CHEMISTRY

41.

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50.

Which of the following set of quantum number is not possible?

n
l
ml
ms
(a) 3
2
1
+1/2
(b) 3
2
1
1/2
(c) 3
2
1
0
(d) 5
2
1
+1/2
The linear structure is assumed by
(a) SnCl2
(b) NCO
(c) CS2
(d) (b) and (c) both
The oxidation number of phosphorus in Ba(H2PO2)2 is
(a) +3
(b) +2
(c) +1
(d) 1
In a reaction, 4 moles of electrons are transferred to one mole of HNO3. The possible product
obtained due to reduction is
(a) 0.5 mole of N2.
(b) 0.5 mole of N2O. (c) 1 mole of NO2. (d) 1 mole of NH3.
At anode in the electrolysis of fused sodium chloride
(a) Na+ is oxidised.
(b) Cl is oxidised.
(c) Cl is reduced.
(d) Na is reduced.
In the following compounds
O
N
H

N
..

N
OH

(I)

(II)

(III)

N
H
(IV)

The order of basicity is

(a) (IV) > (I) > (III) > (II)
(b) (III) > (I) > (IV) > (II)
(c) (II) > (I) > (III) > (IV)
(d) (I) > (III) > (II) > (IV)
Which of the following represents calomel?
(a) HgCl2
(b) Hg2Cl2
(c) HgSO4
(d) K2[HgI4]
0.1 M solution of which one of these substances will act as a buffer?
(a) Borax
(b) Ammonium chloride
(c) Calcium nitrate
(d) Sodium sulphate
In which of the following set all the elements have greater tendency to form simple anions?
(a) Na, Mg, Al
(b) Cr, Mn, V
(c) Cl, Mn, O
(d) O, N, F
Hypo on treatment with I2 forms
(a) Na2SO4 + S
(b) Na2S4O6

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54.

(c) Na2SO3
CrO3 dissolves in NaOH to form

(d) Na2S

(a) CrO 24

(b) Cr(OH)3

(c) Cr2 O 72

(d) Cr(OH)2

A physician wishes to prepare a buffer solution at pH < 7. Which of the following

combinations would be best to be used
(a) NaOH/NaCl
(b) CH3COONa/CH3COOH
(c) NH4OH/NH4Cl
(d) Na2CO3/NaOH
3.2 g of oxygen (At. weight = 16) and 0.2 g of hydrogen (At. wt. = 1) are placed in a 1.12 litre
flask at 0C. The total pressure of the gas mixture will be
(a) 1 atm
(b) 4 atm
(c) 3 atm
(d) 2 atm
Anhydrous mixture of KF and HF contains which ions
(a) K+, H+, F
(b) (KF)+, (HF)
(c) KH+, F

55.

A, B in the reaction are

CH3NO2

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57.

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60.

(d) K+, HF2

Zn HCl

carbylamine
reaction

(a) CH3NH2, CH3NC

(b) (CH3)2NH, HCN
(c) CH3OH, CH4
(d) CH3NH2, CH3CN
One mole of N2O4(g) at 300 K is kept in a closed container under one atmosphere. It is heated
to 600 K when 20% by mass of N2O4(g) decomposes to NO2(g). The resultant pressure is
(a) 1.2 atm
(b) 2.4 atm
(c) 2.0 atm
(d) 1.0 atm
0.2 g of a sample of H2O2 required 10 ml of 1 N KMnO4 in a titration in the presence of
H2SO4.
Purity of H2O2 is
(a) 25%
(b) 85%
(c) 65%
(d) 95%
A container contains CO(g) and another H2(g) in equal molar concentrations at the same
temperature. What is the ratio of average molar kinetic energies of the two gases?
(a) Depends on volume
(b) 1 : 1
(c) KECO > KE H2
(d) KE H2 > KECO
What will happen if LiAlH4 is added to an ester?
(a) Two units of alcohol are obtained.
(b) One unit of alcohol and one unit of acid is obtained.
(c) Two units of acids is obtained.
(d) None of these
Identify Z in the following series

Alc. KOH

61

62.

Br

2
C2H5I
(X)
(Y) KCN (Z)
(a) CH3 CH2CN
(b) CN CH2 CH2CN
(c) Br CH2 CH2CN
(d) BrCH=CHCN
For the reaction, P(White)
P(Red) ; H = 18.4 kJ. It follows that
(a) Red P is readily formed from white P
(b) White P is readily formed from red P
(c) White P can not be converted to red P
(d) White P can be converted into red P and red P is more stable
When sodium metal is dissolved in liquid ammonia, a blue solution is formed. The blue
colour is due to
(a) Solvated Na+ ions
(b) Solvated electrons

(c) Solvated NH 2 ions

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64.

(d) Solvated protons

Amongst the following, the most basic compound is

(a) Benzylamine
(b) Aniline
(c) Acetanilide
(d) p Nitroaniline
The principal organic product in the reaction
CH3
+ one equivalent of HI

is

CH3
I

(a)

CH2l

(b)

OH
CH3
OH

(c)

CH3

(d)

CH2l

65.

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68.

I
CH2l

Which of the following is not tetrahedral?

(a) SCl4

(b) SO 24

(c) Ni(CO)4

(d) NiCl 24

Benzaldehyde reacts with ethanolic KCN to give

(a) C6H5CHOHCN
(b) C6H5CHOHCOOH
(c) C6H5CHOHCOC6H5
(d) C6H5COCOC6H5
The rate of SN1 reaction is fastest in the hydrolysis of which of the following halides?
(a) C6H5CH2Br
(b) CH3Br
(c) (CH3)3CHBr
(d) (CH3)3CBr
0.5 g of a metal gave on oxidation, 0.7 g of its oxide, the equivalent weight of the metal is
(a) 10
(b) 14

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(c) 20
(d) 40
The electronic configuration of the element which is just above the element with atomic
number 43 in the same periodic group is
(a) 1s22s22p63s23p63d54s2
(b) 1s22s22p63s23p63d104s24p5
(c) 1s22s22p63s23p63d64s1
(d) 1s22s22p63s23p63d104s14p6
If the electrons of Hydrogen atoms are excited to 4th excited state, then the total spectral lines
falling in Paschen series are equal to:
(a) 2
(b) 10
(c) 3
(d) 4
Which of the following does not have zero entropy even at absolute zero?
(a) CO
(b) CO2
(c) NaCl
(d) All of the above
If 0.1 M NH4Cl is 1% hydrolysed, then percentage hydrolysis of 0.1 M NH4I is
(a) > 1%
(b) < 1%
(c) 1%
(d) depends on Ka
The decrease in electrical conductivity of metals with increase in temperature is due to
increase in
(a) the velocity of electrons.
(b) the resistance of the metal.
(c) the number of electrons.
(d) the number of metal atoms.
The rate of a chemical reaction generally increases rapidly even for small temperature
increase because of rapid increase in the:
(a) collision frequency.
(b) fraction of molecules with energies in excess of the activation energy.
(c) activation energy.
(d) average kinetic energy of molecules.
The number of moles of BaCO3 which contains 1.5 moles of O atoms is
(a) 0.5 mole
(b) 1 mole
3
(c) 3 moles
(d) moles
2
If the pressure on a NaCl structure is increased, then its co ordination number will
(a) increase
(b) decrease
(c) remain the same
(d) None of these
Which of the following reactions involves the formation of an intermediate, carbene?
(a) Cannizzaro reaction
(b) Kolbe-Schmidt reaction
(c) Reimer-Tiemann reaction
(d) Aldol condensation
Certain primary amino compound on treatment with [X] gave alkyl chloride, N2 and H2O.
[X] can be

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80.

(a) CS2
(b) COCl2
(c) NOCl
(d) HNO2
Tb (elevation of boiling point) for 0.05 M urea solution is 0.025C. Boiling point of 0.1 M
solution of MgCl2 (assuming complete dissolution to free ions) is
(a) 100C
(b) 100.5C
(c) 100.15C
(d) 100.05C
The density of a gaseous oxide at 2 bar is the same as that of oxygen at 5 bar. The molecular
mass of the oxide is:
(a) 40
(b) 80
(c) 160
(d) Unpredictable