anken-olfin

Bi 1:Vit CTCT v gi tn cc ng phn ca: C4H8 v C5H10

Bi 2:Nhng hp cht no trong s cc hp cht sau y c ng phn cis-trans
a/2-brom-3-clobut-2-en
b/1-brom-1-clo-2-metylprop-1-en
c/CH3CH=CH2
d/CH3CH=CHCl
Bi 3:Vit phn ng trng hp ca cc cht cho di y:
a/CH2=CH2
b/CH2=C(CH3)2
c/CH2=CHCl
d/CF2=CF2
e/CH(CH3)=CH(CH3)
f/CH(CH2Br)=CH(CH2Br)
g/CH2=CH(CH=CH2)
Bi 4:Vit phng trnh biu din bin ha sau:

a/hecxan butan
etilen
etylclorua
etilen
PE

b/C3H7OH
C3H6
C3H8
C2H4
C2H4(OH)2

c/ vi
vi sng
canxicacbua
axetilen
etilen
etanol
H 2 SO4
H 2 / Ni

d/C2H5OH
A
(B)
+Cl2, askt
HCl

(C)
Bi 5:Hon thnh cc phng trnh phn ng v gi tn cc sn phm to thnh:

a/CH2=CH2+HBr
..
b/CH 2=CH2+..
CH3CH2-OH

c/CH 3-CH=CH2+HI
.
d/CH 3-CH2-CH2-CH2H 2 SO4

1800 C
OH
.
4
4

H1802 SO

H1802 SO
0
0
C
C
e/CH3-CH(OH)-CH2-CH3
..
f/(CH 3)3C-OH

Bi 6:Cho etilen vo bnh cha brom lng to ra 1,2-ibrom-etan

1/Tnh th tch etilen (kc) tc dng vi brom bit rng sau khi cn li
thy bnh brom tng thm 14g
2/Tnh khi lng brom c th kt hp vi 3,36 lt etilen (kc)
s:11,2 lt; 24g
Bi 7:Khi t mt th tch hirocacbon A cn 6 th tch Oxi v sinh ra 4 th
tch CO2, A c th lm mt mu nc Brom v kt hp vi hiro to ra mt
hirocacbon no mch nhnh. Xc nh CTCT ca A v vit cc phng trnh phn
ngs: C4H8
Bi 8:Cho 3 lt hn hp etan v etilen (kc) sc vo dung dch brom ngi ta thu
c 4,7g 1,2-ibrometan
a/Vit phng trnh phn ng xy ra
b/Tnh thnh phn hn hp theo khi lng v theo th tch gi thit rng
phn ng xy ra hon ton
Bi 9:a/Mun iu ch n-pentan CH3(CH2)3CH3 ta c th hiro ha nhng anken
no? Vit CTCT ca chng

b/Vit phng trnh phn ng iu ch cc hp cht sau y t nhng

anken thch hp
1/CH 3CHBr-CHBrCH3
2/CH 3CHBr-CBr(CH3)2
3/CH 3CHBrCH(CH3)2
Bi 10:Cho hai hrocacbon A v B u th kh. A c cng thc C 2xHy; B c
cng thc CxH2x (tr s x trong hai cng thc bng nhau). Lp CTPT ca A v B;
bit rng t khi ca A i vi khng kh bng 2 v t khi ca B i vi A l
0,482. Vit CTCT cc ng phn ca A v B v gi tn chng? B:C2H4; A:C4H10
Bi 11: hiro ha hon ton 0,7 g mt olfin cn dng 246,4 cm 3 hiro (
27,30C v 1 atm). Xc nh CTPT v CTCT bit rng olfin c cu to mch
thng? s:C5H10
Bi 12:Cho 2,24 lt hn hp kh A (kc) gm etan, propan, propilen sc qua dung
dch Brom d thy khi lng bnh tng thm 2,1g .Nu t chy kh cn li s thu
c mt lng CO2 v 3,24g H2O
a/Tnh thnh phn % th tch mi kh
b/Dn lng CO2 ni trn vo bnh ng 200ml dung dch KOH 2,6M. Hy xc
nh nng mol/lt cc cht trong dung dch sau phn ng?
s:C2H6(20%); C3H8(30%); K2CO3 0,65M; KOH1,3M
Bi 13:Ngi ta mun iu ch 21 g etilen:
a/Tnh khi lng ru etylic nguyn cht phi dng nu hiu sut 100%
b/Tnh th tch etan (kc) phi dng nu hiu sut l 80%?s:34,5g; 21 lt
Bi 14:Sau khi tch hiro hn hp etan v propan to thnh hn hp etilen v
propilen. Khi lng phn t trung bnh ca hn hp etilen v propilen nh hn
khi lng phn t trung bnh ca hn hp u l 6,55%. Hy xc nh thnh
phn % theo th tch ca hn hp u?
s:C 2H6(96,18%);
C3H8(3,82%)
Bi 15:t chy hon ton 0,25 mol kh A thu c 33g CO2 v 13,4g H2O
a/Tm CTPT v CTCT ca A bit rng iu kin chun khi l ng ring ca A
l 1,875g/l
b/Tm lng dung dch KMnO4 40% c th b mt mu va bi lng cht A
trn? s:C3H6
Bi 16:C mt ng ng ca etilen 0,21 hirocacbon kt hp c vi 0,8g
brom. Xc nh CTCT ca
hirocacbon v cho bit nu thay brom bng
clo th phi dng ht bao nhiu cm3 clo (kc)
Bi 17:Mt hn hp X gm hai lfin ng ng k tip nhau c th tch 17,92
lt (o 00C v 2,5 atm) sc qua bnh ng KMnO4 d khi lng bnh tng 70g
a/Vit cc phng trnh phn ng xy ra?
b/Xc nh CTPT , CTCT ca
hai lfin ?
c/t chy hon ton th tch trn ca hn hp X ri cho sn phm vo 5 lt
dung dch NaOH 1,8M s thu c mui g ? bao nhiu gam?
s:C2H4; C3H6; 84g NaHCO3; 424g Na2CO3
Bi 18:A v B l hai anken k tip nhau trong dy ng ng. Cho 13,44 lt
hn hp trn qua mt bnh ng dung dch brom d thy bnh tng thm 28g
a/Xc nh CTPT vit CTCT ca hai anken (c th c)
b/Cho hn hp hai anken tc dng vi HCl th thu c ti a 3 sn phm. Xc
nh
CTCT
ca
hai
anken
v
gi
tn
ca
chng
s:propen; buten-2

Bi 19:Cho 3,36 lt hn hp gm mt ankan v mt anken i qua nc brom thy

c 8g brom tham gia phn ng. Khi lng ca 6,72 lt hn hp l 13 gam
a/Xc nh CTPT ca hai hirocacbon
b/t chy 3,36 lt hn hp th thu c bao nhiu lt kh CO2 v bao nhiu
gam nc
s:a/c 3 cp: C 7H14 v CH4; C5H10 v C2H6; C3H6 v C3H8
b/10,08g CO2 v
9,9g H2O
Bi 20:Mt hn hp mtan v olfin A c th tch l 10,8 lt (kc) cho qua mt
bnh ng dung dch brom d thu c mt kh, em t chy hon ton thu c 5,5g CO2. Bnh ng brom tng 10g
a/Tnh thnh phn % th tch cc kh trong hn hp u?
b/Tm
CTPT ca A
c/Tnh lng cht to thnh trong dung dch brom khi cho hn hp i qua ?
s:25,93% CH 4; 74,07% A; b/ C2H4
c/67,14g
Bi 21:Xc nh CTPT v CTCT ca tt c cc ng phn ca cc anken X, Y, Z,
T bit rng:
a/10,5 g X phn ng va vi 150 g dung dch Br2 40%
b/Hir ha hon ton 1,4 gam Y cn dng va 492,8 cm 3 H2 (o
27,30C v 1atm)
c/1,05 gam Z phn ng va vi dung dch KMnO4 cho 1,9 gam ru 2 chc
d/12,6 gam T phn ng va vi 75,84gam dung dch KMnO4 25%
s:X:C 2H4; Y:C5H10; Z:C3H6;
T:C5H10
Bi 22:Cho 0,74g hn hp A gm mtan v mt anken li t t qua bnh nc brom
d thy khi lng bnh tng thm 0,42g ng thi th tch hn hp kh A gim 1/3
a/Xc nh CTPT anken?
b/Tnh t khi ca hn hp A i vi khng kh
s:a/C3H6 b/0,85
Bi 23:t chy 8,96 lt hn hp X gm hai olfin A v B ng ng k tip th
thy khi lng CO2 ln hn khi lng H2O l 39 gam
a/Xc nh CTPT ca A v B
b/Tnh % theo th tch hn hp X
s:A:C 3H6(25%);
B:C4H8(75%)
Bi 24:2,36 gam hn hp 2 ankan A v B l ng ng k tip nhau c t
chy hon ton thu c 3,96g H2O
a/Tm CTPT v CTCT ca A v B
b/Cho 31,36 lt hn hp (kc) gm A v B v etilen i qua bnh cha dung
dch nc brom d thy tng khi lng ca bnh l 7,84g. t chy sn phm sau
khi sau khi qua bnh brom dn kh sinh ra qua dung dch Ca(OH) 2 thu c 120g
mui trung tnh v 140,94g mui axit
1/Tnh thnh phn % th tch ca hn hp u
2/Tnh t khi hi ca hn hp ban u i vi nit? s:A:C 2H6(30%);
B:C3H8(50%);1,307
Bi 25:t chy hon ton 2,24lt kh C 2H4 (kc) ri hp th ton b sn phm
vo dung dch cha 11,1 gam Ca(OH) 2. Hi sau khi hp th khi lng phn dung
dch tng hay gim bao nhiu gam? s:tng 2,4 gam

Bi 26:t chy hon 1 hirocacbon A sinh ra 16,8 lt CO 2 (kc) v 13,5 gam

H2O. 1g kh A c cng th tch vi 0,761 gam Oxi trong cng iu kin
a/Xc nh CTPT v CTCT ca A bit A c cu to mch h
b/Cho 1 lt hn hp gm hirocacbon trn v hiro qua bt Ni nung nng.
Hn hp kh sn phm sau khi dn qua bnh cha dung dch brom d th cn li
mt hirocacbon duy nht ng thi bnh cha dung dch nng thm 0,21g.
Tnh thnh phn % ca hn hp hai cht u? s:C3H6(55,6%) H2(44,4%)
Bi 27:Hn hp A v B l hai anken c khi lng 12,6g trn theo t l 1:1 v s
mol tc dng va vi 32g brom Nu trn hn hp trn theo t l 1:1 v khi lng th 16,8g hn hp tc dng va vi 0,6g H2 . Tm CTPT ca A v B bit
MA<MB ? s:A:C3H6; B:C6H12