Professional Documents
Culture Documents
Submitted to:
Whom it may concern
Pak-Arab Company limited
Submitted by:
Muhammad Yousaf
Internee #: 04 (TSD)
University of Punjab Lahore.
Page 1
Page 2
Dedicated to:
The One in Whose Hands My Life Is
"And Allah has brought you out from the wombs of your mothers while you know
nothing. And He gave you hearing, sight, and hearts that you might give thanks (to
Allah)"
[Quran, 16:78]
Page 3
Acknowledgement:
This report is only made possible due to combine efforts of all the members MCR and specially the
Engineers from Technical Services Department (TSD-MCR) who has given best of their efforts and
available time to make me things clear.
I would like to thank Mr. Khalil Ur rehman and my respective mentor Engineer Muhammad Abubakar
and Imran rasheed the great and kindest of all in the organization and charming personality who
guided me during my entire internship. I have not seen such a versatile and super kind personality in
my life.
Also to the members of HR and TSD department who has provided me the opportunity for internship
and facilities during stay to the internees. Special thanks to following members.
Finally, I wish to thank my parents and my all Teachers for their support and encouragement
throughout my study.
Page 4
T able Of Contents:
General Training:
Introduction to PARCO
Technical Services Department
Health Safety and Environment
Fire Protection Department
Specific Training:
Assignments:
All assignments that were assigned are attached with report.
Page 5
General Training:
Parco
A Pakistan Abu-Dhabi Joint Venture.
Corporate Objectives
To consolidate financial and organizational gains, PARCO purposes the following objectives;
Page 6
C OMPANY PROFILE:
It was the first AAA credit rated Company by PACRA in the country and
continues to command that credit worthiness for an unprecedented fifth yearrunning. The Management of the Company is vested in a Board often Directors
of which GOP appoints six Directors including the Chairman and the Managing
Director and the remaining four Directors represent ADPI. The Managing
Director is the Chief Executive of the Company and the Federal Ministry for
Petroleum and Natural Resources performs an overview role and represents the
interest of the Government of Pakistan.
PARCO is truly Energy Company.
PARCO as an energy company is the fulcrum and key building block in the
country's strategic oil supply and its logistics. With the synergy of a
PAK-ARAB COMPANY LIMITED
Page 7
Having been ensured a much healthier environment and improved quality of life
Page 8
Pipeline Network
The refined petroleum products transport logistics on road and rail and the
existing pipeline network. The surface transport mode is potentially hazards to
other traffic, human lives and the environment besides wear and tear of road
surfaces. PARCOs pipeline network is a safer and more cost effective
alternative for both crude and product transportation. With the completion of
the White Oil Pipeline in about two years, a more comprehensive, safer, cost
effective, demand responsive and eco-friendly pipeline network will be
available to meet the countrys growing needs for energy.
Location
Project cost
US $886 million
Page 9
Completion Period
36 months
August03, 2000
August25, 2000
September04, 2000
Page 10
An Overview to PARCO;
The refinery complex include onsite
process units beside numerous
offsite/utilities units and other permanent facilities with tanks to store the
crude oil, intermediate feeds stocks and finished products.
Page 11
Accidents can take place anywhere around the world. These accidents affect
profit, companys reputation and environment. There is no budget assigned to
these unpredicted incidents. Over the years, numerous oil companies have
encountered major accidents which resulted loss of billions of dollars and
loss of many lives. Lets put some light on some of the major accidents
hitting oil and gas sector around the world. Some of the disasters are as
follow
Page 12
Wellhead Blowout
Fire on Oil Rig
4.9 million barrels of oil spilled in the Gulf of Mexico
11 people killed
US $20 billion spent on recovery
Above given examples tell us about the consequences a company might have to
suffer in case of an accident. It is evident that there is a dire need of a
department which can help minimize the chances of an accident, which does
regular auditing of the safety around the plant area and which can put a strong
check on the implementation of rules at the refinery area.
PARCO HSE department policy statement PARCO is committed to enhance
customer satisfaction through continual improvement, operational excellence
and in time delivery of quality products while remaining watchful over the
safety, health and environmental concerns of its employees, contractors and
the general public associated with it.
Furthermore HSE policy ensures the provision of health and safety of its
employees and maintains an ecological balance is the responsibility of the
company. The department is not only concerned for the companys employees
and the refinery area, but it is also consistent in protecting the people living
outside PARCO, minimizing hazards, creating a safe atmosphere to work at.
Page 13
Page 14
Fire Detection
Different kinds of detectors are installed around the plant area to detect release
of any dangerous hydrocarbon or detect fire at plant are;
Smoke Detector
Heat Detector
Hydrocarbon Detector
Infra-Red Flame Detector
Fire suppression
Page 15
Parco has state of the art equipment to fight a fire with a complete fire brigade
squad ready 24 hours for firefighting operation. Following is a list of firefighting
equipment;
Fire Brigade Trucks
Fire Hoses installed at different spots including storage tanks area
A network of water Pipeline (red colored) which covers almost every spot of
the area and is fully pressurized by 2 Jockey pumps. In case of fire, rest of the 4
main pumps start within 10 seconds one after the other.
Above mentioned pipeline is used to refill fire brigades, fire suppression
system, hoses etc.
Foam tanks
Fire hydrants
Fire suits
Fire extinguishers
Ladders
Fire Drills
Page 16
Emergency Response
Emergency Alarm
In case of Emergency HSE turns on the master alarm which has a sinusoidal
sound wave and goes on for about two minutes. As soon as the fire alarm goes
on, each employee is supposed to rush to the respective assembly point
assigned for each area at MCR.
Unit
Code
100
Unit
Cap(BPSD)
crude distillation
100,000
Page 17
200
25,600
300
16,350
284
Dieselmax
22,450
130
Visbreaker
15,560
801
Kerosene Merox
20,000
802
LPG Merox
4,500
411
Gas Concentration
22,050(liquid)
11,242(Gas/MMSCR)
810
Amine Treating
7,721(FG/MMSCR)
9,963(sws)
820
Sulfur Recovery
115 MTPD
T ECHNICAL SERVICES
DEPARTMENT (TSD)
Mission Statement:-
Page 18
Main functions:-
Page 19
P rocess Engineering
Section:
The process engineering section is responsible for the trouble shooting,
monitoring of the Refinery Operation and also to give the technical assistance
for further improvements.
The department is directly concerned with the on-site units, which include:
Page 20
L aboratory section:
The MCR has got well-equipped laboratories some of which are listed as under:
Diesel Lab:
Following tests are being carried out in the laboratory:
Distillation
Flash point
Pour point
Specific Gravity
Viscosity
Water Laboratory:
The pH, hardness SiO2 content, conductivity etc. of water is tested prior to
feeding the water to the boiler.
Ca2+, Mg2+ ions are tested by titration.
Introducing ammonium molybedate to water checks SiO2 content.
Respective meters check conductivity and ph.
Page 21
LPG Lab:
Weathering tubes are used to measure the evaporation temperature of the LPG.
95% of LPG should evaporate at not more than 4.4degC.
Page 22
Page 23
The unit functions to separate the crude oil into different cuts: naphtha,
kerosene, diesel and reduced crude. These cuts are further processed to
the gas concentration unit, Kero-merox unit and for blending and vacuum
distillation unit.
Arabian light, upper zakum and murban crude oil coming from Karachi
To Mahmood Kot via several kilometers pipe line is coming to the unit
Crude distillation.
All the crude contains salt water together with sediment depend upon the area
from which the crude is produced
Page 24
Page 25
Page 26
Page 27
Page 28
Page 29
Page 30
Stripping Steam
110-H1
FEED
Reduced Crude
110-V1
110-P1
Slop Wax
HVGO
LVGO
100-E19-17
110-E2
110-EA3
Vacuum Bottom
m3/h
100-E1815-13-11
110-E1
110-EA1
CRUDE
CRUDE
110-P2
110-P3
110-P4
VACUUM
VACUUMDISTILLATION
DISTILLATION UNIT
UNIT
VBU
FOB
RFO
VGO TANK
LS
HS
TWR
ME1-E3
110-P7
110-V7
110-V7
284-E12
945-E7
110-V2
ME1-E1 ME1-E2
110-E2
Fuel Oil
TWS
FOB
DMAX
FOB
DOB
LDO
VGO TK
CWS
CWR
ME1-J1A/B
ME1-J3A/B
ME1-J2A/B
110-V4
110-V4
110
110
V6
V6
110-EA4
LSL
Sour Water
110
110
V3
V3
WASTE GAS
TO 100-H1
MS
Page 31
V isbreaker unit:
The Visbreaker Process Unit is designed to process 15,560 BPSD of vacuum
residue from the Vacuum Distillation Unit, based on the Crude and Vacuum
Distillation Units processing 100% Arabian Light crude oil and 70/30 volume
percent blend of Upper Zakum/Murban crude oils.
The feed of the Visbreaker unit is,
Vacuum residue
the presence of
heat the bottoms are broken to give off gases, naphtha and vacuum bottoms.
Heating the material to predetermined heater outlet temperatures and rapid
quenching of furnace outlets facilitates thermal cracking and altered viscosity
necessary for further processing.
The visbreaking unit is the combination fuel gas and fuel oil fired In
This unit consists of three heaters for heating purpose. For safety purpose the
sour water from this section is forward to the amine treating unit.
Page 32
Page 33
G as concentration unit:The Gas Concentration Process Unit is designed to recover C3/C4 LPG and to
produce a stabilized naphtha feed to the Naphtha Hydro treating Unit. Gases
from various process units will be compressed and routed through an
absorption system to maximize the recovery of LPG.
Gas from the Net Gas Compressor at the Crude Distillation Unit in case of
Upper Zakum and Murban blend oil feed.
Gas from the Flash Fractionator Receiver at the Diesel max Unit.
The liquid feeds to the Gas Concentration Process Unit are as follows:
Page 34
The operation of gas concentration unit consist of the following three major
sections
Compressor section
Absorption section
Distillation section
In the compressor section the gas is pressurize for further use in other two
sections. All incoming gas streams except for the Naphtha Hydro treater
Stripper gas combine and flow into a two stage centrifugal compressor via the
compressor suction cooler and the compressor suction drum. Mists separated
and accumulated in the compressor suction drum is manually drained out and
sent to the CDU.
Gas from the Naphtha Hydrotreater Stripper combines with the first stage
discharge which is pressurized from 3.7 kg/cm2G to 8.2 kg/cm2G, and enters the
second stage of the compressor via the inter stage cooler and the compressor
inter stage suction drum
Gas pressurized to 17.1 kg/cm2G mixes with the Stripper overhead vapor, the
incoming liquid stream, and Primary Absorber bottoms. The combined stream is
cooled in the high pressure cooler and sent to the high pressure receiver Liquid
separated and accumulated in the compressor inter stage suction drum is sent
to the combined stream by the compressor inter stage suction drum pumps.
Page 35
Page 36
Oil used. Instead of trays like those used in the primary absorber, the sponge
absorber has a packed section to cause the intimate contact between the down
flowing liquid and the upward flowing gas. The sponge absorber does not have a
reflux flow as the primary absorber does, but the sponge absorber has a
demister blanket installed near the top of the column to aid in the removal of
liquid from the gas leaving the top of the column. The lean oil used in the
sponge absorber is circulating diesel from the Crude Unit. After passing down
the column, the diesel is collected in the bottom of the column where it is
returned to the Crude Unit as rich oil on level control at the bottom of the
sponge absorber. Pressure control for the absorption section is placed on the
lean gas exiting the top of the sponge absorber. The lean gas after passing
through the pressure control valve is directed to the Amine Treating Process
Unit and then to the refinery fuel gas system. And the pressure control valve
maintains a constant pressure on the entire absorption system.
Liquid hydrocarbon from the high pressure receiver is pumped to the stripper
where hydrogen sulfide (H2S), ethane and lighter components are stripped out.
Feed to the stripper is heated using the total debutanizer bottoms stream in the
stripper feed exchanger. Stripper charge enters the column above the top tray.
Stripping action is provided via reboilers at the bottom of the column through
which heat is supplied from the debutanizer bottoms stream and MP steam. The
steam flows through the tube side of the stripper reboilers with its condensate
flow regulated by a flow controller which is reset by the stripper overhead
vapor rate. The overhead vapor is returned to the high pressure cooler. Bottoms
material is pressured to the debutanizer on level control.
The feed to the debutanizer is the stripper bottoms stream. Heat is supplied via
a reboiler. The heating oil to the reboiler is the circulating diesel from the Crude
Unit. The diesel is regulated by a flow recording controller. The total flow of
Page 37
Page 38
Page 39
The purpose of the reactor section is to remove the naphtha fractions so that it
can be used in the plat forming unit for the further processing. There are six
types of reactions which occur in the reactor section of Nephta hydro treating
unit.
Reactions:
Conversion of organic sulfur compounds to hydrogen sulfide
Conversion of organic nitrogen compounds to ammonia
PAK-ARAB COMPANY LIMITED
Page 40
The feed from the Gas concentration unit or from the stabilizer naphtha tanks is
send to the feed surge drums. Tanks must be gas blanketed so that they can
prevent the oxygen from stabilized naphtha.
Even trace amount of olefins can cause the polymerization of olefin and when
stored for long times it can cause fouling and loss of heat in transfer efficiency.
From feed surge drum the naphtha feed is pumped and combined with
hydrogen rich stream from the recycle compressor.
The feed combines at a point and enters in combined feed exchangers where
the feed is heated and effluent from reactor 2 is cooled.
The combined feed leaving the exchanger is all vapor and this combined feed
leaving the exchanger is heated through the shall side of the reactor no 1
effluent cooler and flow to charge in the heater where it is heated to required
temperature.
And then combined feed enters in the reactor no 1 which is design for down
flow operation and contain sufficient amount of catalyst to remove
contaminants. The reactor no 1 removes the sulfur and saturate olefins while
the second reactor hydrogenates any recombinant sulfur formed in the reactor
no 1.
The effluent from reactor no 1 is cooled in effluent cooler and then enter in to
the second reactor flows through heat exchangers and then into the product
condenser.
A water wash injection points are provided in the reactor so that any salt build
up in the pipes, exchangers can be removed.
Page 41
Page 42
Products:
The light naphtha is sent to tankage and for blending system while the heavy
naphtha from the bottom of splitter is dent to heat exchanger via pump and
then send to the plat forming unit.
The block diagram of the unit is
Page 43
Page 44
L PG-Merox unit:This unit has capability of processing 4500 BPSD of Lpg to achieve a sweet
product with less than 5 wppm mercaptan and less than 20 wppm of total
sulfur.
The feed of the LPG Merox unit is C3/C4 from debutanizer receiver at gas
concentration unit.
This unit consists of three major sections.
Pretreatment section
Extraction section
Caustic regeneration section
The LPG from the gas concentration unit is fed at bottom tray no 10 of amine
absorber for counter current liquid- liquid contacting with a 20% (DEA) solution
from amine treating unit and the lean amine from tray no 1 and at top enters
and goes downward and contacted with the Lpg coming from bottom
Lean amine become rich and removes from the bottom of the absorber and is
returned to the amine treating unit. The LPG is then advanced to prewash vessel
where it is contacted with 10 degree Baume caustic for the removal of residual
hydrogen sulfide. LPG for caustic wash is then sent to the filters for extraction
section. Whereas the spent caustic is sent to effluent treatment plant via spent
caustic degassing drums.
LPG from prewash vessel is send to the bottom of extractor. Lean caustic via
pump is fed at top of extractor. The counter current fashion takes place. The
rich caustic is removed from the bottom of extractor and returned to caustic
knockout drum to separate caustic from hydrocarbons stream.
Then LPG is send to the sand filters which will coalesce and remove any
entrained caustic.
Page 45
Page 46
Page 47
K ero-Merox unit:The processing capability of the Kerosene Merox Process Unit is 20,000 BPSD of
kerosene to achieve a jet fuel product with less than 10 wppm mercaptan and
less than 1 wppm sodium.
The feed of the section is kerosene.
This unit consists on major three sections.
Pretreatment section
Sweetening action
Post treatment section
The purpose of pretreatment section is to remove naphthenic acid from feed is
that if these are not removed then sodium naphthenates are formed in
sweetening reactor which is surfactant and coat the catalyst and block the pores
of charcoal catalyst support. This is achieved by alkaline electrostatic prewash.
Mercaptans are directly converted to disulfides in fixed bed reactor system
which remains in product and there is no reduction in sulfur contents because
the vapors of disulfides are so low reactant to mercaptan so there presence is
much less objective.
Raw crude from CDU is routed directly to electrostatic coalesce prewash at
pressure 8.4kg/cm2 and at a temp of 40 Degree. The feed kerosene before
entering to prewash electrostatic coalescer is mixed with 3 degree Baume
caustic solution by means of mixing device and pumped by caustic injection
pump from caustic storage tank.
PAK-ARAB COMPANY LIMITED
Page 48
The treated kerosene from caustic settler into the water wash vessel to remove
entrained caustic solution and water soluble surfactants.
Wash water when required is injected by was water pump at the bottom of
water wash vessel. The waste water is drawn from the bottom of wash water
vessel.
The washed kerosene is then introduced into the salt filter and then last step is
clay filter which serves basically as a final clean-up step to assure a kerosene
product that is free of solids, color bodies, water and soaps.
The Salt Filter immediately ahead of the Clay Filter protects the clay from being
rendered ineffective prematurely by free water.
The treated kerosene product is run down to Tankage and Blending System at a
pressure of 3.52 Kg/cm2G and at a temperature of 40 under pressure control.
The block diagram of the unit is as,
Page 49
Page 50
S torage tanks:Storage tanks are containers that hold liquids used for short or long term
storage. Storage tanks containing organic liquids, in-organic liquids and can be
found in many industries.
Industries where storage tanks can be found are petroleum producing and
refining, petrochemical and chemical manufacturing and other industries.
Storage tanks are available in many shapes and having different types.
Page 51
Page 52
Floating roof tanks:The floating roof tank has further categorized into,
External floating roof tank
Internal floating roof tank
Dome external floating roof tank
External Floating Roof Tank:A typical external floating roof tank consists of an open-topped cylindrical steel
shell equipped with a roof that floats on the surface of the stored liquid, rising
and falling with the liquid level. The floating roof is comprised of a deck, fittings,
and rim seal system. Floating roof decks are constructed of welded steel plates
and are of three general types: pan, pontoon, and double deck.
Although numerous pan-type decks are currently in use, the present trend is
toward pontoon and double-deck type floating roofs.
Manufacturers supply various versions of these basic types of floating decks,
which are tailored to emphasize particular features, such as full liquid contact,
load-carrying capacity, roof stability, or pontoon arrangement. The liquid
surface is covered by the floating deck, except in the small annular space
between the deck and the shell; the deck may contact the liquid or float directly
above the surface on pontoons.
Page 53
Internal Floating Roof Tank:That tank has both, a permanent fixed roof and a floating roof inside. There are
two basic types of internal floating roof tanks:
Tanks in which the fixed roof is supported by vertical columns within the tank
tanks with a self-supporting fixed roof and no internal support columns
The fixed roof is not necessarily free of openings but does span the entire open
plan area of the vessel. Fixed roof tanks that have been retrofitted to employ an
internal floating roof are typically of the first type, while external floating roof
tanks that have been converted to an internal floating roof tank typically have a
self-supporting roof.
Tanks initially constructed with both a fixed roof and an internal floating roof
may be of either type. An internal floating roof tank has both a permanently
affixed roof and a roof that floats inside the tank on the liquid surface (contact
deck) or is supported on pontoons several inches above the liquid surface
(noncontact deck). The internal floating roof rises and falls with the liquid level.
Domed External Floating Roof Tank:Domed external floating roof tanks have the heavier type of deck used in
external floating roof tanks as well as a fixed roof at the top of the shell like
Page 54
Service
Capacity (m3)
Tk 945:
Crude tanks
44169
Page 55
Tk945: 9,10,11
HOBC product
2390
Tk945: 12,13,14
Regular gasoline
5650
Tk945: 15,16,17
JP-1 product
7130
Tk945: 18,19,20
JP-8 product
2010
Tk945: 22,23
Kerosene product
7940
24
Tk945: 21,
19860
Diesel product
25,26
19860
25420
Tk945: 27,28,29
12760
Tk945: 30,31,32
LPG product
1530
Tk945: 33,34
Heavy naphtha
5770
Page 56
Tk945: 35
VGO intermediate
29730
Tk945: 37,38
1630
Tk945: 30,40
Reformate tank
5670
Tk945: 46
Tk945: 52,53
Stabilized naphtha
17457
Page 57
A ssignments
Page 58
Assignment no 1:-
With the continuous depletion in world oil reserves and increasing demand of
petroleum products, the refiners are forced to process more and heavier crude
the cost advantage of heavy crudes over light crudes has incentivized many
Refineries to process heavier crude, therefore increasing the heavy residue
produced at a time when fuel oil demand is declining. In order to dovetail both
the requirement for processing crude oil of deteriorating quality and enhancing
distillates of improved quality, technological up gradation have been carried out
at refineries which takes care of processing heavy crudes as well as maximizing
value added products and stringent product quality requirements.
Technologies:-
Cracking:-
Page 59
Thermal cracking:-
Thermal cracking technology:Thermal cracking process for up gradation of heavy residue has been used since
long and still it is playing an important role in the modern refinery through up
gradation of heavy residue and improving the economics of the refinery through
the production of lighter distillate and other valuable product like low value fuel
gas and petroleum coke.
Visbreaking
Delayed coking
Fluid coking
Flexi coking
Page 60
Delayed coking:Delayed coking process is used to crack heavy oils into more valuable light liquid
products with less valuable gas and solid coke as byproducts. Typical delayed
coking consists of a furnace to preheat the feed, coking drum where the
fractionation of the product takes place. The process conditions are,
Page 61
Flexi coking:A continuous fluidized bed technology which converts heavy residue to lighter
more valuable product. The process essentially eliminates the coke production.
It has an extra step of gasification.
Temperature 525oC
Page 62
Assignment no 2
What is the advantage of diesel-max unit?
The diesel-max unit is used to maximize the production of diesel. The Dieselmax
Process Unit Catalytically desulfurizes and denitrifies vacuum gas oil (VGO)
feedstock and converts the feedstock to a diesel product, Kerosene, naphtha,
and light ends including LPG in the presence of hydrogen the hydrogen gas
which is used as feed in the diesel maxis used for saturation and removes
oxygenates and other metallic compounds.
Our requirements are achieved we get overhead gases which is used in further
units and distillate is pure diesel which is used as blending component for fuel oil
and also send to storage.
Arabian light
Upper zakum
Murban crude
Local crude
Condensate crude
51%
17%
17%
7%
7%
Page 63
Assignment no 3
The hydrogen gas is producing in the plat forming unit 300 and then routed to
the net gas three stage compressors where its pressure is increased from 3.1
kg/cm2 to 95.6 kg/cm2.
Then it is routed to the chloride treater where hydrogen chloride is removed
which can cause catalyst efficiency.
The production rate of hydrogen in plat forming unit is 29000 Nm3/hr.
The hydrogen gas is very important in refinery; the hydrogen gas used is due to
that it removes impurities or gases from crude.
Page 64
Page 65
Page 66
B ibliography:
Refinery training manual, vol.1,2,3,4,5 PakArab refinery Ltd, Mid country refinery
project, Mahmood Kot, Pakistan, Shazoo Islam
printers Multan, Pakistan
WWW.weikipedia.com
Page 67