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Oxidation Limit : Each material has its own Oxidation limit after which it
starts scaling.
Stainless Steel has is better than CSEF steels but it still not used in the
Super Critical Boilers because it has poor thermal Conductivity and Cost is
also high. For boiler grade materials thermal conductivity should be high.
Also Stainless Steel has poor resistance to thermal expansion as compared
to CSEF steels. So the material might get affected very soon.
Thermal conductivity in inversely proportional to thermal expansion.
For P91, Both 9015 and 9018-B9 can be used for welding but 9015 cannot
be used in all position whereas 9018-B9 can be used in all positions for
welding.
For Gr91/92, materials whose p number is lower than or equal to 4 should
be avoided.
Residua Stress in only in the Weld Metal and not in the Base Metal.
If the impact of raw material is lower than Final fabricated structure then
the component is subjected to improper heat treatment.
Creep Resistant material service temperature should be 454C.
For a Supercritical boiler, Drum is replaced by Separator.
Separator has a service temperature of 372C. For this service temperature
Alstom is using G91 (22mm) while Hubin China is using Gr 22. (80 mm).
This is solely because of the manufacturers policy. Since using Gr91 will
lower the thickness and hence weight of the component and size also
reduces. Also manufacturability as compared to Gr22 is easy.
Soaking Time: Soaking Time is given for the material to undergo uniform
temperature. Basically during tempering, the carbides have to be
dissolved in the matrix. This transformation requires time. Thus soaking
time is always given.
For Stainless Steel, PWTH or preheating is not required this is because
austenite is formed at room temperature. But because of Strain and Grain
Resizing Solution HT is given.
Sensitization: This is a very important and Deletorius effect in this Cr gets
converted to Carbides. Thus CrC are formed along the grain boundary in
the temperature range of 420 -870 C which are then susceptible to
intergranular corrosion. Thus we quench immediately to pass this
range.Several methods have been used to control or minimize the
intergranular corrosion of susceptible alloys like a high-temperature
solution heat treatment, commonly termed solution-annealing, quenchannealing or solution-quenching, has been used. The alloy is heated to a
temperature of about 1,060 to 1,120C and then water quenched. This
method is generally unsuitable for treating large assemblies, and also
ineffective where welding is subsequently used for making repairs or for
attaching other structures. Another control technique for preventing
intergranular corrosion involves incorporating strong carbide formers or
Overtemper
Under Tempering