Professional Documents
Culture Documents
SCHOOL
ARAKKONAM
CHEMISTRY
XII-STD
STUDY MATERIAL -2014
BASED ON
XII
TH
Unit Test-1
2.Periodic Classification-II
3.P-Block Elements
Unit Test -2
8.Solid State
9.Thermodynamics
Unit Test-3
10Chemical Equilibrium-II
15.Isomerism in Organic Compounds
Unit Test-4
16.Hydroxy Derivatives
17.Ethers
Unit Test -5
4.d-Block Elements
5.f-block Elements
Unit Test -6
Unit Test -7
11.Chemical Kinetics-II
12.Surface Chemistry
13.Electro Chemistry I
Unit Test -8
18.Carbonyl Compounds
19.Carboxylic Acid
Unit test 9
14.Electro Chemistry-II
Unit Test 10
21.Biomolecules
22.Chemistry in action
1.Atomic Structure-II
2.Periodic lassification-II
3.P-Block Elements
8.Solid State
Monthly Exam 1
9. Thermodynamics
15.Isomerism in Organic
Compounds
16.Hydroxy Derivatives
4. d-Block Elements
5. f-block Elements
Monthly Exam 2
11.Chemical Kinetics-II
12.Surface Chemistry
18.Carbonyl Compounds
19.Carboxylic Acid
1.Atomic Structure-II
2.Periodic classification-II
3.P-Block Elements
4.d-Block Elements
8.Solid State
9.Thermodynamics
Quarterly Exam
10.Chemical equilibrium-II
11.Chemical Kinetics-II
15.Isomerism in Organic
Compounds
16.Hydroxy Derivatives
18.Carbonyl Compounds
19.Carboxylic Acid
f-Block Elements
Co-Ordination Compounds
Monthly Exam 3
Surface Chemistry
Electro Chemistry-I
Organic Nitrogen Compounds
Co-Ordination Compounds
Nuclear Chemistry
Monthly Exam-4
Electro Chemistry-II
Bio Molecules
Chemistry in Action
Full Portion
3 Marks
1.Atomic Structure -II
THREE MARKS.
3.Define an orbital;
7
7.Define hybridisation.
Hybridization is the concept of intermixing of the orbitals of
an atom having
nearly the same energy to give exactly equivalent orbitals with
same energy, identical
shapes and symmetrical orientations in space.
The new equivalent orbitals formed are known as the hybrid
orbitals or
hybridized orbitals. Hybrid orbitals have properties entirely
different from the
properties of the original orbitals from which they have been
obtained.
2.PERIODIC CLASSIFICATION - II
12
P-Block Elements
1.Prove that phosphorus acid is a powerful reducing agent?
It is a powerful reducing agent because it has P-H bond.
It reduces silver nitrate solution into silver.
2AgNO3+H2O+ H3PO3 2Ag+ H3PO4 + 2HNO3
2.What is Plumbo solvency?
Lead is not attacked by pure water in the absence of air,
but water containing
dissolved air has a solvent action on
it due to the formation of lead hydroxide (a poisonous
substance). This phenomenon is called Plumbo solvency.
13
14
d - BLOCK ELEMENTS
20
21
23
KCl+H2O
Na[B(NO3)4]
Na[B(NO3)4]
26
7.NUCLEAR CHEMISTRY
1.Define radio activity.
The phenomenon of spontaneous disintegration of certain
atomic nuclei resulting in the emission of radioactive rays is
called radioactivity.
Radioactivity is a nuclear phenomenon and it is not affected
by external
factors such as temperature, pressure etc. This phenomenon
was discovered
by Henry Becqurel.
viceversa.
3.Write two difference between chemical reaction and nuclear
reaction
CHEMICAL
REACTIONS
NUCLEAR REACTIONS
Nuclear reactions involve
emission of
alpha, beta and gamma
particles from
the nucleus.
8.SOLID STATE - II
1.Define the terms; space lattice and unit cell
Unit cell is the smallest fundamental repeating portion of a
crystal lattice
from which the crystal is built by repetition in three
dimension.
30
34
35
36
i) when ng = 0, Kp = Kc
37
38
39
11.CHEMICAL KINETICS
1.Explain Pseudo first order reaction
Thus in a second order reaction, when one of the reactants
concentrationis in excess (10 to 100 times) of the other
reactant, then the reaction follows a first order kinetics and
such a reaction is called pseudo-first order reaction.
In a reaction of the type,
CH3COOCH3 + H2O CH3COOH + CH3OH
3.What is electrophoresis?
If electric potential is applied across two platinum electrodes
immersed
in a hydrophilic sol, the dispersed particles move toward one
or the other
electrode. The movement of sol particles under an applied
electric potential
is called electrophoresis or cataphoresis. If the sol particles
here negatively
charged, they migrate toward the positive electrode. On the
other hand, if
they have positively charged they move toward the negative
electrode. From
the direction of movement of the sol particles, we can
determine the charge
of the sol particles.
42
2. What is catalysis ?
A catalyst is a substance which alters the speed of a
chemical reaction
without itself undergoing any chemical change and the
phenomenon is known
as catalysis.
3. What are the two types of catalysis
Catalytic reactions are classified into two broad types;
1. Homogeneous catalysis
2. Heterogeneous catalysis
4. What are active centers ?
The catalytic surface has unbalanced chemical bonds on it.
The reactant
gaseous molecules are adsorbed on the surface by these free
bonds. This accelerates the rate of the reaction. The
distribution of free bonds on the catalytic surface is not
uniform. These are crowded at the peaks, cracks and corners
of the catalyst. The catalytic activity due to adsorption of
reacting molecules is maximum at these spots. These are,
therefore, referred to as the active centres. If a catalyst has
more active centres, then its catalytic
activity is increased.
5. Why colloidal system in gas in gas does not exist ?
A colloidal solution of gas in gas is not possible as gases
are completely
miscible and always form true solutions.
8. Why colloids are purified ?
In the methods of preparation stated above, the resulting sol
frequently
43
47
49
50
3.Williamsons synthesis
This is the most important method. It consists of heating alkyl
halides
with sodium or potassium alkoxide
51
HCOOH
Red ant (formica)
Formic acid
C3H7COOH
Butter (Butyrum)
52
Butyric acid
C11H23COOH.
Laurel Oil
Lauric acid
4. Mention the uses of oxalic acid.
i) for removing ink stains and iron stains.
ii) as mordant in dyeing and calico printing
iii) in manufacture of ink and metal polishes. iv) Redox
titration.
5.Formic acid reduces Tollens reagent but acetic acid does
not. Give reason.
Formic acid is unique because it contains both an
aldehyde group and carboxyl group also. Hence it can act as a
reducing agent. But acetic acid does not.
22. BIOMOLECULES
1. What are carbohydrates ? Give two examples
Carbohydrates are polyhydroxy aldehydes or polyhydroxy
ketones. They
are naturally occuring organic substances. They are present in
both plants
and animals. Carbohydrates are formed in the plants by
photosynthesis from
carbon dioxide and water in sunlight
2. Give the structure of sucrose.
55
are classified into two types. (i) General anaesthetics are the
agent, which
bring about loss of all modalities of sensation, particularly
pain along with
reversible loss of conciousness. (ii) Local anaesthetics
prevent the pain
sensation in localised areas without affecting the degree of
conciousness.
59
60