Professional Documents
Culture Documents
2 ST.,
~ NEW
~ YORK,N. Y.
Fumigation is of great economic benefit. ManufacH E increasing importreated. The forced circulaturers, fruit packers, grain handlers, and warehousetance of fumigation as
tion of air over the surface of
men have been able to eliminate great losses caused by
the liquid aids greatly in the
a means of insect coninsect damage. Furthermore, expensive refrigeration
vaporization of the fumigant.
trol has created a demand for
processes may be supplanted by fumigation, a cheaper
fumigants which can be easily
I n addition to being a good
and more effective means of preventing insect damage
and safely handled without
fumigant, the ethylene dito stored goods.
injury to the materials exchloride mixture has other
Although only recently made available, the use of
posed, a n d w h i c h c a n b e
uses. It is an excellent solthe ethylene dichloride-carbon tetrachloride, ethylene
applied under varying convent for oils and fats and,
oxide, and Carboxide is already established in many
ditions. Many compounds
b ei n g non-inflammable, i s
industries. These materials offer a choice of fumihave insecticidal properties
used as a s p o t - r e m o v i n g
gants which are adaptable to fumigation under widely
but are limited in their use
compound. It makes, therevarying conditions. Separate rooms, apartments, and
as fumigants because of some
fore, an excellent combination
storerooms can be fumigated without vacating other
undesirable characteristics,
fumigant and cleaning soluparts of the same building or inconvenience to other
such as slow vaporization,
tion. Furriers find i t partenants. In like manner expensive shutdowns in
instability, corrosive action,
ticularly suitable for fumifactory operations can be avoided. Foodstuffs can be
odor, retentivity by various
gating and c l e a n i n g f u r s .
fumigated without fear of injury or serious contaminamaterials, difficulty of hanThe mixture is also used in
tion. Finally, fumigation is made easy in many
dling, great inflammability,
the form of emulsions as a
applications which would otherwise be difficult.
or extreme toxicity to man.
contact insecticide.
By the proper choice of processes and fumigants
W h i l e t h e e t h y l e n e diI n the course of an extenmuch of the damage and discomfort caused by insects
chloride-carbon tetrachloride
sive investigation of the possican be eliminated.
m i x t u r e is a very useful
ble use of a large number of
fumigant and solvent, it is
comDounds. the Bureaus of
Entomology and Chemistry and Soils discovered that ethylene not adapted to universal fumigation as is the case with ethyldichloride and ethylene oxide are highly toxic to insects ene oxide.
and have characteristics which make them desirable fumiEthylene Oxide
gants. Both compounds are relatively non-toxic to man.
Ethylene oxide is a colorless, mobile liquid, which boils
Ethylene Dichloride
a t 10.5' C. and is therefore a gas a t ordinary temperatures.
Ethylene dichloride is a colorless liquid of ethereal odor, It has a specific gravity of 0.887 a t 7"/4" C., a molecular
which boils at 83.7" C. It has a specific gravity of 1.27 a t weight of 44.031, and a freezing point of -140" C. The
2Oo/2O0 C. and weighs 10.4 pounds per gallon. It is an ex- liquid is soluble in water and organic solvents. It has a
cellent solvent for oils and fats, but is insoluble in water. faint but distinct ether-like odor, which is easily recognized,
The vapors of ethylene dichloride are approximately 3.5 and its vapors are approximately 1.7 times as heavy as air.
times as heavy as air.
The vapors exhibit remarkable penetration into dense maEthylene dichloride will burn, but it is rendered non- terials such as wheat flour.
inflammable by the addition of approximately 25 per cent by
Extensive experiments with various foodstuffs have shown
volume of carbon tetrachloride. This non-inflammable mix- that no residual taste or odor is left with materials that
have been in contact with the vapors of ethylene oxide.
ture is a very useful fumigant.
A dosage of 8 pounds of the ethylene dichloride-carbon Even the flavor of such a sensitive material as tobacco is
tetrachloride mixture per 1000 cubic feet in an air-tight unaffected by fumigation with it.
A dosage of 1 pound ethylene oxide per 1000 cubic feet
vault a t 70" F. will kill, in 24 hours, clothes moths, carpet
beetles, rice weevils, Indian meal moths, flour beetles, saw- of air in an air-tight vault a t 70" F. will, in 20 hours, kill
toothed grain beetles, and bedbugs. However, for com- clothes moths, carpet beetles, rice weevils, Indian meal
mercial fumigation a dosage of 14 pounds of the mixture moths, saw-toothed grain beetles, red-legged ham beetles,
flour beetles, cockroaches, tobacco beetles, and bedbugs.
per 1000 cubic feet is recommended.
Successful fumigation with the ethylene dichloride mixture For commercial fumigation, however, a dosage of 2 pounds
depends to a large extent upon the method of application. per 1000 cubic feet is recommended. Although the conBecause of its relatively slow rate of vaporization, the liquid centrated vapors of ethylene oxide are inflammable, concensurface exposed should be large. This can be accomplished trations lethal to insects can be used with safety, since the
by placing the mixture in shallow pans and allowing it to lower limit of inflammability is 3 per cent by volume or 3.67
evaporate or in certain cases, provided the walls or floor are pounds per 1000 cubic feet.
Mixtures in air of ethylene oxide and carbon dioxide in
unfinished, the fumigant may be sprayed on the walls or
floor of the fumigation chamber. I n other instances the the ratio of 1 part of ethylene oxide to 7.5 parts or more
liquid may be sprayed or poured upon the material being of carbon dioxide by weight are non-inflammable. Furthermore, ethylene oxide and carbon dioxide have practically
Presented before the Division of Agricul1 Received May 21, 1930.
the same vapor density and do not tend to separate or stratify.
tural and Food Chemistry a t the 79th Meeting of the American Chemical
Therefore, to eliminate possible dangers arising from an overSociety, Atlanta, Ga., April 7 to 11, 1930.
August, 1930
I N D U S T R I A L A N D ENGINEERING CHEMISTRY
The efficiency of fumigation depends largely upon temperature, concentration of fumigant, time of exposure, and nature
of the material treated. The most favorable and economical conditions prevail where the temperature is above 70 F.
and the effective concentration of fumigant can be maintained for the time required to give effective results on the
particular material being treated. These conditions can
be best maintained in vaults or rooms which are specially
equipped for fumigation.
When speed is essential vacuum vaults can be used. When
speed is not important and space is available, atmospheric
vaults are satisfactory for most materials. Some materials,
however, because of their dense nature, are best fumigated
under vacuum.
845
CARBOXIDE
MATERIAL
Atmomhere
Vacuum
Dried fruits
Cereals in cartons
Brans, rice, corn, I
and other grain
in bags
Flour i n 1 0 0 pound bags
Tobacco in bales
Candy in cartons
N u t meats
Almonds and peanuts in shells
Clothing f u r s,
furnitdre, a n d
rugs
Lbs./l000
Lbs./1000
10
12-16
20
20
20
16
20
16-24
16-24
16
12-16
20
1
2
I1/z
10
12-16
20
20
30
30
16
22
24
14
24
28
24
Notrecommended
Not recommended
Not recommended
Not recommended
14
24
Grain Fumigation
846
August, 1930
847
can be inserted in the pipes for the duration of the treatment. Care must be taken, however, to remove the plugs
after fumigation or else the compartments will eventually
be flooded.
The required quantities of fumigant can be introduced
through the ice ports of a refrigerator car. Carboxide cylinders are of such sizes that one cylinder can be used for each
car. The contents of a cylinder may be emptied into the
ice compartment through a hose connected to the cylinder
on the outside, or else the cylinder may be placed bodily
in the compartment. The dosage for dried fruits should be
16 pounds of Carboxide per 1000 cubic feet for an exposure
of 10 to 12 hours at 70 F.
Literature Cited
(1) Back, Cotton, and Ellington, J . Econ. EnlotnoL., 23, S o . 1 (1930).
(2) Cotton, Ihid., 23, S o . 1 (1930).
(3) Cotton and Roark, I b i d . , 20, 636 (1927).
( 4 ) Cotton and Roark, IND.Exc. CHEM.,20, 80: (1928).
( 3 Cotton and Young, Proc. Enfomol. Soc. Washington, 31, 97 (1929)
(6) Hoyt, ISD. ENO.c.HElf., 20, 460 (1928).
(7) Jones and Kennedy, Ibid., 22, 146 (1930).
over the summerwood. The present paper reports empirical tests of certain modifications of painting practice
t h a t have been supposed to improve durability of coatings
over summerwood. The results indicate t h a t past recommendations have usually been based upon inadequate
theory rather than upon sound experience. In the authors opinion the problem of adhesion is a fundamental
one that must be solved before substantial improvement
in the serviceableness of house paints on wood can be
achieved. With permanent adhesion between coatings
and wood, variable paint behavior between woods and
uncertain service on repainting would be eliminated,
leaving the paint chemist free to build wear-resistant
coatings on a firm foundation.
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