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MULTIPLE CHOICES
1. Which is the electronic configuration that describes Mg2+?
a) 1s2, 2s2
b) 1s2, 2s2, 2p6
c) 1s2, 2s2, 2p6, 3s2
d) 1s2, 2s2, 2p6, 3s2, 3p6
2. Which is the electronic configuration that describes C?
a) 1s2, 2s2, 2p5
b) 1s2, 2s2, 2p6, 3s2
c) 1s2, 2s2, 2p2
d) 1s2, 2s2, 2p6
3. Which ion is described by the electronic configuration 1s22s22p63s23p2?
a) Mg+
b) Al+
c) Si+
d) P+
4. Which atom is described by the electron configuration 1s 22s22p63s23p5?
a) S
b) Se
c) Cl
d) Br
A
5. Which atom is described by the Lewis structure
a) C
b) P
c) Se
d) I
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
Na2CO3
II
NH4Cl
III
NaCl
IV
a) I, II
b) II, IV
c) I, II, IV
d) II, III
8. Arrange the bonds in increasing order of ionic character (least first).
C-C
I
Na-O
II
C-N
III
O-H
IV
C-O
V
H
a) H C OH
H
H H
b) H C C H
.. ..
c) H O O H
.. ..
d) H
.. :O : ..
O C O
..
..
H O O H
H H
H N N H
H N O
H C Cl
III
IV
II
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
a)
b)
c)
d)
I, II
II, IV
III, IV
I, III
NH3
CO2
H2O
II
III
a)
b)
c)
d)
CH4
Br2
IV
I, IV
I, III
II, III, IV
III, IV, V
O
H2C
CH2
I
CH2Cl2
H3C
IV
III
II
a) III, IV, V
b) I, IV
c) II, III, V
d) I, III
13. Which functional groups have correct Lewis structures?
O
C O H
C O
hydroxyl
I
carbonyl
II
C O H
carboxyl
III
a) I, II
b) II, III
c) I, II, III
d) I, III
CH3
CH3OH
V
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
14. Which is the correct Lewis structure for acetic acid (CH3CO2H)?
H O
H O
H C C O
H C C O
H H
H H
a)
O H
H C O C H
H O C C H
b)
c)
d)
15. Using the VSEPR model, predict which atoms have bond angles of about 120.
O
H3C
CH2 CH2
CH3OH
III
II
NH4Cl
IV
a) II, IV
b) I, IV
c) II, III
d) I, III
16. According to VSEPR model, what is your prediction for the arrangement of electron pairs for CH3-?
a) linear
b) tetrahedral
c) bent
d) trigonal
17. Using the VSEPR model, predict which species have bond angles of about 109.
NH3
CO2
H2O
H3O
II
III
IV
I
a) I, III, IV
b) II, III, V
c) I, IV
d) III, IV, V
O3
V
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
18. What is the correct structure for the aldehyde which has the formula C4H8O?
OH
a) CH3
CH CH CH2
b) CH3
d) H2C
CH CH2
CH2
CH3
O
c) CH3
CH2
CH2
CH
O CH3
19. Nitrogen has a negative formal charge in which of the following compounds?
a) NaNH2
b) N2
c) NH4Cl
d) HCN
NaC
CH
a) 2
b) 1
c) 0
d) +1
22. The carbon has the correct orbital hybridization in which structures?
H2C O
H2C CH2
sp
I
sp
II
CH4
sp
III
a) II, IV, V
b) II, III, IV
c) I, II, III
d) I, IV, V
HC N
O C O
sp
IV
sp
V
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
23. What are the correct orbital hybridizations for carbon in the following species?
A. CH3
I. sp
B. CH4
II. sp
C. CH
3
III. sp3
CH3
II
III
H2C
CH3
CH3
CH2
OH
H2C O
H2C O
CH CH2
H2C
IV
N C O
CH CH2
N C O
a) II, IV
b) I, II, III
c) III, IV
d) II, III, ,IV
25. Carbon has how many valence electrons?
a) 2
b) 4
c) 6
d) 8
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
O
H3C
O
H
alcohol
I
CH3
OH
aldehyde
II
H3C
H N CH3
CH3
ketone
III
a) III, IV, V
b) II, III, IV
c) I, III, V
d) I, III, IV
CH3
amine
IV
H3C
C OH
carboxylic acid
V
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
H3C
HC
OH
H3C
H3C
OH
H3C
H3C
C
OH
H3C
CH2
HC
H3C
CH3
CH3
I
H3C
II
OH
CH
CH3
III
a) I
b) II
c) III
d) IV
H OH H
F C C C NH2
H H H
7. A __________ bond is characterized by the unequal sharing of electrons.
8. The following molecule contains the _________ and __________ functional groups.
OH
IV
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
9. The following molecule contains the _________ and __________ functional groups.
NH2
OH
O
10. Functional groups undergo the same type of __________ in whatever compound they are found.
11. ______________ are the basis for compound nomenclature.
TRUE-FALSE
1. Each shell can hold two electrons.
2. Orbitals make up the majority of the mass of an atom.
3. The group 7A elements react by losing an electron to achieve a noble gas configuration.
4. The group 2A elements react by losing two electrons to achieve a noble gas configuration.
5. Carbon reacts by gaining 4 electrons to achieve a noble gas configuration.
6. An atom that gains electrons is called an anion.
7. Ionic bonds are characterized by the unequal sharing of electrons.
8. The following molecule is an example of a secondary amine.
H3C
HC
NH2
H3C
9.
10.
CH3CH2CH2CH2CH2OH
CH3ONa
is a polar molecule.
CHAPTER 1
Covalent Bonding and Shapes of Molecules
Modified and prepared by:
Robert Dominic D. Gonzales
ANSWERS
28.
29.
30.
31.
MULTIPLE CHOICE
1. b
2. c
3. d
4. c
5. c
6. a
7. d
8. c
9. d
10. c
11. b
12. c
13. d
14. d
15. d
16. b
17. a
18. c
19. a
20. c
21. b
22. a
23. c
24. c
25. b
26. c
27. b
c
c
a
b
10