Professional Documents
Culture Documents
Abstract
Liquid metal embrittlement (LME) is defined as the brittle fracture (loss of ductility) of usually ductile materials in the presence
of a liquid metal. The sensitivity to LME is likely to increase with irradiation hardening as localised stresses can promote the
aggressive action of a liquid metal. To investigate the mechanical response of irradiated materials in contact with a liquid metal,
an instrumented hot cell has been developed. The testing machine installed inside allows mechanical testing of active materials
in liquid lead lithium under well controlled chemistry conditions. Typical mechanical tests that can be carried out are slow strain
rate tests (SSRT), constant load and rising load tests at temperatures from 150 C to 500 C. In this paper the first results of the
SSRT tests with EUROFER97 in argon and leadlithium at different temperatures with different strain rates will be presented.
The SSRT test method has been chosen due to the accelerated nature of the test, i.e., during straining the oxide layer will be
ruptured and wetting of the sample surface by the leadlithium melt is promoted. The results collected up till now showed no
sign of LME. Tests with longer pre-exposure times and tests with irradiated samples will be carried out in the next phase. A
longer pre-exposure time can enhance wetting and so the susceptibility to LME. An increase of the yield stress due to irradiation
can also enhance the susceptibility to LME.
2007 Elsevier B.V. All rights reserved.
Keywords: LME; SSRT; Hot cell; Leadlithium
1. Introduction
Reduced activation steels have been developed for
application in new reactor concepts, where high neutron fluxes and long life times are anticipated. Within
the framework of the European Fusion Development
0920-3796/$ see front matter 2007 Elsevier B.V. All rights reserved.
doi:10.1016/j.fusengdes.2007.04.006
2616
Previous work showed that unirradiated EUROFER97 is not very sensitive to LME in leadlithium
eutectic. Only a few studies have been carried on LME
in Pb17Li. Cone showed that no LME was found for
stainless steel 316L at temperatures close to the melting
point of leadlithium [12]. Tests with notched tensile
specimens at 350 C under a constant uniaxial tensile
load, below the engineering yield stress, however have
evidenced that many cracks filled with Pb and possibly
Li were formed, not excluding a liquid metal embrittlement effect [13]. Borgstedt showed that with low cycle
fatigue tests with a martensitic steel there was no occurrence of LME [14] A reduced life time for this steel
during creep tests could only be observed for long exposure times, but was related to the reduced diameter of
the specimens. Martensitic steels were tested in P17Li
at 250 C by Sample and it was shown that there was no
LME in the tempered condition [15]. Tests of the heat
affected zone shows a LME susceptibility at 250 C,
while increasing the test temperature up to 400 C led
to a recovery of the ductility. Post-weld treatment was
sufficient to recover the mechanical properties. Concluding, LME could be found when materials are in the
hardened condition (HAZ) and when there is a stress
concentrator (notch). In this work the EUROFER97
samples are in the as-received conditions.
In this paper the first results of the SSRT tests with
EUROFER97 in argon and leadlithium will be presented. This SSRT technique is used to investigate the
susceptibility of a metal or alloy to stress corrosion
cracking in a certain corrosive environment. According to the ASTM-standard G 129-95 [11] the results
of a SSRT experiment are not intended to necessarily represent service conditions, due to the accelerated
nature of the test. However, it provides a basis for
screening, for detection of an environmental interaction with a material, and for comparative evaluation of
the effects of metallurgical and environmental variables
on sensitivity to known environmental cracking problems. The SSRT test method has been chosen due to
the accelerated nature of the test, i.e., during straining
the oxide layer will be ruptured and wetting of the sample surface by the leadlithium melt is promoted. The
susceptibility to LME is then expressed as a difference
in mechanical behaviour in argon and leadlithium.
2. Experiment
The LME test set-up consisted of three vessels;
besides the autoclave and loading unit two more vessels
are used to prepare a test (see Fig. 1). The first vessel
(melting tank) is only used to melt the lead mixture for
the first time. Impurities and the always present oxide
layer on top of the liquid metal can be removed. This
vessel remains outside the hot cell. The second vessel
(dump tank) is used to condition the liquid metal with
2617
Fig. 1. Simplified flow sheet of the LME slow strain rate test set-up; (1) melting tank, (2) dump tank and (3) autoclave.
a gas, for example argon or hydrogen. After the conditioning, the liquid metal mixture is ready to be used for
testing. Part of this set-up consists of a vacuum pump
and an argon gas supply, which are used to prevent the
contact of liquid metal with air and humidity. Tensile
tests can be performed with a loading unit allowing
strain rates in the range of 103 107 s1 with a maximum load of 20 kN. Fig. 2 shows the part of the set-up
that stays in the hot cell. Table 1 shows the technical
specifications.
A typical test is then performed as follows. The first
vessel (melting tank) is filled with solid particles of
lead. Then the melting tank is heated to melt the lead.
Melting can be performed under argon atmosphere.
Then the melted lead is transported to the second vessel
(dump tank) leaving the oxides formed during melting in the first vessel. A small over pressure is used
to move the liquid metal from the melting tank (1)
to the dump tank (2). From the dump tank, the lead
melt can be transported to the autoclave (3) in the same
way. A tensile specimen will be positioned in the tensile rig. This rig is present in the autoclave (3). Then
the autoclave is filled with the melted lead and a slow
strain rate tensile test can be carried out. Notice that the
liquid leadlithium is static, i.e., there is no forced
convection in the autoclave. When this tensile test is fin-
Max. 550 C
Max. 4 bar
20 kN
9 102 to
3 106 mm s1
9 103 to 3 107 s1
30 mm
Tensile specimen,
compact tension, O-ring
1
3.6 l
5.3 l
9.6 l
316 L
Hydrogen, argon
2618
Fig. 2. Schematic of the LIMETS2 with autoclave, dumptank, tensile machine and gas control panel.
Table 2
Test matrix EUROFER97, unirradiated smooth tensile specimen
Concentration (g/g)
Pb
Li
Cr
Ni
Fe
Bal.
60008000
<1
1.4
<100
2619
Table 3
Test matrix EUROFER97, unirradiated smooth tensile specimen
T ( C)
250
300
400
Pb-17Li
Inert gas
Pb-17Li
Inert gas
Pb-17Li
10E4
10E4
10E4
10E4
10E4
10E4
10E5
10E5
10E6
10E6
2620
Acknowledgement
This work, supported by the European Communities under the contract of Association between
EURATOM/TTMS-003 in association with the Belgian State, was carried out within the framework of
the European Fusion Development Agreement. The
views and opinions expressed herein do not necessarily
reflect those of the European Commission. The authors
wish to thank Mr. L. Eysermans for the technical assistance during the tests with and the development of the
LIMETS2 test set-up.
References
[1] S. Van Dyck, R.W. Bosch, Stress corrosion susceptibility
of ferritic-martensitic stainless steels for fusion applications
in high temperature water, in: Proceedings of EUROCORR,
2001.
[2] S. Van Dyck, R.W. Bosch, Fus. Eng. Design 7579 (2005) 973.
[3] C.F. Old, J. Nucl. Mat. 92 (1980) 2.
[4] B. Joseph, M. Picat, F. Barbier, Eur. Phys. J. AP 5 (1999) 19.
[5] R.W. Bosch, A. Al Mazouzi, D. Sapundjiev, H. Dekien,
Development of a Hot Cell Test Set-Up for Liquid Metal Embrittlement (LME) Studies in Lead-Lithium and Lead-Bismuth,
EUROCORR 2005, Lisbon, Portugal, 2005.
[6] R.W. Bosch, A. Al Mazouzi, D. Sapundjiev, H. Dekien,
Development of a Hot Cell Test Set-Up for Liquid Metal Embrittlement (LME) Studies in Lead-Lithium and Lead-Bismuth,
HotLab 2005, Petten, The Netherlands, 2005.
[7] P.J.L. Fernandes, D.R.H. Jones, Int. Mat. Rev. 42 (1997) 251.
[8] P.J.L. Fernandes, R.E. Clegg, D.R.H. Jones, Eng. Fail. Anal. 1
(1994) 51.
[9] ASM Handbook, vol. 13, Corrosion, 1996, p. 426.
[10] D.G. Kolman, R. Chavarria, Corrosion 60 (2004) 254.
[11] Standard Practice for Slow Strain Rate Testing to Evaluate
the Susceptibility of Metallic Materials to Environmentally
Assisted Cracking, ASTM G 129-95, Annual Book of ASTM
Standards, Vol. 03.02, 1995. ASTM SSRT.
[12] V. Coen, P. Fenici, H. Kolbe, L. Orecchia, T. Sasaki, J. Nucl.
Mat. 110 (1982) 108.
[13] V. Coen, H. Kolbe, L. Orecchia, J. Nucl. Mat. 155157 (1988)
740.
[14] H.U. Borgstedt, G. Frees, M. Grundmann, Z. Peric, Fus. Eng.
Design 14 (1991) 329.
[15] T. Sample, J. Nucl. Mat. 283287 (2000) 1336.