Professional Documents
Culture Documents
1.
Product name
Label No.
Supplier/Manufacturer
Emergency telephone
number
Area of application
Material uses
2.
Hazards identification
: R10
Xi; R37
R67
N; R51/53
Risk phrases
: R10- Flammable.
R37- Irritating to respiratory system.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases
Statement of
: HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
hazardous/dangerous nature
3.
Composition/information on ingredients
: Yes.
Mixture
% by weight
Classification
64742-95-6
10 - 25
1,2,4-trimethylbenzene
95-63-6
2.5 - 10
xylene
1330-20-7
2.5 - 10
mesitylene
108-67-8
2.5 - 10
64742-95-6
2.5 - 10
R10
Xn; R65
Xi; R37
R66, R67
N; R51/53
R10
Xn; R20
Xi; R36/37/38
N; R51/53
R10
Xn; R20/21
Xi; R38
R10
Xi; R37
N; R51/53
R10
Xn; R65
Xi; R37
R66, R67
Ingredient name
CAS number
Date of issue
: 29.11.2013.
Page: 1/9
108-88-3
2.5 - 10
64742-82-1
1 - 2.5
cumene
98-82-8
1 - 2.5
propylbenzene
103-65-1
1 - 2.5
1,2,3-trimethylbenzene
Distillates (petroleum), straight-run middle
526-73-8
64741-44-2
1 - 2.5
0-1
2-butanone oxime
96-29-7
0-1
N; R51/53
F; R11
Repr. Cat. 3; R63
Xn; R48/20, R65
Xi; R38
R67
R10
Xn; R65
R66, R67
N; R51/53
R10
Xn; R65
Xi; R37
N; R51/53
R10
Xn; R65
Xi; R37
N; R51/53
R10
Xn; R65
R43, R66
N; R51/53
Carc. Cat. 3; R40
Xn; R21
Xi; R41
R43
Other ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not dangerous
according to the ADG Code, make up the product concentration to 100%.
4.
First-aid measures
First-aid measures
Eye contact
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
Skin contact
: Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Inhalation
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband. In case of inhalation of decomposition
products in a fire, symptoms may be delayed. The exposed person may need to be
kept under medical surveillance for 48 hours.
Ingestion
: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if
the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse
health effects persist or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.
Protection of first-aiders
: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Date of issue
: 29.11.2013.
Page: 2/9
5.
Fire-fighting measures
Extinguishing media
Suitable
Not suitable
Special exposure hazards
Special protective
equipment for fire-fighters
Hazchem code
: 3[Y]
6.
Personal precautions
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
Environmental precautions
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
: Stop leak if without risk. Move containers from spill area. Approach the release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite
or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see section 1 for
emergency contact information and section 13 for waste disposal.
Contain and collect spillage with an electrically protected vacuum cleaner or by wetbrushing and place in container for disposal according to local regulations (see
section 13).
7.
Handling
The handle provided on the package is for manual handling only. Transport and
transfer should be carried out with appropriate equipment and carriage devices.
Date of issue
: 29.11.2013.
Page: 3/9
Storage
8.
Ingredient name
Solvent naphtha (petroleum), light aromatic
1,2,4-trimethylbenzene
xylene
mesitylene
Toluene
cumene
1,2,3-trimethylbenzene
Recommended monitoring
procedures
Date of issue
: 29.11.2013.
Exposure limits
NOHSC (Australia, 11/2004). Notes: Documentation for
the substances with this footnote can be found in the
5th Edition of the ACGIH documentation of the threshold
limit values and biological exposure indices (1). For all
other substances with 'H' in Column 7 the
documentation can be found in the 6th Edition of the
ACGIH documentation of the threshold limit values and
biological exposure indices (2).
TWA: 123 mg/m 8 hour(s). Form: All forms
TWA: 25 ppm 8 hour(s). Form: All forms
Safe Work Australia (Australia, 8/2005).
TWA: 123 mg/m 8 hour(s).
TWA: 25 ppm 8 hour(s).
Safe Work Australia (Australia, 8/2005).
STEL: 655 mg/m 15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 350 mg/m 8 hour(s).
TWA: 80 ppm 8 hour(s).
Safe Work Australia (Australia, 8/2005).
TWA: 123 mg/m 8 hour(s).
TWA: 25 ppm 8 hour(s).
NOHSC (Australia, 11/2004). Notes: Documentation for
the substances with this footnote can be found in the
5th Edition of the ACGIH documentation of the threshold
limit values and biological exposure indices (1). For all
other substances with 'H' in Column 7 the
documentation can be found in the 6th Edition of the
ACGIH documentation of the threshold limit values and
biological exposure indices (2).
TWA: 123 mg/m 8 hour(s). Form: All forms
TWA: 25 ppm 8 hour(s). Form: All forms
Safe Work Australia (Australia, 8/2005). Absorbed
through skin.
STEL: 574 mg/m 15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 191 mg/m 8 hour(s).
TWA: 50 ppm 8 hour(s).
NOHSC (Australia, 11/2004). Notes: Substance requiring
review
: 790 mg/m 8 hour(s). Form: All forms
Safe Work Australia (Australia, 8/2005). Absorbed
through skin.
TWA: 125 mg/m 8 hour(s).
TWA: 25 ppm 8 hour(s).
STEL: 75 ppm 15 minute(s).
STEL: 375 mg/m 15 minute(s).
Safe Work Australia (Australia, 8/2005).
TWA: 123 mg/m 8 hour(s).
TWA: 25 ppm 8 hour(s).
Page: 4/9
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits. The engineering controls also need to
keep gas, vapour or dust concentrations below any lower explosive limits. Use
explosion-proof ventilation equipment.
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protection
Eyes
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Hands
Respiratory
Skin
: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product.
Environmental exposure
controls
9.
Physical state
Colour
Odour
Density
Flash point
: Liquid.
:
:
:
:
Silvery.
Characteristic.
1.195 g/cm3
Closed cup: 43C (109,4F)
: Stable under recommended storage and handling conditions (see section 7).
Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides
of nitrogen.
Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
Hazardous decomposition
products
Materials to avoid/
Hazardous Reactions
Conditions to avoid
11 . Toxicological information
There are no data available on the preparation itself. The preparation has been assessed following the conventional method
of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See sections 2 and
15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver
and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and,
in extreme cases, loss of consciousness.
Date of issue
: 29.11.2013.
Page: 5/9
Carc. 2, H351
Carcinogenicity
Ingredient name
xylene
Toluene
aluminium stabilized
zeolite
ethylbenzene
silica, crystalline - quartz
ACGIH
EPA
OSHA
IARC
A4
A4
A4
A3
A2
3
3
3
2B
1
NIOSH
+
NTP
Proven.
Mutagenicity
: No known significant effects or critical hazards.
Reproductive toxicity
: No known significant effects or critical hazards.
Over-exposure signs/symptoms
: No known significant effects or critical hazards.
Inhalation
Ingestion
Skin
Target organs
12 . Ecological information
There are no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 15 for details.
Ecotoxicity
: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. Water polluting material. May be harmful to the environment if
released in large quantities.
Aquatic ecotoxicity
Product/ingredient name
Result
Species
Exposure
Daphnia
48 hours
Algae
Fish
Fish - Pimephales promelas - 34
days
Daphnia
72 hours
96 hours
96 hours
Date of issue
: 29.11.2013.
48 hours
Page: 6/9
cumene
propylbenzene
ethylbenzene
Algae
Fish
Fish - Oncorhynchus mykiss EMBRYO
Daphnia
Algae
Fish
Daphnia - Daphnia magna Neonate - <=24 hours
Fish - Oncorhynchus mykiss
Algae - Pseudokirchneriella
subcapitata
Fish - Oncorhynchus mykiss
Algae
Daphnia
Fish
72 hours
96 hours
96 hours
48 hours
72 hours
96 hours
48 hours
96 hours
72 hours
96 hours
48 hours
48 hours
96 hours
Conclusion/Summary
: Not available.
Other ecological information
Persistence/degradability
Conclusion/Summary
: Not available.
Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
Not readily
Not readily
Readily
Not readily
Not readily
Not readily
Not readily
Readily
Product/ingredient name
LogPow
BCF
1,2,4-trimethylbenzene
xylene
mesitylene
toluene
cumene
propylbenzene
1,2,3-trimethylbenzene
3,63
3,12
3,42
2,73
3,66
3,69
3,66
120,226443461
186,208713666
8,317637711
35,481338923
194,984459975
Bioaccumulative potential
Potential
high
high
high
low
low
high
high
13 . Disposal considerations
Methods of disposal
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: 29.11.2013.
Page: 7/9
14 . Transport information
Transport within users premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name
: Paint (Solvent naphtha (petroleum), light aromatic)
Marine pollutant
: 1,2,4-trimethylbenzene, Solvent naphtha (petroleum), light arom.
substances
UN Number
Class
Packing group
Label
: 1263
: 3
: III
:
Marking
: The environmental hazardous / marine pollutant mark is only applicable for packages
containing more than 5 litres for liquids and 5 kg for solids.
Additional information
ADG Proper shipping name : Paint (Solvent naphtha (petroleum), light aromatic)
:
ADG Label
: 3[Y]
: Tunnel restriction code: (D/E)
Hazard identification number: 30
: Emergency schedules (EmS): F-E, S-E
Marine pollutant: Yes.
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.
15 . Regulatory information
National regulations
Standard for the Uniform Scheduling of Drugs and Poisons
5
Control of Scheduled Carcinogenic Substances
Ingredient name
No listed substance
Australia inventory (AICS)
EU regulations
Hazard symbol or
symbols
Irritant
: 1,2,4-trimethylbenzene
xylene
Toluene
Solvent naphtha (petroleum), light arom
: R10- Flammable.
R37- Irritating to respiratory system.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Contains
Risk phrases
Date of issue
Schedule
: 29.11.2013.
Page: 8/9
Additional warning
phrases
: Contains 2-butanone oxime; ethyl methyl ketone oxime and Distillates (petroleum),
straight-run middle. May produce an allergic reaction. Repeated exposure may cause
skin dryness or cracking.
US regulations
HCS Classification
: Combustible liquid
Carcinogen
Target organ effects
16 . Other information
Full text of R-phrases referred : R11- Highly flammable.
R10- Flammable.
to in sections 2 and 3
R40- Limited evidence of a carcinogenic effect.
R63- Possible risk of harm to the unborn child.
R20- Harmful by inhalation.
R21- Harmful in contact with skin.
R20/21- Harmful by inhalation and in contact with skin.
R48/20- Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
R65- Harmful: may cause lung damage if swallowed.
R41- Risk of serious damage to eyes.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R36/37/38- Irritating to eyes, respiratory system and skin.
R43- May cause sensitisation by skin contact.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Notice to reader
History
Date of printing
:
:
:
:
Date of issue
Version
Prepared by
29.11.2013.
29.11.2013.
1.01
Jotun Group Product Safety Department
Disclaimer
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier,
nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information
contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards that exist.
Date of issue
: 29.11.2013.
Page: 9/9