CHUYN 6

OXI LU HUNH
PHN I: L THUYT
1. OXI
TAC DUNG HAU HET MOI KIM LOAI (tr Au va Pt), can co t0 tao oxit
o

t
2Mg + O2
2MgO

Magie oxit

t
3Fe + 2O2
Fe3O4
Oxit sat t (FeO, Fe2O3)
TAC DUNG TRC TIEP CAC PHI KIM (tr halogen), can co t0 tao ra oxit
o

t
S + O2
SO2
o

t
C + O2
CO2
TAC DUNG H2 (no theo t le 2 :1 ve so mol), t0
o

t
2H2 + O2
2H2O
TAC DUNG VI CAC HP CHAT CO TNH KH
2SO2 + O2
V2O5 , 4500C
2SO3
o

t
CH4
+ 2O2
CO2 + 2H2O
2. OZON la dang thu hnh cua oxi va co tnh oxhoa manh hn O2 rat nhieu
I2 + 2KOH + O2 (oxi khong co)
O3 + 2KI + H2O
Do tao ra KOH nen O3 lam xanh qu tam dd KI (dung trong nhan biet ozon)
Ag2O + O2 (oxi khong co phan ng)
2Ag + O3
3. LU HUYNH
TAC DUNG VI NHIEU KIM LOAI
o

t
Fe + S0
FeS-2 sat II sunfua

HgS-2 thuy ngan sunfua, phan ng xay ra t0 thng

Hg + S
TAC DUNG HIDRO
o

t
H2 + S

H2S-2

hidrosunfua

TAC DUNG PHI KIM (tr Nit va Iod)

o

t
SO2
S + O2

4. HIDROSUNFUA (H2S)
TAC DUNG OXI cothe tao S hoac SO2 tuy lng oxi va cach tien hanh phan ng.
0

t
2H2S + 3O2
2H2O + 2SO2 (d oxi, ot chay)
0

t thap
2H2S + O2 t
2H2O + 2S (Dung dch H2S trong khong kh hoac lam lanh ngon la H2S ang chay)
TAC DUNG VI CLO co the tao S hay H2SO4 tuy ieu kien phan ng
8HCl + H2SO4
H2S + 4Cl2 + 4H2O
H2S + Cl2
2 HCl + S
DUNG DCH H2S CO TNH AXIT YEU : Khi tac dung dung dch kiem co the tao muoi axit hoac muoi
trung hoa
1:1
H2S + NaOH
NaHS + H2O
1::2
H2S + 2NaOH Na2S + 2H2O
5. LU HUYNH (IV) OXIT

SO2 LA CHAT KH ( S - 2e S ) Khi gap chat oxi hoa manh nh O2, Cl2, Br2 : kh SO2 ong vai tro la
chat kh.
4
V2O5
450 0
2SO3
2 S O2 + O2
4

2HCl + H2 S O 4
S O 2 + Cl2 + 2H2O
1

SO2 LA CHAT OXI HOA ( S + 4e S ) Khi tac dung chat kh manh

4

S O 2 + 2H2S
2H2O + 3 S
4

+ Mg
MgO

Ngoai ra SO2 la mot oxit axit

SO2

1:1
SO2 + NaOH
NaHSO3 (

nNaOH

2)

nSO2

1:2
Na2SO3 + H2O (
SO2 + 2 NaOH

nNaOH

1)

nSO2

Neu 1<

nNaOH

NaHSO3 : x
Na2 SO3 : y

< 2 th tao ra ca hai muoi

nSO2

mol
mol

6. LU HUYNH (VI) OXIT

TAC DUNG VI H2O tao axit sunfuric
H2SO4 + Q
SO3 + H2O
SO3 tan vo han trong H2SO4 tao oleum : H2SO4.nSO3
TAC DUNG BAZ tao muoi
SO3 + 2 NaOH
Na2SO4 + H2O
7. AXT SUNFURIC H2SO4 trang thai loang la mot axit manh, trang thai ac la mot chat oxihoa
manh.
dang loang la axt manh lam o qu tm, tac dung kim loai(trc H) giai phong H2, tac dung baz, oxit
baz va nhieu muoi.
dang ac la mot chat oxihoa manh
TAC DUNG KIM)
0

t
2Fe + 6 H2SO4
Fe2(SO4)3+ 3SO2+ 6H2O
t0
Cu + 2 H2SO4 CuSO4 + SO2+ 2H2O
Al, Fe, Cr khong tac dung vi H2SO4 ac nguoi, v kim loai b thu ong hoa.
TAC DUNG VI CAC PHI KIM
0

t
2H2SO4() + C
CO2 + 2SO2 + 2H2O
t0
2H2SO4() + S
3SO2 + 2H2O

TAC DUNG MOT SO HP CHAT CO TNH KH

t0
FeO + H2SO4 ()
Fe2(SO4)3 + SO2 + 4H2O
0

t
2HBr + H2SO4 ()

Br2 + SO2 + 2H2O

PHN II: BI TP
DNG 1: CHUI PHN NG
Phng php: Da vo tnh cht ha hc vit cc PTP:
BI TP P DNG
Cu 1: Hon thnh cc phng trnh phn ng sau:
a. S SO2 S H2S H2SO4 SO2 Na2SO3 SO2 SO3 H2SO4 FeSO4 Fe(OH)2 FeSO4
b. H2SO4 SO2 H2SO4 Fe2(SO4)3 Fe(OH)3 Fe2(SO4)3 K2SO4 BaSO4.
Cu 2 : Vit cc phng trnh phn ng thc hin cc bin ha sau :
FeS SO2 SO3 H2SO4 CuSO4 BaSO4
S H2S SO2
Cu 3: Hon thnh chui phn ng sau :
S H2S SO2 KHSO3 K2SO3 SO2 CaSO3
Cu 4: Hon thnh cc phng trnh phn ng theo s :

Hidrosunfua lu hunh kh sunfur axir sunfuric lu hunh ioxit canxi sunfit kh

sunfur lu hunh hidrosunfua axit sunfuric.

DNG 2: NHN BIT

Phng php: MUOI SUNFUA VA NHAN BIET GOC SUNFUA (S2- ) hau nh cac muoi sunfua ieu
khong tan, ch co muoi cua kim loai kiem va kiem tho tan (Na2S, K2S, CaS, BaS). Mot so muoi khong tan
va co mau ac trng CuS en, PbS en, CdS vang, SnS o gach, MnS hong.
e nhan biet S2- dung dung dch Pb(NO3)2
MUOI SUNFAT VA NHAN BIET GOC SUNFAT (SO42-)
Phan ln muoi sunfat tan, ch co BaSO4, PbSO4 khong tan co mau trang, CaSO4 t tan co mau trang.
Nhan biet goc sunfat dung dung dch cha SO42BI TP P DNG
Cu 1: Nhn bit cc dung dch mt nhn:
a.
H2SO4, HCl, NaOH, Na2SO4, HNO3.
b.
K2SO3, K2SO4, K2S, KNO3.
Cu 2: Ch dng mt thuc th hy nhn bit cc dung dch:
Na2S, Na2SO3 , BaCl2, NaCl.
Cu 3: Ch dng mt thuc th hy nhn bit cc dung dch:
H2SO4, BaCl2 , NaCl, Na2SO3, Na2S.
Cu 4: Trnh by phng php phn bit 4 cht rn : NaCl, Na2CO3, BaSO4, BaCO3 vi iu kin ch dng thm
dung dch HCl long.

DNG 3: BT VIT PTP V IU CH CHT

Phng php: Da vo tnh cht ha hc
BI TP P DNG
Cu 1: Vit 2 phng trnh chng minh:
a.
SO2 ng vai tr l cht oxi ha. SO2 ng vai tr l cht kh.
b.
H2S l cht kh. H2SO4 c l cht oxi ha.
c.
S l cht kh. S l cht oxi ha.
d.
Ozon c tnh oxi ha mnh hn oxi.
Cu 2: T FeS2, NaCl, O2 v H2O. Vit cc pt phn ng iu ch: Fe2(SO4)3, Na2SO4, nc iaven, Na2SO3,
Fe(OH)3.
Cu 3: T KCl, Cu, Fe, S v H2O. Vit cc phng trnh iu ch FeCl2, CuCl2, H2S, CuSO4, FeSO4, Fe2(SO4)3.

DNG 4: XC NH CHT
Phng php: Nm mt s cng thc tnh s mol:
n = m/M

n = CM. V

n Kh = v/ 22,4
- Tnh t l theo PTP
BI TP P DNG
Cu 1: Cho 3,36 lt O2(ktc) phn ng hon ton vi mt kim loi ha tr (III) thu c 10,2g oxit. Xc nh tn
kim loi.
Cu 2: t chy hon ton 0,84g mt kim loi ha tr (II) ht vi 0,168 lt kh O2 (ktc). Xc nh tn kim loi.
Cu 3: t chy hon ton 2,88g mt kim loi ht vi oxi thu c 4,8g oxit. Xc nh tn kim loi.
Cu 4: Cho 2,8g mt kim loi ha tr (III) tc dng ht vi dung dch axit sunfuric c nng thu c 1,68 lt kh
SO2 ktc. Xc nh tn kim loi.
Cu 5: Cho 12,15g mt kim loi tc dng ht vi 1000ml dung dch axit sunfuric 1,35M. Xc nh tn kim loi.
Cu 6: Ha tan hon ton 1,44g kim loi ha tr (II) bng 250ml dung dch H2SO4 0,3M. Sau phn ng phi
dng ht 60ml
dung dch NaOH 0,5M trung ha lng axit cn d. Xc nh tn kim loi.
Cu 7: 6,3 gam mt kim loi X c ha tr khng i tc dng hon ton vi 0,15 mol O2. Cht rn thu c sau
phn ng em ha tan vo dung dch HCl ( d) thy thot ra 1,12 lt kh H2 ktc. Xc nh kim loi X.
Cu 8: Cho 1,2 gam kim loi X ha tr II vo 150ml dung dch H2SO4 long 0,3M, X tan ht, sau ta cn
thm 60ml dung dch KOH 0,5M trung ha axit d. Xc nh kim loi X.

DNG 5: BT CHT D, CHT P HT

Phng php: p dng cc cng thc tng t DNG 3
- So snh s mol cc cht tham gia P, cht cn d l sn phm sau P.

BI TP P DNG
Cu 1: Nung hn hp gm 3,2g S v 4,2g Fe trong bnh kn n phn ng hon ton. Tnh khi lng cc cht
sau p.ng ?
Cu 2: Nung hn hp gm 3,2g S v 1,3g Zn trong bnh kn n phn ng hon ton. Tnh khi lng cc cht
sau png ?
Cu 4: Nung 5,6 g bt st v 13g km vi mt lng d lu hunh. Sn phm cu phn ng cho tan hon ton
trong dung dch axit clohidric. Kh sinh ra dn vo dung dch Pb(NO3)2 .
a.
Vit cc phng trnh phn ng xy ra?
b.
Tnh th tch dung dch Pb(NO3)2 (D = 1,1g/ml) cn hp th hon ton lng kh sinh ra.
Cu 5: Cho 8,96 lt kh (ktc) H2S vo mt bnh ng 85,2g Cl2 ri vo bnh ng mt lt nc phn ng xy
ra hon ton.
a.
Trong bnh cn kh g? Bao nhiu mol?
b.
Tnh khi lng H2SO4 sinh ra.

DNG 6: XC NH MUI TO THNH T P H2S v SO2 VI BAZ TAN

Phng php: So snh t l s mol
- Nu

nNaOH

1:1
NaHSO3
2 thi SO2 + NaOH

nSO2

- Nu

nNaOH

1:2
Na2SO3 + H2O
1 thi SO2 + 2 NaOH

nSO2

- Neu 1<

nNaOH

NaHSO3 : x
Na2 SO3 : y

< 2 th tao ra ca hai muoi

nSO2

mol
mol

- H2S + KOH tng t SO2 + NaOH

BI TP P DNG
Cu 1. Dn ton b 2,24 lt kh H2S vo 100 ml dung dch KOH 1,6M. Tnh khi lng mui sau phn ng ?
Cu 2: Cho 150 g dung dch H2S 3,4% tc dng vi 250 ml dd NaOH 1M. Tnh khi lng mui to thnh sau
phn ng.
Cu 3: Dn 4,48 lt kh SO2 (ktc) vo 300 ml dung dch NaOH 1M. Tnh khi lng mui to thnh sau phn
ng?
Cu 4: Dn kh sunfur c khi lng 6,4g vo 250g dung dch KOH 12%. Tnh khi lng mui to thnh sau
phn ng?
Cu 6. Hp th hon ton 2,24 lt kh SO2 ( ktc ) vo 100 ml dung dch Ca(OH)2 0,8M thu c m gam kt ta.
Tnh m ?
Cu 7. Hp th hon ton 3,36 lt kh SO2 ( ktc ) vo 125 ml dung dch Ba(OH)2 1M thu c m gam kt ta.
Tnh m ?
Cu 8. Hp th hon ton V lt kh SO2 ( ktc ) vo 200 ml dung dch Ca(OH)2 1M thu c 12 gam kt ta.
Tnh V ?
Cu 9. Hp th hon ton V lt kh SO2 ( ktc ) vo 300 ml dung dch Ba(OH)2 0,8M thu c 21,7 gam kt ta.
Tnh V ?

DNG 7: TON V H2SO4

Phng php: Tnh theo PTP
- CNG THC TNH NHANH GII BI TP TRC NGHIM H2SO4

Cng thc 1 :
o Tnh khi lng mui sunfat thu c khi ha tan ht 1 hoc hn hp kim loi (trc hiro)
bng H2SO4(long) to H2 :
m = mhh + 96.n H 2

Cng thc 2 :
o Tm kim loi khi cho m (gam) kim loi(trc hiro) tc dng H2SO4 (long) gii phng H2 :

M=

m.a
2.n H 2

(a= s oxi ha thp ca kim loi = s e kim loi nhng = ha tr thp ca kim loi )
Cng thc 3:
o c im ca phn ng :
Kim loi (tr Au ,Pt) + H2SO4 c (nng) Mui sunfat + Sn phm kh
+
(Al , Fe khng phn ng vi H2SO4 c ngui )
0

H2O

ne ( n = 1,2,3 )

Cng thc 4:
o Khi lng mui sunfat (m) thu c khi cho 1 hoc hn hp cc kim loai tc dng H2SO4
(c,nng) to mt hoc hn hp cc sn phm kh :
m = mhhkl + 96.n SO2 ;
m = mhhkl + 96.3.n S ; m = mhhkl + 96.4.n H 2 S
Cng thc 5 :
o Tm kim loi khi cho m (gam) kim loi tc dng H2SO4 (c,nng) to mt hoc hn hp cc
sn phm kh :
M=

m.a
2.n SO2

; M=

m.a
6.n S

M=

m.a
8.n H 2 S

Cng thc 6 :
o Tnh khi lng m (gam) mui sunfat thu c khi ha tan ht m(gam) 1 hoc hn hp oxit
kim loi bng H2SO4(long) :
m = moxit + 80. n H 2 SO4
Cng thc 7 :
o Khi lng m (gam)mui thu c khi ha tan ht mhh(gam) Fe ,FeO , Fe2O3,Fe3O4(khng
nht thit phi 4 cht v phi c oxit st) bng H2SO4 (c,nng) to mt hoc hn hp
cc sn phm kh :

400
(m hh 16.n SO2 )
160
400
(m hh 48.n S )
m =
160

m=

m=

400
(m hh 64.n H 2 S ) ;
160

Khi nung m(gam) Fe ngoi khng kh , cho m hh(gam) hn hp cc cht thu c vo H2SO4
(c,nng) to mt hoc hn hp cc sn phm kh :

56
(mhh 16.n SO2 )
80
56
(mhh 48.n S )
m =
80
m=

m=

56
(mhh 64.n H 2S ) ;
80

BI TP P DNG
Cu 1-Ha tan ht 11,1 gam hn hp 3 kim loi trong dung dch H2SO4 long d thu c dung dch A v 8,96
lt kh (ktc) .C cn dung dch A thu c m gam mui khan . m c gi tr l :
A . 59,1 gam
B. 35,1 gam
C. 49,5 gam
D. 30,3 gam
Cu 2-Ha tan ht 20,608 gam mt kim loi M bng dung dch H2SO4 long d thu c dung dch A v V lt
kh (ktc) . C cn dung dch A thu c 70,0672 gam mui khan . M l :
A . Na
B. Mg
C. Fe
D. Ca
Cu 3-Cho 13,33 gam hn hp Al,Cu,Mg tc dng vi dung dch H2SO4long d thu c dung dch A , 7,728
lt kh (ktc) v 6,4 gam cht rn khng tan . C cn dung dch A thu c bao nhiu gam mui khan ?
A . 40,05 gam
B. 42,25 gam
C. 25,35 gam
D. 46,65 gam
Cu 4-Ha tan ht hn hp X gm 0,12 mol Fe v 0,24 mol kim loi M trong dung dch H2SO4 long d thu
c dung dch A v 10,752 lt kh (ktc) C cn dung dch A thu c 59,28 gam mui khan . Ml :
A . Na
B. Mg
C. Ca
D. Al
Cu 5-Cho 15,82 gam hn hp Al,Fe,Cu tc dng ht vi dung dch H2SO4 c nng thu c dung dch A v
9,632 lt SO2 (ktc) . C cn dung dch A s thu c s gam mui khan l :
A. 57,1
B. 60,3
C.58,81
D.54,81

Cu 6-Cho 13,248 gam mt kim loi M tc dng vi dung dch H2SO4 c nng d thu c V lt kh H2S
(ktc) v dung dch A .C cn dung dch A . C cn dung dch A thu c 66,24 gam mui khan . V c gi tr
l :
A . 2,4640 lt
B. 4,2112 lt
C. 4,7488 lt
D. 3,0912 lt
Cu 7-Ha tan ht m gam hn hp 3 kim loi bng H2SO4c nng d thu c 11,782 lt SO2(ktc) v dung
dch A . C cn dung dch A thu c 71,06 gam mui khan . m c gi tr l :
A. 20,57
B. 60,35
C.58,81
D.54,81
Cu 8-Ha tan hn hp A gm 16,8 gam Fe ; 2,7 gam Al v 5,4 gam Ag tc dng vi H2SO4 c nng ch thot
ra kh SO2 . S mol H2SO4 tham gia phn ng l :
A. 1,25 mol
B. 1,20 mol
C.1,45 mol
D.1,85 mol
Cu 9-Cho 7,40 gam hn hp kim loi Ag , Al , Mg tan ht trong dung dch H2SO4 c nng d thu c hn
hp sn phm kh gm 0,015 mol S v 0,0125 mol H2S v dung dch A . C cn dung dch A thu c bao
nhiu gam mui khan ?
A . 12,65 gam
B. 15,62 gam
C. 16,52 gam
D. 15,26 gam
Cu 10-Ha tan hon ton 49,6 gam hn hp X gm Fe , FeO , Fe2O3 v Fe3O4 dung dch H2SO4 c nng thu
c dung dch Y v 8,96 lt kh SO2 (ktc) . C cn dung dch Y thu c m gam mui khan . m c gi tr l :
A . 145 gam
B. 140 gam
C. 150 gam
D. 155 gam
Cu 11-Ha tan 6,76 gam hn hp ba oxit Fe3O4 , Al2O3 , v CuO bng 100ml dung dch H2SO4 1,3 M va ,
thu c dung dch Y c ha tan cc mui . C cn dung dch Y thu c m gam hn hp cc mui khan . m c
gi tr l :
A . 15,47 gam
B. 16,35 gam
C. 17,16 gam
D. 19,5 gam
Cu 12-Cho m gam hn hp A gm 3 oxit kim loi MgO , ZnO , Fe2O3 ha tan va trong 300 ml dung dch
H2SO4 0,1 M , thu c dung dch Y . C cn dung dch Y thu c 5,21 gam hn hp cc mui sunfat khan .
Ga tr ca m l :
A . 2,85 gam
B.2,30 gam
C. 2,35 gam
D. 2,81 gam
Cu 13-Cho 2,81 gam hn hp gm 3 oxit MgO , ZnO , Fe2O3 ha tan va trong 300 ml dung dch H2SO4
long , thu c dung dch Y . C cn dung dch Y thu c 5,21 gam hn hp cc mui sunfat khan . Nng
mol/l ca dung dch H2SO4 :
A . 0,5 M
B. 0,1 M
C. 0,3 M
D. 0,4 M
Cu 14-Cho hn hp X gm 5,4 gam Al , 4,8 gam Mg v 13 gam Zn tc dng vi dung dch H2SO4 c , nng
d thu c 0,175 mol mt sn phm kh duy nht l X . X l :
A . SO2
B. S
C. H2S
D. H2
Cu 15-Cho 9 gam hn hp Al v Mg c t l s mol Al: Mg = 4:3 tc dng vi tc dng vi H2SO4 c nng
va (cha 0,5625 mol H2SO4 ) thu c 1 sn phm kh duy nht X . X l :
B. S
C. H 2S
A . SO2
D. H2
Cu 16-Ha tan ht 1,360 gam hn hp 2 kim loi X,Y trong dung dch H2SO4 long , thu c 0,672 lt kh
(ktc) v m gam mui . Ga tr ca m l :
B. 4,42 gam
A. 2,44 gam
C. 24.4 gam
D. 4,24 gam
Cu 17-Ha tan hon ton 19,2 gam kim loi M trong dung dch H2SO4 c nng d thu c kh mi xc .
Cho kh ny hp th hon ton trong 1 lt dung dch NaOH 0,6 M , sau phn ng em c cn dung dch thu
c 37,8 gam cht rn , kim loi M l :
A. Cu
B. Ca
C. Fe
D. Mg
Cu 18-Oxi ha hon ton 14,30 gam hn hp bt cc kim loi Mg , Al , Zn bng oxi d thu c 22,3 gam
hn hp oxit . Cho lng oxit ny tc dng ht vi dung dch HCl th lng mui to ra l :
A. 48,.90 gam
B. 36,60 gam
C. 32,050 gam
D. 49,80 gam
Cu 19-Cho 5,6 gam Fe tc dng vi dung dch H2SO4 c nng thu c 0,84 lt kh (ktc) gm mt sn phm
kh duy nht . Sn phm kh duy nht l :
A . SO2
B. S
C. H2S
D. H2
Cu 20-Nung m gam bt st ngoi khng kh sau mt thi gian thu c hn hp X gm 4 cht c khi lng
75,2 gam . Cho X tc dng vi H2SO4 c nng , d thu c 6,72 lt kh SO2 duy nht (ktc) . Ga tr m l :
A. 56 gam
B. 5,6 gam
C. 52 gam
D. 11,2 gam
Cu 21-Ha tan hon ton 2,81 gam hn hp Fe2O3 , MgO , ZnO trong 500 ml dung dch H2SO4 0,1 M (va
) . Sau phn ng , khi lng hn hp mui khan khi c cn l :
A. 3,81 gam
B. 4,81 gam
C. 5,81 gam
D. 6,81 gam
Cu 22-Cho 55,2 gam hn hp X gm 2 oxit kim loi FeO v Al2O3 tan va trong 700ml dung dch H2SO4
2M . C cn dung dch sau phn ng thu c m gam mui khan . Ga tr ca m l :
A. 98,8 gam
B. 167,2 gam
C. 136,8 gam
D. 219,2 gam
Cu 23-Cho 2,54 gam hn hp Y gm 3 oxit FeO , MgO , Al2O3 tan va trong 300 ml dung dch H2SO4
0,2M . C cn dung dch sau phn ng thu c m gam mui khan . Ga tr ca m l :
A. 7,34 gam
B. 5,82 gam
C. 4,94 gam
D. 6,34 gam

Cu 24-Cho 38,3 gam hn hp 4 oxit kim loi Fe2O3 , MgO , ZnO v Al2O3 tan va trong 800 ml dung dch
H2SO4 1M . C cn dung dch th thu c a gam mui khan . Ga tr ca a l :
A. 68,1 gam
B. 86,2 gam
C. 102,3 gam
D. 93,3 gam
Cu 25-Ha tan ht 4,20 gam hn hp 3 kim loi X,Y,Z bng dung dch H2SO4 c , nng thu c 0,025 mol
S (sn phm kh duy nht ) . C cn dung dch thu c sau phn ng thu c m gam mui khan . Ga tr ca
m l :
A. 14,10 gam
B. 11,40 gam
C. 6,60 gam
D. 1,410 gam
Cu 26-Ha tan hon ton 11,90 gam hn hp 3 kim loi X,Y,Z bng dung dch H2SO4 c , nng thu c
7,616 lt kh SO2 (ktc) , 0,640 gam S v dung dch X .C cn dung dch X thu c m gam mui khan . Ga
tr ca m l :
A. 50,30 gam
B. 30,50 gam
C. 35,00 gam
D. 30,05 gam
Cu 27-Cho 1,26 gam hn hp Mg v Al c t l mol tng ng l 3:2 tc dng vi H2SO4 c ,nng va
thu c 0,015 mol mt sn phm kh c cha lu hunh . Sn phm kh l :
A . SO2
B. S
C. H2S
D. H2
Cu 28-Ha tan hon ton a gam FexOy bng dung dch H2SO4 bng dung dch H2SO4 m c nng va ,
c cha 0,075 mol H2SO4 thu c b gam mt mui c 168 ml kh SO2 (ktc) duy nht thot ra . Cng thc
ca FexOy v gi tr ca a , b l :
A . Fe3O4 ; 3,48 ; 9 B. Fe2O3 ; 2,45 ; 7
C. FeO ; 3,45 ; 5
D. Fe2O3 ; 2,48 ; 5
Cu 29-Khi ha tan mt oxit kim loi ha tr II bng mt lng va dung dch H2SO4 9,8% th thu c
dung dch mui c nng 14,8% . Cng thc phn t ca oxit kim loi l :
A . CaO
B. CuO
C. MgO
D. BaO
Cu 30-Ha tan 9,6 gam mt kim loi M trong dung dch H2SO4 c nng d thu c 3,36 lt kh SO2 (ktc)
v thu c dung dch A . C cn dung dch A thu c mui sunfat khan . Kim loi M v khi lng mui
sunfat khan l :
A . Mg ; 21gam
B. Fe ; 23 gam
C. Cu ; 24 gam
D. Zn ; 27 gam
Cu 31-Cho 29 gam hn hp Mg,Zn,Fe tc dng ht vi dung dch H2SO4long thy thot ra V lt kh (ktc) .
C cn dung dch sau phn ng thu c 86,6 gam mui khan . Ga tr ca V l :
A . 6,72 lt
B. 13,44 lt
C. 22,4 lt
D. 4,48 lt
Cu 32-Ha tan m gam hn hp X gm FeO , Fe2O3 , Fe3O4 bng H2SO4 c nng , d thu c 11,2 lt kh
SO2 duy nht (ktc) v dung dch X . C cn dung dch X thu c 95 gam mui khan . . Ga tr ca m l :
A. 20 gam
B. 30 gam
C. 40 gam
D. 50 gam
Cu 33-Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c nng , d thu c V lt kh SO2
(ktc) v dung dch X . C cn
dung dch X thu c 58 gam mui khan . Ga tr ca V l :
A . 3,248 lt
B. 13,45 lt
C. 22,40 lt
D. 4,48 lt
Cu 34-Ha tan 30 gam hn hp X gm FeO , Fe 2O3 , Fe3O4 bng H2SO4 c nng , d thu c 11,2 lt kh
SO2 duy nht (ktc) v dung dch X . C cn dung dch X thu c m gam mui khan . . Ga tr ca m l :
A . 56 gam
B. 95 gam
C. 52 gam
D. 112 gam
Cu 35-Ha tan hon ton 11,9 gam Al , Zn vo dung dch H 2SO4 c nng , thu c dung dch X ; 7,616 lt
kh SO2 (ktc) v 0,64 gam S . Tng khi lng mui trong X l :
A. 50,3 gam
B. 49,8 gam
C. 47,15 gam
D. 45,26 gam