S1 TITAN 600-800

Alloy LE Calibrations (P/N: 730.0081)

Low Alloy
Analysis range, %
LLD (Fe pure)
SEC %
Typical accuracy: %
Phase
Tool Steel

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

Nb

Mo

Pb

LLD-2
186
0.095

LLD-0.15
169
0.013

LLD-0.3
61
0.04

0.05 - 1.8
21/85
0.01
0.02
2/1

LLD - 9
18/50
0.04
0.04
2/1

0.1 - 2.0
53
0.02
0.04
1

75 - 100
N.A.
0.5
0.5
1

LLD - 8
27
0.03
0.03
1

LLD - 5
60/80
0.06
0.06
1

LLD - 5
48
0.02
0.03
1

LLD- 0.3
28
0.002
0.01
1

LLD - 8
32
0.01
0.04
1

LLD - 6
80
0.01
0.03
1

LLD-0.3
121
0.009

LLD - 0.1
28/47
0.005
0.02
2/1

Al
Analysis range, % LLD-1.5
LLD (Fe pure) 190
SEC % 0.3
Typical accuracy: %
Phase 2

Stainless Steels
Analysis range, %
LLD (Fe pure)
SEC %
Typical accuracy: %
Phase
Nickels
Analysis range, %
LLD (pure Ni)
SEC %
Typical accuracy: %
Phase
Cobalts
Analysis range, %
LLD (pure Co)
SEC %
Typical accuracy: %
Phase
Zincs
Analysis range, %
LLD (pure Zn)
SEC %
Typical accuracy: %
Phase
Coppers

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zr

Nb

Mo

Sn

Pb

LLD-2
300
0.2

LLD-0.2
66
0.02

LLD-0.3
10
0.05
2

LLD - 5
16/54
0.04
0.04
2/1

0.1 - 2.0
73
0.04
0.05
1

69 - 98
N.A.
0.7
0.5
1

LLD - 8
120
0.09
0.2
1

LLD - 2
100
0.01
0.02
1

LLD - 2
44
0.02
0.03
1

LLD-0.04
24
0.001
0.005
1

LLD- 0.15
27
0.003
0.01
1

LLD - 9
32
0.03
0.04
1

LLD - 19
175
0.03
0.04
1

LLD-0.3
105
0.008

LLD - 2
21/90
0.05
0.02
2/1

LLD-0.05
51
0.007

LLD - 0.3
17/74
0.07
0.03
2/1

Al

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zr

Nb

Mo

Ta

LLD-1.5
190
0.3

LLD-4
232
0.09

LLD-0.1
66
0.02

LLD-0.5
48
0.05
2

0.01-20
60
0.08
0.05
1

30 - 95
N.A.
0.1
0.4
1

LLD - 18
26
0.08
0.03
1

0.05-50
82
0.08
0.08
1

0.01 - 5
57
0.02
0.03
1

LLD - 4.5
32
0.02
0.02
1

0.01 - 10
34
0.06
0.05
1

LLD - 15
96
0.01

0.02 - 26
48
0.2
0.03
1

LLD-0.6
93
0.02

0.05 - 9
81
0.04
0.02
1

LLD-0.05
32
0.003

0.05 - 2
21/120
0.0
0.0
2/1

Al

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zr

Nb

Mo

Hf

Ta

Re

LLD-2
480
0.3

LLD-1.5
171
0.06

LLD-0.1
37
0.02

0.02 - 2
41
0.16
0.05
1

0.02 - 66
44
0.67
0.4
1

0.1 - 20
64
0.08
0.05
1

32 - 100
N.A.
0.7
0.1
1

0.1 - 35
43
0.11
0.1
1

LLD - 5.5
35
0.01
0.02
1

LLD - 28
45
0.05
0.04
1

0.05 - 7
109
0.016

0.1 - 15
138
0.05

LLD-3
106
0.02

0.02 - 30
24/141
0.3
0.3
2/1

LLD - 2
187
0.02

0.05 -0.5
26
0.05
0.05
2

LLD-0.6
27
0.005

0.05 - 3.5
20/51
0.05
0.03
2/1

Al

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

Nb

Mo

Pb

LLD-1.5
694
0.18

LLD-1.5
240
0.11

LLD-0.1
10
0.005

LLD-0.1
10
0.004

0.05 - 35
28/75
0.5
0.05
2/1

LLD - 1.8
68
0.06
0.05
1

0.1 - 55
69
0.15
0.1
1

15 - 100
N.A.
0.46
0.3
1

0.1 - 58
33
0.09
0.1
1

LLD- 4.0
54
0.006
0.01
1

LLD - 10
34
0.04
0.04
1

0.1 - 15.1
295
0.1
0.1
1

LLD-0.4
90
0.009

LLD-0.05
25
0.009
0.02
2

LLD-0.25
4
0.045

LLD-3.5
22/108
0.03
0.03
2/1

Al

Ti

Fe

Cu

Zn

Pb

Bi

LLD-30
547
0.4
0.6
2

LLD-0.15
12/105
0.003
0.006
2/1

LLD-0.5
85
0.004
0.01
1

LLD-2.5
75
0.02
0.04
1

65-100
N.A.
0.4
0.6
1

LLD-0.15
112
0.005

LLD-0.1
80
0.005

Al
Analysis range, % LLD-1.5
LLD (pure Cu) 983
SEC % 0.4
Typical accuracy: %
Phase 2

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn

As (KB1)

Zr

Ag

Sn

Pb (LB1)

Bi

LLD-5
257
0.09

LLD-0.5
101
0.01

LLD-0.2
25
0.01

LLD-0.25
23/132
0.005
0.01
2/1

LLD - 2.5
20/150
0.08
0.02
2/1

LLD - 5.5
35
0.04
0.03
1

LLD- 5
29
0.07
0.06
1

LLD-0.5
18
0.01
0.02
1

LLD- 30
62
0.07
0.06
1

40 - 100
N.A.
1
1
1

0.1 - 40
27
0.15
0.2
1

LLD - 0.3
35
0.01
0.03
1

LLD- 0.5
44
0.01
0.02
1

LLD - 3.0
185
0.01
0.02
1

0.1 - 10
275
0.08
0.1
1

0.1 - 10
122
0.13
0.2
1

LLD-0.05
107
0.01
0.03
1

Bruker Elemental - April 27, 2015

S1 TITAN 600-800
Alloy LE Calibrations (P/N: 730.0081)

Al, Si Bronzes
Analysis range, %
LLD (pure Cu)
SEC %
Typical accuracy: %
Phase
Light Alloys - Titaniums
Analysis range, %
LLD (pure Ti)
SEC %
Typical accuracy: %
Phase
Light Alloys - Al/Mg
Analysis range, %
LLD (1100 or pure Mg)
SEC %
Typical accuracy: %
Phase
Full MultiMatrix FP

Al

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

LLD - 12
983
0.4

LLD - 5
257
0.09

LLD-0.5
101
0.01

LLD-0.2
25
0.01

LLD-0.25
23/132
0.005
0.01
2/1

LLD - 2.5
20/150
0.08
0.02
2/1

LLD - 5.5
35
0.04
0.03
1

LLD- 5
29
0.07
0.06
1

LLD-0.5
18
0.01
0.02
1

LLD- 30
62
0.07
0.06
1

40 - 100
N.A.
1
1
1

Al

Si

Ti

Cr

Mn

Fe

Cu

Zr

Nb

Mo

0-15
1220
0.3

0-1
265
0.09

68 - 100
N.A.
0.9
1.1
2/1

LLD -16
181
0.08
0.15
2

LLD -15.0
290
0.04
0.1
2

LLD - 1.5
106
0.01
0.1
1

LLD - 2
60
0.09
0.1
1

LLD - 4
32
0.01
0.04
1

LLD - 5.5
18
0.02
0.1
1

LLD - 2.0
20
0.02
0.02
1

LLD -16
32
0.04
0.1
1

Mg

Al

Si

Ti

Cr

Mn

Fe

Co (KB1)

Ni

Cu

LLD-100%
957
0.17

LLD-100%
484
1.9

LLD-18
125
0.2

LLD -0.1
96
0.008
0.03
1

LLD -0.1
95
0.004
0.015
1

LLD -0.3
48
0.009
0.02
1

LLD-2
34
0.005
0.015
1

LLD-1.5
22
0.01
0.04
1

0.02 -0.45
140
0.01
0.03
1

LLD - 2.5
15
0.01
0.02
1

LLD - 5
10
0.02
0.05
1

Mg
Analysis range, % LLD-100%
SEC % 0.4
Mo
Analysis range, % LLD-100%
SEC % 0.05

Zn
0.1 - 40
27
0.15
0.2
1

As (KB1)
LLD - 0.3
35
0.01
0.03
1

Zr
LLD- 0.5
44
0.01
0.02
1

Ag
LLD - 3.0
185
0.01
0.02
1

Pd
LLD -0.15
85
0.006
0.01
1

Sn
LLD -2
158
0.04
0.1
1

Ta
LLD-1
60
0.01
0.02
1

W
LLD-0.5
48
0.01
0.04
1

Zn
LLD -7
7
0.02
0.05
1

Zr
LLD-0.2
6
0.001
0.01
1

Sn
LLD-0.1
78
0.005
0.02
1

Pb
LLD -0.1
10
0.002
0.02
1

Sn
0.1 - 10
275
0.08
0.1
1

Pb (LB1)
0.1 - 10
122
0.13
0.2
1

Bi
LLD-0.05
107
0.01
0.03
1

Bi
LLD-0.1
11
0.003
0.01
1

Al

Si

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn

As

Se

Zr

Nb

LLD-100%
0.7

LLD-100%
0.8

LLD-5%
0.3

LLD-5%
0.3

LLD-100%
0.1

LLD-100%
0.03

LLD-100%
0.3

LLD-100%
0.15

LLD-100%
0.5

LLD-100%
0.3

LLD-100%
0.4

LLD-100%
0.4

LLD-100%
0.1

LLD-100%
0.2

LLD-100%
0.2

LLD-100%
0.01

LLD-100%
0.02

LLD-100%
0.05

Ru

Rh

Pd

Ag

Cd

In

Sn

Sb

Hf

Ta

Re

Ir

Pt

Au

Pb

Bi

LLD-100%
0.08

LLD-100%
0.04

LLD-100%
0.04

LLD-100%
70.00%

LLD-100%
0.1

LLD-100%
0.1

LLD-100%
0.2

LLD-100%
0.07

LLD-100%
0.1

LLD-100%
0.1

LLD-100%
0.4

LLD-100%
0.1

LLD-100%
0.3

LLD-100%
0.2

LLD-100%
0.4

LLD-100%
0.2

LLD-100%
0.1

Calibration: FP based (with empirical corrections), with normalization based on BRUKER Intensity scaling when sample is smaller than mask
Analysis range: Concentration range covered by reference samples in the calibration of the application. Can be extened by 15% with FP based calibrations. Empirical calibrations should only be used within the range.
Lower Limit of Detection (LLD): The smallest concentration which can be detected.
a) In this document LLD is specified for a given matrix in three sigma 99.7% confidence level (3 sigma); 60 second phase 1 analysis time, 180 second phase 2 analysis time
b) Individual elemental LLD's improve as a function of the square root of the analysis time.
Actual lower limit of detection range depends on several factors such as matrix interferences, overlapping elements, level of statistical confidence and testing time. Measurement of concentration close to the low
analysis range requires typically long measurement time > 60s
Standard Error of Calibration (SEC): Average error (deviation) between certified and XRF value of the samples used for the calibration expressed as an absolute value in weight %.

Typical accuracy: Typical average error within the analysis range when large set of reference samples are measured. Notice that error of the individual sample may differ
significantly from this value. Measurement time: 30s (2) or less than 10 sec (1)
Phase: Number indicates on which measurement phase the listed LLD was determined

Bruker Elemental - April 27, 2015