PROPOSAL

FOR
OIL-IN-WATER ANALYSERS

Prepared for:
Prepared by:
Rev

Date

P. Ravikumar, Global Process Systems Sdn Bhd

Azlan Yahya
Detail of Revision
st

Prep

CHK

14/07/12

1 issue

AAH

AY

31/07/12

Inline Probe

AAH

AY

14/08/12

Freight Charges and Insurance

AAH

AY

16/08/12

Final

AAH

AY

EDARAN MESRA SDN BHD

No. 12-1, Jalan Suria Puchong 6
Pusat Perdagangan Suria Puchong (Puchong Gateway)
47110 Puchong
SELANGOR, MALAYSIA

TABLE OF CONTENTS
1 MANAGEMENT OVERVIEW ....................................................................................3
1.1 EX-100 Side Stream Analyzers. .........................................................................3
2 TECHNICAL BRIEF ..................................................................................................4
2.1 The principle of measurement FLUORESCENCE ..........................................4
2.2 Key Features of the OIW-EX Products ..............................................................5
3 TECHNICAL SPECIFICATIONS AND DRAWINGS .................................................7
3.1 Technical Specifications - Fluorescence ............................................................7
TECHNICAL DRAWING ...........................................................................................10
Mechanical Drawings Side Stream ........................................................................10
4 COMMERCIAL OFFER ..........................................................................................13
5 ADDITIONAL INFORMATION ................................................................................15
5.1 Manufacturer & Origin ......................................................................................15
5.2 Commissioning And Start-Up Spares ..............................................................15
5.3 Special Tools ....................................................................................................15
6 PARTIAL REFERENCE LIST .................................................................................16
7 TESTIMONIALS......................................................................................................17
8 ATTACHMENTS .....................................................................................................19

Page 2 of 21

1 MANAGEMENT OVERVIEW

Having examined the data sheets applicable to the oil in water analyzers, Advanced Sensors
propose the use of its EX-100 / 1000 model. This unit is a side stream analyzer that uses
fluorescence measurement for the oil in water ppm.
Where provision of the units in the format of in-line probes is deemed essential, then this can
be accommodated using the in-line probe version of our analyzers.
Advanced Sensors has chosen this solution as fluorescence is the best measurement
technique for Oil in Water PPM calculation.

1.1

EX-100 SIDE STREAM ANALYZERS.

The Side Stream analyzers (EX-100/1000) are very suited to end of process monitoring that is,
measurement of produced water immediately prior to discharge or re-injection. The side stream
analyzers take a feed from a main source and provide a continuous ppm value (using
fluorescence). The output of the analyzer can be back in to the process or to a drain.
EX-100 / 1000 has the following benefits:
1) There is NO regular maintenance required and
2) In addition to the continuous on-line readings, samples can be taken periodically by closing the
valve, homogenising the sample (using the ultrasonics) and taking a highly accurate uniform
reading. This is an automatic process configured to meet the customers requirements.

Page 3 of 21

The measurement technique incorporated is laser induced fluorescenc

head and inline probe is a patented combined Optical and Ultrasonic

2 TECHNICAL BRIEF

stream versions, the EX100 and EX1000, the water passes through

(300mL), within the chamber there is a small sapphire window used

larger sapphire window for viewing the inside of the chamber.

2.1 THE PRINCIPLE OF MEASUREMENT FLUORESCENCE

The laser passes through the smaller sapphire window to excite

fluorescent properties are captured via Optical fibre light guides and take

"#!$%&'()*!+'*&,-!)#.!%/$&$!01*&'%*',-!&12,!345678!&/,!$%&'()
$#!&/,!:);,*,#<&/!%-$%,-&',9!'#!&/,!:)&,-=!

"#.!)#!$%&'()*!>?!9%,(&-$0,&,-!3+$-!@ABCCC!DEFG7!!

Laser induced fluorescence is the most accurate way to provide o

measurement, as it uses a set narrow excitation wavelength which is hi

strong fluorescence.

The digital camera and optics used for the microscopy technique are
sapphire window, ensuring that they remain clean and provide accurate
!

2.2 KEY FEATURES OF THE OIW-EX PRODUCTS

!
Page 4 of 21

The measurement technique incorporated is laser-induced fluorescence. The transducer sensor

head and inline probe is a patented combined Optical and Ultrasonic component. In the sidestream versions, the EX100 and EX1000, the water passes through a measurement chamber
(300mL), within the chamber there is a small sapphire window used for measurement and a
larger sapphire window for viewing the inside of the chamber.
The laser passes through the smaller sapphire window to excite the water sample, the
fluorescent properties are captured via Optical fibre light guides and taken to:

An optical filter and photo multiplier tube (PMT), the optical filter selected depends

Page 4 of 21

on the wavelength properties in the water.

And an optical UV spectrometer (for EX1000 ONLY)

Laser induced fluorescence is the most accurate way to provide on-line oil in water PPM
measurement, as it uses a set narrow excitation wavelength which is highly effective in providing
strong fluorescence.
The digital camera and optics used for the microscopy technique are also housed behind the
sapphire window, ensuring that they remain clean and provide accurate results.

2.2 KEY FEATURES OF THE OIW-EX PRODUCTS

Maintenance Free
Using ultrasonic technology the OIW-EX products provide a consistent reliable measurement
environment negating the need for flow mechanisms, mechanical mixers, chemical additives or
human intervention. The units dynamic self-cleaning capabilities eradicate the need for
maintenance. The ultrasonic functions for auto-cleaning the sapphire windows ensure that
measurements do not deteriorate. Periodic homogenization of the sample allows correction for
oil droplet size variation.

Pressure Tolerant
The EX100 / EX1000 are designed to be flow and pressure tolerant.
The large pipe work on the EX100 and EX1000 is not susceptible to slugging or clogging and the
measure chamber is automatically cleaned ultrasonically.

Wide Range of Oil Types

The EX100 / 1000 can store thousands of different oil type characteristics for measurement and
the optics are designed to be tolerant to various oil types. The EX-1000s spectrometer capability
ensures oil type variation can be accurately monitored and accommodated.

Enhanced Measurement Range

The OIW-EX products can be configured to operate over your desired range: from extremely low
oil concentrations (ppb) to 20,000ppm (and steps in between). So whether you want 0-10, 0-100,
0-1000 or 0-10,000, the EX series will work for you. Measured values are recorded every second
in the Data Logs and displayed graphically and numerically on the instruments display.
Particle size information in the range of 0-400 microns is provided for solids, oil and gas.

Page 5 of 21

Data Logging
The operating system is built on the globally recognized Windows operating system, offering a
familiar environment for fast and easy access. The EX100/1000 captures and stores all
measurement every second and can store greater than 10 years of logs. They are stored daily as
Microsoft Excels files. The data logs contain configuration information, measurement of oil
content and temperature.

Easy Installation
The side-stream EX100/1000 has been designed for ease of installation. The unit is delivered
complete, mounted on a stand (316L stainless) fitted with a flow valve and ready to go.
Take any of the analyzers out of their delivery container, wire the mains power, plumb and turn
on, the analyzers will measure immediately. The EX100/1000 are EX d rated and do not require
purged air.

EX1000 with Spectrometer

The Spectrometer is invaluable when the analysis of the water composition is required.
One of the most challenging aspects of measuring oil in water is when the oil present in the water
changes in composition.

Other oil in water analyzers that have attempted to address this

challenge, use a manual interface that will ask the operator to select the oil type that you wish to
measure, this is nearly an impossible task, as they cannot supply the tools to identify which oil is
currently present in the water.
The EX1000 has an inbuilt spectrometer that takes the optical fingerprint of the oil. Should the oil
type change, the analyzer will automatically detect the change and select the appropriate
calibration file to provide consistently accurate measurement. This feature is unique to Advanced
Sensors analyzers.
The Spectrometer logs can be examined should an anomaly occur. By examining the spectra
logs before, during and after an anomaly, the nature and cause of the anomaly can be
determined.
The online spectrometer can also be used to detect changes in produced water composition,
which is useful in selecting process chemical and optimizing the chemical dosage.

Spectrometer Specifications

Page 6 of 21

Integration time
Measurement range
Dynamic range
Sensitivity
Signal: Noise
Dark noise:
Resolution:
Stray light:

1 ms - 10 seconds
475-1025 nm
8
2 x 10
-17
3 x 10 watts @ 1-second integration
250:1 (at full signal)
50 (RMS)
1.5 nm
< 0.05% at 600 nm

3 TECHNICAL SPECIFICATIONS AND DRAWINGS

3.1

TECHNICAL SPECIFICATIONS - FLUORESCENCE

Measurement Performance

Side Stream

In-Line Probe

Measurement principle

UV Fluorescence

UV Fluorescence

Range (ppm)

0-3,000, optional 0-20,000

0-3,000, optional 0-20,000

* User may select any desired measurement from 0 to 10ppb, to 0-20,000ppm

Accuracy

1% of measurement range

1% of measurement range

Repeatability

> 99%

> 99%

Response Time

< 1 Second, continuous results

< 1 Second, continuous results

Operating Conditions

Side Stream

In-Line Probe

Process Temperature

0C to 100C (option to 180C)

0C to 100C (option to 180C)

Process Pressure

0-35barg (design pressure 180 barg)

0-35barg (design pressure 180 barg)

Process Flow

0-25l/min (optional 0-1000l/min)

up to 10m/s

Operational Ambient Temperature

-20C to 60C

-20C to 60C

Cleaning

Ultrasonic (automatic)

Ultrasonic (automatic)

Utilities

Side Stream

In-Line Probe

Power Supply

110 or 230 VAC

110 or 230 VAC

Power Frequency

50 or 60 Hz

50 or 60 Hz

Power Consumption

60W Normal, 300W Peak

60W Normal, 300W Peak

Instrument Air

5-8bar (for pneumatic valve)

not required

Certification

Side Stream

In-Line Probe

Ingress Protection

IP66

IP66 (probe sensor IP68)

Page 7 of 21

Enclosure Material

Aluminium (316SS optional)

Aluminium (316SS optional)

1 Div 1

Purged air not required

Purged air not required

Weight & Dimensions

Side Stream

In-Line Probe

Weight

76.9kg+ inc. stand, valve and chamber

76.9kg+ inc. stand, valve and chamber

Footprint

600W x 640D mm

600W x 640D mm

Clear Space

500mm front and rear

500mm front and rear

Height

1.12m typical (optional variants)

1.12m typical (optional variants)

Communications

Side Stream

In-Line Probe

4-20 mA

Standard (passive)

Standard (passive)

HART

optional

optional

Modbus (over HART)

optional

optional

Ethernet

standard

standard

wireless (Wi-Fi)

optional

optional

2-wire ADSL

standard

standard

Remote Access

VNC, Master Remote Manager

VNC, Master Remote Manager

Internal Data Storage

>10 years

>10 years

Security

Multiple level password protection

Multiple level password protection

Additional Information

Side Stream

In-Line Probe

Hot insertion/extraction

Not applicable

optional

Flange Fitting

1" ANSI standard, options available

2" ANSI standard

316SS (option of Hastelloy, Inconel, CR25,

316SS (option of Hastelloy, Inconel, CR25, CR22, Titanium,

Wetted Parts

CR22, Titanium, Monel)

Monel)

Sample take off point

As standard integral to analyzer

Not applicable

Viewing Window

As standard

Not applicable

Sample Conditioning

Side Stream

In-Line Probe

Homogenisation

Ultrasonic

None

Gas Removal

Not Required

Not Required

Solids Removal

Not Required

Not Required

Temperature Conditioning

Not Required

Not Required

Flow Control

Not Required

Not Required

ATEX Exd II 2 G IIB T4, IECEX, CSA, Class

Page 8 of 21

Automatic Oil Droplet Size Compensation as

Discrepancy for Oil droplet size

standard

None

Page 9 of 21

TECHNICAL DRAWING
MECHANICAL DRAWINGS SIDE STREAM

Page 10 of 21

TEHCNICAL DRAWING INLINE PROBE

Page 11 of 21


Page 12 of 21

4 COMMERCIAL OFFER

Quotation made on 16th Aug 2012

Analyzer

Unit Price

Analyzer EX-100

Qty

Net Price

45,000

45,000

49,500

49,500

Analyzer EX-100P (c/w SS316 extraction/insertion tools 0

5 Barg)

Analyzer Options

Unit Price

Qty

Net Price

316SS Valve (Pneumatic) with CR22 (Duplex) wetted parts

2,500

2,500

CR22 (Duplex) wetted parts for analyzer

5,700

5,700

Stainless Steel Enclosure

2,850

2,850

Modbus

1,200

1,000

Sunshade

1,375

1,375

Two Year Spare Parts

Unit Price

Qty

Net Price

Laser Assembly part no 25ASY10001LAA

2,154

2,154

Sensor Head Assembly part no 25ASY10003SHA

2,450

2,450

Services

Unit Price

Standard Documentation Set

Qty

Net Price

Packaging & Delivery

850

850

NDT testing (X-ray and Dye Penetration)

750

750

Startup/ Commissioning*

850

2,550

FAT*

750

750

Freight Charge- CIF KLIA (Fumigation charges included)

* NOT include air tickets, accommodation and out of pocket expenses

Page 13 of 21

820

820



Training Options
Certified Operator course
At customer premises (max 8 attendees)
At Advanced Sensors - first co. representative
At Advanced Sensors - each additional representative
Certified Engineer course
At customer premises (max 6 attendees)
At Advanced Sensors - first co. representative
At Advanced Sensors - each additional representative

Special Instructions

Unit Price

3,500
1,500
700

5,000
2,000
1,000

Advanced Sensors carries out a final inspection of all its analysers and issues an FAT document. Where
the customer representative (or a nominated 3rd party) is required to supervise the FAT or additional
testing is required a charge is made.




Terms and Payment



All prices are exclusive of travel and expenses costs - to be charged at cost
All prices are in GBP ( Pounds Sterling)
All prices are exclusive of VAT, import/export or other taxes and duties.
Milestone payments are as follow;
10% -Upon Purchase Order (PO)
30% -Upon Readiness of Shipment Ex-work Belfast
60% - Upon CIF KLIA


Standard documentation includes copies of standard certificates, GA drawing and installation and user
handbooks.

The offerings are all for standard analysers with a normal delivery time of 4-6 weeks
This delivery time can be reduced on an exceptional basis.

Quotation valid for 30 days from date of quotation

Page 14 of 21

5 ADDITIONAL INFORMATION
5.1 MANUFACTURER & ORIGIN
Manufacturer

Advanced Sensors Ltd.

Origin

United Kingdom

5.2 COMMISSIONING AND START-UP SPARES

There are no Commissioning and Start-up Spares required.
The recommended spares including annual servicing materials for 2year operation
have been quoted separately.

5.3 SPECIAL TOOLS

There are no Special Tools required for this equipment.

Page 15 of 21

6 PARTIAL REFERENCE LIST

The

following

customers

benefit

from

successful

installations

OIW EX 100/1000 Oil in Water Analyzer.

StatoilHydro North Sea Installations Norwegian Sector
Mr Arne Henriksen (Arne.Henriksen@hydro.com)
Two systems on Brage C with heavy oils. Excellent cleaning experience.
Produced water overboard discharge.

Talisman Energy Flotta Terminal

Mr David Owens at Talisman (dowens@talisman.co.uk)
Operates unit in terminal at Flotta, Orkney Islands.
Multiple oil types, has provided excellent correlation data.
Effluent discharge monitoring to sea.

Chevron Thailand - FPSOs

Mr Darrell L Gallup at Chevron (dgallup@chevron.com)
Stanley Curtice (SCurtice@chevron.com)
Oversees installations in Thailand on Benchamas and Tantawan.
Produced water overboard discharge.
Tantawan:
Maintenance Superintendant Chris Latimar (TWEIAE@chevron.com)
Captain Mark Hamilton (TWEIAE@chevron.com)
Benchamas:
Captain Marian (benfso@chevrontexaco.com)
Murphy Sarawak Oil Corp. West Patricia A & B/ Golok A & B
Produced water discharge.
Petronas Carigali Sdn Bhd Labuan Gas Terminal
Produced water discharge.

Page 16 of 21

of

the

7 TESTIMONIALS

Page 17 of 21


Page 18 of 21

8 ATTACHMENTS
179 Samples - May 07
12
11

OIW-1 PPM Reading

Lab Result

10
9
8

6
5
4
3
2
1

Talisman Flotta Reception Terminal

Page 19 of 21

177

173

169

165

161

157

153

149

145

141

137

133

129

125

121

117

113

109

105

97

101

93

89

85

81

77

73

69

65

61

57

53

49

45

41

37

33

29

25

21

17

13

0
1

PPM

END OF PROPOSAL

Page 20 of 21


Page 21 of 21