Safety Data Sheet Highlights

Safety Data Sheet
according to Regulation (EC) No 1907/2006
Stellatex HC Hardener
Print date: 11.04.2013
Page 1 of 11
Product code: 92074806
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Further trade names
valid for all package sizes
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Reserved for industrial and professional use.

Coatings and paints, fillers, putties, thinners Curing agent (crosslinking agent)
Uses advised against
The product is intended for professional use.

1.3. Details of the supplier of the safety data sheet
Company name:
Street:
Place:
Telephone:
e-mail:
DSB Surebau GmbH

Knigswinter
Bachstrae 38
D-53639 Knigswinter
+49 2223 928 0
info@didiersb.de
Contact person:
e-mail:
Surebau Labor
msds@didiersb.de
Internet:
Responsible Department:
www.didiersb.de
+49 2223 928 321
Telefax: +49 2223 928 461

Telephone: +49 2223 928 321
(001) 352 3233500 Emtel-Customer-No. 99496
1.4. Emergency telephone

number:
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Indications of danger: T - Toxic, Xn - Harmful, N - Dangerous for the environment

R phrases:
May cause cancer.
Harmful by inhalation and if swallowed.
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
May cause sensitisation by skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Possible risks of irreversible effects.
2.2. Label elements
Danger symbols:
T - Toxic
Revision No: 1,00
T - Toxic; N - Dangerous for the environment
N - Dangerous for the

environment
GB - EN
Revision date: 11.04.2013
Safety Data Sheet

Page 2 of 11
Hazardous components which must be listed on the label

benzyl alcohol
4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline
R phrases
45
20/22
39/23/24/25
43
48/20/21/22
51/53
68
S phrases
53
45
61
May cause cancer.

Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
Harmful: danger of serious damage to health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
Avoid exposure - obtain special instructions before use.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
Avoid release to the environment. Refer to special instructions / Safety data sheets.
Special labelling of certain mixtures

Restricted to professional users.
2.3. Other hazards
Keep away from food, drink and animal feedingstuffs. Do not empty into drains or the aquatic
environment. Do not allow to enter into soil/subsoil.
SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Mixture related information:
amines.
Hazardous components
EC No
CAS No
Index No
REACH No
Quantity
Chemical name
Classification
GHS classification
50 - 55 %
202-859-9
100-51-6
benzyl alcohol
Xn - Harmful R20/22
603-057-00-5
Acute Tox. 4, Acute Tox. 4; H332 H302
202-974-4
101-77-9
Carc. Cat. 2, Muta. Cat. 3, T - Toxic, Xn - Harmful, N - Dangerous for the environment
R45-68-39/23/24/25-48/20/21/22-43-51-53
612-051-00-1
Carc. 1B, Muta. 2, STOT SE 1, STOT RE 2, Skin Sens. 1, Aquatic Chronic 2; H350
H341 H370 ** H373 ** H317 H411
200-712-3
69-72-7
Salicylic acid
Xn - Harmful, Xi - Irritant R22-41
45 - 50 %
1-5%
Acute Tox. 4, Eye Dam. 1; H302 H318

01-2119486984-17
Full text of R and H phrases: see Section 16.

Further Information
4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline:
Revision No: 1,00
GB - EN
Safety Data Sheet

Page 3 of 11
This substance is listed on the priority list of substances of very high concern (SVHC) that are subject
to authorization.
SECTION 4: First aid measures

4.1. Description of first aid measures
General information
First aid assistant: Pay attention to self-protection!
Move victim out of danger zone. Take off immediately all contaminated clothing.
If victim is at risk of losing consciousness, position and transport on their side.
After inhalation
Provide fresh air. In case of breathing difficulties administer oxygen. No mouth-to-mouth or
mouth-to-nose resuscitation.Use respiratory bag or oxygen resuscitation apparatus. Immediately get
medical attention. In the case of lung irritation: Primary treatment using corticoide spray, eg. Auxiloson
spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks).
After contact with skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Immediately get medical attention.
After contact with eyes
If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at
least 5 minutes. Subsequently consult an ophthalmologist.
After ingestion
Rinse mouth immediately and drink large quantities of water. Make affected person vomit if conscious.
Immediately get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Following inhalation: Harmful: possible risk of irreversible effects through inhalation.
After skin contact: Possible risks of irreversible effects. May cause sensitization by skin contact.
Following symptoms can occur: Skin corrosion/irritation: Erythema (reddening)
after ingestion: Harmful: possible risk of irreversible effects if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: First Aid, decontamination, treatment of symptoms. Following decontamination of the skin,
pain treatment and shock prophylaxis.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Extinguishing materials should be selected according to the surrounding area.
Suitable extinguishing media: Water spray. Extinguishing powder. Foam. Carbon dioxide (CO2).
Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen.
Extinguishing media which must not be used for safety reasons
High power water jet.
5.2. Special hazards arising from the substance or mixture
Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx).
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical resistant suit.
Additional information
Use a water spray jet to knock down vapours/gases/mists. Collect contaminated fire extinguishing
water separately. Do not allow entering drains or surface water.
SECTION 6: Accidental release measures
Revision No: 1,00
GB - EN
Safety Data Sheet

Page 4 of 11
6.1. Personal precautions, protective equipment and emergency procedures

Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eye and
clothing. Wear personal protection equipment.
6.2. Environmental precautions
Do not empty into drains or the aquatic environment.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the assimilated material according to the section on waste disposal.
6.4. Reference to other sections
See protective measures under point 7 and 8.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
In case of open handling equipment with built-in suction must be used. Do not breathe
gas/fumes/vapour/spray.
Advice on protection against fire and explosion
This material is combustible, but will not ignite readily. Keep away from sources of ignition - No
smoking.
Further information on handling
The regulations of the national employment safety and protection commission about the handling for
polyurethane/epoxy products have to be observed. Industry regulation acid protection observed.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed. Keep locked up. Store in a place accessible only to authorized persons.
Provide for sufficient ventilation and punctiform suction at critical points.
Floors should be impenetrable, resistant to liquids and easy to clean. Moreover, national legislation has
to be observed!
Recommended storage temperature: 2 - 40 C
Advice on storage compatibility
Do not store together with: acid. Food and animal feedingstuff
Further information on storage conditions
Keep container tightly closed and dry.
Storage class:
7.3. Specific end use(s)
Restricted to professional users. Observe technical data sheet.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure limits (EH40)
CAS No
Substance
101-77-9 4,4'-Methylenedianiline
Revision No: 1,00
GB - EN
ppm
mg/m
0.01
0.08
fibres/ml
Category
Origin
TWA (8 h)
WEL
STEL (15 min)
WEL
Safety Data Sheet

Page 5 of 11
Biological Monitoring Guidance Values (EH40)

CAS No
Substance
Parameter
101-77-9 4,4-Methylenedianiline (MDA)
Value
Test material
Sampling time
50 mol/mol urine
total MDA
Post shift for

inhalation and
pre-shift next
day for dermal
exposure
8.2. Exposure controls

Occupational exposure controls
In case of open handling equipment with built-in suction must be used. Do not breathe
gas/fumes/vapour/spray.
Protective and hygiene measures
Take off immediately all contaminated clothing. Protect skin by using skin protective cream. After work,
wash hands and face. When using do not eat or drink. Store work clothing separately. Wear personal
protection equipment.
Respiratory protection
Respiratory protection required in case of: insufficient ventilation. insufficient absorbtion.

Suitable respiratory protective equipment: Filter respirator (DIN EN 147). A 2-P 2
Only use breathing apparatus with CE-label including the four-digit identification number.
Hand protection
Tested protective gloves are to be worn:
Suitable material: NBR (Nitrile rubber). Butyl rubber. PVC (Polyvinyl chloride). CR (polychloroprenes,
Chloroprene rubber). FKM (fluororubber).
Before using check leak tightness / impermeability. Breakthrough times and swelling characteristics of
the material must be taken into consideration. When handling chemical substances, chemical
protective gloves must be worn with CE label including a four digit code.
Eye protection
Tightly sealed safety glasses.
Skin protection
Suitable protection of the body: Single-use suit.
Environmental exposure controls
refer to chapter 7. No further action is necessary.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state:
Colour:
Odour:
liquid
light brown
like: phenol.
Test method
pH-Value:
not determined
Changes in the physical state

Melting point:
not determined
206 C benzyl alcohol
Boiling point:
Sublimation point:
not determined
Softening point:
not determined
> 200 C
Temperature of decomposition::
Flash point:
Revision No: 1,00
94 C benzyl alcohol
GB - EN
Safety Data Sheet

Page 6 of 11
Explosive properties
Product is: not explosive.
Lower explosion limits:

Upper explosion limits:
1,22 vol. % benzyl alcohol

13 vol. % benzyl alcohol
435 C benzyl alcohol
Ignition temperature:
Oxidizing properties
Product is: Not oxidizing.
Vapour pressure:
(at 20 C)
Vapour pressure:
(at 50 C)
Density (at 25 C):
Bulk density:
Water solubility:
(at 20 C)
Solubility in other solvents
mixable with most organic solvent cleaners
0,027 hPa benzyl alcohol

0,67 hPa benzyl alcohol
1,12 g/cm DIN 53217
not applicable
not miscible
Viscosity / dynamic:
(at 25 C)
Flow time:
600 - 1000 mPas DIN 53018

not determined
50,00 %
Solvent content:
9.2. Other information
Solid content:
50,00 %
SECTION 10: Stability and reactivity

10.1. Reactivity
No ignition, explosion, self-heating or visible decomposition.

10.2. Chemical stability
The product is chemically stable.
10.3. Possibility of hazardous reactions
Exothermic reactions with: acid.
10.4. Conditions to avoid
Remove all sources of ignition.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
10.5. Incompatible materials
Strong acid Alkalis (alkalis). Oxidizing agents, strong.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx).
Burning produces large quantities of soot.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity
Toxic. Acute toxicity, oral. Acute toxicity, inhalant. Acute toxicity, dermal. Danger of very serious
irreversible effects.
Revision No: 1,00
GB - EN
Safety Data Sheet

CAS No
Chemical name
Exposure routes
100-51-6
101-77-9
69-72-7
Page 7 of 11
Method
Dose
Species
Source
Rat
GESTIS
benzyl alcohol
oral
LD50
1230 mg/kg
inhalative vapour
ATE
11 mg/l
inhalative aerosol
ATE
1,5 mg/l
oral
LD50
1700 mg/kg
Rat
dermal
LD50
2080 mg/kg
Rat
inhalative (4 h) aerosol
LC50
> 0,85 mg/l
Rat
oral
LD50
891 mg/kg
Rat.
dermal
LD50
mg/kg
> 2000
Rabbit.
Salicylic acid
Specific effects in experiment on an animal

product has not been tested. Toxicological data are not available.
Irritation and corrosivity
Irritating to eyes.
Sensitising effects
May cause sensitization by skin contact.
Severe effects after repeated or prolonged exposure
Danger of serious damage to health by prolonged exposure.
Carcinogenic/mutagenic/toxic effects for reproduction
May cause cancer. May cause heritable genetic damage.
Additional information on tests
The classification was undertaken in accordance with the calculation method governed by the
Preparations Directive (1999/45/EC).
SECTION 12: Ecological information

12.1. Toxicity
CAS No
Chemical name
Aquatic toxicity
101-77-9
69-72-7
Method
Dose
h Species
Source
Acute fish toxicity
LC50
50 mg/l
96 Leuciscus idus (golden orfe)
Acute algae toxicity
ErC50
11 mg/l
72 Scenedesmus subspicatus
IUCLID
EC50
870 mg/l
48 Daphnia magna
GESTIS
Salicylic acid
Acute crustacea toxicity
12.2. Persistence and degradability

Not easily bio-degradable (according to OECD-criteria).
12.3. Bioaccumulative potential
No data available
Revision No: 1,00
GB - EN
Safety Data Sheet

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Partition coefficient n-octanol/water

CAS No
100-51-6
101-77-9
69-72-7
Chemical name
Log Pow
benzyl alcohol
Salicylic acid
1,05
1,59
2,26
12.4. Mobility in soil

Toxicological data are not available.
12.5. Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
12.6. Other adverse effects
No data available
Further information
Do not empty into drains or the aquatic environment. The classification was undertaken in accordance
with the calculation method governed by the Preparations Directive (1999/45/EC).
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Advice on disposal
Do not empty into drains or the aquatic environment. Waste disposal according to official state
regulations. Evidence for disposal must be provided.
Waste disposal number of waste from residues/unused products
WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic
070208
rubber and man-made fibres; other still bottoms and reaction residues
Classified as hazardous waste.
Waste disposal number of contaminated packaging
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
150110
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal
packaging waste); packaging containing residues of or contaminated by dangerous substances
Classified as hazardous waste.
Contaminated packaging
Completely emptied packings can be re-cycled. Handle contaminated packaging in the same way as
the substance itself.
SECTION 14: Transport information

Land transport (ADR/RID)
14.1. UN number:
UN2810
14.2. UN proper shipping name:
TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane)
14.3. Transport hazard class(es):
6.1
14.4. Packing group:
III
Hazard label:
Classification code:
Special Provisions:
Limited quantity:
Transport category:
Hazard No:
Tunnel restriction code:
6.1
T1
274 614
5L
2
60
E
Other applicable information (land transport)

E1
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Safety Data Sheet

Page 9 of 11
Inland waterways transport (ADN)

14.1. UN number:
UN2810
TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane)

6.1
III
Hazard label:
Classification code:
Special Provisions:
Limited quantity:
6.1
T1
274 614 802
5L
Other applicable information (inland waterways transport)

E1
Marine transport (IMDG)
14.1. UN number:
UN2810
TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane-Mixture)
6.1
III
Hazard label:
Marine pollutant:
Special Provisions:
Limited quantity:
EmS:
Segregation group:
6.1
yes
223, 274
5L
F-A, S-A
alkalis
Other applicable information (marine transport)

E1
Air transport (ICAO)
14.1. UN number:
UN2810
TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane-Mixture)
6.1
III
Hazard label:
Special Provisions:
Limited quantity Passenger:
6.1
A3 A4 A137
2L
IATA-packing instructions - Passenger:

IATA-max. quantity - Passenger:
IATA-packing instructions - Cargo:
IATA-max. quantity - Cargo:
655
60 L
663
220 L
Other applicable information (air transport)

E1
Passenger-LQ: Y642
14.5. Environmental hazards
Dangerous for the environment:
yes
14.6. Special precautions for user

May cause cancer. Possible risks of irreversible effects.
Keep away from food, drink and animal feedingstuffs.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not classified for this carrier.
Revision No: 1,00
GB - EN
Safety Data Sheet

Page 10 of 11
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
1999/13/EC (VOC):
53 % (593,6 g/l)
4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline:
This substance is listed on the priority list of substances of very high concern (SVHC) that are subject
to authorization.
National regulatory information
Employment restrictions:
Water contaminating class (D):

Skin resorption/Sensitization:
Observe employment restrictions for young people. Observe employment

restrictions for child bearing mothers and nursing. Observe employment
restrictions for women of child-bearing age.
3 - highly water contaminating
Causes allergic hypersensitivity reactions.
510
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information

Changes
* Data changed from previous versions

Abbreviations and acronyms
ADR: Accord europen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Rglement international concernant le transport des marchandises dangereuses par chemin de
fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Associatio
Full text of R phrases referred to under Sections 2 and 3
20/22
22
Harmful if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
41
Risk of serious damage to eyes.
43
45
May cause cancer.
48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
51
Toxic to aquatic organisms.
51/53
53
May cause long-term adverse effects in the aquatic environment.
68
Full text of H statements referred to under Sections 2 and 3
H302
Harmful if swallowed.
H317
May cause an allergic skin reaction.
H318
Causes serious eye damage.
H332
Harmful if inhaled.
Revision No: 1,00
GB - EN
Safety Data Sheet

H341
H350
H370
H373
H411
Suspected of causing genetic defects.

May cause cancer.
Causes damage to organs.
May cause damage to organs through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.
Page 11 of 11
Further Information
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The
information cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily valid
for the new made-up material.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)
Revision No: 1,00
GB - EN

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Product code: 92074806

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Reserved for industrial and professional use.

The product is intended for professional use.

DSB Surebau GmbH

Telefax: +49 2223 928 461

(001) 352 3233500 Emtel-Customer-No. 99496

1.4. Emergency telephone

SECTION 2: Hazards identification

Indications of danger: T - Toxic, Xn - Harmful, N - Dangerous for the environment

Revision No: 1,00

T - Toxic; N - Dangerous for the environment

N - Dangerous for the

Revision date: 11.04.2013