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sigma-aldrich.com
Morpholine
Product Number
Brand
:
:
394467
Aldrich
Supplier
Telephone
Fax
Emergency Phone # (For
both supplier and
manufacturer)
Preparation Information
:
:
:
Sigma-Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103
USA
+1 800-325-5832
+1 800-325-5052
(314) 776-6555
Sigma-Aldrich Corporation
Product Safety - Americas Region
1-800-521-8956
2. HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Flammable liquid, Target Organ Effect, Harmful by ingestion., Toxic by skin absorption, Corrosive
Target Organs
Liver, Kidney
GHS Classification
Flammable liquids (Category 3)
Acute toxicity, Oral (Category 4)
Acute toxicity, Dermal (Category 3)
Skin corrosion (Category 1B)
Serious eye damage (Category 1)
GHS Label elements, including precautionary statements
Pictogram
Signal word
Hazard statement(s)
H226
H302
H311
H314
Danger
Flammable liquid and vapour.
Harmful if swallowed.
Toxic in contact with skin.
Causes severe skin burns and eye damage.
Precautionary statement(s)
P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310
Immediately call a POISON CENTER or doctor/ physician.
HMIS Classification
Health hazard:
Aldrich - 394467
3
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*
3
0
3
3
0
May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous
membranes and upper respiratory tract.
Toxic if absorbed through skin. Causes skin burns.
Causes eye burns.
Harmful if swallowed.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms
Tetrahydro-1,4-oxazine
Formula
Molecular Weight
:
:
C4H9NO
87.12 g/mol
Component
Morpholine
CAS-No.
EC-No.
Index-No.
Concentration
110-91-8
203-815-1
613-028-00-9
Aldrich - 394467
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Components
CAS-No.
Value
Control
parameters
20 ppm
Basis
Morpholine
110-91-8
TWA
Remarks
Upper Respiratory Tract irritation Eye damage Not classifiable as a human carcinogen Danger of
cutaneous absorption
TWA
20 ppm
70 mg/m3
STEL
30 ppm
105 mg/m3
Skin notation
Skin notation
TWA
20 ppm
USA. Occupational Exposure Limits (OSHA) - Table Z-1
70 mg/m3
Limits for Air Contaminants
Skin designation The value in mg/m3 is approximate.
TWA
20 ppm
70 mg/m3
Potential for dermal absorption
ST
30 ppm
105 mg/m3
Potential for dermal absorption
Aldrich - 394467
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liquid
Colour
colourless
Safety data
pH
Melting
point/freezing point
Boiling point
Flash point
Ignition temperature
310 C (590 F)
Auto-ignition
temperature
no data available
1.8 %(V)
10.8 %(V)
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Vapour pressure
Density
Water solubility
completely miscible
Partition coefficient:
n-octanol/water
Relative vapour
density
3.01
- (Air = 1.0)
Odour
unpleasant
Odour Threshold
no data available
Evapouration rate
no data available
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IARC:
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
Teratogenicity
no data available
May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous
membranes and upper respiratory tract.
Harmful if swallowed.
Toxic if absorbed through skin. Causes skin burns.
Causes eye burns.
Toxicity to daphnia
and other aquatic
invertebrates
Toxicity to algae
Aldrich - 394467
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Packing group: I
Packing group: I
Packing group: I
CAS-No.
110-91-8
Revision Date
1993-04-24
CAS-No.
110-91-8
Revision Date
1993-04-24
CAS-No.
Revision Date
Page 7 of 8
Morpholine
110-91-8
1993-04-24
Aldrich - 394467
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