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INTRODUCTION
This unit provides basic knowledge on Temperature and Heat to help students
understanding one of the principal branches of physics and engineering, which is
the thermodynamics. The thermodynamics is the study and application of the
thermal energy (often called the internal energy) of systems. One of the central
concepts of thermodynamics is temperature. Student will also learn the transfer
of energy (heat) between objects is due to temperature difference between them.
The concept of heat capacity and specific heat will also be discussed.
LEARNING OBJECTIVES
The objectives of this unit are to impart students
i.
ii.
With the basic knowledge in science especially heat and thermal properties of
matters
To apply the concept of heat and thermal properties in Civil Engineering
Technology course.
LEARNING OUTCOMES
After completing this unit, the students should be able:
i.
ii.
iii.
iv.
v.
vi.
vii.
viii.
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3.1 TEMPERATURE
The temperature is one of the basic quantities in physical units. It can be defined
as the measure of the degree of hotness and coldness of matters whether in
solids, liquids or gases. When two or more objects are in contact with each other,
their temperatures (the degree of hotness or coldness) are equal, they are said to
be in thermal equilibrium. The concept of thermal equilibrium is the basic
foundation of temperature definition.
3.1.1 THERMAL EQUILIBRIUM
Temperature is the quantity that may be determine when matters (or objects) are
in thermal equilibrium. Figure 3.1(a) shows two matters with different
temperatures that are not in contact thermally. When two matters in thermal
contact to each other, the energy (heat) from matter with higher temperature will
flow to the matter with lower temperature (Figure 3.1(b)). As the energy
continuously flow, temperatures of two matters will approach each other. At equal
temperatures, there are no longer net flows of energy between them and it is in
its thermal equilibrium.
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3.1.2 THE ZEROTH LAW OF THERMODYNAMICS
The thermometry property is the physical properties of materials that changed
linearly proportional with temperature when the materials becomes hotter or
colder. Table 3.1 shows some types of thermometer with their common
thermometry properties.
Table 3.1
Thermometer
Mercury thermometer
Ideal gas thermometer
Thermometry Properties
The change in expansion of mercury in glass
column with temperature
The change in gas pressure with temperature at
constant volume OR the change in gas volume
with temperature at constant gas pressure.
Thermocouple
Electrical resistance
thermometer
(thermistor)
Thermogram
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T
A
(a)
B
(b)
A
(c)
Ice point: the point where an ice (solid) and water (liquid) are in equilibrium
phase (atmospheric pressure, p = 1 atm)
Steam point: the point where the water (liquid) and steam (gases) are in
equilibrium phase (atmospheric pressure, p = 1 atm)
On Celsius scale, the ice point is numbered as zero (0) and at steam point is
numbered as one hundred (100). The unit being used for Celsius scale is the
degree Celsius (oC).
Another temperature scale commonly used is the Fahrenheit scale. At 1 atm, the
ice point is assigned at the number of 32, while at steam point; the number of
212 is used. The unit for this scale is the degree Fahrenheit ( oF). The difference
between the steam and ice point in Celcius scale is 100 oC while on the
Fahrenheit scale is 180oF.
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Although the Celcius and Fahrenheit scales are widely used, the Kelvin
temperature scale had been chosen as the international standard temperature
scale. The SI unit is the Kelvin (symbol K, without a degree sign). The ice point is
273.15 K and the steam point is at 373.15 K. Zero Kelvin (0 K) represents
absolute zero. There are no temperatures below 0 K. So there are no negative
temperature numbers in Kelvin scale.
Figure 3.3 shows 3 scales that we describe previously. The figure clearly
indicates that the Kelvin scale, TK has the same degree size as the Celsius scale,
TC and are related by
TC = TK 273.15
Steam
Point
100 OC
212 OF
TC=100 OC
Ice
Point
0 OC
373.15 K
Fahrenheit scale
33
TK=100 K
TF=180 OF
32 OF
Celcius scale
(3.1)
273.15 K
Kelvin scale
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While the comparison between the Celsius scale, TC and Fahrenheit scale, TF: a
temperature difference of 1oC is equivalent to a difference of 1.8 oF and are
related by these equations,
O
F
TF 1.8 O TC 32 O F
C
(3.2)
TC 32 O F
TC
O
F
1.8 O
C
(3.3)
And
Example 3.1
A friend suffering from flu has a slight fever. His body temperature is 37.20 oC.
What is his temperature in
(a)
(b)
Kelvin, K
Degree Fahrenheit, oF
Solution
From Equation 3.1, the body temperature in K:
TK = TC + 273.15
= 37.20 oC + 273.15
= 310.35 K
From Equation 3.2, the body temperature in oF:
O
F
TF 1.8 O TC 32 O F
C
F
1.8 O (37.20 O C) 32 O F
C
=
= 98.96 oF
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3.1.4 DETERMINING TEMPERATURE BY USING THERMOMETRY
PROPERTIES
Since thermometers measure temperatures by exploiting property of matters that
are temperature-dependent, we can determine unknown temperature of matters
from its corresponding thermometry properties. The thermometry properties can
be of any parameters of materials that change linearly with the changing of
temperature, as described earlier in Table 3.1.
Firstly the thermometer scale must be calibrated with the melting point of 0 oC
and boiling point of 100 oC of water at pressure of 1 atm. The values of
parameter (X0 and X100) are assigned at their corresponding melting and boiling
points showed in Figure 3.4. Therefore, any unknown temperatures, T with their
corresponding parameters, XT that lies along the straight line of the graph can be
determined by using equation,
XT X0
T
X100 X 0
100 O C
Figure 3.4
35
(3.4)
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Example 3.2
A resistance of a thermometer gives a reading of 30.00 at melting point, 41.58
at boiling point and 34.59 when immersed into a beaker filled with oil.
Calculate the oils temperature
Solution
Resistance at 0 oC
Resistance at 100 oC
Resistance at unknown temperature
:
:
:
R0 = 30.00
R100 = 41.58
RT = 34.59
RT R0
T
R100 R 0
100 O C
(34.59 30.00)
100 O C
(41.58 30.00)
= 39.64 oC
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sum of the molecular kinetic energy, molecular potential energy and other kinds
of molecular energy. The internal energy is also known as a thermal energy.
Molecular kinetic energy originates from the random motion (or vibration) of the
molecules, while molecular potential energy is due to forces that act between the
atoms of a molecule and between molecules.
From Figure 3.1(a), (b) and (c), when heat flows from hot to cold substance, the
internal energy of the hot substance eventually decreases and in contrary, the
internal energy of the cold substance will increases.
3.3 HEAT AND TEMPERATURE CHANGE
3.3.1 HEAT CAPACITY
When a substance is being heated, their temperature increases. Different
substances need different quantity of heat to reach equal elevated temperature.
Physical quantity being used to explain how many heat needed to change
substance temperature by an amount 1 unit is known as the Heat Capacity, C.
For a large number of substances, the temperature change, T is approximately
proportional to the heat, Q.
Q T
(3.5)
The constant of proportionality which relate Q and T is called the Heat Capacity
where,
Q
C
T
(3.6)
The heat capacity of an object is the proportionality constant between the heat Q
being absorbs or loses and the resulting temperature change of that object. The
SI unit for heat capacity is joule per Kelvin (JK-1). Another common unit is cal/oC.
3.3.2 SPECIFIC HEAT
Since the heat capacity of a substance is proportional to its mass, it is therefore
convenient to define another useful quantity. The quantity is the heat capacity per
unit mass or specific heat, c.
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c
Q
m T
(3.7)
The SI unit is joule per kilogram per kelvin (Jkg-1K-1) or joule per kilogram per
degree celcius (Jkg-1oC-1). Another common unit is calorie per gram per degree
celcius(calg-1oC-1). Table 3.2 shows the specific heat of some substances at
room temperature.
Table 3.2
Substance
Aluminium
Brass
Copper
Lead
Mercury
Iron
Steel
Silver
Glass
Ice
Water
Steam
Glycerine
Alcohol
Specific Heat, c
(Jkg-1 oC-1)
910
380
390
130
140
470
450
270
700
2,100
4,200
2,000
2,500
2,430
Example 3.3
How much heat is required to raise the temperature of 200 g of mercury from
20oC to 100oC ?
Solution
When two objects with initially different temperatures are mixed together, they will
eventually reach the same temperature. This is the result of a transfer of thermal
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energy from the hotter object to the cooler object. From the Principle of
Conservation of Energy, the heat lost by the warm bodies must equal the heat
gained by the cool bodies. That is
Heat lost = Heat gained
(3.8)
From Equation 3.8, the heat flowing out from the hotter object numerically equals
the heat flowing into the cooler object, assuming no thermal energy lost from the
system and no external energy comes into the system.
Example 3.4
An aluminum cylinder is heated to 98 oC and then dropped into a styrofoam
container filled with 120 g of water with initial temperature 20 oC. The equilibrium
temperature of the mixture is 31 oC. What was the mass of the aluminum
cylinder? Neglect the containers heat capacity.
Solution
From Equation 3.7 and 3.8, the heat released by aluminium and then absorbed
by water is,
Heat lost by aluminum = Heat gained by water
- mAlcAlTAl = mWacWaTWa
-1 o -1
mAl(910 Jkg C )(31 - 98)oC = (0.12 kg)(4,200 Jkg-1 oC-1)(31 - 20)oC
60970 mAl Jkg-1 = 5,544 J
mAl = 0.091 kg = 91 gram
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substance released heat continuously, where its temperature gradually
decreased, until at a certain stage the substance phase will changed from the
gases phase to liquid phase at its condensing point or from liquid phase to solid
phase at the freezing point.
At the melting point (or freezing point) and boiling points (or condensing point),
the temperature of the phase does not change during such a change of phase,
even the heat is supplied (or released) continuously. This is because the energy
absorbed by the material is used in separating the molecules more than its
previous phase.
Figure 3.5 (a) and (b) depict when a material is in solid form, bond between the
atoms or molecules hold them tightly. Energy must be supplied to break the
bonds and change the solid into liquid. When the substance is changed from
liquid to gas, energy is used to separate the molecules from the loose bonds
holding them together and to move the molecules apart.
The quantity of heat, Q required to melt a unit mass of a substance, m at its
melting point is called the latent heat of fusion for that substance. The heat per
unit mass for the solid-liquid phase transition (in either direction) is called the
latent heat of fusion, Lf.
Lf
(a)
Q
m
(3.9)
(b)
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Q
Lv
m
(3.10)
SI unit for both latent heat are joules per kilogram (Jkg-1). Calories per gram
(calg-1) and Btu per pound (Btulb-1) is another older unit.
Table 3.3
Substance
Aluminium
Copper
Lead
Mercury
Silver
Water
Oxygen
Nitrogen
Melting
Point
(oC)
660
1,083
327
-39
961
0
-219
-210
Latent Heat
of Fusion
(kJkg-1)
377
134
25
11.7
88
333
13.8
25.5
Boiling
Point
(oC)
Latent Heat
of
Vaporization
(kJkg-1)
2,467
2,595
1,620
357
2,193
100
-183
-196
11,390
5,075
871
293
2,340
2264
214
200
Values for the latent heat of fusion and latent heat of vaporization for many
substances are given in Table 3.3.
Graph in Figure 3.6 depicts the changes of phase of a water, showing how the
temperature of the substance varies as thermal energy is applied to the water at
a steady rate.
41
Steam only
Water and steam
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Water only
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From Equation 3.7, calculate the heat required to raise the temperature of 100 g
of ice from -15oC to its melting point (0oC) :
Q1 = miceciceT
= (0.1 kg)(2100 Jkg-1 oC-1)[0-(-15)] oC-1
= 3,150 J
From Equation 3.9, calculate the heat required to melt all of this ice into water at
its melting point (0oC) :
Q2 = (micewater)Lf
= (0.1 kg)(333 103 Jkg-1)
= 33,300 J
From Equation 3.7, calculate the heat required to raise the temperature of 100 g
of water from 0oC to its boiling point (100oC) :
Q3 = mwatercwaterT
= (0.1 kg)(4200 Jkg-1 oC-1)(100-0) oC-1
= 42,000 J
From Equation 3.10, calculate the heat required to vapour all of this water into
steam at its boiling point (100oC) :
Q4 = (mwatersteam)Lv
= (0.1 kg)(2264 103 Jkg-1)
= 226,400 J
From Equation 3.7, calculate the heat required to raise the temperature of 100 g
of steam from 100oC to 110oC :
Q5 = msteamcsteamT
= (0.1 kg)(2000 Jkg-1 oC-1)(110-100) oC-1
= 2,000 J
The total heat required is the sum of these five processes:
Qtotal =
=
=
=
43
Q1 + Q2 + Q3 + Q4 + Q5
3,150 J + 33,300 J + 42,000 J + 226,400 J + 2,000 J
306,850 J
306.9 kJ
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Tcold
A
d
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Figure 3.7 Heat flow through a cylindrical bar
(i)
(ii)
(iii)
In Figure 3.7, the cylindrical bar with length d, uniform cross section A is
maintained at temperatures Thot and Tcold at its both ends. Evidences from
Q
experiments shows that the quantity of heat transferred, per unit of time, t is,
Directly proportional to the temperature difference (T = Thot Tcold) between the
two ends
Directly proportional to the cross sectional area, A of the cylindrical bar
Inversely proportional to the length, d of the cylindrical bar.
By neglecting the heat released at the sides of the cylindrical rod, the above
results can be expressed in equation form as
Q
T Tcold
k A hot
t
d
(3.10)
d
is known as
a material. The SI unit of k is Wm-1K-1. The portion of
o
the temperature gradient. It tells how many K or C the temperature changes per
unit length moved along the path of heat flow. Table 3.4 lists the coefficient of
thermal conductivities for several common substances.
Example 3.6
A block of concrete has a cross section of 5 m 2 and a thickness of 10 cm. One
side is at 40oC, and the other is at 20oC. What is the rate of heat transfer?
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Table 3.4
Substance
Silver
Copper
Aluminum
Brass
Iron
Steel
Lead
Mercury
Concrete
Glass (pyrex)
Brick
Water
Asbestos
Dry soil
Wood
Air
Thermal
Conductivities, k
(Wm-1 K-1)
418
385
238
122
80
46
38
8
1.7
1.1
1
0.6
0.17
0.14
0.13
0.023
Solution
Solving for rate of heat transfer in Equation 3.10 yields,
Q
T Tcold
k A hot
t
d
40 o C 20 o C
0.10 m
(1.7 Wm 1K 1 ) (5m 2 )
=
= 1,700 W
3.5.2 CONVECTION
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Convection of thermal energy occurs in a fluid (liquids or gases) when warm
fluids flows, carrying energy with it, as to displace cooler fluids. Convection
cannot happen in solids since its atoms or molecules keep their tight position.
Therefore, bulk movement or flow is prohibited which forbidden convection to
occur.
Figure 3.8 shows a beaker of water being heated over a flame. Heated water at
the bottom of the beaker will expand and becomes more buoyant, due to the
increased of volume per unit mass; the density of the water will eventually
decrease. The cooler and denser water near the surface will go down replacing
the position of hotter water. So the pattern of circulation is formed within the
beaker of water.
Cooler water
descends
Convection currents
Hotter water
rises
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and convection, which no medium is required for heat transfer via radiation. The
radiation can travel through vacuum for instance from the sun to the earth.
The rate, P at which an object emits energy via electromagnetic radiation is given
by
P A T 4
(3.11)
Where A is the surface area of an emitting object, T is an absolute temperature in
Kelvin, and is the Stefan-Boltzmann constant with value 5.67 10-8 Wm-2K-4.
The symbol, represent the emissivity of the objects surface, which has a value
between 0 and 1. A surface with the maximum emissivity of 1.0 is said to be a
blackbody radiator, but such surface is ideal and does not occur in nature.
From Equation 3.11, it is clear that every object whose absolute temperature is
above 0 Kelvin (including human) emits thermal radiation. And at the same time
the object also absorb thermal energy from surroundings. When an object at
absolute temperature T is in environment where the temperature is TE, the net
energy radiated per second by the object is
P A (T 4 TE4 )
(3.12)
Example 3.7
A spherical body with diameter of 6.0 cm is maintained at 200 oC. Assuming that
the spherical body is an ideal blackbody, at what rate (in watt) is energy radiated
from the sphere?
Solution
The temperature of the spherical body, T = 200oC = 473 K
The surface area, A = 4r2 = 4(0.03 m)2 = 1.13 10-2 m2
For ideal blackbody, = 1
Solving for rate of energy radiated in Equation 3.11 yields,
P A T
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SUMMARY
In this unit we have studied that:
1.
2.
When two matters are in thermal contact to each other, the energy (heat)
from matter with higher temperature will flow to the matter with lower
temperature. As the energy continuously flow, temperatures of two matters
are approaching to each other. When the temperatures are equal, there
are no longer net flows of energy between them. The matters are now said
to be in thermal equilibrium.
3.
4.
5.
6.
TF 1.8 O TC 32 O F
C
7.
8.
Heat is energy that flow from a higher-temperature object to a lowertemperature object because of the difference in temperatures.
9.
10.
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Q
c
m T . The SI unit is joule per kilogram per kelvin (Jkg-1K-1) or joule
per kilogram per degree Celsius (Jkg-1oC-1). Another common unit is
calorie per gram per degree Celsius (calg-1oC-1).
11.
12.
13.
EXERCISES
The melting point of lead is 327.3 oC. What is the corresponding
temperature on the Fahrenheit scale?
(Ans : 621.14 oF)
1.
2.
3.
4.
50
How much heat is loss by the water as its cools back down to 21 oC
(Ans : 71.4 kJ ; -71.4 kJ)
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6.
7.
8.
Determine the temperature when 175 g of ice at 0oC is mixed with 500 g of
water at 65oC.
(Ans : 27.4 oC)
9.
10.
11.
12.
(a)
(b)
(c)
13.
14.
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(0.034 fraction of water changes to the gaseous phase)
15.
16.
17.
REFERENCES
1.
2.
3.
4.
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