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Applied Geochemistry
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Department of Basic Sciences and Humanities, University of Engineering and Technology, KSK Campus, GT Road, Lahore, Pakistan
Chemistry Department, University of Engineering and Technology, GT Road, Lahore, Pakistan
a r t i c l e
i n f o
Article history:
Received 8 September 2011
Accepted 17 April 2012
Available online 25 April 2012
Editorial handling by R. Fuge
a b s t r a c t
In a previous study, oils in the Potwar Basin (Upper Indus) of Pakistan were correlated based on the dissimilarity of source and depositional environment of organic matter (OM) using biomarkers and bulk
stable isotopes. This study is aimed at supporting the classication of Potwar Basin oils into three groups
(A, B and C) using the distribution of alkylnaphthalenes, alkylphenanthrenes, alkyldibenzothiophenes,
alkyldibenzofurans, alkyluorenes, alkylbiphenyls, triaromatic steroids, methyl triaromatic steroids,
retene, methyl retenes and cadalene. The higher relative abundance of specic methyl isomers of naphthalene and phenanthrene and the presence of diagnostic aromatic biomarkers clearly indicate the terrigenous and oxic depositional environment of OM for group A oil. Group B and C oils are of marine origin
and the aforementioned heterocyclic and polycyclic aromatic hydrocarbons (HCs) differentiate them
clearly into two different groups. The relative percentages of heterocyclic aromatic HCs reveal that the
distribution of these compounds is controlled by the depositional environment of the OM. Sulfur-containing heterocyclic aromatic HCs are higher in crude oils generated from source rocks deposited in suboxic
depositional environments, while oxygen-containing heterocyclic aromatic HCs in combination with
alkyluorenes are higher in marine oxic and deltaic oils. Biomarker and aromatic HC parameters do
not indicate signicant differences in the thermal maturity of Potwar Basin oils. Triaromatic and methyl
triaromatic steroids support the division of Potwar Basin oils into the three groups and their relative
abundances are related to source OM rather than thermal maturity. Signicantly higher amounts of
C20 and C21 triaromtic steroids and the presence or absence of long chain triaromatic steroids (C25, C26,
C27, and C28) indicates that these compounds are probably formed from different biological precursors
in each group. Different isomers of methyl substituted triaromatic steroids are present only for short
chain compounds (C20C22) and the origin of these compounds may be short chain methyl steranes from
unknown biological precursors.
2012 Elsevier Ltd. All rights reserved.
1. Introduction
The Potwar Basin (Upper Indus) is one of the main petroliferous
provinces of Pakistan and exploration activities in the basin began
more than a century ago. Although, the origin of Potwar Basin
petroleum has been the subject of discussion for last few decades
(Khan et al., 1986; Asif and Fazeelat, 2006; Ahmed and Alam,
2007; Fazeelat et al., 2009, 2011), geochemical information about
the source rocks and crude oils has not been extensively investigated until recently. A number of source rocks and reservoir rocks
from the basin have been studied and it is generally believed that
the Paleocene Patala shale is the source rock for most of the Potwar
Basin crude oils (Wandrey et al., 2004; Fazeelat et al., 2010). The
correlation between source rocks and crude oils has not yet been
conrmed by any authentic organic geochemical study.
Potwar Basin oils are trapped in small to medium sized reservoirs and are suggested to have originated from tectonic activities
resulting from the collision between the Eurasian and Indian Plates
(Farah et al., 1984). The geological ages of the reservoir formations
of the Potwar Basin oils are quite variable (see Fig. 1) and the reservoir depths range from about 2000 to 4500 m (Table 1). Detailed
descriptions on the quality of the reservoir rocks of the Potwar Basin
oils are given elsewhere (Khan et al., 1986; Wandrey et al., 2004;
Asif et al., 2011). A brief description of the reservoir formations
follows. The ages range from Precambrian to Tertiary (Fig. 1). The
Cambrian rocks of the reservoirs consist of massive layers of carbonates and evaporates along with marine shales, while in Permian
times, siltstone, glacial tillites and shales were deposited in the Potwar Basin. The Jurassic strata of the Basin consist of siliciclastics and
a few non-marine sandstone deposits (Khan et al., 1986). Eocene
deposits are the most signicant reservoir rocks in the area and they
1656
Fig. 1. Location map with analyzed oils indicated, these are also marked on the stratigraphy corresponding to reservoir formations of the Potwar Basin. Possible source rocks
and reservoir rocks in the basin are also marked on the right of the stratigraphic unit. Modied and altered from Wandrey et al. (2004) and references therein.
shown to be a precursor for alkylnaphthalenes (Pttmann and Villar, 1987; Strachan et al., 1988). Similarly, abietane and pimarane
type precursors from diterpenoids are most likely the source of
alkylphenanthrenes (Simoneit et al., 1986). The distribution and
relative abundance of aromatic HCs have been used to identify
the source OM, depositional environment, and as thermal maturity
indicators of source rocks and crude oils (Radke et al., 1982, 1986,
2000; Alexander et al., 1992b; Jinggui et al., 2005; Armstroff et al.,
2006). Heterocyclic aromatic HCs, i.e., dibenzothiophene (DBT),
dibenzofuran (DBF) and uorene (F) have similar structure skeletons and have been suggested to originate from a similar precursor,
biphenyl (Asif et al., 2010). The abundance of these compounds has
been related to the nature of the depositional environment of the
OM and has been applied to source and oil correlations of petroleum (Fan et al., 1990; Radke and Willsch, 1994; Radke et al.,
2000; Jinggui et al., 2005; Xiangchun et al., 2011).
2. Experimental
The sample preparation, liquid chromatography, and gas chromatography mass spectrometery (GCMS) analyses are similar to
those of Asif et al. (2011). Heterocyclic and aromatic HCs were
2680
2187
2063
3640
3545
2773
2694
3063
3318
2687
2179
2103
3612
4096
4174
4485
4450
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
P11
P12
P13
P14
P15
P16
P17
P18
Khewra
Chorgali
Jutana
Jutana
Jutana
Khewra
Khewra
Khewra/
Tobra
Khewra/
Tobra
Khewra
Chorgali
Chorgali/
Sakaser
Chorgali/
Sakaser
Chorgali/
Sakaser
Chorgali/
Sakaser
Chorgali/
Sakaser
Datta
Datta
Formation
Reservoir*
Jurrasic
Jurrasic
Eocene
Eocene
Eocene
Eocene
Cambrian
Eocene
Eocene
Cambrian
Cambrian
Eocene
Cambrian
Cambrian
Cambrian
Cambrian
Cambrian
Cambrian
Age
1.40
1.15
1.27
1.28
1.03
1.57
2.04
2.44
2.36
1.33
3.46
1.19
1.19
2.31
1.93
2.00
1.74
1.75
125-/127TMN
1.84
2.16
1.77
2.20
1.50
1.64
1.47
1.57
1.55
1.36
2.49
1.54
1.46
1.55
1.58
1.52
1.44
1.52
1,2,6-/1,2,4TMN
0.53
0.57
n.d.
0.60
0.70
0.74
n.d
1.17
n.d
0.88
1.73
0.76
0.78
1.12
1.12
1.16
1.09
0.92
1,2,5,6-/1,2,5,7TeMN**
10.2
9.0
n.d.
11.4
8.3
5.5
n.d.
1.4
n.d.
4.0
1.4
6.1
5.3
2.6
2.9
2.7
3.4
3.4
1,3,6,7-/1,2,5,6TeMN**
0.76
0.79
0.72
0.79
0.69
0.74
0.77
0.81
0.77
0.76
0.84
0.85
0.75
0.74
0.76
0.75
0.71
0.75
1-MP/9MP
0.34
0.33
0.34
0.32
0.28
0.27
0.25
0.25
0.25
0.28
0.53
0.27
0.28
0.24
0.28
0.25
0.26
0.27
1,7DMP/X
26
25
34
42
60
62
62
65
61
62
19
50
57
70
61
67
61
56
DBT
60
65
59
55
33
33
25
25
27
13
50
28
14
13
24
16
23
35
Relative
percentages
14
10
13
10
12
25
31
22
29
17
15
17
16
9
DBF
27
32
41
40
53
59
66
70
69
62
13
48
52
67
62
66
62
59
Alkyldibenzothiophenes
Relative percentages
54
54
50
53
40
35
24
21
22
28
49
41
35
22
27
22
27
33
Alkyluorenes
19
14
10
9
9
10
38
11
13
11
11
12
11
8
Alkyldeibenzofurans
TMN: trimethylnaphthalene; TeMN: tetramethylnaphthalene; 1-MP/9-MP: 1-methyl phenanthrene/9-methyl phenanthrene; 1,7-DMP/X; 1,7-dimethyl phenanthrene/(1,3- + 3,9- + 2,10- + 3,10-DMP);
Relative percentage of DBT: DBT/(DBT + F + DBF) and same for F and DBF;
Alkyldibenzothiophenes: dibenzothiophene + methyl dibenzothiophenes; alkyluorenes: uorene + methyl uorenes; alkyldibenzofurans: dibenzofuran + methyl dibenzofurans;
n.d.: not determined.
*
Data used from Asif et al. (2011).
**
Calculated from peak areas of chromatograms using GC WAX column (Asif et al., 2009).
Depth
(m)*
No*
Table 1
Geological information, heterocyclic and aromatic HC ratios and relative percentage data for analyzed Potwar Basin oils.
C
C
B
B
B
A
B
B
B
B
B
B
B
Group*
1658
DMBP
TMN
MN
BP
MF P
MP
TeMN
DMP
DMF
N
TMN
Group-B
(b) P-7
TMP
DMP
DMDBT
MDBT
MP
DMN
Relative intensity
Group-A
(a) P-1
DMN
TAS
TeMN P
MN
DMN
MN
Group-C
(c) P-18
TMN
TeMN P
MP DMP
TMP
30
40
50
60
70
80
90
100
(see Fig. 2. for abbreviations) than group B oils while the abundance
of TMN is higher in the latter group. The MP and DMP are equally
abundant in all groups while TMP is most abundant in group B
and C oils. It is notable that in group B oils the relative abundance
of alkylnaphthalenes and alkylphenanthrenes increases with
increase in methyl substitution, i.e. TMN > DMN > MN and
Fig. 3. Histogram showing the relative amounts of heterocyclic and aromatic HCs classes for each group of Potwar Basin oils. For abbreviations see Fig. 2.
1659
(a)
4.0
3.5
3.0
2.5
2.0
C
1.5
1.0
0.5
0.0
0.0
0.5
1.0
1.5
2.0
1,2,5,6-/1,2,5,7-TeMN
(b)
0.6
A
0.5
0.4
0.3
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1-MP/9-MP
Fig. 4. Classication of Potwar Basin oils using plots between the ratios of
naphthalene and phenanthrene isomers, a) 1,2,5-/1,2,7-TMN versus 1,2,5,6-/
1,2,5,7-TeMN ratios (b) 1,7-DMP/X versus 1-MP/9-MP ratios (Alexander et al.,
1992b).
1.8
Retene/9-MP
0.18
Retene/9-MP
2-methylretene/9-MP
Eromanga
0.12
1.2
Cooper
0.6
Gippsland
Potwar
group A
0.06
Carnarvon
DBT
2-Methylretene/9-MP
1660
B
C
Sydney
Zhanhua
0
0
0
2
Pr/Ph
Fig. 5. A three value plot showing the comparison of abundances of retene and 9methyl retene in Potwar Basin (group A oil) with oils from different basins of the
world (Bastow et al., 2001).
DBF
Fig. 6. A triplot of relative amounts of DBT, DBF and F differentiating Potwar Basin
oils into the same three groups.
is found to possess higher values for both ratios. This higher abundance of 1-MP and 1,7-DMP indicates a terrigenous source origin
for these isomers and hence for group A oil. Both group B and C oils
show close positions in the 1-MP/9-MP versus 1,7-DMP/X cross plot
(Fig. 4b) but the 1,7-DMP/X ratios are higher for group C oils separating them from group B oils.
The distributions of alkylnaphthalene and alkylphenanthrene
isomers show that the group A oil is terrigenous and group B and
C oils are marine. This is further supported by the presence of typical
terrigenous aromatic biomarkers, i.e. cadalene, retene and methyl
retenes. Retene has been suggested to be the diagenetic product of
abietic acid type biological precursors present as major constituents
of conifer resins (van Aarssen et al., 2000; Hautevelle et al., 2006).
Similarly, 2-methyl retene has been suggested to be derived from
higher plant diterpenoid biological precursors (Bastow et al.,
2001). Retene/9-MP and 2-methyl retene/9-MP ratios are plotted
against Pr/Ph from group A oil and some oils from the worlds different basins (Fig. 5). These oils have been reported to have originated
from OM of higher plant input (Ellis et al., 1995; Bastow et al., 2001).
Group A oil located in the middle of the plot (Fig. 5) shows the signicant presence of retene as well as 2-methyl retene relative to the
plotted oils of the world. This comparison shows that the group A oil
is generated from source rocks containing higher plant input. Moreover, the abundance of retene and 2-methyl retene in conjunction
with 1-MP and 1,7-DMP reveals that the origin of these compounds
is abietane type diterpenoids (Alexander et al., 1995; Tuo and Philp,
2005). Cadalene is another terrigenous marker in crude oils and sediments, but its origin is not specic and it occurs in various types of
vascular plants (van Aarssen et al., 2000; Romero-Sarmiento et al.,
2011). Cadalene is also observed in noticeable abundance only in
the group A oil aromatic hydrocarbon fraction. The occurrence of
these aromatic biomarkers clearly suggests that the source OM
of group A is terrigenous and this differentiates this group from
other groups of Potwar Basin oils.
3.3. Dibenzothiophenes, dibenzofurans and uorenes in Potwar Basin
oils
The distributions of heterocyclic aromatic HCs have been related
to the source rock lithology and depositional environment of the
OM (Hughes, 1984; Schou and Myhr, 1988; Jinggui et al., 2005).
Whereas, the abundance of S-containing heterocyclic aromatic
HCs, i.e. DBT and alkyldibenzothiophenes have been related to marine source rocks while abundance of O-containing heterocyclic
aromatic HCs, i.e. DBF and alkyldibenzofurans, and alkyluorenes
1661
alkyldibenzothiophenes
Alkylfluorenes
(a) Group A
P-1
alkyldibenzofurans
C20
P18
Group C
C21
P17
P16
C27,S
C28,S
C28,R
C27,R
P15
C20
P14
(b) Group-B
P-6
R C22
S
P13
Relative intensity
C26,R+C27,S
Group B
P12
Sample no
P11
P10
C21
C26,S
C28,S
C28,R
C25,S
C25,R
C27,R
C19
P9
(c) Group-C
P-18
P8
P7
P6
P5
P4
72
P3
Group A
P2
P1
20
40
60
76
80
84
92
88
80
Relative percentage
Fig. 7. A histogram constructed from relative percentages of alkyldibenzothiophenes, alkyldibenzofurans and alkyluorenes (see Table 1 for data) in three groups of
oils from the Potwar Basin.
shows only C27 and C28 triaromatic steroids while the group B representative ion chromatogram shows C25C28 triaromatic steroids
Table 2
Thermal maturity and source OM parameters from saturated biomarkers, triaromatic and methyl triaromatic steroids for Potwar Basin oils.
No
(bb/aa + bb)
C29Stereranes
(S/S + R)
C29steranes
MPI1
Rc
(%)
Ts/
(Ts + Tm)
C28/C27
20R
steranes
C28/C27
diasteranes
C27/C28 20R
triaromatic
steroids
S/(S + R) C28
triaromatic
steroids
C21/C22 methyl
triaromatic
steroids
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
P11
P12
P13
P14
P15
P16
P17
P18
0.59
0.66
0.65
0.64
0.63
0.61
0.63
0.61
0.64
0.59
0.59
0.62
0.63
0.63
0.61
0.61
0.63
0.62
0.41
0.43
0.41
0.44
0.45
0.45
0.45
0.47
0.47
0.48
0.46
0.45
0.45
0.47
0.45
0.43
0.44
0.47
0.75
1.07
1.02
0.80
0.90
0.85
0.92
1.04
0.89
0.91
0.85
0.90
1.26
1.14
1.16
1.14
1.07
1.09
0.85
1.04
1.01
0.88
0.94
0.91
0.95
1.03
0.93
0.94
0.91
0.94
1.16
1.08
1.10
1.08
1.04
1.05
0.53
0.40
0.36
0.36
0.37
0.38
0.41
0.40
0.45
0.35
0.31
0.38
0.45
0.73
0.67
0.66
0.70
0.70
0.37
0.18
0.33
0.22
0.16
0.24
0.23
0.19
0.22
0.21
0.34
0.27
0.24
0.24
0.97
0.79
0.78
1.06
1.4
0.4
0.8
0.5
0.6
0.5
0.4
0.5
0.5
0.5
0.6
0.8
0.4
0.5
0.8
0.47
0.33
0.89
0.92
0.63
0.58
0.56
0.58
0.64
0.83
0.73
0.66
0.43
0.56
0.49
0.75
0.59
0.51
0.50
0.55
0.55
0.54
0.54
0.53
0.55
0.50
0.52
0.51
0.60
3.2
2.5
4.8
4.0
3.5
3.1
4.1
2.5
4.6
4.1
4.1
3.4
1.5
1.1
2.0
0.6
0.6
MP + 2
MP]/[P + 1
MP + 9
Relative
percentages
triaromatic
steroids
C19
C20
C21
42
5
5
3
3
3
4
3
6
2
2
2
4
12
14
14
12
12
37
52
53
63
62
61
60
61
57
66
68
69
57
43
42
44
46
45
21
43
42
34
35
36
36
36
37
32
30
29
40
45
44
42
41
43
(a)
C19
C
B
C21
0.60
C20
1.8
1.4
(b)
C28 /C27 20R, Steranes
(Fig. 8). The absence (or below detection limit) of long chain triaromatic steroids in the group C oil representative ion chromatogram
differentiates this group from other groups (Fig. 8). Therefore, it is
very reasonable to consider that three dissimilar distributions of
triaromatic steroids are present in the Potwar Basin oils.
Triaromatic steroids from C26 to C28 compounds are supposed to
originate from demethylation and aromatization of monoaroamtic
steriods from corresponding C27 to C29 compounds (Riolo et al.,
1986; Peters et al., 2005). On the other hand short chain triaromatic steroids appear to have been generated from homolytic scission
of long chain triaromatic steroids with an increase in thermal
maturity (Seifert and Moldowan, 1978; Mackenzie et al., 1981).
Signicantly higher abundances of C20 and C21 triaromatic steroids
relative to long chain triaromatic steroids and a comparatively
negligible presence of C19 and C22 triaromatic steroids indicate factors other than thermal maturity affecting short chain triaromatic
steroids distributions (Fig. 8). Biomarker thermal maturity parameters, the (bb/aa + bb) and S/(S + R) ratios for ethylcholestane falls
in narrow ranges of 0.590.66 and 0.410.48, respectively, suggesting no major differences in thermal maturity of the Potwar Basin
oils (Table 2). Aromatic HC maturity parameters such as MPI-1
and calculated vitrinite reectance (Rc) values indicate a small variation in thermal maturity of Potwar Basin oils. MPI-1 and Rc values
for group A oil are 0.75 and 0.85, respectively, indicating a peak oil
generation window of thermal maturity while higher values are
observed for group B and C oils (0.851.26, 0.881.2, respectively)
suggesting a peak to late oil generation window of thermal maturity (Table 2). These results indicate that group A oil is less mature
than group B and C oils. The triaromatic steroids maturity parameter, S/(S + R) for the C28 compound, is available for group A and B
oils (Table 2), while this compound is absent in group C oils. Values
(0.510.60) for this parameter are indicative of a similar range of
thermal maturity for these oils. Therefore, while the thermal maturity of Potwar Basin oils show little difference, the distribution of
short chain triaromatic steroids shows differences between the
oil groups. Oil correlation is further determined using a triplot of
relative abundances of C19, C20 and C21 triaromatic steroids available for all three groups (Fig 9a and Table 2) which clearly shows
that the same three groups are present in the Potwar Basin. Long
chain triaromatic steroids show an odd distribution, where the
presence of only two compounds (C27 and C28) is detected in the
group A oil, C25C28 compounds are detected in the group B oils,
and their complete absence is observed in the group C oils. The
source origin of these compounds in Potwar Basin oils is questionable. In combination with the results from thermal maturity evaluation and short chain triaromatic steroids, it is reasonable to
suggest that the long chain triaromatic steroids in Potwar Basin
oils are generated from different source precursors for each group.
Typical source precursors for these compounds, i.e. regular and
rearranged steranes (C27, C28, C29), are signicantly abundant in
all Potwar Basin oils (Asif et al., 2011). The C27/C28 ratio for 20R
triaromatic steroids has been shown to be source dependent and
has been used for source to oil correlations (Picha and Peters,
1998). This ratio from Potwar Basin oils is compared to source
OM biomarker parameters from steranes and diasteranes (Table
2) and a three values plot is shown in Fig. 9b. Both group A and
B oils are clearly discriminated from each other. These ndings reveal that the abundance of triaromatic steroids in Potwar Basin oils
are source/depositional environment dependent and this data is
valuable for making source to oil correlations.
0.40
1.0
0.6
0.20
0.2
0.00
0.00
0.40
-0.2
1.20
0.80
(c)
1662
5.0
4.0
B
3.0
2.0
1.0
0.0
0.0
0.2
0.4
0.6
0.8
Ts/(Ts+Tm)
Fig. 9. Classication of Potwar Basin oils based on the triaromatic steroids
distribution, (a) triplot between the relative percentages of short chain triaromatic
steroids (C19, C20 and C21), (b) relationship of the three different ratios, one from
long chain triaromatic steroids i.e. C27/C28 20R and two, each from steranes and
diasteranes i.e. C28/C27 20R and C28/C27, respectively, (c) variation in C21/C22 ratio of
methyl triaromatic steroids (peaks 1/2, see Fig. 10) and Ts/(Ts + Tm) separating out
group B oils from group C oils.
1663
Group A
C 20 H 20
245
C21 H22
C22 H24
215
231
260
202
189
114
55
152
68
100
Group B
b
200
300
245
c
215
274
229
55
114
101
100
259
202
189
200
245
300
Group C
215
229
114
60
75
77
79
100
259
288
202
189
200
300
81
m/z: 245
Fig. 10. Representative ion chromatograms m/z 245 for methyl triaromatic steroids from each group of the Potwar Basin oils. The three methyl triaromatic steroids are
identied using mass spectra (small letters are used to show the mass spectra of corresponding peaks). Chromatogram at the bottom of the gure showing extended region of
ion 245 to show the absence (or presence below the detection limit) of long chain methyl triaromatic steroids.
(Fig. 10). It is apparent that reasonable difference in the distribution of methyl isomers of these compounds is present in group B
and C representative ion chromatograms. This observation is reinforced using a plot between the ratio of C21/C22 methyl triaromatic
steroids of selected methyl isomers and Ts/(Ts + Tm) (Fig. 9c and
Table 2), where the Ts/(Ts + Tm) ratio has been related to the
source/depositional environment of source rocks for the Potwar
Basin oils (Asif et al., 2011). The plot clearly differentiates group
1664
B and C oils and shows that the methyl triaromatic steroids distribution supports the classication of Potwar Basin oils.
The reason for the higher abundance of C20 and C21 triaromatic
steroids and C21 and C22 methyl triaromatic steroids in Potwar Basin oils is unknown. A possible explanation could be the extent of
thermal maturity, which would increase the abundance of short
chain triaromatic steroids (Peters et al., 2005). Conversely, thermal
maturity results do not show sufcient signicant variation to be
the reason for such differences in distribution between long chain
and short chain triaromatic steroids. Therefore, it is easy to suggest
that triaromatic and methyl triaromatic steroids in the Potwar Basin are source dependent. Short chain steranes and methyl steranes
may be the direct precursors for these short chain triaromatic and
methyl triaromatic steroids, respectively, in the Potwar Basin oils
from unknown biological origin (Lichtfouse et al., 1990, 1993).
4. Conclusions
The distribution and relative amounts of heterocyclic and polycyclic aromatic HCs support the previous classication of Potwar
Basin crude oils into the three groups (A, B and C). A highly oxic
environment of deposition and enrichment in terrigenous OM is
the characteristics of group A oil. Abundance of specic methyl isomers from naphthalene and phenanthrene indicate higher plant input from gymnosperms. Diagnostic aromatic biomarkers such as
retene, methyl retenes and cadalene also reveal the higher plant
resin contributions to group A oil OM. Groups B and C are marine
oils. Difference in source and depositional environment of OM discriminates them into two groups. Heterocyclic aromatic HCs provide good indicators for the depositional environments whereas
the abundance of alkyluorenes and alkyldibenzofurans can be related to the oxic/deltaic depositional environment and terrigenous
source OM. Source rocks deposited in marine suboxic depositional
environments generate an abundance of S-containing heterocyclic
aromatic HCs while marine oxic oils show an abundance of alkyluorenes in conjunction with S heterocyclic compounds. The distribution of triaromatic and methyl triaromatic steroids clearly
classied Potwar Basin oils into the same three groups. The relative
abundance and odd distribution of these compounds in the Potwar
Basin is source and depositional environment dependent. The thermal maturity of Potwar Basin oils is indicative of a peak to late oil
generation window which is determined from biomarker, aromatic
HC and triaromatic steroid maturity parameters.
Acknowledgements
The authors are very grateful to the Director WA-OIGC Perth,
Australia for provided an opportunity to conduct this research
work. The authors also thank Mr. G. Chidlow for assistance with
GCMS analysis. The Higher Education Commission, Islamabad,
Pakistan is thanked for an IRSIP fellowship and a travel award
Grant (IRSIP-5-Ps-20) to M. Asif. The authors are grateful to the following exploration companies for providing crude oil samples: Oil
and Gas Development Cooperation Ltd. (OGDCL), Islamabad, Pakistan Petroleum Ltd. (PPL) and Pakistan Oilelds Ltd. (POL). Asif is
thankful to his friends Karl J. Jalkanen from California and Muneeb
Rathore from UET, KSK campus for help in revision of this manuscript. Professor Simon George, Dr. Zhibin Wei, Dr. Haiping Huang
and Professor Ron Fuge are acknowledged for constructive reviews
and editorial handling.
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