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Version number 2
Revision: 18.02.2011
2 Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS07
Acute Tox. 4
Acute Tox. 4
Acute Tox. 4
Skin Irrit. 2
Eye Irrit. 2
H302
H312
H332
H315
H319
Harmful if swallowed.
Harmful in contact with skin.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
Xi; Irritant
R36/38:
R10:
Flammable.
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
(Contd. on page 2)
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Label elements
Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
Code letter and hazard designation of product:
Xn Harmful
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
CAS: 111-76-2
2-butoxyethanol
EINECS: 203-905-0
Xn R20/21/22;
Xi R36/38
Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2,
H315; Eye Irrit. 2, H319
CAS: 1330-20-7
xylene
EINECS: 215-535-7
Xn R20/21;
Xi R38
R10
Flam. Liq. 3, H226;
Acute Tox. 4, H312; Acute Tox. 4, H332; Skin
Irrit. 2, H315
Additional information: For the wording of the listed risk phrases refer to section 16.
50-100%
25-50%
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5 Firefighting measures
Extinguishing media
Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture No further relevant information available.
Advice for firefighters
Protective equipment: Mouth respiratory protective device.
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Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Not determined.
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Undetermined.
137C
Flash point:
30C
Not applicable.
Ignition temperature:
240C
Decomposition temperature:
Not determined.
Self-igniting:
Danger of explosion:
Explosion limits:
Lower:
1.1 Vol %
(Contd. on page 6)
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Upper:
10.6 Vol %
6.7 hPa
Density at 20C:
Relative density
Vapour density
Evaporation rate
0.8919 g/cm
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Solvent content:
Organic solvents:
VOC (EC)
Other information
100.0 %
891 g/Li
No further relevant information available.
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values relevant for classification:
111-76-2 2-butoxyethanol
Oral
LD50 1480 mg/kg (rat)
Dermal LD50 400 mg/kg (rab)
1330-20-7 xylene
Oral
LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
(Contd. on page 7)
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Irritant
12 Ecological information
Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behaviour in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
UN-Number
ADR, IMDG, IATA
UN1263
Class
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Label
IMDG, IATA
Class
Label
3 Flammable liquids.
3
Packing group
ADR, IMDG, IATA
III
Environmental hazards:
Marine pollutant:
No
D/E
UN1263, PAINT RELATED MATERIAL, special provision 640E,
3, III
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Philippines Inventory of Chemicals and Chemical Substances
All ingredients are listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
*
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases
H226
Flammable liquid and vapour.
H302
Harmful if swallowed.
H312
Harmful in contact with skin.
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H332
Harmful if inhaled.
R10
Flammable.
R20/21
Harmful by inhalation and in contact with skin.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
(Contd. on page 9)
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R36/38
R38
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