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SECOND PUC PREPARATORY EXAMINATION -2,016
Max Marks:70
Time: 3-15 hours
No.of Pages: O2
General Instructions:

cHEMISTRY

(a+)

Total No.of Ques.:37

i] The questlon paper has four pafis A, B, C, and D. All_ the parts are compulsory
question
iit p"rt.A carriei tb *u.ir, Each question carries one mark. Part-B caries 10 marks , Each
35
carries
Part-D
carries two marks. part-'C canies 15 marks. Each question carries three marks.
marks . Each question caries five marks.
iii] write balanced chemical equations and draw diagrams wherever necessary.
iv]us" logtables and simple calculators if necessary. (Use of scientifrc calculators are not allowed)

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mark.

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2)

What is the name of the solution which distills without chanle in composition
withtemPerature?
Why is common salt added to water used for boiling'eggs to get hard boiled

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PART-A
AnswerAll the questions in one word or in a sentence.Each q''estion carries

One Coulomb of electrical charge is passed through solutions ofAgNO. and


CuSOo connected in series using platinum electrode. What is the mass ratio

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6)

explossively?
IdentiSz the reducing agent in the following reactions
3MnO, + 4AL -+ 3Mn + 2AlrO"

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of Ag/Cu?
A reaction is 50% complete in 4 hours andl5oh complets in 8 hours. What is
the order of the reaction ?
Give reason. A lump of coal burns at moderate rate in air, which coal dust burns

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eggs?

7)
8)
9)

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Why does Ammonia NH. form hydrogen bond but PH" does not ?
Complete the reaction: CH3CH2CH: CHr+HBr-lgrs41dsJ,
CHO.
Write the IUPAC name of Oproducts obtained r,vhen sucrose is subjected to hydrolysis.
10)
.Name
PART -B
Answer any FIVE of the following questions,Each question carries 2 marks.

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Gold with atomic radius 0.144 nm crystalises in fcc form. What is the edge
length of the unit cell?
The standard electrode potential for Daniel cell is 1.1V. Calculate the standard
free energy change for the reaction. Zt'\s1+ Cu2tuq) -> Zn2\uq1+ Cu(s)
13) Explain psuedo first order reaction rvith an example.
14) What is lanthanoid contraction? Mention one of its consequences.
15) Name the reagents used in the follor,ving reactions.
i) Oxidation of Primary alcohol to aldehyde.
ii) Bromination of phenol to2,4,6 tribromo phenol.
16) Explain Gattermann-Koch reaction with equation .
17) What are food preservatives? Give an example.
18) Give an example for each ofthe follorving.
i) Non-narcotic analgesic ii) Narcdtic analgesic
PART-C
Answer any FIVE of the fotlowing questions.Each question carries 3 marks .

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Write the reactions occuring in different zones in the blast furnace during the
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manufacture oflron from heamatite ore'

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22)

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Complete the foliowing reactions and write the balanced equations.


i)KCIO3
ii)SO2+O2 \,',o,
iii) C,rHrrD,,_c:fldg*

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Give reasons. For More Question Papers Visit i)HF acid is stored in wax coated glass bottles.
ii) DF2 is called oxygen deflouride not flourine oxide.
iii) ClF3 exists but FCl, does not.

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How is potassium dichrornats prepared from chromite ore? Write dquations .


24) a] Why do transitron elements form compiex compounds ?
b] Name the element which shows highest oxidation state in 3d elements .
state any three postulates of werner's theory of coordination compounds .
"2r)
26) using vBT account for geometry hybridisation and magnetic properry of
I coG{H3)6]3*.
PART:D
Answer any THREE of the following questions.Each question carries 5 marks .
Jx5:15
alcalculate the packing efficiency in BCC crystal lattice .
b] Mention any trvo differences between Schotty and Frenkel defects .(3+2)
28) a] The vapour pressure ofpure benzene at ceftain temperature is 0.850bar. A
non volatile, non-electrolyte solid weighing 0.5g rvhen added to 39.0 g
of
benzene (molar mass 78g mol-l) The vapour pressure of the solution
then is
0.845bar. Calculate molar mass of the sorid substance .
b] State Henry's law and mention one application of it .
(3+2)
29) al Describe the construction and working of SHE.
bl rhe value_ of )"0* forHCr, Nacl and CH"cooNa are 426.1, 126.5 and
91.0f1-rcm2mol-l iespectively. calculate ion of acetic acid.
(3+2)
30) a] Derive an expression for the rate constant of a zero order reaction .
bl Calculat: tlr. half life period of a first order reaction having the constant
of2xl0-3s-1.
(3+2)
31) alMention any three diff'erences betw,een hyophillic andhyophobic solutions
b] Explain homogeneous catalysis r,vith an example.
G+2)
Answer any FOUR of the following . Each question carries
five rnarks .4xS:20
32) al Explain with equations SN, mechanism forthe hydrolysis oftert. butyl
bromide into tert. butyl alcohol.
b]complete the following reaction and name the reaction .
(1+4)
2.C6HsCl + 2Na dry ether
,
33)
a] How is phenol manufactured f,y cumene's process.
Give the chemical
equations.
(.2+3)
b] Explain the mechanism of acid catalysed dehydration
of ethanol to ethene .
34) a]Name the follgwing reactions .

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i) RCOCI--Td-E

sol

iii) RCOR Zn-HgHCt


3 5)

RCHO

,RCH,R

ii) RCH2COOH XrlredP .R-qHCOOH

b] Explain Cannizaro's reaction with equation.


al Explain the follor,ving reactions with equations

--?

i)carbylaminereaction ii)Hofinann'sbromamidereaction.

36)

37)

(3+2)

bl write the IUPAC name ofthe following compound (cH")3cNH2.


a] Draw the structure of Lactose
b] Write theZwitter ion form of an o_amino acid.
cl Mention the name of the disease caused by the deficiency ofthe
following
vitamins i) VitaminA ii) Vitamin B.
a]write the monomers used for getting the follor.ving polymers
i)Poiyvinyl chloride ii) Teflon iii) Baketite

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