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Precambrian Research
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Review
Department of Earth and Planetary Sciences/GEOTOP, McGill University, Montral, Qubec H3A 2A7, Canada
Instituto de Geocincias, Universidade Federal de Minas Gerais, Av. Antnio Carlos 6627, CEP 31270-901, Belo Horizonte, MG, Brazil
Dpartement des Sciences de la Terre et de lAtmosphre///GEOTOP, Universit du Qubec Montral, P.O. Box 8888, Montral, Qubec H3C 3P8, Canada
a r t i c l e
i n f o
Article history:
Received 24 September 2011
Received in revised form 12 January 2012
Accepted 17 January 2012
Available online 24 January 2012
Keywords:
Neoproterozoic
Isotope stratigraphy
Marinoan glaciation
So Francisco craton
Bambu Group
Cap carbonate
a b s t r a c t
Remnants of a Neoproterozoic glaciation in east central Brazil are represented by thin diamictite layers (Jequita Formation and correlative units), locally overlying striated pavements on the So Francisco
craton. The diamictites are covered by the Sete Lagoas Formation of the basal Bambu Group, which is
generally accepted to be a typical cap carbonate sequence. Although most authors have preferred a midCryogenian (post-Sturtian) age for it, based mainly on Pb-Pb whole rock data, the Sete Lagoas Formation
bears lithostratigraphic and isotopic characteristics that are identical to early Ediacaran cap carbonates
worldwide, including a basal thin (010 m) pale and inty cap dolostone, preserving a drop in 13 C values from around 3.2 to 4.5 with associated 18 O around 5, and crystal-fan facies interpreted
as aragonite pseudomorphs. Ediacaran zircons have been recovered from the middle of the Sete Lagoas
Formation, constraining the deposition of its upper half to be younger than 610 Ma (Rodrigues, 2008).
Although there is an unconformity below the point where the zircons were collected, it is short-lived, as
suggested by the identical, typically Ediacaran 87 Sr/86 Sr values above and below (0.70740.7076). Carbonate clasts from the Jequita Formation and correlative diamictite-bearing units in the fold belts that
surround the So Francisco craton (Canabravinha and Serra do Catuni formations) display similar ranges
in 13 C (6.7 to +2.6), suggesting the erosion of a pre-glacial carbonate platform with negative 13 C
values (i.e. the Islay and/or Trezona anomalies). The cratonic Carrancas Formation, on the other hand,
yielded pale dolostone clasts with 13 C in a small range between 4.2 and 3.4, and 18 O values around
6.5. These clasts could be derived from the cap dolostone unit itself, in which case the Carrancas Formation would represent resedimented basal Sete Lagoas Formation and imply that sections of the Sete
Lagoas Formation sitting atop the Carrancas Formation are incomplete. The base-truncated sections have
confused previous attempts to correlate the Sete Lagoas Formation with other cap carbonate successions. In light of the available lithostratigraphic, isotopic and U-Pb zircon data, we propose that the Sete
Lagoas Formation represents a basal Ediacaran cap carbonate sequence (635610 Ma) deposited after
the Marinoan glaciation in east central Brazil.
2012 Elsevier B.V. All rights reserved.
Contents
1.
2.
3.
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Lithofacies of the Neoproterozoic glaciation in east central Brazil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.1.
Bambu Group . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2.
Jequita Formation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.3.
Carrancas Formation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.4.
Sete Lagoas Formation: the cap carbonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.5.
Fold belts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
New data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.1.
Materials and methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Corresponding author at: Instituto de Geocincias, Universidade Federal de Minas Gerais, Av. Antnio Carlos 6627, CEP 31270-901, Belo Horizonte, MG, Brazil.
Tel.: +55 31 34095444; fax: +55 31 34095410.
E-mail address: boni@ufmg.br (F.d.A. Caxito).
0301-9268/$ see front matter 2012 Elsevier B.V. All rights reserved.
doi:10.1016/j.precamres.2012.01.005
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3.2.
3.3.
4.
5.
1. Introduction
The Neoproterozoic Era (1000542 Ma) was a time of extreme
climatic variation as recorded in sedimentary rocks of this age
across the globe (Gaucher et al., 2009). Especially intriguing is an
association of glacial deposits with warm climate carbonate platforms that is a trademark feature of the Neoproterozoic record
(Fairchild, 1993; Hoffman, 2011). This climatic dichotomy has
led to a number of controversial explanations, including extreme
icehouse-greenhouse uctuations (snowball Earth glaciations),
which are unprecedented in the Phanerozoic record (Kirschvink,
1992; Hoffman et al., 1998; Hoffman and Schrag, 2002).
One of the predictable consequences of an abrupt shift from
icehouse to greenhouse conditions is the worldwide distribution of lithologically and isotopically similar strata (Kirschvink,
1992; Hoffman and Schrag, 2002). Despite local differences in
the sedimentation regime (clastic, mixed or carbonate), these
events are represented by glacial deposits of diverse nature, overlain by distinctive cap carbonate sequences corresponding to
the mid-Cryogenian (Sturtian) and end-Cryogenian (Marinoan)
glaciations (Kennedy et al., 1998; Hoffman and Schrag, 2002;
Halverson et al., 2005). Unfortunately, Neoproterozoic successions are largely devoid of useful biostratigraphic markers, and
the general scarcity of directly datable material (i.e., interbedded
felsic volcanic units) leads to difculties in assigning sequences
to a particular glacial event. The chemostratigraphy of carbonate
sequences has been invoked as a promising alternative tool for
regional and global correlation, as well as for the assignment of relative ages (Knoll and Walter, 1992; Jacobsen and Kaufman, 1999;
Melezhik et al., 2001; Halverson et al., 2010). The isotopic signatures of 13 C and 87 Sr/86 Sr have proven especially useful in this
respect, as they provide proxies for seawater composition at the
time of deposition and vary considerably throughout the Neoproterozoic.
In east central Brazil, a number of Neoproterozoic glacial
deposits have long been recognized (Moraes and Guimares, 1931;
Isotta et al., 1969; Pug and Schll, 1975; Hettich, 1977, Hettich
and Karfunkel, 1978; Rocha-Campos and Hasui, 1981; Gravenor
and Monteiro, 1983; Karfunkel and Hoppe, 1988; Rocha-Campos
et al., 1996; Uhlein et al., 1999, 2004; Karfunkel et al., 2002). The
climatic dichotomy here is represented by the Jequita Formation
diamictites and overlying Sete Lagoas Formation carbonates at the
base of the Bambu Group, which is the Neoproterozoic cover of the
So Francisco craton in Minas Gerais (MG), Bahia (BA), Gois (GO)
and Tocantins (TO) states (Figs. 1 and 2). Although there is currently
a consensus that the basal Sete Lagoas Formation is a typical postglacial cap carbonate, the age of the glacial event is the subject of
much debate (e.g. Misi and Veizer, 1998; Babinski et al., 2007, 2012;
Vieira et al., 2007; Sial et al., 2009; Misi et al., 2011). In this paper,
we reassess the chronostratigraphic position of the Neoproterozoic
glaciation documented in east central Brazil using available stratigraphic, sedimentary, geochronological and isotopic data from the
Bambu Group. To this data set, we add our own new stratigraphic
and C, O and Sr isotopic data from a previously unpublished section
of the Sete Lagoas Formation in the central portion of the basin and
from carbonate clasts from four separate diamictite occurrences.
The combination of new and published data overwhelmingly favors
an Ediacaran age for the basal Bambu Group, implying an end
Cryogenian age for the Jequita Formation glacial sediments.
2. Lithofacies of the Neoproterozoic glaciation in east
central Brazil
The So Francisco craton (Fig. 1; Almeida, 1977; Alkmim, 2004)
is a geotectonic unit characterized by an Archean to Paleoproterozoic basement covered by predominantly clastic Mesoproterozoic
units (Espinhaco Supergroup, Parano and Canastra groups) and
a Neoproterozoic mixed carbonate-siliciclastic sequence (Bambu
Group). It is surrounded by the late Neoproterozoic (Brasiliano
Fig. 1. The So Francisco craton and surrounding fold belts. The dashed rectangle
indicates the location of the map in Fig. 2. Modied from Alkmim (2004).
40
Fig. 2. Simplied geologic map of the So Francisco Basin, showing the main outcrop areas of the Sete Lagoas Formation. The schematic lithostratigraphic and isotopic proles
are simplied after: (a) Vieira et al. (2007), Babinski et al. (2007); (b) Kuchenbecker (2011); (c) Alvarenga et al. (2007); and (d) Powis et al. (2001) in Misi et al. (2007). The
square near Correntina (BA) indicates the approximate location of Fig. 6.
Cycle, 630500 Ma) Aracua, Braslia, Rio Preto, Riacho do Pontal and Sergipano fold belts (Fig. 1; Trompette, 1994; Sial et al.,
2009), which contains deformed and metamorphosed diamictitebearing rift to passive margin sequences that were deposited on
the margins of the craton (Figs. 3 and 4).
2.1. Bambu Group
The Bambu Group covers over 300,000 km2 of the So Francisco
craton in east central Brazil (Figs. 1 and 2; Costa and Branco, 1961;
Braun, 1968; Dardenne, 1978a, 1979; Sial et al., 2009). The classically dened stratigraphy of the Bambu Group (Dardenne, 1978a)
41
Fig. 3. Comparative stratigraphy of the diamictite-bearing sequences in fold belts rimming the So Francisco craton. The ages on the rectangles represent estimates of the
Brasiliano deformation and peak metamorphism for each fold belt. Although the sequences are generally metamorphosed to greenschist facies, sedimentary names of the
rocks have been kept for simplication, as most sedimentary features can still be recognized. The west and east sectors of the Aracua Fold Belt are separated by a basement
block (Porteirinha block); the Vaza-Barris Group is thrusted southwards upon the Miaba Group on the Sergipano Fold Belt. From: (a) Pedrosa-Soares et al., 2000, 2011;
Queiroga et al., 2007; Martins et al., 2008; Babinski et al., 2012; (b) Pereira et al., 1994; Valeriano et al., 2004; Rodrigues et al., 2010; Amorim Dias, 2011; (c) Egydio-Silva
et al., 1989; Caxito et al., 2011; (d) Oliveira et al., 2005, 2006, 2010; Sial et al., 2010.
which might divide the Bambu Group into a lower, glaciallyrelated sequence, and an upper, foreland basin sequence (Martins
and Lemos, 2007; Zaln and Romeiro-Silva, 2007).
On the craton margins, the Bambu Group was affected
by the Brasiliano Orogeny and cratonic-directed deformation
of the surrounding Aracua, Braslia and Rio Preto fold belts
(Figs. 1 and 4; Dardenne, 1978b; Chang et al., 1988; Chemale
et al., 1993; Dardenne, 2000; Alkmim and Martins-Neto, 2001).
Thin-skin deformation fronts on the Bambu Group reach up
to 200 km in width before passing laterally into horizontal
cratonic cover (Fig. 4). The timing of emplacement of the
external nappes of the Braslia fold belt, which were thrust
upon the cratonic cover on the southern So Francisco craton, provides a minimum depositional age for the Bambu
Group at around 567 Ma (K-Ar muscovite age; Valeriano et al.,
2000).
2.2. Jequita Formation
The Jequita Formation outcrops on the borders of the Cabral
and gua Fria ranges in north central Minas Gerais, near the
boundary between the Aracua fold belt and the So Francisco craton (Figs. 2 and 4; Isotta et al., 1969; Viveiros and Walde, 1976;
Uhlein et al., 1999, 2011; Cukrov et al., 2005). These ranges are
the topographic expression of east-west open anticlinal folding
with a north-plunging axis, with younger strata towards the anks
(Fig. 4). The Jequita Formation consists mainly of massive, clastpoor diamictite with rare and thin (cm to dm) intercalations of
sandstone and rhythmite, reaching up to 100 m thick. The diamictite contains clasts of carbonates, gneiss, quartzite, granite and
quartz, up to boulder size, oating in a pelitic matrix (Fig. 5c).
On the northeastern ank of the gua Fria range, 10 km southeast of Jequita, Isotta et al. (1969) described beautifully preserved
striated pavements in quartzites underlying a diamictite of the
Jequita Formation (Figs. 4 and 5a and b). East-west trending striae
vary from ne, V-shaped thin scratches to U-shaped grooves up
to 20 cm wide 5 cm deep, bearing crescent-shaped cracks that
consistently indicate a roughly eastward ice ow direction (Fig. 5a
and b). Individual grooves reach up to 18 meters in length with no
widening or shallowing at the ends (Isotta et al., 1969). This spectacular striated pavement is the best evidence for Neoproterozoic
glaciation in east central Brazil (e.g. Uhlein et al., 1999 and references therein). Karfunkel and Hoppe (1988) also recovered striated
and faceted pebbles from a diamictite layer 4 km north of Jequita.
Although Isotta et al. (1969) originally interpreted the striae to
be formed over an indurated quartzite pavement, Rocha-Campos
et al. (1996) re-interpreted the glacial abrasion marks as having
been formed over a soft-sediment substratum, in the uctuating grounding zone of a marine ice sheet, based on evidence that
includes internal striae in the U-shaped groove walls that are covered by slumped plow ridges, clasts partially embedded in the
basement quartzites, and striae and ripple marks occupying the
same bedding plane. These observations imply that the underlying sandstones were still unlithied during glaciation, and hence
belong to the basal Jequita Formation and not to the Mesoproterozoic Espinhaco Supergroup, as conventionally interpreted (Uhlein
et al., 2011).
Until recently, the Jequita Formation diamictites were interpreted as tillites resting directly above the grooved and striated
pavement (Fig. 5d, Gravenor and Monteiro, 1983; Karfunkel and
Hoppe, 1988; Karfunkel et al., 2002). However, Uhlein et al. (1999,
2011), Cukrov et al. (2005) and Chaves et al. (2010) noted the
42
Fig. 4. Schematic cross-sections across the craton-fold belt transition zone in the northwestern (a) and eastern (b) margins of the So Francisco craton. See Fig. 2 for location
of the sections. The arrows indicate sites where carbonate clasts were collected. (b) Modied from Uhlein et al. (1999).
43
Fig. 5. (a and b) The Serra da gua Fria striated pavement. (a) deep and wide U-shaped furrows with internal crescent-shaped cracks showing eastward ice ow direction
(arrow). Note large quartzite cobble partially embedded on the striated pavement near hammers head. (b) Striae and ripple marks on the same bedding plane. (c) Jequita
Formation diamictite, at an abondoned quarry on the km 66 of the BR-365 road, 36 km northeast of Jequita. Note stromatolite clast in lower left corner. (d) Serra do Catuni
Formation metadiamictite at Couto de Magalhes (MG). (e) Canabravinha Formation metadiamictite at Canabravinha stream, near Monte Alegre dos Cardosos (BA). Note
angular carbonate clast in upper right corner. (f) Contact between the Carrancas paraconglomerate (below) and the Sete Lagoas limestone (above), at km 30 of the MG-424
road between Belo Horizonte and Vespasiano (MG). Hammer is 30 cm long; diameter of coin is 2.5 cm; bottle on d is 30 cm long.
44
locally, in sharp contact atop thin diamictite layers, generally correlated to the Jequita Formation (Fig. 2). Recent studies have
suggested that an unconformity in the middle of the Sete Lagoas
Formation, marked by a facies, isotopic and seismic break, divides
it into two shallowing-upwards cycles (Martins and Lemos, 2007;
Zaln and Romeiro-Silva, 2007; Vieira et al., 2007).
The base of the lower Sete Lagoas Formation is marked by
a thin (010 m), lenticular, pink or pale inty dolostone layer
(Misi et al., 2007; Sial et al., 2009). It generally consists of a
microcrystalline massive or nely laminated dololutite, sometimes
containing peloids (Alvarenga et al., 2007; Lima, 2011). Locally,
reworked equivalents, containing detrital quartz, carbonate and
lithic clasts, have been described (Kuchenbecker, 2011). Recent
studies have shown that this basal dolostone yields an upwards
decreasing 13 C pattern from around 3.2 to 4.5, with associated 18 O between 4.5 and 6.5 (Fig. 2b and c; Alvarenga
et al., 2007; Kuchenbecker, 2011). Above this thin dolostone, a
100 m package of laminated limestone prevails. The dolostonelimestone shift is marked by an abrupt drop in 13 C values of
about 1 and up to 4 in 18 O values. Up section, 13 C gradually increases towards positive values, remaining homogeneous
around 0 or rising to around +4 (Fig. 2; Santos et al., 2000;
Alvarenga et al., 2007; Vieira et al., 2007; Kuchenbecker, 2011;
Lima, 2011).
In places, the thin basal pale dolostone is absent, most notably in
the classic Sete Lagoas Formation outcrops, between Belo Horizonte
to the south and Sete Lagoas to the north. Here, the Sete Lagoas
Formation sits atop paraconglomerate and rhythmite of the Carrancas Formation, generally with a sharp contact (Figs. 2a and 5f).
The lower Sete Lagoas Formation is characterized by deep-water
limestone bearing spectacular calcite crystal fan beds interpreted
as aragonite pseudomorphs. An excellent example is found in the
5 m wall of the Sambra Quarry (Inhamas Site), 50 km to the northwest of Belo Horizonte (Peryt et al., 1990; Hoppe et al., 2002; Vieira
et al., 2007; Babinski et al., 2007). Up section, storm-wave and tide
inuenced limestones predominate (Vieira et al., 2007). The 13 C
prole of the Sambra Quarry is identical to proles of the laminated
limestones that overlie the basal cap dolostone in other parts of the
So Francisco basin, with negative 13 C around 5 at the base,
quickly rising upwards, within 20 m, to values around 0 (Kaufman
et al., 2001; Vieira et al., 2007; Babinski et al., 2007). Aragonite
pseudomorphs were also described by Kuchenbecker (2011) in the
Arcos-Pains region, on the southern So Francisco craton (Fig. 2b),
in the same stratigraphic position.
The top of the rst shallowing-upwards cycle is characterized by
dissolution features, tepees, mud cracks, dolomitization and other
facies changes, as well as subtle variations in regional dip (Martins
and Lemos, 2007). Isotopically, this surface is marked by a positive
shift in 13 C values from around +4 below to +8 above, while in
other places this increase is less abrupt, with a gradual rise towards
more positive values (Fig. 2). This surface is also recognizable in
seismic proles (Zaln and Romeiro-Silva, 2007), and is, therefore,
an important unconformity in the middle of the Sete Lagoas Formation, which provides a chronostratigraphic tie that can be traced
across the whole So Francisco Basin (Fig. 2).
Above this unconformity, the upper Sete Lagoas Formation, up
to 160 m thick, is characterized by deep-water grey micrite, pelitic
rhythmite, and black, bituminous, crystalline limestone, locally
with dark Gymnosolenida columnar stromatolites (Marchese, 1974;
Vieira et al., 2007). Upwards, wave-related structures indicate the
progressive shallowing of the platform. The upper Sete Lagoas Formation generally displays 13 C values around +8 near the base,
rising upwards to values >10 (Fig. 2). The upper Sete Lagoas Formation is superseded by deep-water pelites of the Serra de Santa
Helena Formation, marking a ooding of the basin and the beginning of a new regressive cycle (Dardenne, 2000).
quarries, just about 5 km apart, despite the fact that the latter
are heavily recrystalized and yielded a younger overlapping Pb-Pb
isochron of 681 50 Ma (Babinski et al., 2007). Hence, Sr isotopic
signatures clearly withstood the Pb isotopic resetting event proposed by Babinski et al. (1999) and DAgrella-Filho et al. (2000).
2.5. Fold belts
A number of diamictite-bearing units in the fold belts that surround the So Francisco craton are thought to record the precursor
rift to passive margin sequences, which were inverted and metamorphosed during the Brasiliano Orogeny, around 630570 Ma.
These sequences are generally thicker and more complex than the
diamictite-bearing cratonic units (Fig. 3); nevertheless, they are
broadly considered as chronostratigraphic equivalents that reect
a deep marine continuation of the cratonic platform sedimentation, mainly by down-slope gravity ow deposition (e.g. Uhlein
et al., 1999, 2004; Sial et al., 2009; Pedrosa-Soares et al., 2011). The
Sergipano fold belt is the only belt that contains a thick carbonate
succession; the others comprise mainly siliciclastic sediments with
no cap carbonate sequence. The younger detrital zircon U-Pb age
populations of most of these units yielded very similar Tonian ages
(8501000 Ma; Fig. 3; Pedrosa-Soares et al., 2000; Rodrigues et al.,
2010; Caxito et al., 2011; Amorim Dias, 2011; Babinski et al., 2012).
The only exceptions are the Rio Verde Formation schists, which
pass vertically downwards to the Cubato Formation diamictites of
the Braslia fold belt, and the Palestina Formation in the Sergipano
fold belt, both of which yielded 650640 Ma zircons (Fig. 3b and
d; Oliveira et al., 2005, 2006, 2010; Rodrigues et al., 2010; Amorim
Dias, 2011). As the onset of compressional deformation in both fold
belts is estimated at about 630 Ma (Pimentel et al., 1999; Dardenne,
2000; Valeriano et al., 2004; Oliveira et al., 2006, 2010), the deposition of these two units is tightly constrained to 640630 Ma,
which suggests a correlation with the global 635 Ma Marinoan
(end-Cryogenian) glaciation (Hoffmann et al., 2004; Condon et al.,
2005).
3. New data
3.1. Materials and methods
We present lithostratigraphic and isotopic data for a previously
unstudied section of the Sete Lagoas Formation in the north central
part of the So Francisco basin, near the town of Correntina, Bahia
(Figs. 2 and 6). Here, Archean to Paleoproterozoic gneiss and granites of the So Francisco craton basement (Cordani et al., 1979) are
directly overlain by the Sete Lagoas Formation carbonates (Fig. 6).
The section was sampled on a SN transect on the unpaved road
between Jaborandi and So Manoel, where the basement is exposed
(Fig. 6). Downcutting through the Paleogene peneplane surface
(King, 1956) by the Arrojado River provides access to a 127 m-thick
section of the Sete Lagoas Formation (Fig. 6).
The Correntina section begins with a two-meter thick massive to nely laminated pink dolostone (Fig. 7a), which grades
upward into a reddish to purple limestone rhythmite composed of
centimeter-scale undulating layers of calcilutite intercalated with
marly siltstone (Fig. 7b). The most common sedimentary features
are plane-parallel and undulating laminations, wavy and linsen
cross-laminations, marly mud drapes, cross-bedding in the marl
layers, and, locally, mud cracks, suggesting deposition in a tidal at
environment. This laminated limestone shows no facies change for
123 m; the top of the section is a black, plane-parallel laminated
calcarenite. Although no diamictite was observed between the Sete
Lagoas Formation and the basement, thin, meter-scale diamictite
layers at the base of the Sete Lagoas Formation have been described
45
46
Fig. 6. Simplied geological map and section of the Correntina region, BA. For location see Fig. 2. The map is in part from Souza et al. (2004).
mass spectrometer operating in static mode at the Radiogenic Isotope Geochemistry Laboratory at GEOTOPUQAM. All data were
corrected for internal mass bias using 86 Sr/88 Sr = 0.1194. Repeated
measurements of the NBS SRM 987 standard yielded a long-term
average of 0.710245 0.000007 (n = 7).
3.3. Results
3.3.1. Correntina section
The Correntina section yielded a coupled 13 C and 18 O pattern
(Table 1; Fig. 8). The basal pink dolostone preserves a drop in 13 C
values from 3.8 to 4.2 through the rst 1.5 m, accompanied by
a drop in 18 O values from 4.5 to 5.1. The red laminated limestone that sits immediately above it yielded 13 C values averaging
Fig. 7. Sete Lagoas Formation carbonates at Correntina, Bahia: (a) hand sample of the pink, thinly laminated cap dolostone at the base of the section (0.5 meters); (b)
plane-parallel and undulose laminated limestone and marl intercalations; width of hammers head is about 10 cm.
47
Table 1
13 C, 18 O and Sr isotope data from the Sete Lagoas Formation at Correntina, Bahia. 13 C and 18 O values in PDB (normalized to Pee Dee Belemnite).
Sample
COR0
COR0.5
COR1
COR1.5
COR2
COR7
COR8
COR9
COR10
COR11
COR12
COR13
COR20
COR20.5
COR21
COR21.5
COR22
COR22.5
COR28
COR36
COR37
COR46
COR47
COR50
COR51
COR52
COR53
COR54
COR55
COR60
COR61
COR62
COR63
COR64
COR65
COR66
COR67
COR68
COR69
COR70
COR71
COR72
COR75
COR97
COR105
COR126
COR127
525
525.5
526
526.5
527
532
533
534
535
536
537
538
545
545.5
546
546.5
547
547.5
553
561
562
571
572
575
576
577
578
579
580
585
586
587
588
589
590
591
592
593
594
595
596
597
600
622
630
651
652
13 C
3.77
3.89
3.94
4.17
5.75
5.60
5.67
5.43
5.26
4.95
4.75
5.31
5.67
5.66
5.70
6.05
5.72
5.61
5.07
5.02
5.59
4.72
4.43
5.21
5.18
5.04
4.91
4.85
4.28
0.30
0.35
0.37
0.36
0.54
0.52
0.57
0.59
0.58
0.59
0.78
0.31
0.37
0.97
0.88
0.79
0.99
1.72
sections fringing the Brasiliano fold belt margins (Fig. 2). However,
it differs signicantly from sections in the Sete Lagoas region
(on the southeastern margin of the So Francisco craton) insofar
as these lack the basal pink dolostone layer which preserves a
drop of 13 C values and coupled decline in 18 O (Fig. 2a). The rise
from negative values around 5 towards values around 0 in
the lower Sete Lagoas Formation usually occurs within 210 m.
Therefore, the isotopic break observed between 55 and 60 m in
the Correntina section probably correlates with this abrupt rise,
which is recorded by the crystal-fan facies on the Sete Lagoas and
Arcos-Pains regions (Fig. 2a and b; Vieira et al., 2007; Babinski
et al., 2007; Kuchenbecker, 2011). Hence, the Correntina section
likely represents the lower Sete Lagoas Formation.
Samples of the Correntina section above the 60 m mark have
Sr concentrations ([Sr]) between 250300 ppm, while a limestone
sample at 12 m have 173 ppm Sr and a sample from the cap dolostone is less than 50 ppm. Most of the samples have 87 Sr/86 Sr
ratios around 0.7080 (Table 1). The least radiogenic 87 Sr/86 Sr ratios,
around 0.7076, were obtained on two samples of the black calcarenite at the top of the section, which have the highest [Sr],
above 1000 ppm. These results are broadly consistent with previously reported 87 Sr/86 Sr for the Sete Lagoas Formation (Table 4;
18 O
4.48
4.60
4.80
5.10
10.79
10.86
11.02
10.91
10.76
10.48
10.43
12.59
11.04
10.98
10.98
11.66
10.91
10.77
13.34
7.68
12.23
11.05
10.70
11.06
10.91
10.78
10.62
10.67
8.18
7.30
7.34
7.22
7.26
7.24
7.21
7.25
7.23
7.12
7.14
7.14
7.39
7.28
6.95
6.77
7.21
6.65
6.46
Sr (ppm)
87
Sr/86 Sr (2)
<50
173.11
327.74
243.61
0.708021 (19)
246.79
256.13
0.708146 (11)
284.69
312.01
296.87
308.42
319.24
2171.76
1584.38
0.708005 (14)
0.708176 (8)
0.708499 (21)
0.707598 (5)
0.707567 (5)
Chang et al., 1993; Kawashita, 1998; Misi and Veizer, 1998; Babinski
et al., 2007; Alvarenga et al., 2007; Misi et al., 2007; Kuchenbecker,
2011; Lima, 2011). We tentatively consider a minimum cut-off [Sr]
of 1000 ppm as indicating the least altered 87 Sr/86 Sr to best approximate the original seawater ratio of about 0.7076.
3.3.2. Carbonate clast data
The wide range in 13 C values and consistently increasing
87 Sr/86 Sr signatures that characterizes Neoproterozoic seawater (Halverson et al., 2010; Halverson and Shields-Zhou, 2011)
make carbonate clast data (Table 2; Fig. 9) a promising tool for
provenance and chronological constraints (cf. Hork and Evans,
2011). Unfortunately, Sr concentrations are invariably lowered by
post-depositional alteration (Brand and Veizer, 1980; Banner and
Hanson, 1990; Halverson et al., 2007a), which hampers the recovery of primary 87 Sr/86 Sr ratios on carbonate clasts. Most of the
clasts analyzed yielded [Sr] < 50 ppm, with some preserving [Sr] of
around 100 ppm. The radiogenic signature of the 87 Sr/86 Sr ratios
(0.7130.728) clearly indicates that some samples have been heavily altered with respect to Sr. Despite the attempt to collect only
unweathered and homogeneous clasts, the fact that they represent
eroded fragments from the glacial substrate might explain their
48
Fig. 8. 13 C and 18 O isotopic proles of the Correntina section. The insets magnify the basal 10 m of section.
Fig. 9. 13 C-18 O diagram of carbonate clasts compared with possible source areas in east central Brazil. See Table 2 for data. Possible source elds compiled from data from
the Paleoproterozoic Gandarela and Fecho do Funil formations (Sial et al., 2000; Bekker et al., 2003; Maheshwari et al., 2010); Mesoproterozoic Rio Pardo Grande Formation
and Parano Group (Santos et al., 2000, 2004; Alvarenga et al., 2007) and the Lapa Formation (Azmy et al., 2006), of purported late Mesoproterozoic age (Azmy et al., 2008).
Sr (ppm)
87
Carrancas Formation
4.05
CAR7
4.23
CAR4
CAR6
4.13
CAR3
4.01
CAR2
4.00
CAR5
3.76
CAR1
3.74
11.23
6.83
8.03
6.56
6.72
6.53
6.32
155.14
<50
77.62
<50
<50
<50
<50
0.713020 (18)
Jequita Formation
JEQ14
JEQ03
JEQ18
JEQ19
JEQ12
JEQ24
JEQ17
JEQ15
JEQ01
JEQ02
JEQ13
JEQ09
JEQ20
JEQ04
JEQ21
JEQ05
JEQ27
JEQ07
JEQ06
JEQ11
JEQ23
JEQ25
JEQ29
JEQ08
JEQ30
JEQ22
JEQ26
JEQ28
JEQ16
10.17
9.83
13.88
10.80
13.31
11.48
11.08
11.09
9.76
12.75
14.35
12.13
11.24
10.12
11.18
12.22
10.61
9.68
12.03
11.54
9.85
10.16
10.20
8.69
10.22
9.80
9.66
6.86
7.06
Sample
13 C
7.70
4.73
4.06
3.83
3.15
2.95
2.37
2.33
1.78
1.60
1.46
1.44
0.86
0.84
0.81
0.81
0.79
0.61
0.59
0.45
0.33
0.29
0.05
0.00
0.01
0.55
0.64
1.91
2.12
13.05
10.08
12.33
12.78
11.61
13.11
11.99
12.84
15.16
15.59
15.37
12.32
8.52
14.85
9.31
7.68
15.36
Canabravinha Formation
CAN10
4.47
3.30
CAN6
3.09
CAN13
2.84
CAN8
2.81
CAN2
2.49
CAN9
2.48
CAN14
1.74
CAN11
1.44
CAN5
1.41
CAN1
0.11
CAN4
0.00
CAN7
3.01
J0.5 (matrix)
12.74
13.09
12.93
10.97
12.07
12.07
12.32
10.64
11.80
10.83
10.69
10.64
12.91
Sr/ 86 Sr ( 2)
49
<50
<50
<50
<50
<50
<50
<50
<50
113.69
0.728088 (30)
<50
<50
<50
<50
99.18
98.09
<50
<50
0.729834 (8)
0.727384 (71)
50
Table 3
Disponible stable isotope data from the thin cap dolostone unit at the base of the Sete Lagoas Formation. 13 C and 18 O values in PDB (normalized to Pee Dee Belemnite).
The top sample in each column is from the rst occurence of limestone above the cap dolostone, highlighting the 13 C and 18 O negative jump in the dolostone-limestone
transition.
Alvarenga et al. (2007)
Kuchenbecker (2011)
This study
Sample
Height (m)
13 C
18 O
Sample
Height (m)
13 C
18 O
Sample
Height (m)
13 C
18 O
Bz18E
Bz18D
Bz18C
Bz18B
7
6.5
3
1
5.7
4.7
4.4
3.2
9.1
5.3
5.4
5.6
M9
M8
M7
M6
M5
M4
M3
9
8
7
6
5
4
3
5.38
4.44
4.37
4.23
4.38
4.05
3.72
12.99
8.37
8.56
11.59
11.27
6.18
6.49
COR2
COR1.5
COR1
COR0.5
COR0
2
1.5
1
0.5
0
5.75
4.17
3.94
3.89
3.77
10.79
5.10
4.80
4.60
4.48
boulders of grey limestone are found near the top of the layer, close
to the sharp contact with the Sete Lagoas Formation (Fig. 5f). These
clasts are very lithologically similar to the overlying limestone of
the Sete Lagoas Formation. We collected two samples of these limestone clasts (samples CAR6 and CAR7). The other ve samples are
from dolostone clasts (CAR1 to CAR5).
The ve dolostone clasts yielded a restricted range of 13 C from
3.7 to 4.2, and 18 O from 6.3 to 6.8. These values are
different from any of the other analyzed diamictite clasts, but virtually identical to the basal Sete Lagoas dolostone values (Fig. 9).
The samples of the two limestone clasts (CAR6 and CAR7) yielded
Table 4
Sete Lagoas Formation 13 C, 18 O and least radiogenic 87 Sr/86 Sr data. Data from the Lagoa do Jacar Formation (upper Bambu Group) and from the Salitre Formation, Una
Group in Bahia are added for comparison.
Sample
13 C
18 O
Sr (ppm)
Mn/Sr
87
COR126
COR127
BB 16H
BB 16N
M40
M45
M46
M48
TMG16
TMG17
TMG18
TMG19
LU.10.4
LU.10.5
LU.10.6
Bz38
Bz37
Bz36
3.5
SR AM 111
MF 7-C
0.99
1.72
0.08
0.2
1.5
1.4
1.6
1.9
3.8
3.7
3.1
2.2
2.8
1.8
0.6
6.3
2.7
3.6
1.4
6.65
6.46
7.54
7.57
7.9
8.4
7.8
6.7
7.8
8.2
7.3
7.9
10.7
10.3
8.6
5
6
5.5
2171.76
1584.38
2328
643
1618
1817
1957
3304
1990
1616
3064
1733
1590
2050
0
0.2
0.02
0.13
0.08
0.01
0.01
0.707598
0.707567
0.70768
0.7078
0.707683
0.707622
0.707648
0.707493
0.7074
0.7075
0.7076
0.7081
0.7079
0.7081
0.7082
0.70748
0.70758
0.70745
0.70745
0.70755
0.70739
This study
This study
Lima (2011)
Lima (2011)
Kuchenbecker (2011)
Kuchenbecker (2011)
Kuchenbecker (2011)
Kuchenbecker (2011)
Vieira et al. (2007), Babinski et al. (2007)
Vieira et al. (2007), Babinski et al. (2007)
Vieira et al. (2007), Babinski et al. (2007)
Vieira et al. (2007), Babinski et al. (2007)
Vieira et al. (2007), Babinski et al. (2007)
Vieira et al. (2007), Babinski et al. (2007)
Vieira et al. (2007), Babinski et al. (2007)
Alvarenga et al. (2007)
Alvarenga et al. (2007)
Alvarenga et al. (2007)
Powis et al. (2001) in Misi et al. (2007)
Misi and Veizer (1998)
Kawashita (1998)
Sr/86 Sr
Reference
BDI 31B
BDI 31C
BDI 31D
CA-IE-14
14
SR AM 1
3H
7.1
1260
954
1189
625
3874
1430
4050
0.04
0.03
0.02
0.02
0.01
0.01
0.70749
0.70756
0.70744
0.70757
0.70743
0.70767
0.70738
Lima (2011)
Lima (2011)
Lima (2011)
Lima (2011)
Powis et al. (2001) in Misi et al. (2007)
Misi and Veizer (1998)
Kawashita (1998)
6.4
5.9
5.2
6.3
6.5
7.2
7
7.5
6.5
6.2
461
792
374
2384
1275
896
790
963
1429
1717
0.03
0.02
0.05
0.03
0.01
0.01
0.01
0.09
0.01
0.02
0.70769
0.70745
0.70759
0.70752
0.70765
0.70782
0.7078
0.70789
0.70765
0.7078
Fig. 10. 13 C-18 O diagram of carbonate clast data from the Carrancas Formation
as compared to the thin cap dolostone layer found at the base of the Sete Lagoas
Formation (Table 3).
51
52
Fig. 11. 87 Sr/86 Sr-13 C diagram showing available data from the Sete Lagoas Formation, compared to worldwide Sturtian and Marinoan carbonate data. Data from
the Lagoa do Jacar Formation of the upper Bambu Group and from the Salitre Formation of the Una Group is added for comparison. See Table 4 for data sources.
The Sturtian and Marinoan elds are drawn from the databases of Halverson et al.
(2007a, 2010), Halverson and Shields-Zhou (2011), and references therein.
53
Fig. 12. Chemostratigraphic correlation of lower Ediacaran successions on the So Francisco and Congo cratons. Inset map shows the approximate position of the stratigraphic
sections on a paelogeographic reconstruction of the So Francisco (SFC)Congo craton, during the lower Ediacaran. Note change in scale from columns a and c to column b.
See text for data sources. Dots in the upper Schisto-Calcaire Subgroup represent dispersion of 13 C data (Frimmel et al., 2006).
54
5. Conclusions
Based on available radiometric, lithostratigraphic, and
chemostratigraphic data, including new data presented here,
we suggest that the entire Sete Lagoas Formation is Ediacaran
in age. Hence, the lower part of this unit comprises the cap
carbonate sequence to the end-Cryogenian (Marinoan) glaciation,
which is represented by the Jequita Formation and equivalent
units elsewhere on the So Francisco craton (e.g. the Bebedouro
Formation) and in the neighboring fold belts (e.g. the Palestina
Formation of the Sergipano fold belt). This conclusion is based on
multiple data sets and lines of reasoning. First, the Sete Lagoas
Formation displays lithostratigraphic features that are similar
to basal Ediacaran cap carbonates worldwide, including a thin
basal pale pink cap dolostone unit and calcite crystal-fan facies
interpreted as aragonite pseudomorphs. Second, the 13 C and 18 O
proles of the Sete Lagoas Formation are nearly identical to those
of other basal Ediacaran cap carbonates, in particular through the
cap dolostone unit where 13 C drops from 3.7 to 5, accompanied by 18 O values around 5. Exceptionally, at the southern
tip of the So Francisco craton, the usual cap dolostone and its
associated isotopic pattern are not observed, most likely because
the basal Sete Lagoas Formation was eroded and resedimented
over the Sete Lagoas paleohigh. Here, the isotopic signature is
preserved in dolostone clasts within the Carrancas Formation,
which is an intraformational, lateral equivalent of the basal Sete
Lagoas Formation, and therefore belongs to the post-glacial cap
carbonate sequence. Third, 87 Sr/86 Sr signatures in the Sete Lagoas
Formation (0.70740.7076) are identical to those in other basal
Acknowledgements
This work is the result of a sustained research interest on the
Bambu Group, supported mostly by the Universidade Federal de
Minas Gerais and Fundaco de Apoio Pesquisa de Minas Gerais,
Brazil. Prof. Lcio Fraga of the Universidade Federal dos Vales do
Jequitinhonha e Mucuri (UFVJM), Brazil, aided in the collection of
carbonate clasts near Diamantina (MG). The elemental and isotopic
analyses were supported by a Graduate Research Traineeship of FAC
at McGill University and GEOTOP, Montral, Canada. We thank Jean
Francois Hlie (UQAM) and Bill Minarik (McGill) for assistance in
acquisition of stable isotope and Sr element analysis, respectively.
The manuscript was greatly improved after suggestions by A.N. Sial
and an anonymous reviewer.
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