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catalytic)
Prof. K.K.Pant
Department of Chemical Engineering
IIT Delhi.
kkpant@chemical.iitd.ac.in
-r =
A
'
CAg
H
H
H
A +
A
+ A +
k a k a k ac k ' C f
Ag i
Al i
Ac
A B s
1
-r ' =k vgC
A
Ag
CB >> CA
Since pure hydrogen; p A is constant throughout the packed column. And since
the rate is only dependent on CA and not on CB, this means that the rate of
reaction is constant throughout the column.
Thiele Modulus MT or
= 1/ = ~0.01
6
Here two resistances in series, of the gas film and of the liquid
film. The rate of transfer of A from gas to liquid is given by the rate
expressions, for the gas film
13
All sorts of special forms of the rate equation can result depending
on the relative values of the rate constants k, kg, and k,, the
concentration ratio of reactants pA /CB, and Henry's law constant HA.
There are eight cases to consider, going from the extreme of
infinitely fast reaction rate (mass transfer control) to the other
extreme of very slow reaction rate (no mass transfer resistance
need be considered)
Case A: Instantaneous reaction with low CB,
Case B: Instantaneous reaction with high CB
Case C: Fast reaction in liquid film, with low CB
Case D: Fast reaction in liquid film, with high C,
Case E and F: Intermediate rate with reaction in the film and in the
main body of the liquid
Case G: Slow reaction in main body but with film resistance
Case W: Slow reaction, no mass transfer resistance
Figure : Concentration of reactants as visualized by the twofilm theory for an infinitely fast irreversible reactions of any
order, A + bB products. Case A-low CB, Case B high CB,
16
The absorption of A from gas is larger when reaction occurs within the
liquid film than for straight mass transfer.
Thus for the same concentrations at the two boundaries of the liquid film
we have
E >1
19
The absorption of A from gas is larger when reaction occurs within the
liquid film than for straight mass transfer.
Thus for the same concentrations at the two boundaries of the liquid film
we have
E >1
MH >1 ALL REACTION IN FILM and surface area is controlling factor. MH >2 ,
REAXN IN FILM, INSTANTANEOUS Reaction (BUBBLE COLUMN)
MH < 1, No Reaction in Film, and bulk liquid volume is controlling
MH < 0.02 INFINITELY SLOW REACTION ( BUBBLE COLUMN )