables and simple calculators if necessary. (Use of scientifrc calculators are not allowed)
k)
l0x1:10
mark.
one
'
2)
What is the name of the solution which distills without chanle in composition
withtemPerature?
Why is common salt added to water used for boiling'eggs to get hard boiled
g.
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PART-A
AnswerAll the questions in one word or in a sentence.Each q''estion carries
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2f
6)
explossively?
IdentiSz the reducing agent in the following reactions
3MnO, + 4AL -+ 3Mn + 2AlrO"
aw
ik
of Ag/Cu?
A reaction is 50% complete in 4 hours andl5oh complets in 8 hours. What is
the order of the reaction ?
Give reason. A lump of coal burns at moderate rate in air, which coal dust burns
g
5
lo
eggs?
7)
8)
9)
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di
Why does Ammonia NH. form hydrogen bond but PH" does not ?
Complete the reaction: CH3CH2CH: CHr+HBr-lgrs41dsJ,
CHO.
Write the IUPAC name of Oproducts obtained r,vhen sucrose is subjected to hydrolysis.
10)
.Name
PART -B
Answer any FIVE of the following questions,Each question carries 2 marks.
tr
5x2:10
Gold with atomic radius 0.144 nm crystalises in fcc form. What is the edge
length of the unit cell?
The standard electrode potential for Daniel cell is 1.1V. Calculate the standard
free energy change for the reaction. Zt'\s1+ Cu2tuq) -> Zn2\uq1+ Cu(s)
13) Explain psuedo first order reaction rvith an example.
14) What is lanthanoid contraction? Mention one of its consequences.
15) Name the reagents used in the follor,ving reactions.
i) Oxidation of Primary alcohol to aldehyde.
ii) Bromination of phenol to2,4,6 tribromo phenol.
16) Explain Gattermann-Koch reaction with equation .
17) What are food preservatives? Give an example.
18) Give an example for each ofthe follorving.
i) Non-narcotic analgesic ii) Narcdtic analgesic
PART-C
Answer any FIVE of the fotlowing questions.Each question carries 3 marks .
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Give reasons. For More Question Papers Visit i)HF acid is stored in wax coated glass bottles.
ii) DF2 is called oxygen deflouride not flourine oxide.
iii) ClF3 exists but FCl, does not.
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g.
21)
i) RCOCI--Td-E
sol
RCHO
,RCH,R
--?
i)carbylaminereaction ii)Hofinann'sbromamidereaction.
36)
37)
(3+2)