Professional Documents
Culture Documents
5070/01
CHEMISTRY
Paper 1 Multiple Choice
May/June 2008
1 hour
Additional Materials:
*6681210173*
[Turn over
2
1
Oxygen was prepared from hydrogen peroxide and collected as shown in the diagram.
2H2O2 2H2O + O2
aqueous
hydrogen
peroxide
oxygen
water
manganese(IV) oxide
The first few tubes of gas were rejected because the gas was contaminated by
water vapour.
hydrogen peroxide.
hydrogen.
nitrogen.
melting point
/ C
boiling point
/ C
electrical
conductivity
when solid
electrical
conductivity
when molten
808
1465
key
98
890
= conducts
119
445
39
357
UCLES 2008
5070/01/M/J/08
3
3
Nitrogen dioxide is a dark brown gas and is more dense than air.
A gas jar containing nitrogen dioxide is sealed with a glass plate and is then inverted on top of a
gas jar containing air.
nitrogen dioxide
glass plate
air
brown
brown
dark brown
light brown
colourless
dark brown
light brown
dark brown
A student tested a solution by adding aqueous sodium hydroxide. A precipitate was not seen
because the reagent was added too quickly.
What could not have been present in the solution?
A
Al 3+
Ca2+
NH4+
Zn2+
methane
sand
sodium chloride
water
UCLES 2008
5070/01/M/J/08
[Turn over
4
6
When a covalent liquid boils its molecules become more widely spaced.
Which property of the molecules has the most influence on the energy required to boil a covalent
liquid?
final position of
solvent front
original level
of solvent
x
x+y
y
x+y
x
x+y+z
65
The atoms 64
29 Cu and 30 Zn have the same
nucleon number.
number of electrons.
number of neutrons.
proton number.
UCLES 2008
5070/01/M/J/08
y
x+y+z
5
9
The sodium ions and the chloride ions are free to move.
10 Which equation describes the most suitable reaction for making lead sulphate?
A
Pb
+ H2SO4
PbSO4
H2
PbCO3
+ H2SO4
PbSO4
CO2 + H2O
Pb(NO3)2 + H2SO4
PbSO4
2HNO3
Pb(OH)2
+ H2SO4
PbSO4
2H2O
11 In which oxide does X have the same oxidation state as in the chloride, XCl3?
A
X3O
X2O
XO2
X2O3
12 A sample of copper contains a metal impurity which is below copper in the reactivity series.
The diagram shows the apparatus used for refining the sample.
pure
copper
cathode
(negative)
impure
copper
anode
(positive)
aqueous
copper(II)
sulphate
The loss in mass of the anode (positive electrode) is 50 g and the gain in mass of the cathode
(negative electrode) is 45 g.
What is the percentage purity of this sample of copper?
A
10.0 %
11.1 %
90.0 %
95.0 %
13 One mole of a sample of hydrated sodium sulphide contains 162 g of water of crystallisation.
What is the correct formula of this compound?
A
Na2S.3H2O
UCLES 2008
Na2S.5H2O
Na2S.7H2O
5070/01/M/J/08
Na2S.9H2O
[Turn over
6
14 The diagram shows the electrolytic production of aluminium.
waste gases
carbon
anodes
(positive)
cathode
(negative)
positive electrode
solid aluminium
hydrogen
solid aluminium
oxygen
liquid aluminium
hydrogen
liquid aluminium
oxygen
15 When dilute sulphuric acid is electrolysed between platinum electrodes, which statements are
correct?
1 and 2
1 and 3
2 and 4
4 only
the formation of a carbohydrate and oxygen from carbon dioxide and water
UCLES 2008
5070/01/M/J/08
7
17 At 400 C the reaction between hydrogen and iodine reaches an equilibrium.
H2(g) + I2(g)
2HI(g)
H = 13 kJ
Which change in conditions would increase the percentage of hydrogen iodide in the equilibrium
mixture?
A
a decrease in pressure
a decrease in temperature
an increase in pressure
an increase in temperature
18 The diagram shows the reaction pathway for a reaction without a catalyst.
energy
reaction pathway
Which diagram shows the addition of a catalyst which speeds up the reaction?
energy
energy
reaction pathway
reaction pathway
energy
energy
reaction pathway
UCLES 2008
reaction pathway
5070/01/M/J/08
[Turn over
8
19 Sulphur dioxide reacts with aqueous bromine according to the following equation.
SO2(g) + Br2(aq) + 2H2O(l) H2SO4(aq) + 2HBr(aq)
Which element has been oxidised?
A bromine
B hydrogen
C oxygen
D sulphur
20 When 20 cm3 of a 2 mol/dm3 solution of potassium hydroxide is mixed with 20 cm3 of a 1 mol/dm3
solution of sulphuric acid, the temperature of the mixture rises.
What best explains this?
A
The potassium hydroxide solution is more concentrated than the sulphuric acid solution.
21 A colourless gas is passed into each of three different solutions. The results for each solution are
shown in the table.
solution
result
potassium iodide
stays colourless
orange to green
purple to colourless
an acid
an alkali
an oxidising agent
a reducing agent
It conducts electricity.
UCLES 2008
5070/01/M/J/08
9
23 Which equation represents the reaction between hydrochloric acid and sodium hydroxide?
A
Cl + Na+ NaCl
2H+ + O2 H2O
C
D
1
2
O2 + H2 H2O
H+ + OH H2O
24 The following statements about dilute sulphuric acid are all correct.
1
Addition of Universal Indicator shows that the solution has a pH value of less than 7.0.
1 and 2
1 and 3
2 and 4
3 and 4
calcium hydroxide.
calcium sulphate.
hydrochloric acid.
magnesium nitrate.
26 Sulphur and selenium (Se) are in the same group of the Periodic Table.
From this, we would expect selenium to form compounds having the formulae
A
UCLES 2008
5070/01/M/J/08
[Turn over
10
27 X and Y are diatomic elements. X is less reactive than Y.
What are elements X and Y?
X
chlorine
iodine
fluorine
nitrogen
iodine
bromine
oxygen
nitrogen
grease
UCLES 2008
water
water
water
water
iron
iron
iron
iron
paint
plastic
5070/01/M/J/08
zinc
11
30 Three types of steel have different properties.
steel 1 easily shaped
steel 2 brittle
steel 3 resistant to corrosion
What are the names of these three types of steel?
steel 1
steel 2
steel 3
high carbon
mild
stainless
high carbon
stainless
mild
mild
high carbon
stainless
mild
stainless
high carbon
UCLES 2008
5070/01/M/J/08
[Turn over
12
32 The diagram shows the apparatus used in an experiment to reduce substance Q with the gas
generated in the flask.
Q
heat
dilute
hydrochloric
acid
copper
copper(II) oxide
lead
lead(II) oxide
magnesium
zinc oxide
zinc
copper(II) oxide
33 The flow chart shows how impure water can be treated to produce drinkable water.
impure
water
pass
through
large-sized
gravel
pass
through
small-sized
gravel
pass
through
carbon
clay particles
microbes
nitrates
odours
UCLES 2008
5070/01/M/J/08
pass
chlorine
through it
drinkable
water
13
34 A solid substance Z burns in air to form a product that is gaseous at 20 C.
What is Z?
A
hydrogen
carbon monoxide
carbon
magnesium
hydrogen molecules, H2
hydroxide ions, OH
oxygen atoms, O
C
OCH3
UCLES 2008
5070/01/M/J/08
[Turn over
14
37 Which two compounds are members of the same homologous series?
1
H
H
H
O
1 and 2
4
H
H
O
1 and 3
1 and 4
2 and 4
How many molecules of hydrogen are needed to saturate one molecule of 1,3-butadiene?
A
39 Which compound has more than two carbon atoms per molecule?
A
ethyl ethanoate
ethene
ethane
ethanoic acid
Their boiling points increase as the length of the carbon chain increases.
UCLES 2008
5070/01/M/J/08
15
BLANK PAGE
5070/01/M/J/08
Magnesium
Sodium
Calcium
5070/01/M/J/08
Strontium
Key
X = atomic symbol
Actinium
Ac
89
Ra
Radium
88
Fr
Francium
87
Hafnium
72
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
22
48
Ti
La
39
89
Scandium
21
227
Barium
56
Caesium
45
Sc
226
55
137
Ba
133
Cs
38
Rubidium
37
88
Sr
85
Rb
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
93
Ta
181
Niobium
Nb
90
58
73
52
96
Mo
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
Sm
150
Iridium
Ir
192
Pu
94
Plutonium
62
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
Eu
152
Platinum
Pt
195
Am
95
Americium
63
Europium
78
46
Palladium
Pd
106
Nickel
Ni
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
Dy
162
Thallium
Tl
204
Indium
In
115
Gallium
Cf
98
Californium
66
Dysprosium
81
49
31
70
Ga
Ge
73
Silicon
119
Es
Holmium
Ho
165
Lead
Pb
207
Tin
Sn
99
Einsteinium
67
82
50
32
Germanium
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
11
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
14
Se
79
Sulphur
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
32
Oxygen
16
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
VII
Hydrogen
VI
He
IV
III
1
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
51
Group
DATA SHEET
The Periodic Table of the Elements
16
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.