BGD v T

THI TH THPT QUC GIA MN HA

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
S 2
Cu 1: Dung dch X c 0,1mol K+; 0,2mol Mg2+; 0,1mol Na+; 0,2mol Cl- v a mol Y-. C cn dung dch
X thu c m gam mui khan. Ion Y- v gi tr ca m l :
A. OH- v 20,3
B. NO3- v 42,9
C. NO3- v 23,1
D. OH- v 30,3
Cu 2: Cho cc cht sau: K, Fe, Ba, Cu, Na, Ca, Al, Li, Mg. S cht tc dng c vi nc nhit
thng:
A. 4.
B. 5
C. 6.
D. 7.
2+
3+
+
2+
2+
Cu 3: Cho cc ion kim loi: Cu ; Fe ; Ag ; Zn ; Ca . Chiu tang dn tnh oxi ho cu cc ion kim
loi l:
A. Ca2+ < Zn2+ < Fe3+ < Cu2+ < Ag+
B. Ca2+ < Fe3+ < Zn2+ < Cu2+ < Ag+
2+
2+
3+
+
2+
C. Ca < Zn < Fe < Ag < Cu
D. Ca2+ < Zn2+ < Cu2+ < Fe3+ < Ag+
Cu 4: Cht no sau y khng thu phn c:
A. Saccaroz
B. Mantoz
C. Tinh bt
D. Fructoz
Cu 5: kh hon ton 20,8g hn hp gm Fe, FeO, Fe 2O3, Fe3O4 cn va 5,6 lt (ktc) CO. Khi
lng Fe thu c sau phn ng l:
A. 16,8g
B. 18,6g
C. 20,4g
D. 26,5g
2
2
6
2
Cu 6: Nguyn t ca nguyn t X c cu hnh electron 1s 2s 2p 3s 3p64s1, nguyn t ca nguyn t Y
c cu hnh electron 1s22s22p5. Lin kt ho hc gia nguyn t X v nguyn t Y thuc lao lien kt:
A. Cho-nhn
B. Cng ho tr
C. ion
D. Kim loi
Cu 7: Cc dung dch no sau y c pH > 7: CH 3NH2, H2NCH2COOH, CH3COONa, NH4Cl,
H2NCH2CH2CH2CH(NH2)COOH, C6H5NH2, K2CO3:
A. 2.
B. 7.
C. 6.
D. 4.
Cu 8: Cho cc polime sau: t tm, nilon-6, t axetat, nilon-6,6, t visco, poli(vinyl clorua), t lapsan.
S polime l t nhn to l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 9: Cho amino axit X no, mch h, cha 1 nhm chc mi loi. Cho 0,1 mol X phn ng ht vi
HCl d thu c dung dch cha 11,15g mui. Tn gi ca X l:
A.Glyxin
B. valin
C. alanin
D. lysin
Cu 10: Cho cc cht: (1) NH3, (2) C6H5NH2, (3) CH3NH2, (4) CH3NHCH3. Th t tnh baz tang dn
l:
A. 1, 2, 3, 4.
B. 2, 1, 3, 4.
C. 2, 3, 1, 4.
D. 2, 4, 1, 3.
Cu 11: Cu no sau y khng ng:
A. Cc cht in li mnh l axit mnh, baz mnh v cc mui tan.
B. Cc cht in li c trong dung dch s dn in c.
C. C2H5OH l cht khng in li.
D. CH3COOH l cht in li mnh.
Cu 12: Trong cc cht sau y u l amin bc 2 :
A. H2N-[CH2]6-NH2. B. (CH3)2CH-NH2 .
C. CH3-NH-CH3.
D. C6H5NH2.
Cu 13: Cho t t n d dung dch NaOH vo cc ng phenol c cha vi git phenolphthalein.
Hin tng xy ra l:
A. Cc ng phenol chuyn t hng sang xanh.
B. Cc ng phenol chuyn t xanh sang hng.
C. Cc ng phenol chuyn t khng mu sang hng.
D. Cc ng phenol chuyn t hng sang khng mu.
Cu 14: Polime X c khi lng phn t l 400000 g/mol v h s trng hp l n=4000. X l
A. [-CH2-CH2-]n.
B. [-CF2-CF2-]n.
C. [-CH2-CHCl-]n.
D. [-CH2-CH(CH3)-]n.
Cu 15: Khi i t Li ti Cs trong mt phn nhm bn kn nguyn t s:
A. gim dn.
B. va tang va gim.
C. tng dn.
D. khng i.
Cu 16: phn bit Gly-Ala-Val vi Gly-Ala ch dung ho cht no di y:
A. NaCl.
B. NaOH
C. qu tm.
D. Cu(OH)2.
Cu 17: Cho phng trnh phn ng: Mg + HNO 3 X + N2O + Y. Tng h s (ti gin) ca phn ng
trn khi cn bng l:
A. 20.
B. 32.
C. 24
D. 30.
Trang 1

Cu 18: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dung rc ln

thu ngn ri gom li l:
A. Lu hunh
B. mui n
C. ct
D. vi sng
Cu 19: C 4 l mt nhn ng cc dung dch sau: anhit axetic, glucoz, saccaroz, axit axetic.
Thuc th no c th dung xc nh dung dch c trong mi l:
A. Kim loi Na
B. AgNO3 trong dung dch NH3
C. Cu(OH)2 trong dung dch NaOH
D. CuO, nung nng.
Cu 20: Cho cc cht c cha vng benzene v c phn t l C 7H9N. Hy cho bit c bao nhiu cht
tc dng vi dung dch Br2 cho kt ta trng?
A. 3
B. 5
C. 4
D. 2
Cu 21: Cho cc phn ng sau: (1) Cu(NO3)2 t cao
; (2) NH4NO2 t ; (3) NH3 + O2 850 C , Pt
; (4) NH3 + Cl2 ; (5) NH4Cl t ; (6) NH3 + CuO t .
Cc phn ng u to kh N2 l:
A. (1), (2), (5)
B. (3), (5), (6)
C. (2), (4), (6)
D. (1), (3), (4)
Cu 22: Thu phn pentapeptit X thu c cc ipeptit l Ala-Gly; Glu-Gly v tripeptit l Gly-Ala-Glu.
Vy cu trc ca peptit X l:
A. Glu-Ala-Gly-Ala-Gly
B. Ala-Gly-Ala-Glu-Gly
C. Ala-Gly-Gly-Ala-Glu
D. Gly-Gly-Ala-Glu-Ala
Cu 23: Nguyn t H c cc ng v 1H; 2H; 3H. Nguyn t Cl c cc ng v 35Cl v 37Cl. S loi phn
t HCl c th l:
A. 3
B. 4
C. 5
D. 6
Cu 24: Thnh phn chnh ca qng photphorit l:
A. Ca(H2PO4)2
B. CaHPO4
C. Ca3(PO4)2
D. NH4H2PO4
Cu 25: Cht X c cng thc CH3-CH(CH3)-CH = CH2. Tn thay th ca X l:
A. 2-metylbut-3-in
B. 2-metylbut-3-en
C. 3-metylbut-1-in
D. 3-metylbut-1-en
Cu 26: Pht biu no sau y khng ng khi so snh tnh cht ho hc ca Al v Cr:
A. Nhm c tnh kh mnh hn crom
B. Nhm v crom u bn trong khng kh v nc
C. Nhm v crom u b th ng ho trong dung dch H2SO4 c ngui
D. Nhm v crom u phn ng vi dd HCl theo cng t l mol
Cu 27: Cho cc cht: axit propionic (X), axit axetic (Y), ancol etylic (Z) v imetyl ete (T). Dy cc
cht c sp xp theo chiu tng dn nhit si l:
A. T, Z, Y, X
B. Z, T, Y, X
C. T, X, Y, Z
D. Y, T, X, Z
Cu 28: Dy gm cc ion u oxi ho c kim loi Fe l:
A. Fe3+ , Cu2+ , Ag+
B. Zn2+ , Cu2+ , Ag+
C. Cr2+ , Au3+ , Fe3+ D. Cr2+ , Cu2+ , Ag+
Cu 29: Cho t t 300ml dung dch HCl 1M vo 100ml dung dch hn hp Na 2CO3 1M v NaHCO3
1M c V lt kh (ktc). Gi tr ca V l:
A. 2,24 lt
B. 4,48 lt
C. 3,36 lt
D. 5,6 lt
Cu 30: Ho tan hon ton 2,85g hn hp Al v Al2O3 vo dung dch NaOH ly d. Sauk hi phn ng
xy ra hon ton thy gii phng ra 1,008 lt kh (ktc). Phn trm lng cu Al 2O3 trong hn ban u
l:
A. 28,42%
B. 36,57%
C. 71,58%
D. 75,09%
Cu 31: Ho tan hon ton 10g hn hp gm FeSO 4 v Fe2(SO4)3 vo nc thu c dung dch X. X
phn ng va vi 100ml dung dch KMnO 4 0,1M trong mi trng axit. Thnh phn phn tram v
khi lng ca Fe2(SO4)3 trong hn hp ban u l :
A. 15,2%
B. 76,0%
C. 24,0%
D. 84,8%
Cu 32. Trn 200 ml dung dch trong c cha a gam BaCl 2 vo 300 ml dung dch Na2SO4 sau khi
phn ng xy ra hon ton thu c 6.99 gam kt ta v thu c dung dch Y. Nng mol/lt ca ion
Ba2+ trong dung dch Y l 0.02 mol/lt. Gi tr ca a l:
A. 8.32 gam
B. 7.26 gam
C. 12.1 gam
D. 8.47 gam
Cu 33: Cho 4,48 lt kh CO2 (ktc) vo 100ml dung dch hn hp gm NaOH 1M v Ca(OH)2 1M.
Sau hi phn ng hon ton th khi lng kt ta thu c:
A. 10g.
B. 20g.
C. 15g.
D. 30g.
Cu 34: Nung nng hon ton 28,9g hn hp KNO 3 v Cu(NO3)2. Hn hp kh thot ra c dn vo
nc d th thy c 1,12 lit kh thot ra (ktc) (lng oxi b ho tan khng ng k). Thnh phn phn
tram khi lng Cu(NO3)2 trong hn hp ban u l:
A. 65,05%
B. 34,95%
C. 27,38%
D. 68,34%
Trang 2

Cu 35: Cho cc mnh sau:

(1) Nc cng c cha nhiu ion Ca2+, Mg2+.
(2) C th lm mm nc cng ton phn bng dung dch K2CO3.
(3) Phn bit nc cng tm thi v nc cng vnh cu bng cch un nng.
(4) Lm mm nc cng tm thi bng dung dch HC1.
(5) Dng NaOH va lm mm nc cng tm thi.
S mnh ng l:
A. 3.
B. 2.
C.4.
D.1.
Cu 36: Hn hp X gm cc cht Y (C3H10N2O4) v cht z (C4H8N2O3); trong Y l mui ca axit a
chc, z l ipeptit mch h. Cho 28,08 gam X tc dng vi dung dch NaOH d, un nng, thu c
0,12mol hn hp kh u lm xanh qu tm m. Mt khc 28,08 gam X tc dng vi dung dch HC1 d
thu uc m gam cht hu c. Gi tr ca m l:
A. 37,65
B. 39,15
C. 38,85
D.42,9
Cu 37: Thy phn hon ton 0,1 mol este X bng NaOH, thu c mui ca axit cacboxylic v 6,2
gam ancol z. Mui thu c c phn ng trng bc, z ha tan Cu(OH) 2 cho dung dch mu xanh lam.
Cng thc cu to ca X l:
A.HCOOCH2CH2CH2OOCH
B. HCOOCH2CH(CH3)OOCH
C.HCOOCH2CH2OOCCH3
D. CH3COOCH2CH2OOCCH3
Cu 38: Cho phng trnh ha hc:
CH3CH2OH + K2Cr2O7 + H2SO4 CH3CHO + Cr2(SO4)3+ K2SO4 + H2O
Sau khi cn bng vi h s nguyn n gin nht th tng h s cc cht trc phn ng l
A .7
B. 8.
C. 6.
D.11
Cu 39: Hai este X v Y (phn t u cha vng benzen) c cng thc phn t l C9H8O2. X v Y u
tc dng c vi Br2 theo t l mol 1:1. X tc dng vi dung dch NaOH d cho mt mui v mt
anehit. Y tc dng vi dung dch NaOH d cho hai mui v nc. Cng thc cu to ca X v Y c
th l:
A.HOOC-C6H4-CH=CH2 v CH2=CH-COOC6H5.
B.C6H5-COO -CH=CH2 v C6H5-CHCH-COOH.
C. HCOO-C6H4-CH=CH2 v HCOO-CH=CH-C6H5.
D.C6H5COO-CH=CH2 v CH2=CH-COOC6H5.
Cu 40: Ho tan hon ton m gam hn hp gm Mg, Fe, Cu trong dung dch HNO 3 thu c V lt hn
hp kh D (ktc) gm NO2 v NO ( ktc, khng cn sn phm kh no khc).t khi hi ca D vi
hiro bng 18,2. Tng s gam mui khan to thnh theo m v V l :
V
V
V
314V
A.m+
B.m C. m +
D. m 22, 4
22, 4
7, 75
56
Cu 41: Trong t nhin, c nhiu ngun cht hu c sau khi b thi ra to ra kh H 2S. Tuy nhin, trong
khng kh hm lng H2S rt t v
A.H2S tan c trong nc.
B.H2S b CO2 trong khng kh oxi ho thnh cht khc
C. H2S b oxi trong khng kh oxi ho chm thnh cht khc.
D.H2S b phn hy nhit thng to ra lu hunh v hiro.
Cu 42: Thy phn 0,01 mol este ca mt ancol a chc vi mt axit n chc cn 1,2 gam NaOH.
Mt khc khi thy phn 4,36 gam este th cn 2,4 gam NaOH v thu c 4,92 gam mui. Cng
thc ca este l
A. (CH3COO)3C3H5 B. (C2H3COO)3C3H5
C. C3H5(COOCH3)3
D. C3H5(COOC2H3)3
Cu 43: Cho 9,86 gam hn hp gm Mg v Zn vo mt cc cha 430 ml dung dch H 2SO4 1M. Sau khi
phn ng hon ton, thm tip vo cc 1,2 lit dung dch hn hp gm Ba(OH)2 0,05M v NaOH 0.7M,
khuy u cho phn ng hon ton, ri lc ly kt ta v nung nng n khi lng khng i th thu
c 26,08 gam cht rn. Khi lng magie trong hn hp ban u l:
A. 7,26 gam.
B. 2,6 gam.
C. 4,8 gam.
D. 1,24 gam.
Cu 44: Cho kh CO i qua ng s cha 16 gam Fe 2O3 un nng, sau phn ng thu c hn hp rn X
gm Fe, FeO, Fe3O4 v Fe2O3. Ho tan hon ton X bng HNO3 c, nng, d thu c dung dch Y. C
cn dung dch Y th khi lng mui khan thu c l
A. 24,2 g.
B. 36g.
C.40g.
D. 48,4 g.
Trang 3

Cu 45: Oxi ho hon ton a gam hn hp Mg, Zn v AI thu c b gam hn hp oxit. Cho hn hp
kim loi trn tc dng vi lng d dung dch H2SO4 long thu c V lt kh (ktc). V c gi tr theo a,
b l
22, 4 b a
22, 4 b a
11, 2 b a
22, 4 a b
A.
B.
C.
D.
16
32
16
32
Cu 46: Thc hin cc th nghim vi hn hp gm Ag v Cu (hn hp X): a. Cho X vo bnh cha
mt lng d kh O2 iu kin thng; b. Cho X vo mt lng d dung dch HNO 3 c; c. Cho X vo
dung dch HCl d (khng c mt oxi); d. Cho X vo lng d dung dch FeCl 3. TH nghim m Cu b oxi
ho cn Ag khng b oxi ho l:
A. d
B. a
C. b
D. c
Cu 47: Nung nng hn hp bt X gm a Fe v b mol S trong kh nit, hiu sut phn ng bng 50%
thu c hn hp rn Y. Cho Y vo dung dch HCl d, sau khi cc phn ng xy ra hon ton thu c
hn hp kh Z c t khi so vi H2 bng 4,2. T l a:b bng:
A. 5:1
B. 1:5
C. 2:5
D. 5:2
Cu 48: Cho 150ml dung dch Ba(OH)2 1M vo 250 ml dung dch Al2(SO4)3 x M c 42,75 gam kt
ta. Thm tip 200 ml dung dch Ba(OH) 2 1M vo hn hp phn ng th lng kt ta thu c l
94,2375 gam. Gi tr ca x l:
A. 0,25M
B. 0,45M
C. 0,3M
D. 3,5M
Cu 49: Thu phn hon ton 1 mol oligopeptit X mch h thu c 2 mol Gly, 1 mol Ala, 1 mol Val,
1 mol Tyr. Mc khc, nu thu phn khng hon ton th thu c sn phm c cha Gly-Val v
Val-Gly. S cng thc cu to ph hp ca X l:
A. 4
B. 5
C. 2
D. 6
Cu 50: Cho cc cp cht ( trng thi rn hoc dung dch) phn ng vi nhau:
(1) Pb(NO3)2 + H2S.
(2) Pb(NO3)2 + CuCl2
(3) H2S + SO2
(4) FeCl3 + H2S
(5) AlCl3 + NH3
(6) NaAlO2 + AlCl3
(7) FeS + HCl
(8) Na2SiO3 + HCl
(9) NaHCO3 + Ba(OH)2 d.
S lng cc phn ng to kt ta l:
A. 6
B. 9
C. 8
D. 7

Trang 4

 S 3
Cho bit nguyn t khi (theo vC) ca cc nguyn t:
H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40;
Fe = 56; Cu = 64; Zn = 65; Rb = 85,5; Ag = 108; .
Cu 1: Cho X, Y, G c cu hnh electron lp ngoi cng l: ns 2np1; ns2np3 v ns2np5. Hy cho bit kt lun no
sau y l ng:
A. Tnh phi kim: X<Y<G
B. Bn knh nguyn t: X<Y<G
C. m in: X>Y>G
D. Tnh kim loi: X < Y < G
Cu 2: Phn ng ca oxit no vi HI khng phi l phn ng oxi ho-kh:
A.Fe2O3
B.FeO
C.Fe3O4
D.Fe2O3 v FeO
Cu 3: Cho 13,5g Al tan hon ton trong dung dch HNO 3 long nng d thy thot ra hn hp kh gm 0,1 mol
NO v 0,1 mol N2O. Vy s mol HNO3 b kh v phn ng l:
A.0,4 va 1,85
B.0,35 v 1,85
C.0,3 v 1,4
D.0,35 v 1,9
Cu 4: Cho cc cht: Ca(HCO 3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2, NaHSO4. S cht trong dy c
tnh lng tnh l:
A.2
B.3
C.4
D.5
Cu 5: Vi cng 1 lng HCl th khi tc dng vi lng d cht no di y s thu c nhiu kh Clo nht:
A.KMnO4
B.PbO2
C.CaOCl2
D.K2Cr2O7
Cu 6: un nng hn hp 3 ancol: ancol metylic; propan-1-ol; ancol isopropylic vi H 2SO4 c trong k thch
hp th s anken v s ete c th thu c l:
A.2,6
B.1,6
C.3,4
D.3,3
Cu 7: Cho Fe tc dng ln lt vi O 2;Cl2;S;HCl;HNO3;H2SO4 c nng v dung dch AgNO 3. C bao nhiu
trng hp to c st(II) v st(III):
A.6
B.3
C.4
D.5
Cu 8: T cc cht HNO 3 c, Cu, Fe(NO3)3, HCl c v NaNO 3. Bng phn ng trc tip c my phn ng to
kh:
A.7
B.4
C.5
D.6
Cu 9: Cho hn hp kim loai Mg,Zn,Fe vo dung dch cha AgNO 3 v Cu(NO3)2. Sau phn ng xy ra hon
ton thu c dung dch X gm 3 mui v cht rn Y gm 3 kim loi. Ba mui trong X l:
A.Mg(NO3)2, Fe(NO3)3, AgNO3
B.Mg(NO3)2, Zn(NO3)2, Cu(NO3)2
C.Mg(NO3)2, Zn(NO3)2, Fe(NO3)3
D.Mg(NO3)2, Zn(NO3)2, Fe(NO3)2
Cu 10: Dy gm cc cht u lm kh bng dung dich H2SO4 c l:
A.CO2,N2,O2,HBr,HI,NH3,CH4
B.CO2,O2,N2,Cl2,O3,HF
C.HCl,HBr,HI,H2S,CH4,C2H6,H2
D.SO3,N2,O3,O2,Cl2,CO2,H2
Cu 11: Cho etilenglycol tc dng vi hn hp 2 axit bo RCOOH v RCOOH. S cht c chc este ti a thu
c l:
A.5
B.3
C.6
D.4
Cu 12: Cht hu c X c CTCT: CH3CHBrCH2C(CH3)2CHClCH3. Hy cho bit tn no sau y ng:
A.2-clo-3,3-imetyl-5-brom hexan
B.2-brom-5-clo-4,4-imetyl hexan
C.5-brom-2-clo-3,3-imetyl hexan
D.5-brom-3,3-imeyl-2-clo hexan
Cu 13: Trng hp no sau y khng xy ra s n mn in ho:
A.Hai thanh Zn,Cu c ni vi nhau bi dy dn v cng nhng vo dung dch HCl
B. tm st c m kn thic ngoi khng kh m
C.Hai dy Cu,Al c ni trc tip vi nhau v ngoi khng kh m
D. thanh thp ngoi khng kh m
Cu 14. Cho cc phn ng sau y:
(1) Rt rt t t dung dch HCl cho n d vo dung dch Na2CO3.
(2). Rt rt t t dung dch NaOH cho n d vo dung dch ZnCl 2.
(3). Dn kh CO2 t t cho n d vo dung dch Ca(OH)2.
(4). Rt rt t t dung dch NaOH n d vo dung dch FeCl 3.
C bao nhiu phn ng ha hc xy ra theo hai giai on.
A. 1
B. 2
C. 3
D. 4
Cu 15: Peptit X c cng thc cu to Ala - gly lys.Tnh khi lng mui thu c khi thy phn hon ton
0,1 mol X trong H2SO4 d un nng:
A.70,2
B.45,7
C.60,4
D.50,6
Cu 16: Hn hp ClCH = CH CH = CHBr c bao nhiu ng phn hnh hc:
A.3
B.5
C.2
D.4
Cu 17: Mt mc xch polyme X c dng (- CH 2 C(CH3) = CH CH2 -). Vy tn thng ca monome to ra X
l:
A.isopren
B.2 metylbuta 1,3 ien

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C.3 metylbuta 1,3 ien

D.Poliisopren
Cu 18: Cho cc hp cht hu c n chc (cha C,H,O), mch h v c M= 46 ln lt tc dng vi Na,
NaOH, NaHCO3 v AgNO3 trong NH3. S phn ng xy ra l:
A.5
B.4
C.3
D.6
Cu 19: C hn hp gm: Fe(OH) 3, Zn(OH)2, Cu(OH)2, Ag2O. Ch dng 1 ha cht no sau y c th tch c
Fe(OH)3 ra khi hn hp:
A.dung dch NaOH
B.dung dch HCl
C.kh NH3
D.dung dich NH3
Cu 20: Tng s lin kt trong phn t ankan X l 16. Khi X tc dng vi Cl/nh sng thu c 4 loai dn xut monoclo.
Trong cu to ca X c s nguyn t C bc 1 l:
A.2
B.3
C.4
D.5
Cu 21: Cho benzen, toluen, nitrobenzen tc dng vi Br2/Fe, to th kh nng phn ng th tng dn theo th t sau:
A.Benzen,toluen,nitobenzen
B.Toluen, benzen, nitrobenzen
C.Nitrobenzen, benzen, toluen
D.Nitrobenzen, toluen, benzen
Cu 22: Cho buta 1,3 dien tc dng vi HBr th s sn phm cng theo t l 1:1 thu c l:
A. 1
B. 2
C. 3
D. 4
Cu 23: Cho cc dung dch Na2CO3, NaOH v CH3COONa c cng nng mol/l v c cc gi tr pH tng ng l pH 1,
pH2, pH3. S sp xp no ng vi trnh t tng dn pH:
A.pH3<pH1<pH2
B.pH3<pH2<pH1
C.pH1<pH3<pH2
D.pH1<pH2<pH3
Cu 24: Loi nc no di y khi un nng n phn ng hon ton tnh cng gim:
A.Nc cng tm thi
B.Nc mm
C.Nc cng vnh vin
D.Nc cng ton phn
Cu 25: Cho cc axit hu c axit benzoic, axit o metylbenzoic, axit m metylbenzoic, axit p metylbenzoic.
Cht c tnh axit cao nht l:
A.axit benzoic
B. axit o metylbenzoic
C. axit m nitro benzoic
D. axit p metylbenzoic
Cu 26: Cho s phn ng sau :
(1) MnO2 + HCl => kh X;
(2) FeS + HCl => kh Y;
(3) Na2SO3 + HCl => kh Z;
(4) NH4HCO3 + NaOH(d) => kh G.
Hy cho bit kh no tc dng c vi NaOH:
A.Y,Z,G
B.X,Y,G
C.X,Z,G
D.X,Y,Z
Cu 27: iu ch etyl axetat t tinh bt theo s : tinh bt => glucoz => ancol etylic => axit axetic => etyl
axetat. Bit hiu sut ca mi giai on iu ch u t 50%. Khi lng tinh bt cn dng iu ch 1 mol
etyl axetat l:
A.1012
B.1296
C.405
D.324
Cu 28. R c tng s ht l 40. S ht mang in nhiu hn s ht khng mang in l 12. Chn cu cha ng.
A. R l nguyn t thuc nguyn t Nhm.
B. S khi A ca R bng 27
C. S ht khng mang in ca R bng 14.
D. Trong ht nhn ca R s ht mang in l 26.
Cu 29. Hn hp A gm 3 kim loi Al, Cu, Fe tc dng va vi 0.3 mol O 2 thu c hn hp X gm cc oxit
kim loi . ha tan ht hn hp X th ngi ta dng va dung dch cha x mol HCl. Gi tr ca x l:
A. 1,2 mol
B. 0.6 mol
C. 0.9 mol
D. 1.5 mol
Cu 30. Trng hp no sau y , sau khi phn ng xy ra hon ton th khng thu c cht rn.
A. 1 mol Cu v 1 mol AgNO3 vo nc d
B. 1 mol Cu v 1 mol Fe2O3 cho vo dd HCl d
C. 1 mol NaOH v 1 mol Al2O3 cho vo nc d D. 1 mol Na2CO3 v 1 mol BaCl2 cho vo nc d.
Cu 31: Thu phn hon ton 0,1 mol este X cn 200ml dung dch NaOH 1,5M. C cn dung dch sau phn ng
thu c glixerol v 24,6g cht rn khan. Hy cho bit X c bao nhiu CTCT:
A.7
B.5
C.8
D.6

Cu 32: Cho kh CO i qua ng nghim ng 37,12g Fe 3O4 nung nng thu c hn hp rn X. Kh i

ra khi ng s c hp th ht vo dung dch Ba(OH) 2 d thu dc 43,34g kt ta. Ho tan ht lng
hn hp X trong dung dch H2SO4 c nng, d thy bay ra V lt kh SO2 (ktc). Gi tr ca V l:
A.4,48
B.3,584
C.3,36
D.6,72
Cu 33: t chy hon ton 18,8g hn hp gm ancol anlylic; anhit propionic; axit acrylic; vinyl
fomiat ri cho ton b sn phm chy qua dung dch nc vi trong d. Sau phn ng thu c 90g kt
ta v dung dch A. Khi lng A so vi khi lng nc vi trong ban u thay i nh th no:
A.tng 54g
B.gim 36g
C.gim 50,4g
D.tng 39,6g
Cu 34: Cho 5.6 lt CO2 hp th trong 200 ml dung dch X cha BaCl 2 0,5M v NaOH xM. Tm gi tr
nh nht ca x kt ta thu c l ln nht:
A.1,5
B.1,0
C.1,75
D.2,0
Cu 35: Cho 11,2g bt Fe vo 100 ml dung dch cha HNO 3 2M v H2SO4 2M thu c 3,36 lt kh
NO (sn phm kh duy nht ca HNO3, ktc). Tnh khi lng mui thu c:
A.33,5
B.27,4
C.30,8
D.31,5
Trang 6

Cu 36: Cho hn hp cha x mol Mg, y mol Fe vo dung dch cha z mol CuSO 4.Sau khi kt thc cc phn
ng th thu c hn hp gm 2 kim loi. Mun tho mn k th:
A.z= x+y
B.x<z<y
C.x =< z < x+y
D.z >= x
Cu 37: Cho cc hn hp c cng s mol di y vo nc d: Hn hp A (Na v Al), hn hp B (K
v Zn), hn hp C (Fe2(SO4)3 v Cu), hn hp D (CuS v H2SO4), hn hp E (Cu,H2SO4 v Fe(NO3)3),
hn hp F (CaCO3 v HCl). S hn hp tan ht l:
A.2
B.3
C.4
D.5
Cu 38: Cho 3,36g bt st vo dung dch cha 0,15 mol H 2SO4 c, nng ( gi thit SO2 l sn phm
kh duy nht). Sau khi phn ng xy ra hon ton th thu c:
A.0,025 mol Fe2(SO4)3 v 0,01 mol Fe d
B.0,015 mol Fe2(SO4)3 v 0,03 mol FeSO4
C.0,06 mol FeSO4
D.0,01 mol Fe2(SO4)3 v 0,04 mol FeSO4
Cu 39: in phn dung dch cha m g hn hp CuSO 4 v NaCl vi 2 in cc tr, c mng ngn xp,
khi thy c 2 in cc u xut hin bt kh th ngng in phn. Kt qu anot c 0,02 mol kh
thot ra, cn dung dch sau in phn c th ho tan ti a 0,005 mol Fe3O4. Gi tr ca m l:
A.5,64
B.7,98
C.5,97
D.6,81
Cu 40: Cho hnh v m t th nghim iu ch kh Cl2 t MnO2 v dung dch HCl :

Kh Cl2 sinh ra thng ln hi nc v hidro clorua. thu c kh Cl 2 kh th bnh (1) v bnh (2) ln lt
ng
A. Dung dch NaOH v dung dch H2SO4 c.
B. Dung dch H2SO4 c v dung dch AgNO3.
C. Dung dch H2SO4 c v dung dch NaCl
D. Dung dch NaCl v dung dch H2SO4 c.

Cu 41: Ho tan m gam Al, Mg vo HCl d cho 6,72 lt kh (ktc). Cho m gam hn hp Al, Mg trn
vo 400 ml dung dch gm AgNO3 1M v Cu(NO3)2 0,8M, phn ng xong c bao nhiu gam kt ta:
A.43,2
B.49,6
C.54,8
D.63,68
Cu 42: Hn hp X gm 1 ancol no n chc mch h v 1 axit cacboxylic n chc (c cng s nguyn t
cacbon v c t l mol tng ng l 1:2). t chy hon ton 5,1g X thu c 5,04 lt CO 2 ktc v 3,6g nc.
Thc hin phn ng este ho 5,1g X trn vi hiu sut 80% th thu c m gam este. Gi tr ca m l:
A.2,85
B.4,56
C.2,28
D.5,7
Cu 43: khi trung ha 0,59g hn hp 2 amin n chc,bc 1 (c s nguyn t C trong phn t khng qu 4)
cn ht 1 lt dung dch Y cha hn hp H2SO4 v HCl c pH = 2. Cng thc ca 2 amin l:
A.C4H9NH2 v C2H5NH2
B.CH3NH2 v C3H7NH2
C.C3H7NH2 v C4H9NH2
D.C3H7NH2 v C2H5NH2
Cu 44: Thy phn hn hp gm 136,8g mantoz v 34,2g saccaroz trong mi trng axit vi hiu sut phn
ng thy phn mi cht t 60% thu c hn hp X. Trung ha hn hp X thu c hn hp Y. Cho Y tc
dng vi dung dch AgNO3 d, un nng thu c m gam Ag kt ta. Gi tr ca m l:
A.164,16
B.129,6
C.172,8
D.146,88
Cu 45. Cho 2,7g CHC CHO tc dng vi dung dch AgNO3 trong NH3 d. S mol AgNO3 b kh l:
A.0,05
B.0,1
C.0,15
D.0,2
2+
Cu 46: Hirat ha 8g propin c mt mui Hg trong mi trng axit,un nng thu c hn hp cht sn
phm cht hu c X. Cho X tc dng vi dung dch AgNO 3/NH3 d thu c 20,4g kt ta. Mt khc, hidro
ha hon ton X cn 6,272 lit H2 (ktc). Hiu sut ca phn ng chuyn ha propin thnh andehit l:
Trang 7

A.20%

B.30%

C.40%

D.50%

Cu 47: Rt t t dung dch Ba(OH)2 0,2M vo 150 ml dung dch AlCl3 0,04M thy lng kt ta ph thuc
vo s ml dung dch Ba(OH)2 theo th di y. Gi tr ca a v b tng ng l:
a Al(OH)3
0.006
0

V ml Ba(OH)2

A.45ml v 60ml
B.45ml v 90ml
C.90ml v 120ml
D.60ml v 90ml
Cu 48: Nh t t tng git cho n ht 300 ml dung dch NaHCO 3 0,1M; K2CO3 0,2M vo 100 ml
dung dch HCl 0,2M; NaHSO4 0,6M v khuy u thu c V lt CO2 thot ra (ktc) v dung dch X.
Thm vo dung dch X 100 ml dung dch KOH 0,6M; BaCl 2 1,5M thu c m gam kt ta. Bit cc
phn ng u xy ra hon ton. Gi tr ca V v m l
A. 1,0752 v 22,254.
B. 0,448 v 25,8.
C. 0,448 v 11,82.
D. 1,0752 v 20,678.
Cu 49: Trong cc th nghim sau:
(1) Sc etilen vo dung dch brom trong CCl4.
(2) Cho phenol vo dung dch un nng cha ng thi HNO3 c v H2SO4 c.
(3) Cho axit stearic vo dung dch Ca(OH)2.
(4) Cho phenol vo nc brom.
(5) Cho anilin vo nc brom.
(6) Cho gly-ala vo dung dch NaOH long, d.
Nhng th nghim c kt ta xut hin l
A. (1), (2), (3), (4), (5).
B. (2), (3), (4), (5).
C. (2), (4), (5).
D. (1), (2), (3), (4), (5), (6).
Cu 50. Cho hnh v m t th nghim iu ch kh Y t cht rn X:

Hnh v trn minh ha iu ch kh Y no sau y:

A. HCl
B. Cl2

C. O2

D. NH3

Trang 8

 S 4
Cho bit nguyn t khi (theo vC) ca cc nguyn t:
H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40;
Fe = 56; Cu = 64; Zn = 65; Rb = 85,5; Ag = 108; .
Cu 1: Cho m gam bt Cu vo 400 ml dung dch AgNO 3 1M sau mt thi gian phn ng thu c 42g hn hp
rn X v dung dch Y gm hai mui. Lc tch X ri them 16,25g bt Zn vo Y, sau khi phn ng xy ra hon
ton thu c 23,65g cht rn Z gm 3 kim loi. Gi tr ca m l:
A.19,2
B. 12,8
C.16,0
D.9,6
Cu 2: khi cho 0,1 mol este n chc, mch h X tc dng vi dung dch NaOH d sau khi phn ng kt thc th
lng NaOH phn ng l 8g v tng khi lng sn phm hu c thu c l 21,0g. S ng phn cu to
ca X tha mn cc tnh cht trn l:
A.5
B.3
C.4
D.2
Cu 3: cho dy cc cht: N2, H2, NH3, NaCl, HCl, H2O. S cht trong dy m phn t ch cha lin kt cng ha
tr khng cc l:
A.2
B.4
C.3
D.5
Cu 4: Hn hp X gm etilen, metan, propin, vinyl axetilen c t khi so vi H 2 l 17. t chy hon ton 5,1
gam hn hp X ri hp th sn phm chy vo dung dch Ca(OH) 2 d th khi lng bnh tng thm m gam. Gi
tr ca m l:
A. 25,5
B.20,1
C.18,3
D.21,9
Cu 5: Cho tng cht : Fe, FeO, Fe(OH) 2 , Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3,FeCO3,
NaBr, KCl, NaI ln lt phn ng vi H2SO4 c, nng. S phn ng thuc loi phn ng oxi ha kh l:
A.7
B.6
C.9
D.8
Cu 6. Cho phn ng C6H5CH3 + KMnO4 C6H5COOK+ MnO2+KOH + H2O. Tng h s (nguyn, ti

gin)ca tt c cc cht trong phn ng trn:

A.8
B.10
C.12

D.11

Cu 7: Pht biu no sau y l sai:

A. m in ca brom ln hn m in ca iot
B. Tnh axit ca HF mnh hn tnh axit ca HCl
C. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo
D. Tnh kh ca ion Br ln hn tnh kh ca Cl
Cu 8: ng dng no sau y khng phi ca ozon:
A. Ty trng tinh bt du n
B. Cha su rng
C. iu ch oxi trong phng th nghim
D. St trng nc sinh hot
Cu 9. Cho cc phn ng ha hc sau:(a) S + O 2SO2; (b)S+3F2SF6; (c) S + HgHgS; (d) S+ 6HNO3 c H2SO4
+ 6SO2 + 2H2O. S phn ng trong S th hin tnh kh l:
A.1
B.2
C.3
D.4
Cu 10: Hn hp X gm Fe(NO 3)2, Cu(NO3)2, v AgNO3. Thnh phn phn trm khi lng ca N trong X l
11,864%. C th iu ch c ti a bao nhiu gam hn hp 3 kim loi t 70,8g X:
A. 39,6g
B.36,8g
C.30,4g
D.33,6g
Cu 11: Cho m gam bt km vo 500ml dung dch Fe 2(SO4)3 0,2M. Sau khi cc phn ng xy ra hon ton, khi
lng dung dch tng thm 7,85g so vi dung dch ban u. Gi tr ca m l :
A.16,25
B.15,60
C.11,05
D.11,70
Cu 12: Cho phng trnh ha hc: N2 (k) + O2(k) 2NO (k); H>0. Hy cho bit nhng yu t no sau y
nh hng n s chuyn dch cn bng ha hc trn:
A. Nhit v nng
B. p sut v nng
C.Nng v cht xc tc
D. Cht xc tc v nhit
Cu 13:Cc hp cht sau, hp cht no thuc loi lng tnh:
A. Cr(OH)3, Fe(OH)2, Mg(OH)2
B. Cr(OH)3, Zn(OH)2, Pb(OH)2
C. Cr(OH)3, Zn(OH)2 , Mg(OH)2
D, Mg(OH)2. Cr(OH)3, Pb(OH)2
Cu 14: Pht biu no sau y ng:
A. Phn hn hp cha nito, photpho, kali c gi chung l NPK
B. Phn ure c cng thc (NH4)2CO3
C. Phn ln cung cp nito cho cy di dng ion NO3 - v NH4 +
D. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3
Cu 15: iu kin thch hp xy ra cc phn ng sau:
(a) 2C +CaCaC2;
(b)C + 2H2CH4;
(c) C + CO2 2CO;
(d) 3C +4AlAl4C3.
Trong cc phn ng trn tnh kh ca cacbon th hin phn ng :
A.(a)
B.(c)
C.(d)
D.(b)

Trang 9

Cu 16:Hp th ht 3,36 l CO2 (ktc) vo 100ml dung dch gm K2CO3 0,2M v KOH x mol/lit, sau khi cc
phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi BaCl 2 d thu c 13,79g kt ta.
Gi tr x l :
A.1,6
B.2,2
C.2,0
D.1,8
Cu 17: Tn thay th (theo IUPAC) ca (CH3)3C-CH2-CH(CH3)2 l:
A. 2,2,4,4- tetrametylbutan
B.2,4,4- trimetylpentan
C.2,2,4-trimetylpentan
D.2,4,4,4-tetrametylbutan
Cu 18: Trong cng nghip, axeton c iu ch t:
A.xiclopropan
B.propan-1-ol
C.propan-2-ol
D.cumen
Cu 19: Phn trm khi lng ca N trong hp cht CxHyN l 23,73%. S ng phn amin tha mn cc d
kin trn l:
A.3
B.4
C.2
D.1
Cu 20: Pht biu khng ng l:
A. Trong dung dch H2NCH2COOH tn ti dng ion lng cc H3N+CH2COOB. Amino axit l hp cht hu c tp chc phn t cha ng thi nhm amino v nhm cacboxyl
C. Hp cht H2NCH2COOH3NCH3 l este ca glyxin
D. Amino axit l nhng cht rn kt tinh, tan tt trong nc v c v ngt
Cu 21: Braikinin c tc dng lm gim huyt p. l mt nonapeptit c cng thc l: Arg-Pro-Pro-Gly-PheSer-Pro-Phe-Arg. Khi thy phn khng hon ton peptit ny c th thu c bao nhiu tripeptit no c cha
phenylalanine (Phe):
A. 5
B.6
C.4
D.3
Cu 22: Miu t khng ng v cu trc mch ca cc polime l :
A. Poli(vinyl axetat) c dng mch khng phn nhnh
B. Amilopectin c dng mch mng li khng gian
C. Cao su lu ha c dng mch mng li khng gian
D. Poli(vinyl clorua) c dng mch khng phn nhnh
Cu 23: Tng s hp cht hu c no, n chc, mch h c cng CTPT C 5H10O2 phn ng c vi dung dch
NaOH cho sn phm l mui v ancol nhng khng c phn ng trng bc l:
A.4
B.5
C.8
D.9
Cu 24: Khi lng nguyn t ca Bo l 10,81. Bo c 2 ng v bn l 10B v 11B. % khi lng ca ng v 11B
trong H3BO3 (bit nguyn t khi ca H v O tng ng l 1 v 16) l:
A. 15,00%
B. 14,42%
C.14,51%
D.14,16%
Cu 25:Cho hn hp Al v Zn vo dung dch AgNO 3. Sauk hi cc phn ng xy ra hon ton, thu c dung
dch X ch cha 1 mui v phn khng tan Y gm 2 kim loi. Hai kim loi trong Y v mui trong X l:
A. Zn, Ag v Zn(NO3)2
B. Al, Ag v Al(NO3)3
C.Al, Ag v Zn(NO3)2
D.Zn, Ag v Al(NO3)3

Cu 26: Dung dch X gm 0,12 mol H+, z mol Al3+, t mol NO3- v 0,02 mol SO42-. Cho 100mldung dch
Y gm KOH 1,9 M v Ba(OH)2 0,15M vo X. Sauk hi cc phn ng kt thc thu c 5,055g kt ta.
Gi tr ca z v t ln lt l:
A. 0,02 v 0,012
B.0,03 v 0,17
C.0,02 v 0,14
D.0,04 v 0,2
Cu 27: Cht X c CTPT l C4H8O3. X tc dng vi NaHCO 3 v mui thu c tc dng vi Na gii phng H 2.
Hi ca X khng tc dng vi CuO nung nng. Vy cng thc cu to ca X l:
A.CH3C(CH3)(OH)COOH
B. HOCH2CH2CH2COOH
C.HOCH2-CO-CH2CH2OH
D.HOCH2CH2COOCH3
Cu 28: luyn 900 tn gang c hm lng st 90% cn dung x tn qung manhetit cha 75% Fe 3O4( cn li l
tp cht khng cha st). Bit hm lng st b hao ht trong qu trnh sn xut l 2%. Gi tr ca X l:
A.1246,63
B.1118,57
C.1521,87
D.1491,43
Cu 29: Thc hin phn ng nhit nhm hn hp gm m gamAl v 30,4g Cr 2O3 trong iu kin khng c khng
kh sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl long
nng, sau khi cc phn ng xy ra hon ton thu c 12,32lit kh (ktc). Cn nu cho ton b X tc dng
vi dung dch NaOH c nng d, sau khi phn ng kt thc th s mol NaOH phn ng l:
A.0,9mol
B.0,5 mol
C. 0,1 mol
D. 0,4 mol

Cu 30. Cho 400 ml dung dch E gm AlCl 3 x mol/lit v Al2(SO4)3 y mol/lit tc dng vi 612ml dung
dch NaOH 1M, sau khi phn ng kt thc thu c 8,424g kt ta. Mt khc, khi cho 400ml E tc
dng vi BaCl2 d thu c 33,552g kt ta. T l x:y l:
A.3:4
B. 3:2
C.4:3
D. 7:4
Cu 31: Nhit phn hon ton mt lng Cu(NO3)2 c cht rn X v hn hp kh Y. Dn ton b Y
vo mt lng d nc thu c dung dch Z. Cho kh CO d qua X nung nng n phn ng hon
ton ri ly cht rn sinh ra cho vo Z, thy cht rn ch tan mt phn v thot ra kh NO l sn phm
kh duy nht. Bit cc phn ng xy ra hon ton.Phn trm khi lng ca X phn ng l:
A.70%
B.25%
C.60%
D.75%
Trang 10

Cu 32. Cho 11,64g hn hp X gm Cu v Ag c t l mol tng ng l 1:3 vo 50 ml dung dch gm

H2SO4 2M v HNO3 1M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (l sn phm
kh duy nht ca N+5). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc
dng vi nc thu c 500ml dung dch c pH=z. Gi tr ca z l :
A.2
B.4
C.3
D.1
Cu 33. Hidro ha hon ton 0,025 mol hn hp X gm 2 andehit c khi lng 1,625g cn 1,12 lit H 2
(ktc).Mt khc khi cho cng lng X trn phn ng vi lng d dung dch AgNO 3 trong NH3 thu
c 10,8g Ag.CTCT ca 2 andehit trong X l:
A.CH2=C(CH3)CHO v OHCCHO
B. OHCCH2CHO, OHCCHO
C.HCHO, OHCCH2CHO
D. CH2=CHCHO, OHCCH2CHO
Cu 34. Cht hu c X mch h c dng H2N-R-COOR (R,R l cc gc hidroacbon), phn trm khi
lng ca O trong X l 35,96%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b ln
ancol sinh ra cho tc dng vi CuO un nng c andhit Y. Cho ton b Y tc dng vi lng d dung
dch AgNO3 trong NH3 thu c 34,56g Ag kt ta. Gi tr ca m l:
A. 8,01
B.10,68
C.7,12
D.14,24
Cu 35: Hn hp kh X gm O2 v O3 c t khi so vi H2 l 22,4. Hn hp kh Y gm propyl amin v
etyl amin c t khi so vi H 2 l 24,6. t chy hon ton V1 lit Y cn v V2 lit X (bit sn phm
chy gm CO2, H2O v N2, cc cht kh c o cng iu kin nhit v p sut). T l V1:V2 l:
A. 5:1
B.1:5
C.3:1
D.1:3
Cu 36: Hn hp M gm anken X v hai amin no, n chc, mch h Y, Z (M Y < MZ). t chy hon ton mt
lng M cn dng 21 lt O2 sinh ra 11,2 lt CO2 ( cc th tch kh u o dktc). Cng thc ca Y l:
A.CH3NH2.
B.CH3CH2CH2NH2.
C.C2H5NH2.
D.CH3CH2NHCH3.

Cu 37: S ng phn este mch h ca C4H6O2 l:

A.3.
B.4.
C.5.
D.6.
Cu 38: Dung dch nc mui c tnh st trng v:
A. Do qu trnh khuch tn v thm thu lm mt nc ca vi khun.
B. Do vi khun khng chu c mn.
C. Do vi khun khng c thc n.
D. Do tnh cht ha hc ca nc mui.
Cu 39: Cho dy cc cht: glucozo, xenlulozo, saccarozo, tinh bt, mantozo. S cht trong dy tham
gia phn ng trng bc l:
A.3
B.4
C.2
D.5
Cu 40: Hiu ng nh knh l h qu ca:
A.s ph hy ozon trn tng kh quyn
B.s lu gi bc x hng ngoi bi lng d kh cacbonnic trn kh quyn
C.s chuyn ng xanh duy tr trong s bo tn rng
D.s hin din ca lu hunh oxit trong kh quyn
Cu 41: t chy hon ton 3,42gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit
oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH) 2 (d). Sau phn ng thu c 18 gam
kt ta v dung dch X. Khi lng X so vi khi lng dung dc Ca(OH) 2 ban u thay i nh th
no?
A.Tng 2,70 gam.
B.Gim 7,74 gam.
C.Tng 7,92 gam.
D.Gim 7,38 gam.
Cu 42. Cho cc cht sau y:
H2NCH2CONHCH2CONHCH2COOH
(X)
H2NCH2CONHCH(CH3) COOH
(Y)
H2NCH2CH2CONHCH2CH2COOH
(Z)
H2NCH2CH2CONHCH2COOH
(T)
H2NCH2CONHCH2CONHCH(CH3) COOH
(U)
C bao nhiu cht thuc loi ipeptit:
A.3
B.2
C.1
D.4
Cu 43: tri peptit M v tetrapeptit Q u c to ra t mt -amino axit X mch h, phn t c mt
nhm NH2. Phn trm khi lng ca N trong X l 18,667%. Thy phn khng hon ton m gam hn
hp M,Q (t l mol 1:1) trong mi trng axit thu c 0,945 gam M ; 4,62 gam ipeptit v 3,75 gam
X. Gi tr ca m l:
A. 8,389
B. 58,725
C. 5,580
D. 9,315
Cu 44: Thy phn triglixerit X trong NaOH ngi ta thu c hn hp hai mui gm natrioleat v
natristearat theo t l mol ln lt l 2:1. Khi t chy a mol X thu c b mol CO2 v c mol H2O.
Trang 11

Lin h gia a,b,c l:

A.b - c = 4a
B. b - c = 2a
C. b - c = 3a
D. b = c - a
Cu 45. un nng hn hp gm : 22,5 gam glyxin ; 17,8 gam alanin ; 11,7 gam valin, vi xc tc thch
hp, sau khi phn ng cy ra hon ton thu c m gam hn hp X hm 6 tripeptit. Gi tr ca m l :
A.44,8 gam.
B.52 gam.
C.43 gam.
D. 41,2 gam.
Cu 46: Cho cc polime sau : (1) PE; (2) poli(vinyl clorua) ; (3) poli(metyl metacrylat) ; (4) PPF ; (5)
polistiren ; (6) poli(vinyl axetat) ; (7) nilon-7 ; (8)poli(etylen-terephtalat) ; (9) t nilon ; (10) t capron ;
(11) caosu buna-S ; (12) cao su clopren ; (13) keo dn ure- fomanehit. S polime l sn phm ca phn
ng trng ngng l :
A.4
B.5
C.6
D.7
Cu 47: Cho phn ng oxi ha- kh: As2S3 + HNO3 + H2O H3AsO4+ H2SO4+ NO. Tng h s cn
bng ca phn ng trn l:
A.105
B.43
C.27
D.78
Cu 48: Oxi ha 4,0 gam ancol n chc Z bng O 2 ( c mt xc tc) thu c 5,6 gam hn hp X
gm anehit, ancol d v nc. Tn ca Z v hiu sut l:
A.metanol; 80%.
B.etanol; 80%.
C.metanol; 75%.
D.etanol;75%.
Cu 49: Cho 0,1 mol cht X (CH 6O3N2) tc dng vi dd cha 0,2 mol NaOH un nng thu c cht
kh lm xanh giy qu tm m v dd Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m
l:
A.8,5
B.12,5
C.15
D.21,8
2+
+
Cu 50: Dung dch X cha cc ion: Ca ,Na , HCO3- v Cl-,trong mol ca ion Cl- l 0,1. Cho dung
dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch
Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m
gam cht rn khan. Gi tr ca m l:
A.9,21.
B.9,26.
C.8,97.
D.7,47.

Trang 12

 S 5.
Cu 1: Cho tt c cc ng phn mch h, c cng cng thc phn t C 2H4O2 ln lt tc dng vi Na, NaOH v
NaHCO3. s phn ng xy ra l
A.5
.B.2.
C.4
D. 3
Cu 2: Cho cc mnh sau:
(1) Nc cng c cha nhiu ion Ca2+, Mg2+.
(2) C th lm mm nc cng ton phn bng dung dch K2CO3.
(3) Phn bit nc cng tm thi v nc cng vnh cu bng cch un nng.
(4) Lm mm nc cng tm thi bng dung dch HC1.
(5) Dng NaOH va lm mm nc cng tm thi.
S mnh ng l:
A. 3.
B. 2.
C.4.
D.1.
Cu 3: Cho glixerol phn ng vi hn hp axit bo gm C 17H35COOH, C17H33COOH v C15H31COOH. S trieste
ti a c to ra l
A.6.
B. 18.
C.9
D.27.
Cu 4: Thy phn hon ton 0,1 mol este X bng NaOH, thu c mui ca axit cacboxylic v 6,2 gam ancol z.
Mui thu c c phn ng trng bc, z ha tan Cu(OH) 2 cho dung dch mu xanh lam. Cng thc cu to ca X
l:
A.HCOOCH2CH2CH2OOCH
B. HCOOCH 2CH(CH3)OOCH
C.HCOOCH2CH2OOCCH3
D. CH3COOCH2CH2OOCCH3
Cu 5: Cho s sau:

Xenluloz H 2O , H ,t
X men ruou
Y men giam Z C2 H 5OH , xt
T
Cht T c tn gi l
A. vinyl acrylat
B.etyl axetat.
C. metyl acrylat.
D. vinyl axetat.
Cu 6: iu no sau y khng ng khi ni v xenluloz:
A Tan trong dung dch nc svayde: [Cu(NH3)4](OH)2 C. Dng sn xut t enang
B. C th dng iu ch ancol etylic
D. Thy phn trong mi trng axit to glucozo.
Cu 7: Thy phn hon ton 68,4 gam saccarozo ri cho ton b sn phm tc dng vi lng dAgNO 3/NH3,
un nng th thu c X gam kt ta, cn nu cho ton b lung sn phm ny tc dng vi nc brom d th c
Y gam brom tham gia phn ng. Gi tr ca X v Y ln lt l
A. 86,4 v 32.
B.86,4 v 64.
C. 28,8 v 32.
D. 43,2 v 32.
Cu 8: ng dng khng ng ca crom l:
A. iu kin thng, crom to lp mng oxit mn, bn chc nn c dng m bo v thp.
B. Crom l kim loi rt cng c th dng ct thy tinh.
C. Crom l kim loi nh, nn uc s dng to cc hp kim dng trong ngnh hng khng.
D. Crom lm hp kim cng v chu nhit, nn dng to thp cng, khng g, chu nhit.
Cu 9. M t no di y v tnh cht vt l ca nhm l cha chnh xc:
A. Mm, d ko si v dt mng
B. Dn nhit v in tt, tt hn Fe, Cu
C. L kim loi nh
D. Mu trng bc
Cu 10: So vi nguyn t phi kim cng chu k, nguyn t kim loi
A. thng c bn knh nguyn t nh hn.
B. thng c s electron cc phn lp ngoi cng nhiu hn.
C. thng c nng lng ion ho nh hn.
D. thng d nhn electron trong cc phn ng ho hc.
Cu 11: T l v s nguyn t ca hai ng v A v B trong t nhin ca nguyn t X l 27:23.ng v A c 35
proton v 44 ntron, ng v B c nhiu hn ng v A 2 ntron. Nguyn t khi trung bnh ca nguyn t X l
A. 79,92.
B. 80,01.
C .81,86.
D.79,35.
Cu 12: Phn ng: Cu + 2FeCl3 2FeCl2 + CuCl2 chng t
A. ion Fe 2+ c tnh oxi ho mnh hn ion Fe3+.
B . ion Fe 3+ c tnh oxi ho mnh hn ion Cu2+.
3+
2+
C. ion Fe c tnh oxi ho yu hn ion Cu .
D. ion Fe 3+ c tnh kh mnh hn ion Fe2+.
Cu 13: Cho kh N2 tc dng vi kh H2 c bt Fe xc tc t v p sut p th tc phn ng l V. Nu gi
nguyn nhit v tng p sut ln 2p th tc ca phn ng
N2 (k) + 3H2 (k) 2NH3 (k) s tng ln

Trang 13

A. 2 ln.
B 4 ln
C. 8 ln.
D. 16 ln.
Cu 14: Trong t nhin, c nhiu ngun cht hu c sau khi b thi ra to ra kh H 2S. Tuy nhin, trong khng
kh hm lng H2S rt t v
A.H2S tan c trong nc.
B.H2S b CO2 trong khng kh oxi ho thnh cht khc
C. H2S b oxi trong khng kh oxi ho chm thnh cht khc.
D.H2S b phn hy nhit thng to ra lu hunh v hiro.
Cu 15: Trong cc polime sau, polime no khng thuc loi tng hp?
A PVC
B. T xenluloz axetat
C.
T
capron
D.Polistiren
Cu 16: t chy hon ton 29.6 gam hn hp X gm CH 3COOH, CxHyCOOH v (COOH)2 thu c 14,4 gam
H2O v m gam CO2. Mt khc 29,6 gam hn hp X phn ng hon ton vi NaHCO3 thu c 11,2 lt (ktc) khi
CO2. Gi tr ca m l
A. 33,0.
B. 48,4
.C. 44,0.
D. 52,8.
Cu 17: Cu hnh electron ng l:
2
2
6
2
6
2
6
A. 26Fe: ls22s22p63s23p63d44s2
B.
26Fe: ls 2s 2p 3s 3p 4s 3d
3+
2
2
6
2
6
5
C. 26Fe2+: ls22s22p63s23p64s23d4
D.
26Fe : ls 2s 2p 3s 3p 3d
Cu 18: Cng thc tng qut ca andehit khng no, mch h, hai chc, c cha mt lin kt ba trong phn t l:
A. CnH2n-2O2
B. CnH2n-4O2.
C. CnH2n-6O2.
D. CnH2n-8O2.
Cu 19: Nit v photpho l hai phi kim thuc nhm VA, nhn xt no sau y ng.
A Hai nguyn t u c mc oxi ha +5, ha tr V trong hp cht.
B. m in ca photpho nh hn ca nit nn iu kin thng, phn t photpho bn hn phn t nit.
C. Phn t NH3 km bn hn phn t PH3.
D. Axit H3PO4 kh b kh, khng c tnh oxi ha.
Cu 20: Cho kh CO i qua ng s cha 16 gam Fe 2O3 un nng, sau phn ng thu c hn hp rn X gm Fe,
FeO, Fe3O4 v Fe2O3. Ho tan hon ton X bng HNO 3 c, nng, d thu c dung dch Y. C cn dung dch Y
th khi lng mui khan thu c l
A. 24,2 g.
B. 36g.
C.40g.
D. 48,4 g.
Cu 21: Cho cc dung dch sau: anilin (1), metylamin (2), glyxin (3), lysin (4), natri phenolat (5); H 2N-CH2COONa (6). s dung dch lm qu tm i thnh mu xanh l
A. 5.
B. 4.
C. 3.
D. 2.
Cu 22: Oxi ho hon ton a gam hn hp Mg, Zn v AI thu c b gam hn hp oxit. Cho hn hp kim loi
trn tc dng vi lng d dung dch H2SO4 long thu c V lt kh (ktc). V c gi tr theo a, b l
A.

22, 4 b a
16

B.

22, 4 b a
32

C.

11, 2 b a
16

D.

22, 4 a b
32

Cu 23: Cho cc cht: CH2=CH-CH=CH2; CH3-CH2 - CH = C(CH3)2;

CH3 - CH = CH - CH=CH2; CH3 CH = CH2; CH3 CH= CH -COOH. s cht c ng phn hnh hc l:
A. 3
B. 2
C. 4
D. 1
Cu 24 : Cho cc cht l O2, SO2, H2O2, CO2, S, H2SO4, FeCl2 Cc cht va c tnh kh, va c tnh oxi ha l
A. SO2, ZnS, FeCl2
B. H2O2, S, SO2, CO2
C. CO2, O2, H2SO4
D. FeCl2, S, SO2, H2O2
Cu 25: Dy gm cc kim loi c iu ch theo phng php in phn nng chy cc hp cht ca chng l:
A. Na, Ca, Zn
B. Na, Ca, Al
C. Fe, Cu, Al
D. Na, Cu, Al
Cu 26: Dy gm cc cht u tc dng vi ancol etylic l
A. HBr (t), Na, CuO (t), CH3COOH (xc tc).
B. NaOH, K, MgO, HCOOH (xc tc).
C. Ca, CuO (t), C6H5OH (phenol), HOCH2CH2OH
D. Na2CO3 , CuO (t), CH3COOH (xc tc), (CH3CO)2O
Cu 27: Nhit phn hon ton hn hp hai mui nitrat, thu c cht rn X. Nu cho X tc dng vi lng d
dung dch HCl long th thy X tan mt phn .Hai mui nitrat l
A. Fe(NO3)2 , Al(NO3)3
B. AgNO3, Au(NO3)3.
C. KNO3 , Cu(NO3)2
D. Cu(NO3)2 , AgNO3.
Cu 28: Trong cc dung dch: HNO 3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, s dung dch tc dng c
vi Ba(HCO3)2 l

Trang 14

A.5.
B. 3.
C.4.
D. 6.
Cu 29: Cho phng trnh ha hc:
CH3CH2OH + K2CR2O7 + H2SO4 CH3CHO + Cr2(SO4)3+ K2SO4 + H2O
Sau khi cn bng vi h s nguyn n gin nht th tng h s cc cht trc phn ng l
A .7
B. 8.
C. 6.
D.11
Cu 30. Ho tan hon ton 23,8 gam hn hp mt mui cacbonat ca cc kim loi ho tr (I) v mui cacbonat
ca kim loi ho tr (II) trong dung dch HCl. Sau phn ng thu c 4,48 lt kh (ktc). em c cn
dung dch thu c bao nhiu gam mui khan?
A. 13 gam.
B. 15 gam.
C. 26 gam.
D. 30 gam.
Cu 31. Chn cu khng ng:
A. pH l ch s dng nh gi mnh hay yu v tnh axit hay bazo ca dung dch cn xt.
B. pH ca nc s dng cho sinh hot t 6 n 8,5.
C. Da vo ch s pH ngi ta c th c nhng bin php thch hp x l ngun nc cho ph hp
vi nhu cu s dng.
D. Dung dch c pH >7 c mi trng axit, v dung dch c pH < 7 c mi trng kim.
Cu 32: Cho mt lung CO i qua ng s ng 0,04 mol hn hp A gm FeO v Fe 2O3 t nng. Sau khi kt
thc th nghim thu c B gm 4 cht nng 4,784 gam. Kh i ra khi ng s cho hp th vo dung
dch Ba(OH)2 d th thu c 9,062 gam kt ta. Phn trm khi lng Fe2O3 trong hn hp A l
A. 86,96%.

B. 16,04%.

C. 13,04%.

D.6,01%.

Cu 33: Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H 2 ( ktc). Th
tch dung dch axit H2SO4 2M cn dng trung ho dung dch X l
A. 150 ml.

B. 75 ml.

C. 60 ml.

D. 30 ml.

Cu 34: Cho 12,9 gam hn hp Al v Mg phn ng vi dung dch hn hp hai axit HNO3 v H2SO4 (c nng) thu
c 0,1 mol mi kh SO2, NO, NO2. C cn dung dch sau phn ng khi lng mui khan thu c
l:
A. 31,5 gam.

B. 37,7 gam.

C. 47,3 gam.

D. 34,9 gam.

Cu 35: t chy hon ton 2,6 gam hn hp cht X gm mui natri ca hai axit cacboxylic no n chc k tip
nhau trong dy ng ng thu c 1,59 gam Na2CO3 v hn hp kh Y gm CO2, H2O. Cng thc phn t ca
hai mui trong hn hp X v khi lng hn hp Y l
A. CH3COONa; C2H5COONa; 3,4 gam.
B. C2H5COONa; C3H7COONa; 3,4 gam.
C. CH3COONa; C2H5COONa; 4,3 gam.
D. C4H9COONa; C3H7COONa; 3,4 gam.
Cu 36: Thy phn 0,01 mol este ca mt ancol a chc vi mt axit n chc cn 1,2 gam NaOH. Mt khc
khi thy phn 4,36 gam este th cn 2,4 gam NaOH v thu c 4,92 gam mui. Cng thc ca este l
A. (CH3COO)3C3H5
B. (C2H3COO)3C3H5 C. C3H5(COOCH3)3
D. C3H5(COOC2H3)3
Cu 37: t chy hon ton amin X, bc I c kh nng to kt ta vi dung dch brom thu c 3,08 gam CO 2.
0,81 gam H2O v 112 ml N2 (ktc). Cng thc cu to ca X l
A. C6H5NH2
B.C6H5NHCH3 C. C6H5CH2NH2
D. CH3C6H4NH2
Cu 38. trung ha 200 ml dung dch H2SO4 c pH = 2 th cn va Vml dung dch NaOH c pH = 13. Gi tr
ca V l:
A. 10 ml
B. 20 ml
C. 40 ml
D. 50 ml
Cu 39. Rt t t 360 ml dung dch NaOH 1M vo 100 ml dung dch AlCl 3 1M cho n khi phn ng xy ra
hon ton thu c m gam kt ta Al(OH)3. Gi tr ca m l:
A. 7,8 gam
B. 9,36 gam
C. 3,12 gam
D. 4,68 gam
Cu 40: Hai este X v Y (phn t u cha vng benzen) c cng thc phn t l C9H8O2. X v Y u tc dng
c vi Br2 theo t l mol 1:1. X tc dng vi dung dch NaOH d cho mt mui v mt anehit. Y tc dng vi
dung dch NaOH d cho hai mui v nc. Cng thc cu to ca X v Y c th l:
A.HOOC-C6H4-CH=CH2 v CH2=CH-COOC6H5.
B.C6H5-COO -CH=CH2 v C6H5-CHCH-COOH.
C. HCOO-C6H4-CH=CH2 v HCOO-CH=CH-C6H5.
D.C6H5COO-CH=CH2 v CH2=CH-COOC6H5.
Cu 41: Nhn xt no sau y khng ng.
A.C th dng nc brom phn bit phenol, anehit axetic, etanol.
B.CH2=CH-CH=CH-CH2C1 c ng phn hnh hc.

Trang 15

C. Cc amino axit u l cht rn iu kin thng.

D.Clo gn trn vng benzen nh hng th sau v tr ortho v para s lm tng kh nng phn ng th H
vng benzen
Cu 42: Cho m gam hn hp X gm CH 4, C2H2, C2H4, C2H6 v H2 qua ng ng Ni, nung nng thu c hn
hp kh Y. Dn ton b hn hp Y t t qua bnh ng dung dch brom (d) thy khi lung bnh tng 0,8 gam
v c hn hp kh Z thot ra. t chy hon ton hn hp Z thu c 0,5 mol CO 2 v 0,8 mol H2O. Gi tr ca
m l
A. 37,2.
B. 7,32.
C. 6,64
D.8,4.
Cu 43: Ho tan hon ton m gam hn hp gm Mg, Fe, Cu trong dung dch HNO3 thu c
c hn hp kh D (ktc) gm NO2 v NO ( ktc, khng cn sn phm kh no khc).t khi hi so vi
hiro bng 18,2. Tng s gam mui khan to thnh theo m v V l :
A.m+

V
22, 4

B.m -

V
22, 4

C. m +

314V
56

D. m -

V
7, 75

Cu 44: Bit rng trong dung dch mui kaliicromat lun lun c cn bng:
Cr2O72- + H2O 2CrO42- + 2H+
(da cam)
(vng)
Nu thm dung dch HCl c, d vo dung dch K2Cr2O7 th dung dch chuyn thnh
A. mu da cam.
B. mu vng.
C.mu xanh lc.
D. khng mu.
Cu 45: Hn hp X gm cc cht Y (C3H10N2O4) v cht z (C4H8N2O3); trong Y l mui ca axit a chc, z l
ipeptit mch h. Cho 28,08 gam X tc dng vi dung dch NaOH d, un nng, thu c 0,12mol hn hp kh
u lm xanh qu tm m. Mt khc 28,08 gam X tc dng vi dung dch HC1 d thu uc m gam cht hu c.
Gi tr ca m l:
A. 37,65
B. 39,15
C. 38,85
D.42,9
Cu 46: Chia 52,4 gam hn hp 2 anehit n chc l ng ng k tip thnh 2 phn bng nhau:
- Phn I tc dng vi lng d dung dch AgNO3 trong NH3 un nng thu c 108 gam Ag.
- Phn II tc dng hon ton vi H2 d (xc tc Ni, t ) thu c hn hp X gm 2 ancol Y v Z (My < Mz ) un
nng X vi H2SO4 c 140C thu c 12,09 gam hn hp 3 este. Bit hiu sut phn ng to este ca Y l
60%. Hiu sut phn ng to este ca Z l:
A 40%
B. 60%
C. 30%
D. 50%
Cu 47: Mt bnh kn ch cha cc cht: axetilen (0,3mol), vinyl axetilen (0,5mol) v hidro (0,8mol) v mt t
bi Niken . Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi H 2 l 17,7. kh X phn ng
va vi 0,7mol AgNO3 trong dung dch NH3 thu c m gam kt ta v 10,08 lit hn hp khi Y (ktc). Kh Y
phn ng ti a vi 0,1 mol Br2 trong dung dch. Gi tr ca m l:
A. 99,8
B. 99,6
C. 98,4
D. 98,2
Cu 48: t chy hon ton 23,8 gam hn hp X gm axit acrylic, axit adipic, axit propanoic v glixerol (trong
s mol axit acrylic bng s mol axit propanoic) bng O 2 d thu c hn hp Y gm kh v hi. Dn Y vo
dung dch cha 0,7 mol Ba(OH) 2 thu c 98,5 gam kt ta v dung dch z. un nng z li thy xut hin kt
ta. Cho 23,8 gam hn hp X tc dng vi 300ml dung dch KOH 1M, sau khi cc phn ng xy ra hon ton, c
cn dung dch thu c cht rn khan c khi lng l:
A. 15,8 gam
B. 22,2 gam
C. 27,8 gam
D. 30,8 gam
Cu 49: Trn V1 lt dung dch axit c pH = 5 vi V 2 lt dung dch baz c pH = 9 thu c dung dch c pH = 8.
T l V1 : V2 bng
A. 9:10.
B. 11:9.
C. 9:11.
D.10:9.
Cu 50: Trn 2,7 gam Al vi 20 gam hn hp Fe 2O3 v Fe3O4 ri tin hnh phn ng nhit nhm, thu c hn
hp X. Ho tan X trong dung dch HNO 3 c nng d thu c 0,36 mol NO2 (l sn phm kh duy nht). Khi
lng ca Fe2O3 trong hn hp ban u l
A. 6,08 gam.
B. 16,36 gam.
C. 10,72 gam.
D. 1,44 gam.

Trang 16

 S 6
Cu 1:Cho cc dung dch sau phn ng vi nhau tng i mt nhit thng
:BaCl2;NaHCO3;Na2CO3;NaHSO4.S phn ng xy ra l :
A.2
B.1
C.3
D.4
Cu 2: linh hot ca nguyn t H trong nhm OH ca cc cht C 2H5OH(1),C6H5OH(2),H2O(3),HCOOH(4),
CH3COOH(5) tng dn theo th t no :

A.

(3)<(2)<(1)<(5)<(4)

B. (5)<(4)<(2)<(1)<(3)

C. (1)<(3)<(2)<(4)<(5)

D.(1)<(3)<(2)<(5)<(4)

Cu 3 : Cho cc khng nh sau:

(1) Phn ng to este ca glucoz vi anhirit axetic chng minh glucoz c mch cacbon khng phn
nhnh .
(2) Saccaroz ch c cu trc dng mch vng .
(3) Phn ng tch nc t ancol no, n chc bc 1 (H2SO4, 1800C) ta lun thu c duy nht mt olefin .
(4) HNO3 hoa tan c hon ton c SiO2
(5) Khi t chy hon ton mt axit no, n chc hay mt este no, n chc u thu c s mol H 2O bng
s mol CO2.
(6) Ancol no , n chc hay ete no , n chc c CTTQ l CnH2n+2O
(7) Oxi ha ancol bc 1 vi CuO lun thu c anehit tng ng
S khng nh ng l :
A.3
B.4
C.2
D.5
Cu 4.Cho cc cht lng sau : axit axetic ,glixerol,triolein. phn bit cc cht lng trn , c th ch cn dng
A.Nc brom
B.Nc v qu tm
C.Nc v dung dch NaOH
D.NaOH
Cu 5. in phn vi (in cc tr) mt dung dch NaCl v CuSO 4 c cng s mol, n khi catot xut hin bt
kh th dng in phn .Trong c qu trnh in phn trn ,sn phm thu c anot l
A.kh Cl2 v H2
B. kh Cl2 v O2
C.ch c kh Cl2
D.kh H2 v O2
Cu 6: Cho cc cht : CH3COONH4; Na2CO3; Ba(OH)2; Al2O3; CH3COONa; C6H5ONa; Zn(OH)2; NH4Cl;
KHCO3; NH4HSO4; Al; (NH4)2CO3. S cht khi cho vo dung dch HCl hay dung dch Ba(OH) 2 u phn ng l
A.7
B.9
C.8
D.6
Cu 7: cho 16.0 gam FeO tc dng vi m gam Al ( nhit cao ) n khi phn ng xy ra hon ton thu c
hn hp rn A . Cho A tc dng vi dung dch HCl d thu c 7.84 lt kh H2 ( ktc) . Gi tr ca m l :
A.8.1
B.2.7
C.5.4
D.6.3
Cu 8: Cho cc cht :Fe , dung dch FeCl 2;dung dch HCl;dung dch Fe(NO3)2;dung dch FeCl3;dung dch AgNO3.
Cho tng cp cht phn ng vi nhau th s phn ng thuc loi phn ng oxi ha kh c th c l :
A.4
B.7
C.5
D.6
Cu 9: Cho 4.48 gam hn hp gm CH 3COOC2H5 v CH3COOC6H5(c t l mol 1:1) tc dng vi 800ml dung
dch NaOH 0.1M thu c dung dch X . C cn dung dch X th khi lng cht rn thu c l :
A.5.60 gam
B.4.88 gam
C.6.40 gam
D.3.28 gam
2+
2+
Cu 10 : Dung dch A cha : 0.15 mol Ca , 0.6 mol Cl ,0.1 mol Mg ,a mol HCO3 , 0,8 mol Na+. un nng dung
dch A c dung dch B. C cn dung dch B v nung nng n khi lng khng i thu c m gam cht rn.
Gi tr ca m l :
A.41,3
B.53,7
C. 45,7
D.69,1
Cu 11: Cho 8.4 gam st tan ht vo dung dch HNO 3 long . Sau khi phn ng xy ra hon ton thu c 2.688
lt kh NO ( sn phm kh duy nht ) v dung dch X . C cn dung dch X thu c m gam mui khan . Gi tr
ca m l :
A.30.72g
B.29.04g
C.36.30g
D.32.40g
Cu 12 :a mol cht bo X c th cng hp ti a vi 4a mol Br 2 . t chy hon ton a mol X thu c b mol
H2O v V lt kh CO2 (ktc).Biu thc lin h gia V vi a,b l:
A.V=22.4(4a-b)
B.V=22.4(b+3a)
C.V=22.4(b+6a)
D.22.4(b+7a)

Trang 17

Cu 13 : Mui A c cng thc l C 3H10O3N2 . Ly 10.98 gam A phn ng ht vi 200ml dung dch KOH 0.5M .
C cn dung dch sau phn ng th c phn hi v phn cht rn , trong phn hi c 1 cht hu c bc 3 ,
trong phn rn ch l cht v c . Khi lng phn hi l :
A.5.31g
B.11.52g
C.1.62g
D.6.93g
Cu 14. Dy cc kim loi c cu trc lp phng tm khi l :
A.Ca,Sr,Ba
B.Ba,K,Ba
C.Na,K,Mg
D.Mg,Ca,Ba
Cu 15/37: Tn quc t ca ancol CH3-CH(OH)-CH3 l :
A.Propan-2-ol
B.Ancol propylic
C.Ancol iso propylic
D.Ancol sec -propylic

Cu 16. Cho s ca mt nguyn t X c biu din nh sau, chn cu khng ng.

A. X l nguyn t thuc nguyn t Liti.
B. S khi ca X bng 7.
C. Trong X, s ht mang in nhiu hn ht mang in l 2.
D. S ht mang in trong ht nhn l 7.
Cu 17: t chy hon ton hn hp X (glucoz,fructoz,axit etanoic) cn 4.48 lt O 2 (ktc). Dn sn phm chy
qua bnh ng dung dch Ca(OH)2 d, sau phn ng hon ton thu c m gam kt ta . Gi tr ca m l:
A.20
B.12
C.15
D.20.5
Cu 18: Cho cc poime sau: t nilon -6,6,poli9vinyl clorua),thy tinh plexiglas,teflon, nha novolac,t visco ,t
nitron,cao su buna .Trong ,s polime c iu ch bng phn ng trng hp l :
A.5
B.4
C.6
D.7
Cu 19. Cho cc cht : FeCO3; Fe(NO3)2, Fe2(SO4)3, FeSO4, FeS, CuS, FeS2 S lng cht c th c kh thot ra
khi cho vo dung dch HCl v un nh l:
A.6
B.3
C.5
D.4
Cu 20. Dy Cu co sch cm vo bnh hoa th hoa s ti lu hn v :
A. C to ra mt s ion Cu2+ c tc dng dit khun
B. Cung cp nguyn t vi lng cn cung cp cho hoa .
C. Cu kch thch qu trnh tng trng ca hoa.
D. Cu2+ to ra s to kt ta vi 1 s ion to ta lm nc trong hn.
Cu 21:Phn ng tng hp amoniac trong cng nghip xy ra theo phng trnh :N 2 +3H2 2NH3, H<0.
Mun tng hiu sut to sn phm cn:
A. Tng nhit v gim p sut
B.Gim nhit v tng p sut
C.Tng nhit v tng p sut
D. Gim nhit v gim p sut
Cu 22; iu no sau y khng ng :
A.Cht do l nhng vt liu b bin dng di tc dng ca nhit v p sut m vn gi nguyn dng
khi thi tc dng
B. T visco,t axetat l nhng t tng hp
C. Nilon -6.6 v t capron l nhng poliamit
D. T tm ,bng ,len l polime thin nhin
Cu 23:Cho cc cht v ion sau :Cl -,Na, HCl, O2-, Fe2+,SO2 ,Cl2.Cc cht v ion ch th hin c tnh kh trong
phn ng oxi ha kh l:
A.Na, O2-, HCl
B.Cl-,Na,O2-, Fe2+
C. :Cl-, Na, O2D. Na, O2-, HCl, Fe2+
Cu 24. Hn hp X cha :K2O; NH4Cl; KHCO3 v BaCl2 c s mol bng nhau . Cho X vo nc d un nng
,dung dch thu c cha cht tan l ;
A.KCl;BaCl2
B.KCl;KOH
C.KCl ,KHCO3, BaCl2
D.KCl
Cu 25. Cng thc chung ca amin no, n chc ,mch h l :
A.CnH2n-1N(n2)
B.CnH2n-5N(n6)
C.CnH2n+1N(n2)
D.CnH2n+3N(n1)
Cu 26: Cht c dng lm kh kh clo m l:
A.CaO
B.Na2SO3khan
C. dd NaOH c
D. dd H 2SO4 c

Trang 18

Cu 27: Mt nguyn t R to hp cht kh vi H c dng RH 3 . Nguyn t ny chim 25.93% khi lng trong
oxit cao nht .R l:
A.Al
B.N
C.P
D.As
Cu 28: Cho Ba kim loi ln lt vo cc dung dch sau:NaHCO 3,CuSO4,(NH4)2CO3,NaNO3,MgCl2,Na2SiO3.
S dung dch to kt ta l:
A.5
B.4
C.2
D.3
Cu 29 : C cc pht biu sau y :
1. Amilopectin coa cu trc mch phn nhnh
2. Glucoz b kh bi dung dch Ag NO3 trong NH3
3. Xenluloz c cu trc mch phn nhnh
4. Saccaroz lm mt mu nc brom
5. Glucoz tn ti dang mch h v dng mch vng
6. dng mch h ,glucoz c 5 nhm OH k nhau
7. Glucoz tc dng c vi nc brom
S nhn nh ng l :
A.6
B.4
C .5
D.7
Cu 30.Khng th phn bit glucoz v saccaroz bng phn ng vi cht no sau y :
A.Cu(OH)/OH-,to
B.AgNO3/NH3 C.Na
D.Dung dch Br2
Cu 31.Cht X tc dng vi dung dch NaOH cho dung dch X 1.C cn c cht rn X2 v hn hp hi
X3,chng ct X3 thu c X4 .Cho X4 trng gng c sn phm X 5 .Cho X5 tc dng vi dung dch NaOH li
thu c X2 . Cng thc cu to ca X l :
A.HCOO-C(CH3)=CH2
B.HCOOCH=CHCH3
C.CH2=CH-CH2-OCOH
D.CH2=CH-OCOCH3
Cu 32: So snh no sau y khng ng khi ni v n mn in ha v s in phn :
A.Trong h phn ng u c dng in mt chiu
B. u xy ra phn ng oxi ha-kh trn b mt cc in cc
C. trn in cc u c qu trnh cho electron hoc nhn electron.
D. Anot l cc dng , catot l cc m
Cu 33. S nguyn t m nguyn t ca n trng thi c bn c tng s electron trn cc phn lp s bng 7 l:
A.11
B.1
C.9
D.3
Cu 34. Hn hp X gm Na , Ba , Na 2O, BaO . ha tan ht 107.9 gam hn hp X vo nc thu c 7.84 lt H 2
(ddktc) v dung dch kim Y trong c 28 gam NaOH . Hp th 17.92 lt kh SO 2 (ktc) vo dung dch Y thu
c m gam kt ta . Gi tr ca m l :
A.130,2 gam
B. 173,6 gam
C. 108,5 gam
D. 21,7 gam
Cu 35. Ha tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO 3 long thu c dung dch X
v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu , trong c mt kh ha nu trong khng kh . Khi
lng ca Y l 5,18 gam . Nu cho dung dch NaOH d vo dung dch X v un nng , khng c kh mi khai
thot ra . Phn trm khi lng ca Al rong hn hp ban u l
A.11,37%
B.11,54%
C. 18,278%
D. 12,80%
Cu 36. Cho 4.48 lt CO2 (ktc) vo 400 ml dung dch hn hp KOH 0.25M v K 2CO3 0.4M c dung dch X .
Cho dung dch BaCl2 d vo dung dch X thu c kt ta , lc ly kt ta em nung n khi lng khng i
thu c m gam cht rn . Gi tr ca m l :
A.21.67
B.9.18
C.71.91
D.48.96
Cu 37. Ha tan 20.8 gam hn hp bt gm FeS,FeS 2,S bng dung dch HNO3 c nng d thu c 53.76 lt
NO2 ( sn phm kh duy nht , ktc ) v dung dch X. Cho X tc dng vi dung dch NaOH (d ), lc ly kt
ta nung trong khng kh n khi lng khng i th khi lng cht rn thu c l :
A.9 g
B.8.2g
C.10.7g
D.16g
Cu 38. Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d . Sau phn ng lm
bay hi cn thn dung dch thu c ( m +11.68) gam mui khan . Nu cho m gam hn hp X tc dng vi dung

Trang 19

dch KOH va , sau phn ng lm bay hi cn thn dung dch thu c (m+19) gam mui khan .Gi tr ca m
l :
A.36.6 gam
B.38.92gam
C.38.61gam
D.35.4 gam
Cu 39:Cho 36.56 gam hn hp X gm Cu v FeCO 3 vo dung dch HNO3 long un nng v khuy u .Sau
khi cc phn ng xy ra hon ton thu c kh NO ,448ml CO 2;dung dch Y v 22.4 gam kim loi .C cn dung
dch Y thu c khi lng cht rn khan l :
A.38.82
B.36.24
C.39.62
D.38.38
Cu 40. Trn ancol C3H7OH vi axit CH3COOH ri chia thnh hai phn bng nhau . Phn 1 cho tc dng ht
vi Na thu c 3.36 lt kh H2 (ktc).Phn 2 un nng cho xy ra phn ng este ha ,sau mt thi gian , ngui
ri cho tc dng ht vi Na ,thu c 2.24 lt H2(ktc). S gam este to thnh l :
A.5.1 gam
B.10.2 gam
C.15.3 gam
D.20.4 gam
Cu 41: X phng ha tan m gam mt este n chc A bng 200ml dung dch KOH 1M . C cn dung dch sau
phn ng c 19.3 gam cht rn khan v hi mt ancol B. Oxi ha B bng lng d CuO , sn phm thu c
em trng bc hon ton thu c 64.8 gam Ag . Khi lng m v cng thc ca A l:
A.12.9 g v C2H3COOCH3
B. 13.2 g v C2H5COOCH3
C.17.2 g v C2H3COOCH3
D.26.4g v CH3COOC2H5
Cu 42. T l theo s lng ca ca hai ng v

27
13

Al v

29
13

Al l 23/2. % theo khi lng ca

27
13

Al trong phn t

Al2X3 l 33,05%. Nguyn t khi ca X bng:

A. 32
B. 96
C. 16
D. 48
Cu 43. t chy 25,7 gam hn hp gm Cu, Fe, Al trong O 2 d thu c 39,3 gam hn hp oxit (X). Ha tan
hon ton X trong dung dch HCl th s mol HCl phn ng l a mol. Gi tr ca a l:
A. 0.85 mol.
B. 1,7 mol
C. 0.425 mol
D. 1.275 mol
Cu 44. Ha tan hon ton 24,1 gam Mg, Fe, Al trong dung dch HCl d n khi phn ng xy ra hon ton thu
c m gam mui v 0.85 mol H2. Gi tr ca m l:
A. 54,275 gam
B. 39,19 gam
D. 78,45 gam
D. 84,45 gam
Cu 45: Ha tan ht m gam AlCl3 vo nc c dung dch X.Cho 110ml dung dch KOH 3M vo X , thu c
a gam kt ta .Mt khc , nu cho 150ml dung dch KOH 3M vo X th cng thu c a gam kt ta .Gi tr ca
m l :
A.14.685
B.18.690
C.17.710
D.20.025
Cu 46. hn hp X gm C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m
gam hn hp X thu c 3.06 gam H 2O v 3.136 lt CO2 ( ktc) .Mt khc 13.2 gam h hp X thc hin
phn ng trng bc thy c x gam Ag kt ta . Gi tr ca x l :
A.10.8 gam
B.2.16 gam
C.8.64 gam
D.4.32 gam
Cu 47. X l tetrapetit Ala-Gly-Val-Ala ,Y l tripeptit Val-Gly-Val . un nng m gam hn hp X v Y c t l s
mol nx:ny =1:3 vi dung dch NaOH va ,sau khi phn ng kt thc thu c dung dch Z.C cn dung
dch thu c 89,94 gam mui . Gi tr ca m l:
A.63,06g
B.64.86g
C.77.04g
D.65.13g
Cu 48. t chy hon ton hn hp gm hai este no ,n chc mch h cn 5.68 g kh oxi v thu c 3.248 lt
kh CO2 (ktc).Cho hn hp este trn tc dng va vi KOH thu c hai ru l ng dng k tip v
3.92 gam mui ca mt axit hu c .Cng thc cu to ca hai este l
A.C3H7COOCH3v CH3COOC2H5
B.HCOOCH3 v HCOOC2H5
C.C2H5COOCH3 v CH3COOCH3
D.CH3COOCH3 v CH3COOC2H5
Cu 49. Cho a gam bt Fe vo 400ml dung dch hn hp gm Cu(NO 3)2 0.4M v H2SO4 0.5M .Sau khi cc phn
ng xy ra hon ton ,thu c 0.8a gam hn hp bt kim loi v V lt kh NO ( sn phm kh duy nht ,
ktc). Gi tr ca a v V ln lt l :
A.30.8 v 2.24
B.17.8 v 4.48
C.20.8 v 4.48
D. 35.6 v 2.24
Cu 50: Cho 50 ml dung dch A cha RCOOH v RCOOM (M: kim loi kim ) vi tng s mol 2 cht l 0.035
mol , tc dng vi 12 ml dung dch Ba(OH) 2 1.25 M c dung dch B . Sau phn ng cho thm 3.75 gam dung
dch HCl 14.6 % vo dung dch A trung ha Ba(OH) 2 d c dung dung dch C. Sau c cn dung dch C
th thu c 5.4325 gam mui khan . Nu em 50 ml dung dch A trn tc dng vi 20 ml dung dch NaOH
1M,phn ng hon ton , c cn dung dch th khi lng cht rn thu c l :
A.2.87gam
B.3.43gam
C.3.39gam
D.3.19gam

Trang 20

 S 7
Cho bit nguyn t khi (theo vC) ca cc nguyn t:
H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40;
Fe = 56; Cu = 64; Zn = 65; Rb = 85,5; Ag = 108; .
Cu 1: Cng thc chung ca axit no, hai chc, mch h l:
A. CnH2n-2O4 vi n nguyn dng, n 3.
B. CnH2nO4 vi n nguyn dng, n 2.
C. CnH2n-2O4 vi n nguyn dng, n 2.
D. CnH2n+2O4 vi n nguyn dng, n 2.
Cu 2: Cc nguyn t halogen c cu hnh e lp ngoi cng l
A. ns2.
B. ns2np3.
C. ns2np4.
D. ns2np5.
Cu 3 : Khi nu canh cua th thy cc mng riu cua ni ln l do :
A. S ng t ca protein do nhit .
B. Phn ng thy phn ca protein.
C. Phn ng mu ca protein.
C. S ng t ca lipit.
Cu 4 : Dy gm cc cht khng tc dng vi dung dch NaOH:
A. Al2O3, Na2CO3, AlCl3
B. Al, NaHCO3, Al(OH)3
C. NaAlO2, Na2CO3, NaCl
D. Al, FeCl2, FeCl3
Cu 5 : Hp cht X c cc tnh cht :
(1) L cht kh nhit thng, nng hn khng kh.
(2) Lm nht mu dung dch thuc tm.
(3) B hp th bi dung dch Ba(OH)2 d to kt ta trng.
X l cht no trong cc cht sau :
A. NO2
B. SO2
C. CO2
D. H2S
Cu 6 : CO2 khng phn ng vi cht no trong cc cht sau :
A. NaOH
B. CaO
C. O2
D. Mg
Cu 7 : Cht no sau y l monosaccarit?
A. Saccarozo
B. Xenlulozo
C. Amilozo
D. Glucozo
Cu 8: C bao nhiu hp cht hu c tc dng c vi dung dch NaOH c cng cng thc phn t C 7H8O?
A. 3
B. 2
C. 4
D. 1
Cu 9: Dy no c xp ng th t tnh axit v tnh kh gim dn
A. HCl, HBr, HI, HF. B. HI, HBr, HCl, HF. C. HCl, HI, HBr, HF. D. HF, HCl, HBr, HI.
Cu 10: Xt cn bng ho hc: 2SO2 (k) + O2 (k) SO3 (k) H= -198kJ
T l SO3 trong hn hp lc cn bng s ln hn khi
A. tng nhit v gim p sut.
B. tng nhit , v p sut khng i.
C. gim nhit v tng p sut.
D. c nh nhit v gim p sut.
Cu 11: Tc nhn ch yu gy ma axit l
A. CO v CH4.
B. CH4 v NH3.
C. SO2 v NO2.
D. CO v CO2.
Cu 12: Cho 0,1 mol este to bi 2 ln axit vtc dng hon ton vi NaOH thu c 6,4 gam ru v mt
lng mi c khi lng nhiu hn lng este l 13,56% (so vi lng este). Xc nh cng thc cu
to ca este.
A. CH3COO CH3.
B. CH3OCOCOOCH3.
C. CH3COOCOOCH3.
D. CH3COOCH2COOCH3.
Cu 13. Cho dung dch cha 0,05 mol NaOH vo dung dch cha 0,02 mol ZnSO 4 thu c a gam kt ta. Gi tr
ca a l:
A. 1,98 gam
B. 1,485 gam
C. 2,475 gam
D. 0,99 gam
Cu 14 : Ma ty d dng no khi a vo c th con ngi u c th lm ri lon chc nng sinh l. .Nhm
cht no sau y l ma ty (cm dng) ?
A. Penixilin, ampixilin, erythromixin.
B. Thuc phin, cn sa, heroin, cocain.
C. Thuc phin, penixilin, moocphin.
D. Seduxen, cn sa, ampixilin, cocain.
Cu 15. Cc hnh v sau m t cc cch thu kh thng c s dng khi iu ch v thu kh trong phng th
nghim. Hnh 3 c th dng thu c nhng kh no trong cc kh sau: H2, C2H2 , NH3 , SO2 , HCl , N2.

A. H2, N2 , C2H2

B. HCl, SO2, NH3

C. N2, H2

D. H2 , N2, NH3

Cu 16: Thi rt chm 2,24 lt (ktc) mt hn hp kh gm CO v H 2 qua mt ng s ng hn hp Al 2O3, CuO,

Fe3O4, Fe2O3 c khi lng l 24 gam d ang c un nng. Sau khi kt thc phn ng khi lng
cht rn cn li trong ng s l
A. 22,4 gam.

B. 11,2 gam.

C. 20,8 gam.

D. 16,8 gam.

Trang 21

X 2(k ) Y2(k ) 2Z(k )

Cu 17 : Thc hin phn ng sau trong bnh kn c dung tch khng i 2 lt.
Lc u s mol ca kh X2 l 0,6 mol, sau 10 pht s mol ca kh X 2 cn li 0,12 mol. Tc trung bnh ca
phn ng tnh theo X2 trong khong thi gian trn l :
A. 4.104 mol / (l.s). B. 2, 4 mol / (l.s).
C. 4, 6 mol / (l.s).
D. 8.104 mol / (l.s).
Cu 18 : Thc hin cc th nghim sau :
(1) Sc kh SO2 vo dung dch KMnO4 .
(2) Sc kh Cl2 vo dung dch H2S.
(3) Sc hn hp kh thu c khi nhit phn Cu(NO3)2 vo nc.
(4) Cho Na2CO3 vo dung dch AlCl3.
(5) Cho HCl vo dung dch Fe(NO3)2.
(6) Cho Fe2O3 vo dung dch HI.
S th nghim c phn ng oxi ha kh xy ra l :
A. 3
B. 5
C. 6
D. 4
Cu 19 : Cho cc cht sau : CO 2, NO2, CO, CrO3, P2O5, Al2O3. C bao nhiu cht tc dng c vi dung dch
NaOH long nhit thng?
A. 3
B. 6
C. 4
D. 5
Cu 20 : Nhn xt no sau y khng ng ?
A. Hidro ha hon ton triolein hoc trilinolein u thu c tristearin.
B. Cht bo l este ca glixerol v cc axit bo.
C. Du m ng thc vt b i thiu do ni i C = C gc axit khng no ca cht bo b oxi ha chm
bi oxi khng kh to thnh peoxit, cht ny b phn hy thnh cc sn phm c mi kh chu.
D. Cht bo nh hn nc v khng tan trong nc.
Cu 21 : Ha tan hon ton hn hp X gm BaO, NH 4HCO3, NaHCO3 (c t l mol ln lt l 5 : 4 : 2) vo
nc d, un nng. n khi cc phn ng xy ra hon ton thu c dung dch Y cha :
A. NaHCO3 v Ba(HCO3)2
B. Na2CO3.
C. NaHCO3
D. NaHCO3 v (NH4)2CO3.
Cu 22: Trong cc cht: m-HOC6H4OH, p-CH3COOC6H4OH, CH3CH2COOH, (CH3NH3)2CO3,
HOOCCH2CH(NH2)COOH, ClH3NCH(CH3)COOH. C bao nhiu cht m 1 mol cht phn ng c ti a
vi 2 mol NaOH?
A. 4
B. 3
C. 6
D. 5
Cu 23: Tnh cht no sau y khng phi ca kim loi kim
A. u kh c nc d dng
B. Ch iu ch c bng phng php in phn nng chy
C. Hidroxyt du l nhng baz mnh .
D. u c cu to mng tinh th lp phng tm din
Cu 24: Cho cc th nghim sau:
(1) cho etanol tc dng vi Na kim loi
(2) cho etanol tc dng vi dung dch HCl bc khi
(3) cho glixerol tc dng vi Cu(OH)2
(4) cho etanol tc dng vi CH3COOH c H2SO4 c xc tc
C bao nhiu th nghim trong c phn ng th H ca nhm OH ancol
A. 4
B. 3
C. 2
D. 1
Cu 25: t chy hon ton 0,1 mol mt axit cacbonxylic n chc cn va V lt O 2 ( ktc), thu c 0,3
mol CO2 v 0,2 mol H2O. Gi tr ca V l
A. 8,96 lt.

B. 11,2 lt.

C. 6,72 lt.
+

D. 4,48 lt.
-

Cu 26. Cho cc cp ion sau trong dung dch : (1); H v HCO3 , (2); AlO2 v OH-, (3) Mg2+ v OH-,
(4): Ca2+ + HCO3-, (5). OH- v Zn2+, (6), K+ + NO3-, (7): Na+ v HS-; (8). H+ + AlO2-.
Nhng cp ion no phn ng c vi nhau:
A. (1), (2), (4), (7).
B. (1), (2), (3), (8).
C. (1), (3), (5), (8)
D. (2), (3), (6),(7).
Cu 27: Cht no trong cc cht sau y khng phi l cht c tnh lng tnh
A. NaHCO3
B. Al(OH)3
C. ZnO
D. Al
Cu 28: Mt loi qung st (sau khi loi b tp cht) cho tc dng vi HNO 3 khng c kh thot ra. Tn ca
qung l:
A. hematit
B. manhetit
C. pirit
D. xierit
Cu 29: Dung dch X c cha 0,5 mol Na +; 0,2 mol Cl-; 0,1 mol NO3-; 0,1 mol Ca2+; 0,1 mol Mg2+;v HCO3-.
un si dung dch X n khi cc phn ng xy ra hon ton thu c dung dch Y. Dung dch Y l:
A. Nc mm
B. nc c tnh cng tm thi
C. nc c tnh cng vnh cu
D. nc c tnh cng ton phn
Cu 30. Cp ion no sau y kt hp vi nhau to ta m mu sc kt ta khng ng.
A. Ca2+ + CO32- ( To kt ta mu trng).
B. Fe2+ + OH- ( to kt ta mu trng hi xanh).
+
3C. Ag + PO4 ( To kt ta mu vng).
D. Cu2+ + OH- ( to kt ta mu )

Trang 22

Cu 31: Mt loi phn kali cha 59,6% KCl, 34,5% K2CO3 v khi lng, cn li l SiO2. dinh dng ca
loi phn bn trn l:
A. 6,10
B. 49,35
C. 50,70
D. 60,20
Cu 32: Dung dch X cha hn hp NaOH 0,25M v Ba(OH) 2 0,15M dung dch Y cha hn hp H 2SO4 0,5M
v HNO3 0,2M.Trn V lt dung dch X vi V lit dung dch Y thu c dung dch Z c pH =3. T l V/V l
A. 2,17
B. 1,25
C. 0,46
D. 0,08
Cu 33: Cho m(g) Mg vo dung dch cha 0,1 mol AgNO 3 v 0.25 mol Cu(NO3)2, sau mt thi gian thu c
19,44g kt ta v dung dch X cha 2 mui. Tch ly kt ta, thm tip 8,4g bt st vo dd X, sau khi cc phn
ng hon ton, thu c 9,36g kt ta. Gi tr ca m l:
A. 4,8g
B. 4,32g
C. 4,64g
D. 5,28g
Cu 34: Cho 5 gam bt Mg vo dung dch hn hp KNO3 v H2SO4, un nh, trong iu kin thch hp, n khi
phn ng xy ra hon ton thu c dung dch A cha m gam mui; 1,792 lt hn hp kh B ( ktc) gm hai kh
khng mu, trong c mt kh ha nu ngoi khng kh v cn li 0,44 gam cht rn khng tan. Bit t khi hi
ca B i vi H2 l 11,5. Gi tr ca m l
A. 27,96.
B. 29,72
C. 31,08.
D. 36,04.
Cu 35: Tin hnh phn ng nhit nhm hon ton m gam hn hp X gm bt Al v Fe xOy trong iu kin khng
c khng kh thu c hn hp Y. Nghin nh, trn u hn hp Y ri chia thnh 2 phn:
Phn 1 c khi lng 14,49 gam c ha tan ht trong dung dch HNO 3 long, d, un nng thu c dung
dch Z v 0,165 mol NO (sn phm kh duy nht).
Phn 2 em tc dng vi dung dch NaOH d un nng thu c 0,015 mol kh H2 v cn li 2,52 gam cht rn.
Cng thc ca oxit st v gi tr ca m ln lt l
A. Fe3O4 v 28,98.
B. Fe2O3 v 28,98.
C. Fe3O4 v 19,32. D. FeO v 19,32.
Cu 36 : Khi sc t t n d CO 2 vo dung dch c cha 0,1 mol NaOH, x mol KOH v y mol Ba(OH) 2. Kt
qu th nghim thu c biu din trn th sau :
S mol BaCO3

0,6
0,2
S mol CO2

1,6

Gi tr ca x, y, z ln lt l :
A. 0,6 ; 0,4 v 1,5
B. 0,3 ; 0,6 v 1,2
C. 0,2 ; 0,6 v 1,25
D. 0,3 ; 0,6 v
1,4
Cu 37: Hn hp T gm X, Y, Z (58<Mx<MY <MZ<78) l hp cht hu c tp phc, phn t ch cha C, H v O
c cc tnh cht sau:
- X, Y, Z u tc dng c vi Na; Y, Z tc dng c vi NaHCO 3; X, Y u c phn ng trng bc
Nu t chy ht 0,25 mol hn hp T th thu c m gam cht CO2, m gn nht vi gi tr:
A. 44,4
B. 22,2
C. 11,1
D. 33,3
Cu 38: Cho 61,2 gam hn hp X gm Cu v Fe 3O4 tc dng vi dung dch HNO 3 long, un nng v khuy
u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung
dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l
A. 151,5.
`B. 137,1.
C. 97,5.
D. 108,9.
Cu 39. X phng ha hon ton 17,24g cht bo cn va 0,06mol NaOH. C cn dung dch sau phn ng
thu c khi lng x phng l
A. 17,80g
B. 18,24g
C. 16,68g
D. 18,38g
Cu 40: Trong cng nghip polietilen (PE) c iu ch t metan theo s

CH
4

H 2 80%

C2 H
2

H 2 80%

C2 H 4

H 2 80%

PE

tng hp 5,376 kg PE theo s trn cn V m kh thin nhin (ktc, cha 75% metan theo th tch). Gi tr
ca V l
A. 11,47
B. 22,4
C. 28,0
D. 16,8
Cu 41: t chy hon ton 4,02 gam hn hp gm axit acrylic, vinyl axetat v metyl metacrylat ri cho ton b
sn phm chy vo bnh 1 ng dung dch H2SO4 c, bnh 2 ng dung dch Ba(OH)2 d thy khi lng bnh 1
tng m gam, bnh 2 xut hin 35,46 gam kt ta. Gi tr ca m l
A. 2,70.
B. 2,34.
C. 3,24.
D. 3,65.

Trang 23

Cu 42: Este n chc X khng c nhnh, ch cha C,H,O v khng cha cc nhm chc khc. Bit t khi hi
ca X so vi O2 l 3,125. Khi cho 15 gam X tc dng va vi dung dch NaOH un nng, c cn dung dch
sau phn ng thu c 21 gam mui khan. Cng thc cu to ca X l
A. HCOO-CH2-CH2 CH=CH2.
B. CH3COO-CH2-CH=CH2.

Cu 43: Cc cht trong dy no sau y u to kt ta khi cho tc dng vi dung dch AgNO3 trong
NH3 d, un nng?
A. vinylaxetilen, glucoz, axit propionic.
B. glucoz, imetylaxetilen, anehit axetic.
C. vinylaxetilen, glucoz, imetylaxetilen.
D. vinylaxetilen, glucoz, anehit axetic.
Cu 44. Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6
(benzen), CH3CHO. S cht trong dy phn ng c vi dung dch nc brom l :
A. 7
B. 6
C. 5
D. 8
Cu 45: un nng hn hp gm : 22,5 gam glyxin ; 17,8 gam alanin ; 11,7 gam valin, vi xc tc thch

hp, sau khi phn ng cy ra hon ton thu c m gam hn hp X hm 6 tripeptit. Gi tr ca m l :

A.44,8 gam.
B.52 gam.
C.43 gam.
D. 41,2 gam.
Cu 46. Cht bo thc t bao gi cng gm triglixerit v cc axit bo t do. trung ha lng axit bo t do
c trong 1 gam mt loi cht bo (G) th cn cng 7miligam KOH. X phng ha hon ton 10 kg cht bo G
trn th ngi ta cn dng 1,42 kg NaOH. Sau khi phn ng xy ra hon ton ngi ta trung ha lng NaOH
cn d bng 500ml dung dch HCl 1M. Sau cc phn ng trn ta thu c x kg Glixerol v y kg x phng
nguyn cht. Gi tr ca x v y l:
A. 1.035 kg v 10,3425 kg
B. 3,105kg v 11.3744 kg
C. 1.035kg v 10,4561 kg
D. 3.105 kg v 10.145 kg
Cu 47: Cho 0,1 mol cht X (CH6O3N2) tc dng vi dd cha 0,2 mol NaOH un nng thu c cht kh lm
xanh giy qu tm m v dd Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l:
A.8,5
B.12,5
C.15
D.21,8
Cu 48: Cho cc cu sau:
(1) PVC l cht v nh hnh.
(2) Keo h tinh bt c to ra bng cch ha tan tinh bt trong nc.
(3) Poli(metyl metacrylat ) c c tnh trong sut, cho nh sng truyn qua.
(4) T lapsan c to ra do phng php trng hp.
(5) Vt lin compozit c bn, nhu nhit tt hn polime thnh phn.
(6) Cao su thin nhin khng dn in, c th tan trong xng, benzen v c tnh do.
(7) T nitron bn v gi nhit tt nn thng c dng dt vi may o m.
S nhn nh khng ng l :
A.2.
B.3.
C.4.
D.5.
Cu 49. Amino axit X c cng thc H 2N CxHy (COOH)2. Cho 0,1 mol X vo 0,2 lt dung dch H 2SO4 0,5M,
thu c dung dch Y. Cho Y phn ng va vi 100ml dung dch gm NaOH 1M v KOH 3M thu c dung
dch cha 36,7 gam mui. Phn trm khi lng ca nito trong X l :
A. 11,966%.
B. 10,687%.
C. 10,526%
D. 9,524%.
Cu 50: Nung nng hn hp cht rn A gm a mol Mg v 0,25 mol Cu(NO 3)2, sau mt thi gian thu c cht
rn X v 0,45 mol hn hp kh NO2 v O2. X tan hon ton trong dung dch cha va 1,3 mol HCl, thu c
dung dch Y cha m gam hn hp mui clorua, v thot ra 0,05 mol hn hp kh Z gm N 2 v H2, t khi ca Z so
vi H2 l 11,4. Gi tr m gn nht l
A.82.
B. 74.
C. 72.
D. 80.

Trang 24

P N

P N 2
1B
2B
3D
4D
5A

6C
7D
8A
9A
10B

11D
12C
13C
14B
15C

16D
17C
18A
19C
20C

21C
22B
23D
24C
25D

26D
27A
28A
29B
30C

31C
32A
33A
34A
35C

36D
37C
38B
39D
40C

41C
42A
43A
44D
45A

46A
47D
48D
49D
50C

Cu 1:
- tn ti dung dch, cc ion trong dung dch phi khng c phn ng vi nhau loi A v D v OH- to kt ta vi Mg2+.
-p dng bo ton din tch nNO3 = 0,1 + 0,2.2 + 0,1 0,2 = 0,4mol.
-p dng bo ton khi lng: mmui = mcation + manion = 0,1.39 + 0,2.24 + 0,1.23 + 0,2.35,5 + 0,4.62 = 42,9 gam
Cu 2: Nh Tc dng vi H2O gm kim loi nhm IA; cc kim loi Ca, Ba, Sr nhm IIA.
Cu ny s l: K, Ba, Na, Ca, Li
Cu 4. Ch c isaccarit v polisaccarit thu phn cn monosaccarit th khng.
Cu 5: Ta c: nCO (p) = nO (trong oxit) = 0,25 mFe = mhh oxit mO = 20,8 0,25.16 = 16,8 gam.
Cu 6: Da vo cu hnh e thy X l kim loi in hnh (nhm IA), Y l phi kim in hnh (nhm VIIA) lin kt gia X
v Y l lien kt ion.
Cu 7: Dung dch c pH > 7: CH3NH2, CH3COONa, H2NCH2CH2CH2CH(NH2)COOH v K2CO3.
Cu 8: T nhn to xut pht t polime thin nhin ( xenlulozo) nhng c ch bin thm bng phng php ho hc
T xenluloz ch to ra t visco, t axetat.
Cu 9: -Phn ng: R(NH2)COOH + HCl R(NH3Cl)COOH.
- na.a = nmui = 0,1 Mmui = 11,15/0,1 = 111,5 = R + 97,5 R = 14 (CH2)
Amino axit l CH2(NH2)COOH (glyxin).
Cu 10: -Nhm ankyl c nh hng lm tng mt electron nguyn t Nit do lm tng lc baz, cng nhiu nhm
ankyl lc baz cng mnh; nhm phenyl (-C6H5) lm gim mt electron nguyn t Nit lm gim lc baz; cng nhiu
nhm phenyl lc baz cng yu.
-Lc baz: C6H5NH2 < NH3 < CH3NH2 < CH3NHCH3.
Cu 11. CH3COOH l axit yu v l cht in li yu.
Cu 12. Bc ca amin c tnh bng s nguyn t H trong phn t NH 3 b thay th bi gc hirocabon ( hoc bng s gc
hirocacbon gn vi N) Amin bc 2 l CH3NHCH3.
Cu 13: Cho t t NaOH vo cc ng phenol c cha vi git phenolphthalein
NaOH + C6H5OH C6H5ONa + H2O
Khi lng NaOH d th cc bt u chuyn sang mu hng. ( phenol phtalein s ha hng trong dung dch c mi trng
bazo)
Cu 14: Khi lng mt mc xch l: 400000/4000 = 100. [-CF2 - CF2-] = 12.2 + 19.4 = 100
Cu 15: i t Li Cs bn knh nguyn t tng dn
Kim loi
Li
Na
K
Rb
Cs
Bn knh nguyn t (nm)
0,123
0,157 0,203 0,216 0,235
Cu 16. Gly-Ala l i peptit khng c phn ng mu biure nn dung Cu(OH)2 nhn ra Gly-Ala-Val (sn phm c mu tm).
Cu 17. Phng trnh hon chnh: 4Mg + 10HNO3 4Mg(NO3)2 + N2O + 5H2O Tng h s = 24.
Cu 18. Hg c v d bay hi. S d dng kt hp vi Hg ngay nhit thng to mui rn HgS khng c.
Cu 19. -Dng Cu(OH)2 nhit thng chia cc cht cn nhn bit thnh 3 nhm:
+ Nhm to phc mu xanh lam m: glucoz, saccaroz (nhm I).
+ Nhm khng phn ng (khng ho tan Cu(OH)2: anhit axetic.
+ Nhm c phn ng to dung dch mu xanh: axit axetic.
-Dng Cu(OH)2 un nng nhn vi 2 cht trong nhm I nhn ra glucoz do to kt ta gch Cu2O.
Cu 20. Cc amin mun to kt ta vi dung dch Br 2 phi c N gn trc tip vi vng benzen v t nht 1 trong cc v tr ohoc p- so vi nhm amin khng c nhnh.
Cc cu to tho mn: C6H5NHCH3; C6H4(NH2)CH3 (3 ng phn o-; p-; m-).
Cu 21. Cc N2 c to ra N2:
(2). NH4NO2 N2 + 2H2O
(4). 2NH3 + 3Cl2 N2 + 6HCl
(6)2NH3 + 3CuO 3Cu + 3H2O + N2
Cu 22. ch cn nm c cch ph v lin kt trong phn ng thu phn khng hon ton.
- Loi A, D v khng to c Glu Gly.
- Loi C v khng to c Ala Gly.
Cu 23: Phn t HCl c to thnh t 1 nguyn t H v 1 nguyn t Cl. V H c 3 loi ng v nn c 3 hng la chn;
Cl c 2loi ng v nn c 2 hng la chn s phn t HCl l 2.3 = 6.
Cu 26. im khc bit c bn gia Al v Cr l Al ch c ho tr III cn Cr tu thuc cht oxi ho tham gia phn ng c th
to thnh Cr(II) hoc Cr(III).
Cu 28. Cc ion mui phn ng c vi Fe phi nm sau cp Fe2+/Fe trong dy in ho.
Cu 29. Phn ng ln t xy ra nh sau:
H+ + CO32- HCO3- sau : H+d + HCO3- CO2 + H2O
0,1 0,1
0,1
0,2
0,2
0,2
VCO2 = 4,48 lt.

Trang 25

Hoc ta dng cng thc tnh nhanh: nCO2= nH+ - nCO32-.

Cu 30: p dng bo ton e: 3nAl = 2nH2 = 0,045.2 nAl = 0,03.
mAl = 0,81 gam mAl2O3 = 2,04 gam %mAl2O3 = 71,58%.
Cu 31.p dng bo ton e: 1.nFeSO4 = 5nKMnO4 = 0,05mol mFeSO4 = 7,6 gam mFeSO4 = 2,4 gam %mFe2(SO4)3 = 24%.
Cu 32. nBaSO4 = 0.03 v nBa2+ trong dung dch = 0.01 mol BaCl2 = 0.04 (mol) mBaCl2 = 8.32 gam.
Cu 33. C: nCO2 = 0,2 mol; nOH- = 0,3mol nOH- / nCO2 = 0,3 / 0,2 = 1,5 < 2
Phn ng to hai mui HCO3- x (mol) v CO32- y (mol).
nCO32- = nOH- - nCO2 y = 0.3-0.2 = 0.1
bo ton mol cacbon n HCO3- = 0.1
Ca2+ + CO32- CaCO3
0,1
0,1
0,1
Vy khi lng jkt ta thu c l: mCaCO3 = 0,1.100 = 100 gam.
Cu 34: Cc phng trnh phn ng xy ra l:
KNO3 KNO2 + O2 (1)
0,1
0,05
Cu(NO3)2 CuO + 2NO2 + O2 (2)
2NO2 + O2 + H2O 2HNO3 (3)
Ta thy t l phn ng ca kh phng trnh (3) ng bn t l kh sinh ra phng trnh (2) nn ta coi nh ton b kh ca
phng trnh 2 sinh ra b hp th ht, cn li 1,12 lit kh sinh ra l O 2 ca phng trnh (1) m KNO3 = 10,1 gam mCu(NO3)2
= 18,8 gam %mCu(NO3)2 = 65,05%.
Cu 35:
Mnh ng l (1), (2), (3), (5)
(1) Nuc cng c cha nhiu ion Ca2+, Mg2+.
(2) C th lm mm nc cng ton phn bng dung dch K2CO3.
Nc cng ton phn gm c nc cng tm thi v nc cng vnh cu. Dung dch Na2CO3 cng c dng lm mm
nc cng theo phng trnh: M2+ + CO32- MCO3
(3) Phn bit nc cng tm thi v nc cng vnh cu bng cch un nng.
un si nc cng tm thi to kt ta, nc cng vnh cu khng to kt ta: M2+ + 2HCO3- MCO3 + CO2 + H2O
(4) lm mm nc cng tm thi bng dung dch HC1. M(HCO3)2 + HC1 CaCl2 + CO2 + H2O
nn HC1 khng lm gim tnh cng ca nc
(5) Dng NaOH va lm mm nc cng tm thi. M(HCO3)2 + 2NaOH Na2CO3 + MCO3 + H2O
Cu 36.
Cng thc cu to ca Y: H4NOOC COOH3NCH3
Cng th cu to ca X : H2N-CH2CO-NH-CH2COOH.
- Cho X tc dng vi NaOH, ch c Y to kh:
H4NOOC COOH3NCH3 + 2NaOH NH3 + CH3NH2 + (COONa)2 + 2H2O
Ta c: nNH3 + nCH3NH2 = 0,12 ny = 0,06 My = 8,28 gam Mz = 19,8 gam nz = 0,15 mol
Cho 28,08 gam X tc dng vs HCl thu c cc cht hu c theo s :
H4NOOC COOH3NCH3 (COOH)2 + NH4Cl + CH3NH3Cl
H2N-CH2CO-NH-CH2COOH + H2O + 2HCl 2 ClH3N-CH2COOH.
( lu : NH4Cl ) khng phi l hp cht hu c.
m= m(COOH)2 + m CH3NH3Cl + m cht hu c = 0,06.90 + 0,06.67,5 + 0,3 . 111,5 = 42.9 gam
Cu 37. - mui thu c c phn ng trng bc phi c mui ca axit fomic HCOOONa loi D
- Ancol Z thu c c phn ng ha tan Cu(OH)2 Z c cha t nht 2 nhm OH lin k loi A
- nhn thy nZ = neste =0,1 MZ = 62 Z l CH2OH- CH2OH chn C
Cu 38. 3CH3CH2OH+ K2Cr2O7 + 4H2SO4 3CH3CHO + Cr2(SO4)3 + K2SO4+ 7H2O
Cu 39.
- Khi X tc dng vi NaOH d th cho mt mui v mt andehit nn X l este c chc COO- lin kt trc tip vi C ni
i u mch X l C6H5-COO-CH=CH2
- Y tc dng vi NaOH th cho hai mui v nc nh vy Y l este ca hp cht phenol Y l CH2=CH-COOC6H5.
Cu 40. - Ta c hn hp kh D gm NO2 v NO. T khi so vi H2 l 18,2.
Da vo s ng cho nNO2 / nNO = 2/3
mol hn hp = V /22.4 . Ta chia thnh 5 phn mi phn = V/22.4x5 = V/112
NO2 chim 2 phn v NO chim 3 phn.
nNO= 3V/112 v n NO2 = 2V/112 Cng thc nNO3- to mui = 3 n NO + n NO2 = 11V/112
Vy mmui = mKL + mNO3- = m + 62.
- Bo ton khi lng: m mui = m kim loi + 62 ne = m + 62(11V/112 ) = m + 341V/56
Ghi nh: cng thc tnh mui: m mui = mKL + 62(3nNO3 + nNO2 + 8nN2O + 10nN2)
+) Nu c s to thnh NH4NO3 th cng thm vo mNH4NO3 c trong dung dch sau phn ng.
Cu 41. nhit thng H2S b oxi khng kh oxi ha thnh S: H2S + O2 H2O + S
Cu 42. nNaOH = 3n
este ba chc. T y kt hp p n th ta c este ca glixerol.
este
Thu phn hon ton 4,36 g X cn 0,06 mol NaOH

Trang 26

4,92
=82 Maxit=60 CH3COOH
0, 06
9,86
Cu 43. n hn hp Mg, Zn <
= 0,41 < n H2S04 = 0,43 mol
24
Mmui=

Mg, Zn tan ht, d H2SO4 Thu c dung dch gm Mg2+ (x mol); Zn2+ (y mol) ; H+ d (z mol) ; SO42- 0,43 mol.
Bo ton in tch: 2x + 2y + z = 2x0.43 = 0.86 mol
Khi cho OH- vo: Mg2+; Zn2+; H+ va ht cn nOH- = 2x + 2y + z = 0,86 mol < 0,96 mol OH- dng
cn 0,1 mol OH- dng ha tan Zn(OH)2
TH1. Kt ta ch gm BaSO4 v Mg(OH)2. Zn(OH)2 tan hon ton.
cht rn gm BaSO4 0,06 mol v MgO mMgO = 26,08- 0,06.233=12,1 gam nMgO = 0,3025 mMg = 7,26 gam
TH2. Kt ta gm BaSO4, Mg(OH)2 v Zn(OH)2 cn d. ( OH- to ta Zn(OH)2 sau kt ta tan mt phn.)
Cc phn ng: Ba2+ + SO42- BaSO4 ( tnh theo mol Ba2+)
H+ + OH- H2O
Mg2+ + 2OH- Mg(OH)2
Zn2+ + 2OH- Zn(OH)2
Zn(OH)2 + 2OH- ZnO22- + 2H2O.
0.05
0.1
Vy m ta = mBaSO4 + mMg(OH)2 + mZn(OH)2 cn li.
M rn = mBaSO4 + mMgO + mZnO
(1). m hh = 24x + 65 y = 9,86
(2). m rn = mBaSO4 + mMgO + m ZnO = 233.0,06 + 40x + 81(y 0.05) = 26.08
40x + 81 y = 16.15
Gii ra: x = 0.383 v y = 0.01 ( ta thy kt qu y < 0.05 : v l).
Nu khng thy c s v l ta c th da vo kt qu mMg = 0.383.24 = 9.192 ( khng c p n)
Cu 44. Ta c: nFe2O3 = 0,1 nFe(NO3)2 = 0,3 m = 0,2.242 = 48,4 gam.
Cu 45. bo ton khi lng v bo ton e ta c:

nO =

b A
22, 4(b a )
= nH2 V =
16
16

Cu 46
- p n A, B: c Cu v Ag u phn ng.
- p n C: c Cu v Ag u khng phn ng.
- p n D: Cu phn ng, Ag khng.
Cu 47.
-Hn hp kh gm H2 v H2S. Theo t khi v s ng cho ta c nH2 : nH2S = 4:1.
Fe
+
S
FeS
a
b
x
x
x
a-x
b-x
x
Khi ha tan vo HCl th Fe v FeS phn ng ln lt to ra H2 v H2S
nH2 + nH2S = nFe du + nFeS = a - x + x = nFe = a
T suy ra: nH2 = 0,8a
nH2S = 0,2a = x = nS phn ng = nFe phn ng.
* Nu hiu sut tnh theo Fe: H% = (nFe phn ng/ nFe u).100% = (0,2a/a).100 = 20% 50% ( bi)
==> Hiu sut phi tnh theo S.
H % = (nSp /nS u).100 = 50%
nS u = 2nS p = 0,4a = b.
Vy t l = a: b = a: 0,4a = 5:2
Cu 48. Ta quy v bi ton sau:
TN1. Cho 150ml dung dch Ba(OH)2 1M vo 250 ml dung dch Al2(SO4)3 x M c 42,75 gam kt ta.
TN2. CHo 350 ml dung dch Ba(OH)2 1M vo 250 ml dung dch Al2(SO4)3 x M c 94,2375 gam kt ta.
Ta thy: Khi dng lng bazo t 350ml so vi 150 ml gp 2.33 ln nhng lng kt ta ch gp 2.2 ln
iu chng t TN2. C mt lng Al(OH)3 b tan mt phn trong bazo d.
c 3 phn ng xy ra: Ba2+ + SO42- --> BaSO4
(1)( do Ba(OH)2 d nn (1) tnh theo SO420.75x
0.75x
3OH- + Al3+ --> Al(OH)3
(2)
OH- + Al(OH)3 --> AlO3- + H2O (3).
ADCT: nOH- = 4nAl3+ - n Al(OH)3 --> nAl(OH)3 = 4nAl3+ - nOH- = 4.0.5x - 0.7
m = 233.0,75x + 78(4. 0,5x - 0,7) = 94,2375 ==> x = 0.45
Cu 49: Ta d dng xc nh oligopeptit l pentapeptit.
-Theo bi cha 2 gc Gly, 1 Ala, 1 Val v 1 Tyr.
-Do thu phn khng hon ton thu c Gly Val v Val Gly nn trong X phi cha hm Gly Val Gly.
-Cc cu to tho mn:

Trang 27

Gly Val Gly - Ala Tyr

Gly Val Gly - Tyr Ala
Ala Tyr Gly Val - Gly
Tyr Ala Gly Val Gly
Tyr Gly Val Gly Ala
Ala Gly Val Gly Tyr
Cu 50: p n C
ng v c cc cp ta kt ta l (1), (2), (3), (4), (5), (6), (8), (9)
(1) Pb(NO3)2 + H2S PbS + 2HNO3
(2) Pb(NO3)2 + CuCl2 Cu(NO3)2 + PbCl2
(3) 2H2S + SO2 2H2O + 3S
(4) 2FeCl3 + H2S S + 2FeCl2 + 2HCl
(5) AlCl3 + 3NH3 + 3H2O Al(OH)3 + 3NH4Cl
(6) 3NaAlO2 + AlCl3 + 6H2O 4Al(OH)3 + 3NaCl
(7) FeS + 2HCl FeCl2 + H2S
( khng thu c ta)
(8) Na2SiO3 + 2HCl 2NaCl + H2SiO3 ( l cht khng tan)
(9) NaHCO3 + Ba(OH)2 d 2BaCO3 + NaOH + 2H2O
c 8 phn ng to kt ta.

P N 3
1A
2B
3D
4C
5C

6B
7C
8C
9D
10B

11A
12C
13B
14C
15A

16D
17A
18A
19D
20B

21C
22D
23A
24D
25C

26D
27B
28D
29A
30B

31C
32D
33B
34C
35A

36C
37B
38B
39C
40D

41B
42C
43A
44A
45B

46A
47A
48A
49B
50C

Cu 1.A
Da vo cu hnh e lp ngoi cng thy: X,Y,G ln lt thuc nhm IIIA, VA v VIIA ca cng chu k.
(Ngang teo, dc to) : Bn knh gim , kim loi gim, m in tng, nng lng ion, Phi kim tng.
Trong chu k, theo chiu tng dn ca in tch ht nhn, tnh phi kim tng dn, tnh kim loi gim dn, m in
tng dn, nng lng ion ho tng dn.
Cu 2. B
(A,C,D) Khi phn ng vi HI to ra hp cht Fe(III), khi s c phn ng tip 2Fe 3+ +2 I- --> 2Fe2+ + I2 (l phn ng oxi
ha kh).
phn ng vi HI khng l phn ng oxi ho kh th cht phn ng phi l hp cht st(II) v sn phm ch thu
c l FeI2.
Cu 3. D
Bo ton e: 3Al = 3NO + 8N2O + 8NH4NO3 --> nNH4NO3 = 0.05
mol HNO3 phn ng = 4NO + 10 N2O + 10 NH4NO3 = 1.9
nol HNO3 b kh ( c s oxi ha thay i) = nNO + nN2O + nNH4+ = 0.35
Cu 4. C
Cc cht lng tnh gm: Ca(HCO3)2, (NH4)2CO3, Al(OH)3, Zn(OH)2.
Cu 5: C
2KMnO4 + 16HCl => 2KCl + 2MnO2 + 5Cl2 + 8H2O ( 1 mol HCl --> 0.3125 mol Cl2)
PbO2 + 4HCl => PbCl2 + Cl2 + 2H2O
( 1 mol HCl --> 0.25 mol Cl2)
CaOCl2 + 2HCl => CaCl2 + Cl2+ H2O
( 1 mol HCl --> 0.5 mol Cl2)
K2Cr2O7 + 14HCl => 2KCl +CrCl3 + 3Cl2 + 7H2O
( 1 mol HCl --> 0.2143 mol Cl2)
Cu 6: B
CH3OH khng phn ng to anken ( v mch ch c 1 cacbon)
2 ng phn ca C3H7OH tch nc ch to ra anken C3H6 duy nht.
T 3 ancol, s ng phn ete thu c l : AOA, BOB, COC, AOB, AOB, AOC ( 6 ete)
Cu 7: C
O2 : To Fe3O4 ; HNO3; H2SO4 c nng v AgNO3 to hp cht st(II) v st (III) tu thuc vo t l mol ca Fe v cc cht em phn
ng.

Cu 8: C
Cu + HNO3 --> Cu(NO3)2 + NO + H2O
Cu + HCl + NaNO3 --> CuCl2 + NaCl + NO + H2O ( do c Cu + H+ + NO3-)
Cu + HCl + Fe(NO3)3 --> CuCl2 + FeCl3 + NO + H2O ( do c Cu + H+ + NO3-)
Nhit phn Fe(NO3)3 --> Fe2O3 + NO2 + O2
Nhit phn 4HNO3 --> 4NO2 + O2 + H2O
Cu 9: D
- Sau phn ng cn kim loi d => khng tn ti Fe3+ trung dung dch sau: loi A, C
- Dung dch sau gm 3 kim loi : Vy l Ag, Cu v 1 kim loi cn d --> v cn kim loi d nn Cu(NO 3)2 phn
ng ht --> trong dung dch khng cn Cu(NO3)2 --> loi B.
Cu 10: B
H2SO4 lm kh kh no m khng phn ng c vi H2SO4.
A.
Sai v HBr, HI (c tnh kh mnh) : Kh S6+ trong H2SO4 to ra SO2 ; NH3(c tnh bazo) c phn ng vi H2SO4
c to mui.
C.
Sai v HBr, HI, H2S (c tnh kh mnh) c phn ng vi H2SO4 c to ra SO2
D.
Sai v SO3 b hp th bi H2SO4 to oleum
Cu 11: A
(RCOO)2C2H4; (RCOO)2C2H4; RCOO-CH2CH2-OOC-R; RCOO-CH2-CH2OH;RCOO-CH2-CH2OH.
Cu 12: C
(1) nh s mch chnh t phi sang tri v s gp nhnh v tr 2 v 3 ;
(2)Nu nh t tri qua phi s gp khnh 2 v 4.

Trang 28

n s u tin nh s theo cch 1. => 5 brom 2 clo 3,3 imetyl hexan

Cu 13: B
V m kn nn ch c lp thic bn ngoi tip xc vi mi trng in li. ( ch c 1 in cc tip xc vi mi
trng .li ) ==> khng xy ra n mn in ha.
Cu 14. C.
(1), (2), (3). Xy ra theo hai giai on.
Cu 15: A
Do H2SO4 d nn mui to thnh l mui axit: c ngha l ch phn ng vi 1H+ trong H2SO4.
Ta c 0,1 mol Ala Gly Lys phn ng vi 0,2 mol H2O v 0,4 mol H2SO4
( 2 lin kt peptit cn 2 mol H2O, c 4 nhm NH2 ( Lys c 2 nhm NH2) cn 4 mol H2SO4)
Theo bo ton khi lng:
mmui = mAla Gly lys + mH2O + mH2SO4 = 0,1.(89 + 75 + 146 2.18) + 0,2.18 + 0,4.98 = 70,2
Cu 16: D
Cht hu c c hai lin kt i v c ng phn hnh hc c hai v tr ny =>
c cc ng phn cis cis, trans trans, cis trans, trans cis.
Cu 17: A
Cu 18: A
Cc cht hu c n chc c M = 46 gm C2H5OH; CH3OCH3; HCOOH.
- C2H5OH ch tc dng vi Na.
- HCOOH ch tc dng vi Na,NaOH,NaHCO3,AgNO3 trong NH3.
CH3OCH3 khng tc dng vi cc cht. s phn ng l 5.
Cu 19: D
Zn(OH)2, Cu(OH)2, Ag2O u tan ht trong dung dch NH3 to thnh dung dch phc.
Cu 20: B
Lu : C 2 electron ha tr s hnh thnh 1 lin kt cng ha tr.
C c 4 electron ha tr, H c 1 electron ha tr
Nu 1 ankan c cng thc phn t CnH2n+2 th s electron ha tr s l: 4n + 2n+2 = 6n+2 --> s lin kt : 3n+1
Theo : 3n + 1 = 16 => n = 5
Ankan C5H12 th monoclo thu c 4 sn phm th ==> cng thc ankan l: CH3CH(CH3)CH2CH3
s nguyn t C bc 1 l 3 (u nhm CH3)
Cu 21: C
- Nu trong vng benzen c nhm th y e, kh nng phn ng th d hn benzen.
- Nu trong vng benzen c nhm th ht e, kh nng phn ng th trn vng benzen gim.
Nhm NO2 ht e mnh nn kh nng th s kh nht, CH3- y e nn kh nng th s d nht.
Cu 22: D
Cng hng (1,2), (2,1), (1,4). Trong hp cht cng 1,4 c ng phn hnh hc.
Cu 23: A
Cc cht Na2CO3, NaOH, v CH3COONa u c tnh baz.
Tnh axit ca cc axit tng ng cnh yu th hp cht ca n vi Na cng mnh.
Nu so snh tnh axit
: CH3COOH > H2CO3 > H2O
Bazo lin hp
: CH3COO- < HCO3- < CO32- < OHDung dch bazo:
CH3COONa < NaHCO3 < Na2CO3 < NaOH.
pH
pHCH3COONa (3)< pHNa2CO3 (1) < pHNaOH (2)
Cu 24. Nc cng
ton2+phn c Ca 2+, Mg 2+, HCO3 -, Cl -, SO42-. Khi un nng ch c HCO 3 - phn hu to thnh CO32-
2+
kt ta 1 phn Ca , Mg ,
Dung dch sau khi un nng vn cn:c Ca 2+, Mg 2+, Cl -, SO4 2- l nc cng vnh cu. Vy tnh cng gim.
Lu kt lun: * Cho nc cng tm thi khi un nng th mt hon ton Ca 2+, Mg 2+ thu c nc mm.
* nc cng vnh cu khi un nng th Ca 2+, Mg 2+ khng b kt ta, tnh cng khng gim.
* Nc cng ton phn khi un nng th cng gim.
Cu 25. C
Nhm NO2 ht e mnh --> tnh axit mnh.
Cu 26: D
X: Cl2
Y:H2S
Z: SO2
G: NH3
Cu 27: B
(C6H10O5)n => nC6H12O6 => 2nC2H5OH => 2nCH3COOH => 2nCH3COOC2H5
0.5mol <-1 mol
HS chung: H = 504/1003 = 6.25%
Vy m tinh bt = 162.0, 5.

100
1296
6.25

Cu 28. D
Gii ra: p = 13, n = 14
A. Z = p = 13 . R l nguyn t nhm.
C. S ht khng mang in n = 14
B. A = p + n = 14
D. Trong ht nhn s ht mang in l p = 13
Cu 29. A.
nHCl = 4 nO2
Cu 30. B.
A. to 1 mol Ag v cn Cu d cha tan.
C. 1 mol Al2O3 cn 2 mol NaOH -> cn 0.5 mol Al2O3 cha tan.
D. c to ta BaCO3.
(B). Fe2O3 tan trong HCl to 2 mol FeCl3, 2 mol FeCl3 hon tan va 1 mol Cu.
Cu 31: C
NNaOH = 3neste => este X c 3 chc. Bo ton khi lng c
meste = 24,6 + 0,1.92 0,3.40 = 21,8g ==> MC3H5(OOCR)3 = 218 => 3R = 45.
TH1. R1 = R2 = R3 = 15 ( CH3 -) c 1 cht
TH2. R1 = 1 (H); R2 = 15 (CH3); R3 = 29 (C2H5) c 3 ng phn.
TH3. R1 = 1(H); R2 = 1(H); R3 = 43 ( C3H7) dng mch thng : 2 ng phn.
TH4. R1 = 1(H); R2 = 1(H); R3 = 43 ( C3H7) dng mch nhnh: 2 ng phn.
Tng s cht l 8.
Cu 32: D
S mol cc cht: n Fe3O4 = 0,16 mol; n BaCO3= 0,22 mol = nCO2
Fe: 0.48

CO2 : 0.22

Trang 29

+ CO
O : 0.64

Fe : 0.48
O: 0.42
+ H2SO4 --> Fe3+ + SO42- + SO2 + H2O
Bo ton e: 3Fe = 2 SO2 + 2O
==> 3.0,48 = 2a + 2.0,42 ==> a = 0.3 => V = 6.72 lt
Cu 33: B
Ancol anlylic v andehit propionic: C3H6O ( x mol).
Axit acrylic v vinyl fomiat: C3H4O2 ( y mol).
58x + 72y = 18,8 v 3x + 3y = n CO2 = n CaCO3 = 0,9 mol
x = 0,2; y = 0,1
n H2O = 3n C3H6O + 2n C3H4O2 = 0,8 mol
gim khi lng dd Ca(OH)2 l: mdd = mCO2 + mH2O - mCaCO3 = -36 gam
Cu 34: C
nCO2 = 0.25 mol ; Dung dch X gm Ba2+ 0,1 mol, Na+ 0,2x mol, Cl- 0,2 mol v OH- 0,2x mol.
V CO2 phn ng ht nn thu c dung dich cha
Ba2+ 0,1 mol, Na+ 0,2x mol, Cl- 0,2 mol
v 0,25 mol hn hp HCO3- v CO32 thu c lng kt ta ln nht khi n CO22- 0,1 mol = mol Ba2+
Khi nCO32- = 0,1 th mol NaOH dng l nh nht.
Na2CO3 : 0.1
CO2 + NaOH
0.25
NaHCO3 : 0.15
Bo ton mol nguyn t: mol NaOH = 0.35 => CNaOH = 1,75M
Cau 35. A
S mol cc cht: nFe = 0,2 mol
mol H+ = 0.6 , mol NO3- = 0.2 ; mol SO42- = 0.2 mol
+
3+
Fe + 4H + NO3 --> Fe + NO + 2H2O
0.15 0.6 0.15
0.15
2Fe3+ + Fed --> 2Fe2+
0.1
0.05
Qua hai phng trnh trn ta thy Fe chuyn thnh ion Fe2+ v Fe3+ trong dung dch.
mmui = mFe + mSO42- + mNO3- d = 56.0,2 + 96.0,2+62.0,05 =33.5 gam
Cu 36. Chn C.
Hn hp sau gm 2 kim loi: V vy bt buc hai kim loi phi l: Cu v Fe d v kim loi Mg phi tan ht.
(1). Mg + Cu2+ => Mg2+ + Cu
x
x
Mg tan ht th Cu2+ phi va hoc d: z x (*)
Sau phn ng (1). Cu2+ d = z - x
(2). Fe + Cu2+ => Fe2+ + Cu
z-x z - x
Fe cn d : y > z -x => z < x + y
(2*)
Kt hp (*) v (2*) ta c iu kin ph hp:
x z<x+y
Cu 37: B
Cc hn hp c th tan ht l A;C; E.
Hn hp A: Na + H2O => NaOH + 1/H2 ; Al + H2O + NaOH => NaAlO2 + 3/2 H2
Hn hp C: Cu + Fe2(SO4)3 => CuSO4 + FeSO4.
Hn hp E: H+ ( 2 mol) ; Cu ( 1 mol), Fe3+ ( 2 mol)
Cu + 2Fe3+ --> 2Fe2+ + Cu2+
Cu 38: B
Ta c cng thc: mol H2SO4 = 2nSO2 => nSO2 = 0.075 mol.
T p n ta nhn thy sn phm thu c kh nng to ra Fe2+ ( x mol) v Fe3+ ( y mol).
Biu thc:
+ bo ton mol Fe : x + y = 0.06
+ bo ton electron: 2x + 3y = 2SO2 = 0.15
Gii ta: x = 0.03 => FeSO4 ( 0.03) ; y = 0.03 => Fe2(SO4)3 = 0.15
Cu 39: C
Dung dch sau ha tan c Fe3O4 ==> dung dch sau khi in phn c H+ ==> Giai on (2) l in phn CuSO4 d.
C hai in cc c bt kh th dng in phn : l du hiu bit c mui in phn va ht.
Gi x, y l mol CuSO4 in phn (1) v (2)
CuSO4 + 2NaCl --> Cu + Na2SO4 + Cl2
(1)
x
2x
x
CuSO4 + H2O --> Cu + H2SO4 + 1/2 O2
(2).
y
y
y/2
Fe3O4 + 8H+ => Fe2+ + 2Fe3+ + 4H2O
0.005
0.04
nH+ = 2y = 0.04 => y = 0.02
mol kh = x + y/2 = 0.02 => x = 0.01
Vy m hh = 160 .( 0,01 + 0,02) + 58,5.2.0.01 = 5,97 gam
Cu 40. D
Loi b A, D v hai bnh ny phi cha cc cht khng tc dng c vi Cl 2. M A, D c bnh ng NaOH hay AgNO 3
p vi Cl2.
Trong k thut phi gi li HCl ( kh) trc sau gi li hi nc sau. Nn ta dng bnh ng NaCl trc v bnh
H2SO4 sau.
Cu 41: B

Trang 30

* Khi tc dng vi HCl.

Tng s mol electron m Al v Mg nhng khi tc dng vi HCl: 3Al + 2Mg = 2nH2 = 0.6 mol
* Khi tc dng vi dung dch mui: th tng mol electron nhng cng s l: 0.6 mol.
th t: Ag+ + 1e => Ag
0,4
0,4
0.4
nhn: 0.4 mol
Cu2+ + 2e => Cu
0.1 0.2
0.1
=> Khi lng kt ta l: m = 0,4.108 + 0,1.64 = 49,6g
Cu 42: C
Ancol n chc: RCH2OH a
+ O2 =>
CO2
+
H2O
axit n chc
RCOOH 2a
( cng cacbon)
5.1 gam
0.225 mol
0.2 mol
Bo ton khi lng: c m O2 p = 8,4g => n O2 p = 0,2625 mol
Bo ton nguyn t oxi: nO(X) = 0,125 mol
Gi s mol ancol l a, s mol axit l 2a. Bo ton oxi ta c
a + 2.2a = 0,125 => a = 0,025
CTPT ca ancol v axit: CnH2n+ 2O v CnH2mO2: 0,025n + 0,05n = 0,225 => n = 3
Hai cht l C3H8O v C3HmO2 => 0,025.8 + 0,05.m = 0,2.2 => m = 4 => C3H4O2
Este l CH2=CH-COOC3H7 c m l 114.0,025.80% = 2,28g
Cu 43: A
Ta c pH = 2 => [H+] = 10-2 => nH+ = 10-2 mol = namin = 0,59/0,01 = 59
trong hn hp phi c amin C4H9NH2 => amin cn li l CH3NH2 hoc C2H5NH2
Cu 44: A
S mol cc cht: nMantoz = 0,4 mol; nsaccaroz = 0,1 mol
S phn ng: M => 2G v S => G + F
nG + F = (0,4 + 0,1).0,6.2 = 0,6 mol; nM d = 0,4.0,4 = 0,16 mol.
Phn ng trng bc: G,F,M => 2Ag
nAg = 0,6.2 + 0,16.2 = 1,52 mol => m = 164,16g.
Cu 45: B
CHC-CHO + 3AgNO3 + 4NH3 --> AgCC-COONH4 + 2Ag + 3NH4NO3
Lu : Mc d c n 3 mol AgNO 3 tham gia phn ng nhng ch c 2 mol Ag+ b kh, cn 1 mol Ag+ s th vi H
nn s oxi ha khng i.
S mol AgNO3 b kh = 2 mol Andehit = 0,1.
Cu 46: A
nC3H4 = 0,2 mol; nH2 = 0,28 mol
CH3CH2CHO (x)
2
Hg
CH3 - CCH + H2O
+ AgNO3/NH3 --> Ag: 2x
CH3COCH3 (y)
Gi nC2H5CHO v n(CH3)2CO ln lt l x v y ==> nC3H4 d = 0,2 (x + y)
Khi lng ca kt ta: 208.2x + 147(0,2 x y) =20,4 => 69x + 147y = 9 (1)
nH2 = x + y + 2(0,2 x y) = 0,28 => x + y = 0,12 (2)
T (1), (2) => x = 0,04 ; y = 0,08
=> % propin chuyn ho thnh anehit l = 0,04.100/0,2 = 20%.
Cu 47: A
nAl(OH)3 max = 0,006 mol
Vi V= a ml dung dch Ba(OH) 2 thu c kt ta ln nht.
nOH- = 3n = 0.018 ==> nBa(OH)2 = 0.009 ==> V = 0,045 l = 45 ml.
Khi V = b ml th lng kt ta tam ht
nOH- = 4nAl3+ = 0.024 =>nBa(OH)2 = 0,012 mol => V = 0,06 l = 60 ml.
Cu 48: A
Vi bi ton lin quan ti pha trn

CO32

HCO

vi

H cc bn cn ch tin trnh .

Bi ny rt t t mui vo axit: ( nCO32- = 0.06 ; nHCO3-= 0.03, nH+ = 0.08)

CO32- + 2H+ --> CO2 + H2O
a
2a
HCO3- + H+ --> CO2 + H2O
b
b
Ta c: a/b = 0.06/0.03 = 2 => 2a - b = 0
nH+ = 2a + b = 0.08
Gii ra: a = 0.032 v b = 0.016 . Vy VCO2 = (a+b).22,4 = 1.0572 lt.
Dung dch lc sau: gm CO32- d = 0.06 - 0.032 = 0.028
SO42- d = 0.06
HCO3- d = 0.03 - 0.016 = 0.014

Trang 31

1A
2C
3B
4C
5B
6C
7A
8C
9B
10C

11C
12B
13D
14C
15B
16C
17D
18C
19A
20D
HCO3 : 0,014

21B
22A
23B
24D
25B
26A
27D
28C
29B
30A

31D
32A
33B
34C
35A
36A
37D
38B
39C
40D

41D
42D
43C
44C
45D
46D
47A
48C
49C
50A

OH : 0,06 BaSO4 : 0,06

X CO : 0,028

m 22,254

2
BaCO
:
0,042
Ba
:
0,15

2
SO4 : 0,06

2
3

Chn B
Cu 49: B
(1) Khng c kt ta.
(2) Kt ta l axit picric hay cn c gi l 2,4,6-trinitrophenol.

C6H5OH 3HNO3 C6H 2OH NO2 3 3H 2O

(3) Kt ta l

C17H35COO 2 Ca .

(4) C kt ta trng
(5) C kt ta trng

C6H5OH 3Br2 Br 3 C6H 2OH 3HBr

C6H5NH2 3Br2 Br 3 C6H2NH2 3HBr

(6) Khng c kt ta .
Cu 50. C
Kh c iu ch bng phng php y nc phi l kh khng tan hoc tan rt t trong nc : O2

P N 4
1A
2B
3A
4D
5C
Cu 1: A

6A
7B
8C
9C
10D

11A
12A
13B
14A
15B

16C
17C
18D
19B
20C

21A
22B
23B
24B
25D

26B
27A
28C
29B
30D

31D
32D
33B
34C
35D

36A
37D
38C
39C
40B

41D
42C
43A
44A
45A

46A
47D
48A
49C
50C

hh rn (42 gam)
Cu +
m (g)

AgNO3
0.4 mol

23,65 gam rn Z ( Cu, Au, Zn d)

dd

dd Y + 16,25 gam Zn
Cu2+ :
Ag+ d :
NO3- : 0.4mol

Dd G : Zn2+ : 0.2 mol

nNO3- : 0.4 mol

Bo ton khi lng ln 1:

m Cu2+(Y) + mAg+(Y) + 16,25 = 23,65 + 0,2.65 => m Cu2+ + mAg+ = 20,4 gam.
Bo ton khi lng ln 2.
mCu + mAg+u = 42 + m Cu2+(Y) + mAg+(Y)
mCu = 42 + 20,4 - 108.0,4 = 19,2 gam.
Cu 2: p n B
- n NaOH =0,2 mol X phn ng vi NaOH theo t l 1:2 X l este ca phenol.
RCOOR + 2NaOH RCOONa +RONa +H2O
- Bo ton khi lng: mx =21,0 -8 +0,1.18 = 14,8gam Mx=148 =12x+y +32 (X l CxHyO 2) 12x +y =116 ch c cp
x =9; y =8 ph hp x l C9H8O2 .
- Cc cu to ca X l: HCOOC6H4CH=CH2 ( 3 ng phn)
Cu 3: p n A
Cc cht c lin kt cng ha tr khng phn cc gm: N2 v H2
Cu 4: p n D
- Cng thc cc cht : etilen C2H4; metan CH4; propin C3H4 v vinyl axetilen C4H4. Gi cng thc chung ca cc cht
trong X l CxH4.

Trang 32

V Mx =34 x= 2,5 nx = 0,15 mol

- S t chy:
C2,5H4 2,5 CO2 + 2H2O
0,15
0,375
0,3
m bnh tng = m CO2 + m H2O = 0,375.44+ 0,3.18= 21,9 gam
Cu 5: p n C
Cc hp cht ca st c phn ng oxi ha-kh vi H2SO4 c phi cha Fe cha t n mc oxi ha cao nht +3 gm: Fe,
FeO, Fe(OH)2, Fe3O4, Fe(NO3)2, FeSO4, FeCO3 , v NaBr, KI.
Cu 6: p n A
Cn bng: C6H5CH3 + 2 KMnO4 C6H5COOK + 2 MnO2 + KOH + H O
Cu 7. p n B
Cu hi l thuyt v nhm halogen
B sai v HF c tnh axit yu hn HCl
Cu 8: p n C
Cu 9: p n C
Khi phn ng vi cc cht c tnh oxi ha mnh hn th S th hin vai tr ca cht kh: a, b, d
Cu 10: p n D
mN = 11,864%.70,8 nN = 0,6 mol = nNO3 m NO3- = 37,2g m kim loi = 70,8 -37,2 =33,6
Cu 11: p n A
- nFe2(SO4)3= 0,1 mol
- Nu phn ng gia Zn v Fe3+ xy ra hon tn theo phn ng:
Zn + Fe2(SO4)3 ZnSO4 + 2FeSO4 m dung dch tng (1) = mZn tan = 0,1.65 =6,5 gam < 7,85 gam
0,1
0,1
phi c thm phn ng: Zn
+ FeSO4 ZnSO4 + Fe
dd tng thm 7,85-6,5 = 1,35
x
x
mdd tng(2) = mZn- mFe = (65x-56x) = 1.35 x = 0.14
Vy: m = (0,1 + 0,15) .65 =16,25 gam
Cu 12. p n A
Cc yu t c th lm chuyn dch cn bng ha hc l nhit , nng , p sut. V phn ng c tng h s kh 2 v
bng nhau nn p sut khng lm chuyn dch cn bng
Cu 13. p n B
Lu : Fe(OH)2 v Mg(OH)2 ch c tnh bazo nn loi A, C, D
Cu 14: p n A
- B sai v cng thc ca ure l (NH2)2CO
- C sai v phn m mi cung cp N cho cy dng NO3- v NH4+
D sai v amophot l hn hp ca (NH4)2HPO4 v NH4H2PO4
Cu 15: p n B. Trong cc phn ng a, b v d, C th hin vai tr ca cht oxi ha
Cu 16: p n C
-nCO2 =0,15 mol; n K2CO3= 0,02 mol; nKOH = 0,1x mol.
- Phn ng ca Y vi BaCl2 d:
K2CO3 + BaCl2 BaCO3 + 2KCl
nK2CO3 (Y) = n BaCO3 = 0,07 mol c 0,05mol K2CO3 mi c to thnh
nK2CO3 mi to thnh = nOH- - nCO2= 0.1x 0.15 = 0,05
=> x = 2.
Cu 19. p n B %N=23,3% M amin = 59 amin l C3H9N c 4 ng phn
Cu 20: p n C
Hp cht H2NCH2COOH3NCH3 l mui ca amin ch khng phi este
Cu 21:p n A
Cc tripeptit cha Phe thu c gm:
Pro-gly- phe ; Gly-Phe-Ser ; Phe-ser-Pro;Ser-Pro-Phe ;Pro- Phe Arg
Cu 22: p n B
Cu 23: p n B
V C5H10O2 thuc loi hp cht hu c n chc, khi phn ng vi NaOH to mui v ancol hp cht thuc loi este
Este khng c phn ng trng bc khng c dng HCOOR. Cc cu to tha mn l:
CH3-COO-CH2-CH2-CH3 ; CH3-COO-CH(CH3)2 ; CH3-CH2-COO-CH2-CH3 ; CH3-CH2-CH2-COO-CH3 ; (CH3)2CH-COO-CH3

Cu 24: p n B
Tnh c % mi loi ng v ln lt l : 19% v 81%.
%m 11B = (81%.11) / ( 3 + 10,81 + 16.3)= 14,42%
Cu 25: p n D
- Dung dch thu c cha mt mui mui l Al(NO3)3 v Al phn ng trc.
- Cht rn thu c gm 2 kim loi 2 kim loi l Zn cha p v Ag
Cu 26: p n B
- Bo ton in tch: 3z + 0,12 = t + 0,02.2 -3z +t = 0,08 (1)
- Dung dch Y gm : 0,015 mol Ba2+ v 0,22 mol OH-. Cho Y vo X c cc phn ng:
Ba2+ + SO4 2- BaSO4 (1)
H+ + OH- H2O (2)
Al3+ + 3OH- Al(OH)3
0,015
0,02
0,015
0,12
0,12
m BaSO4 = 3,495 gam m Al(OH)3 = 1,56 gam nAl(OH)3 = 0,02 mol
Sau(2). nOH- cn li = 0.1 mol > 3mol Al(OH)3. Chng t to kt ta v ta tan bt.

Trang 33

ADCT: nOH- = 4Al3+ - n + nH+ nAl3+ = z = 0,03 t = 0,17

Cu 27. p n A
- X tc dng vi NaHCO3 X c nhm COOH loi D v C
- Mui sinh ra c phn ng vi Na mui c nhm OH X c nhm OH
- Hi ca X khng tc dng vi CuO un nng Chng t nhm chc ancol khng l ancol bc 1 hoc 2 m l ancol bc
3.
Cu 28: p n C
Khi lng Fe cn luyn l: 810 tn.
Qung Fe3O4 3Fe
810/56.3 810/56 (T.mol)
mFe3O4 = 232.(810/56.3) = 7830/7 ( tn).
m qung = (7830/7) x (100/98)x(100/75) = 1521,87 tn.
Cu 29: p n B
S mol cc cht: nCr2O3 = 0,2 mol; nH2 = 0,55 mol > 2n Cr2O3 trong X c Al d
( v nu Al khng d, nCr to ra l 0.4 mol nH2 = 0.4 mol).
Cc phn ng :
2Al +Cr2O3 2Cr + Al2O3
0,2
0,4
0,2
Cr + 2HCl CrCl2 + H2
0,4
0,4
Al d + 3HCl AlCl3 + 3/2 H2
0,1
0,15
Vy trong X gm: Al d = 0.1 mol ; Cr = 0.4 mol , Al2O3 = 0.2 mol.
* Nu cho hn hp X tc dng vi NaOH c, nng d. ( Cr s khng phn ng m ch c Al v Al2O3 phn ng).
Al d + NaOH + H2O NaAlO2 + 3/2H2
Al2O3 + 2 NaOH 2 NaAlO2 + H2O
n NaOH = nAl d +2 nAl2O3 = 0,5
Cu 30: p n D
nAlCl3 = 0,4x
dd ban u gm: Al3+ = 0,4x + 0,8y ; Cl- = 1,2x ; SO42- = 1,2y
nAl2(SO4)3 = 0,4y
* Khi cho 400 ml dung dch E + BaCl2 d nBaSO4 = nSO42- = 1,2y = 0,144 (mol)
y = 0,12 mol.
* Khi cho 400 ml dung dch E + NaOH thu c 8,424 gam Al(OH)3 nAl(OH)3= 0,108
Ta thy nOH- = 0,612 > 3 nAl(OH)3 = 3. 0.108
Chng t to ta v ta tan.
ADCT: nOH- = 4nAl3+ - nAl(OH)3
0.612 = 4 (0,4x + 0,8y) 0,108 0,4x + 0,8y = 0,18 x = 0,21
Vy t l x: y = 0,21 : 0,12 = 7:4
Cu 31: p n D
T chn mol Cu(NO3)2 = 1 mol.
Cu(NO3)2CuO +2NO2+1/2 O2
4NO2 +O2 + 2H2O 4HNO3
CuO +CO Cu + CO2
1
1
2

2
1/2
2
1
1
3Cu + 8HNO3
3Cu(NO3)2 + 2NO +4H2O
0,75
2
n Cu phn ng = 0,75 mol %Cu phn ng = 75%
Cu 32: p n D
-Trong 11,64 gam hn hp X c 0,03 mol Cu v 0,09 mol Ag.
-n H2SO4 =0,1; n HNO3 = 0,05 = nNO3-n H+= 0,25
3Cu + 8 H+ +2 NO3- 3Cu2+ +2NO + 4H2O
4Ag + 4H+ + NO3- 3Ag+ + NO +2 H2O
0,03 0,08
0,02
0,02
0,09 0,12
0,03
0,03
n NO = 0,05 mol
4NO +3O2 + 2H2O 4HNO3
0,05 0,1
( O2 d sau phn ng)
n HNO3 = 0,05 mol C HNO3 = 0,1 = [H+] pH =1
Cu 33: p n B
-phn ng cng H2: nH2= 0,05 = 2nx loi C. Mx = 1,625/0,025 =65
- phn ng trng bc: n Ag = 0,1 = 4 nx loi D
- gi s p n B :Gi s mol ca OHCCH2CHO l x; OHCCHO l y
x+ y = 0, 025 v 72x + 58y = 1,625 x = 0,0125; y= 0,0125 tha mn
Cu 34: p n C
%m O = 35,96% Mx = 89 cng thc ca X l: H2N-CH2COOCH3.
H2NCH2COOCH3 + NaOH H2NCH2COONa + CH3OH
CH3OH HCHO 4 Ag
n CH3OH = 1/4 .34,56/108 = 0,08 mol = n x m = 0,08.89 =7,12 gam

Trang 34

Cu 35: p n D
- Mx = 44,8 ; My =49,2
O2 (a mol)
32

3.2

44,8

nO2 / nO3 = a/b = 4a b = 0

O3 (b mol)
48
12,8 4
Gi cng thc chung ca 2 amin l CnH2n+3N. V My =49,2 n = 2,3.

T chn mol cht: Ta t chn mol ca hn hp amin Y = 1 mol

C2,3H7,6N + 8,4O 2,3CO2 + 3,8 H2O
1 mol
8,4 mol
Ta li c : nO = 2a + 3b = 8.4
Gii h phng trnh: a = 0,6 v b = 2,4 tng mol X = a + b = 3
Vy t l V1: V2 = nX + nY = 1:3
Cu 36: p n A
Bi ton v phn ng t chy cc cht hu c.
-Bo ton O ta c: n

H2O

= 2(

) = 0,875 mol

namin(Y+Z) =(nH2O-nCO2)/1,5 =

(Y+Z)

<

= 0,25 mol

=2 C CH3 NH2 (Y)

Cu 37: p n D
Cc ng phn ca este C4H6O2
H COO CH = CH CH3 ; H COO CH2 CH = CH2
H COO C(CH3) = CH2 : CH3 COO CH = CH2
CH2 = CH COO CH3
Cu 41: p n D
Cng thc chung ca hn hp l: C H2
CnH2n-2O2 +
14n + 30
3,42 g

-2

O2.

O2

nCO2 + (n-1)H2O
n
(n-1)
0,18 0.15

n=6
mdd = (mCO2 + mH2O) m = (44.0,18 + 18.0,15) 18 = -7,38 gam
Cu 42: p n C Ch c (Y) tha mn.
Cu 43: p n A
MX =

= 75 X: NH2 CH2 COOH (gly)

+H2O
xt, to
m (gam)

Bo ton mol (Gly) : 3x + 4x =

= 0.135 x =

0.135
7

0.135
= 8,389 gam.
7
Cu 44: p n A. Trong cu to c 2 gc oleat: C17H33COO v 1 gc stearat : C17H35COO
Tng k = 3 ( trong 3 chc este) + 2 ( trong hai gc oleat) = 5.
m gam = (189 + 246)x= (189 + 246)

kX = 3 +2 = 5 nX =

nCO 2 nH 2 O
k-1

a =

b c = 4a

Cu 45: p n A

Ala:

mol

Val:

mol

Trang 35

Gly :

xt, to

Tripeptit + H2O

mol

Tng qut: 3 H2N- R COOH

a mol

Tripeptit + H2O.

H2N R CO NH R CO NH R COOH + 2H2O

2a/3 mol

Tng mol aminoaxit =

= a mol H2O = nHO = .

= 0,4 mol

Bo ton khi lng: mpeptit = ma.a - mH2O = (22,5 + 17,8 + 11,7) 18.0,4 = 44,8 gam
Cu 46: p n A
C 4 cht polime trng ngng l: (4) PPF; (7) nilon-7; (8) poli(etylen-terephtalat); (13) keo dn ure-fomanehit.
Cu 47: p n D
Theo thng bng electron: 3As2S3 + 28HNO3 + 4H2O 6H3AsO4 + 9H2SO4 + 28NO
Cu 48: p n A
Nhn thy khi lng sn phm X tng so vi ancol Z ban u l khi lng ca O2 tham gia phn ng.
no p =
MZ <

mol = nancol p < nancol u (Z)

= 40 Z: CH3OH (metanol)

Cu 49: p n C
CH3NH3NO3 (0,1 mol)

H% =

NaOH (0,2 mol)dd Y

NaOH (0,2 mol)

-CH3NH2

. 100% = 80%
NaNO3 : 0,1 mol
NaOHd:0,1 mol

mrn = 12,5 gam

Cu 50: p n C
NaOH d

Ca2+: x mol
Na+: y mol
HCO3- : z mol
Cl-: 0,1 mol

Ca(OH)2 d

CaCO3 : 0,04 mol = min (x, z)

CaCO3 : 0,06 mol = z

HCO3- + OH- CO32- + H2O.

z
z
Ca2+ + CO32- CaCO3
x
x = 0,04
* Cho Ca(OH)2 d: HCO3- + OH- CO32- + H2O.
z
z
Ca2+ + CO32- CaCO3
z
z = 0,06
* Cho NaOH d:

x = 0,04
y = 0,08
z = 0,06

Khi un si c phn ng: 2HCO3- CO32- + CO2 + H2O

0.06
0.03

Ca2+ : 0,04 mol

Na+: 0,08 mol
un si X n cn Rn khan

; 0,03 mol

= 8,79 gam

Cl-: 0,1 mol

P N 5
Cu 1. p n A
3 ng phn: CH3COOH(1) HCOOCH3 (2) v HOCH2CHO (3)
+ Tc dng vi Na: (1), (3)
+ Tc dng NaOH: (1), (2)
+ tc dng vi NaHCO3 : (1)
Cu 2: p n C.
Mnh ng l (1), (2), (3), (5)

Trang 36

Nc cng ton phn gm c nc cng tm thi v nc cng vnh cu. Cho dd Na2CO3 c phn ng.
M2+ + CO32- MCO3

( M2+ l Mg2+v Ca2+)

(3) un si nc cng tm thi to kt ta theo pt sau, nc cng vnh cu khng to kt ta:

M2+ + 2HCO3- MCO3 + CO2 + H2O
(4) sai: v c phn ng ( khng loi c Ca2+ v Mg2+)
M(HCO3)2 + HC1 CaCl2 + CO2 + H2O
nn HC1 khng lm gim tnh cng ca nc
(5) Dng NaOH va lm mm nc cng tm thi.
M(HCO3)2 + 2NaOH Na2CO3 + MCO3 + H2O
(M l Ca, Mg)
Cu 3. p n B
- Nu 3 gc axit ging nhau c 3 hng chn ng vi 3 ng phn. (R1COO)3C3H5; (R2COO)3C3H5; (R3COO)3C3H5
- Nu 2 gc axit ging nhau v khc vi 1 gc cn li:
R1

R1

R2

R2

R1

R2

R2

R1

R2

R1

R1

R2

Mi cp ta s c 4 ng phn. V d cp R1 v R2

Vy cp R1, R3 4 ng phn.
R2, R3 4 ng phn.
- Nu 3 gc axit khc nhau: c 1 hng chn tng ng vi 3 ng phn.
R1

R1

R2

R2

R3

R1

R3

R2

R3

Cu 4 : p n C
- mui thu c c phn ng trng bc phi c mui ca axit fomic HCOOONa loi D
- Ancol Z thu c c phn ng ha tan Cu(OH)2 Z c cha t nht 2 nhm OH lin k loi A
- nhn thy nZ = neste =0,1 MZ = 62 Z l CH2OH- CH2OH
Cu 5. p n B
X l C6H12O6; Y l C2H5OH; z l CH3COOH
CH3COOH + C2H5 CH3COOC2H3 + H2O
Vy tn gi ca T l etyl axetat.
Cu 6. p n C
-C sai v t enang c sn xut t axit co-aminoenantoic.
-A ng v Xenluloz tan trong dung dch [Cu(NH3)4](OH)2 to cht lng nht dng to t visco
- B ng v (C6H10O5)n+ nH2O C6H12O6

C6H12O6 C2H5OH + 2CO2

D. ng ( tng t B)
Cu 7. p n A
-

Thu phn saccarozota thu c Glucozo + Fructozo

Khi cho tc dng vi lng d AgNO3/NH3 th kt ta thu c Ag.

Ta c nAg= 2(ng +nF) = 4nsaccarozo = 0,8 mol m= 86.4 gam.

- Nu cho ton b sn phm sau thu phn tc dng vi brom th ta c nBr2 = nglucozo = 0.2 mbrom = 32 gam
Cu 8. p n C

Trang 37

 Sai v Crom l kim loi nng, khi lng ring 7,2 gam/cm3
Cu 9. p n B
- Kh nng dn in gim theo trt t: Ag > Cu > Au > AI > Fe.
Cu 10 : p n C
So vi cc nguyn t phi kim cng chu k, cc nguyn t kim loi thng c bn knh ln hn, c t electron lp ngoi cng
hn v d nhng e hn. Do lc lin kt gia ht nhn v e lp ngoi cng ca kim loi nh hn phi kim nn kim loi d
mt e hn
nng lng ion ha nh hn.
Cu 11. p n A
S khi ca cc nguyn t A, B l: MA = 79; MB = 81

79.27 81.23
=79,92
23 27

Cu 12. Chn B.
Cn nm vng v tr cc cp oxi ha kh.

Fe 2 Cu 2 Fe3
;
;
Fe Cu Fe 2
Dy in ha xp theo chiu tng dn tnh oxi ha v gim dn tnh kh.
Chn B. Tnh Oxi ha Fe3+ > Cu2+.
Cu 13. p n D
C V = k.[N2].[H2]3 vi k = hng s.
Khi nhit phn ng khng i
PV
Ta c p sut tng 2 ln nn n =

PV
tng 2 ln
RT

nng cc cht tng 2 ln

N2 (k) + 3H2 (k) 2NH3 (k)

V tng = [N2]1.[H2]3 = 21. 23 = 16. (tnh theo cht tham gia)
Cu 14. p n C
nhit thng H2S b oxi khng kh oxi ha thnh S:
H2S +

1
O2 H2O + S
2

Cu 15. p n B
Xenluloz axetat c ngun gc t xenluloz thuc loi t bn tng hp (nhn to).
Cc em hc sinh cn lu v cc loi t:
Cu 16 : p n C
* da vo phn ng vi HCO3- :
H+ = nHCO3- = nCO2 = 0,5.
C 1H+ c 2O nO(x) = 0,5.2 = 1 mol mO(x)=16 gam
Li c: nH2O=0,8 mol mH=1,6 gam
Bo ton khi lng: mC(x) =29,6-16-1,6= 12 gam
nC(x) =1 mol = nCO2 mCO2=44 gam
Cu 17: p n D
Cu 18. p n C
+ 2 chc andehit (-CH=O) (k=2)
+ 1 lin kt ba ( k =2)

Trang 38

Tng k = 4 ( mt 8 H)
CnH2n+2 -8O2 = CnH2n-6O2
Cu 19. p n A.
A. ng v d N2O5 v P2O5.
B. Sai v N2 c lin kt ba bn. N2 bn hn.
C. Sai v bn knh nguyn t N nh hn, m in N ln hn nn NH3 bn hn PH3.
D. Sai v H3PO4 th hin tnh oxi ha H+
Cu 20. p n D
Ta c: nFe2O3 = 0,1 nFe(NO3)3 = 0,3 m = 0,2.242 = 48,4 gam.
Cu 21. p n B
Dung dch lm qu tm ha mu xanh l (2), (4), (5), (6).
Cu 22. p n A
Ta cn nh: nHCl = 2nO = 4nO2
nH2SO4 = nO = 2nO2
nH2 = nH2SO4 = 1/2nHCl
bo ton khi lng nO =

b A
22, 4(b a )
= nH2 V =
16
16

Cu 23. p n B
CH3 - CH = CH - CH =CH2;CH3-CH = CH2;
CH3 - CH = CH - COOH c ng phn hnh hc.
Cu 24. p n D
Cc cht va c tnh kh, va c tnh oxi ha phi cha nguyn t va c kh nng tng s oxi ha; va c kh nng gim
s oxi ha. FeCl2 , S , SO2, H2O2 cc cht ny u c th b kh v cht c s oxi ha thp hn hoc b oxi ha v cht c s
oxi ha cao hn
Cu 25. p n B
in phn nng chy thng dng iu ch kim loi t Al v u dy in ha.
Cu 26. p n A
Cu 27. p n D
Cc phng trnh phn ng xy ra:
2AgNO3 2Ag + 2NO2 + O2
2Au(NO3)32Au + 6NO2 +. 3O2
2KNO3 2KNO2 + O2
4Fe(NO3) 2Fe2O3 + 8NO2 + O2
4A1(NO3)3 2Al2O3 + 12NO2 + 3O2
2Cu(NO3)2 2CuO + 4NO2 + O2
D. Rn X l CuO v Ag. CuO tan trong HCl
Cu 28. p n C
Cc cht tc dng c vi dung dch Ba(HCO3)2 gm: HNO3, Na2SO4, Ca(OH)2,KHSO4.
Cu 29. p n B
3CH3CH2OH+ K2Cr2O7 + 4H2SO4
3CH3CHO + Cr2(SO4)3 + K2SO4+ 7H2O
Tng h s trc phn ng l 8.
Cu 30. Chn C.
M2CO3 + 2HCl

2MCl + CO2 + H2O

Trang 39

R2CO3 + 2HCl

n CO2

2MCl2 + CO2 + H2O

4,88
0,2 mol
22,4

Tng nHCl = 0,4 mol v

n H 2O 0,2 mol.

p dng nh lut bo ton khi lng ta c:

23,8 + 0,436,5 = mmui + 0,244 + 0,218

mmui = 26 gam.

Cu 31. Chn D.
Cu 32. Chn A.
0,04 mol hn hp A (FeO v Fe2O3) + CO 4,784 gam hn hp B + CO2.
CO2 + Ba(OH)2 d

BaCO3 + H2O

n CO2 n BaCO3 0,046 mol

v n CO ( p.

n CO2 0,046 mol

p dng nh lut bo ton khi lng ta c:

mA + mCO = mB +

mCO2

mA = 4,784 + 0,04644 0,04628 = 5,52 gam.

t nFeO = x mol,

n Fe2O 3 y mol trong hn hp B ta c:

x y 0,04
x 0,01 mol

72x 160y 5,52

y 0,03 mol
0,01 72 101
13,04% %Fe2O3 = 86,96%.
5,52

%mFeO =
Cu 33. Chn B.

Na + H2O
Ba + 2H2O

NaOH +

1
H2
2

Ba(OH)2 + H2

n H 2 = 0,15 mol, theo phng trnh tng s n OH (d 2 X ) 2n H 2 = 0,3 mol.

Phng trnh ion rt gn ca dung dch axit vi dung dch baz l
H+ + OH

H2O

n H = n OH = 0,3 mol n H 2SO4 = 0,15 mol

VH2SO4

0,15
= 0,075 lt (75 ml). (p n B)
2

Cu 34. Chn C
nNO3- to mui = 3NO + NO2 = 0.4 mol.
nSO42- to mui = nSO2 = 0.1
mmui = mk.loi +

m NO + m SO2
3
4

= 12,9 + 62 0,4 + 96 0,1 = 47,3.

Cu 35. p n A
2CnH2n-1O2Na + 2 O2 Na2CO3 + (2n-1)CO2+ (2n - 1)H2O

Trang 40

: n Na2CO3 = 015 n RCOONa = 0,03 mol

MRCOONa = m/mol = 2,6/0,03 =86,67 MR = 19,67
CH3COONa (a mol) v C2H5COONa (b mol)
nhh = a + b = 0,03
a= 0,02
mmui = 82a + 96b = 2,6
b = 0,01
T phng trnh
nCO2 = nH2O =0,02.2 + 0,01.3-0,015 = 0,055(mol)
m = 3,41 (gam).
Cu 36. p n A
nNaOH = 3n este este ba chc. T y kt hp p n th ta c este ca glixerol.
Thu phn hon ton 4,36 g X cn 0,06 mol NaOH 4 92
Mx=218,Mmui=

4,92
=82 Maxit=60 CH3COOH
0, 06

Cu 37. p n D
nCO2 = 0.07 ; nH2O = 0.045 nH = 0.09
nC/nH = 7/9 C7H9N loi A.
V X bc 1 loi B.
V X c phn ng to kt ta vi dung dch Br2 nn c nhm NH2 lin kt trc tip vi vng benzen
Chn D. CTCT: CH3C6H4NH2
Cu 38. Chn B.
pH = 2 [H+] = 0,01 nH+ = 0,002 (mol)
pH = 13 pOH = 1 [OH-] = 0,1 nOH- =0,1V
p trung ha: nH+ = nOH0,1V = 0,002 V = 0.02 lt = 20 ml
Cu 39. Chn C.
3NaOH + AlCl3 Al(OH)3 + 3NaCl
0.3
0.1 0.1
nNaOH d = 0,06
NaOH + Al(OH)3 NaAlO2 + H2O
0,06
0,06
nAl(OH)3 cha tan = 0,04 m = 3,12 gam.
Cu 40. p n D
- Khi X tc dng vi NaOH d th cho mt mui v mt andehit nn X l este ca ancol c nhm -OH lin kt trc tip vi
C ni i u mch
X l C6H5-COO-CH=CH2
- Y tc dng vi NaOH th cho hai mui v nc nh vy Y l este ca hp cht phenol Y l CH2=CH-COOC6H5.
Cu 41. p n D
V Halogen c m in ln nn ht e s lm gim kh nng phn ng ng , tuy nhin trong halogen khng c lin kt
pi nn nh hng nhm th sau ti o,p)
Cu 42. p n D
Ta c: n C(z) = n CO2= 0,5(mol),nH(z) =2nH2O = l,6mol.
mz = 7,6 (gam)
Khi lng bnh brom tng chnh l khi lng ca anken v ankin d. Nh vy ta c: m = manken+ankin + m ankan = 8,4(gam)
Cu 43.
- Ta c hn hp kh D gm NO2 v NO. T khi so vi H2 l 18,2.

nNO 2 2
3V
=
nNO=
;
nNO
3
112
2V
nNO2 =
112
11V
nNO3- to mui = 3 n NO + n NO2 =
112
Da vo s ng cho

- Bo ton khi lng: m mui = m kim loi + 62 nNO3-

Trang 41

= m + 62.

11V
341V
m+
112
56

Cu 44. p n C
HCl l cht kh mnh v K2Cr2O7 l cht oxi ha mnh nn xy ra phn ng:
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O
CrCl3 mu xanh lc
Cu 45. p n C
Cng thc cu to ca Y: H4NOOC COOH3NCH3
Cng th cu to ca X : H2N-CH2CO-NH-CH2COOH.
- Cho X tc dng vi NaOH, ch c Y to kh:
H4NOOC COOH3NCH3 + 2NaOH NH3 + CH3NH2 + (COONa)2 + 2H2O
Ta c: nNH3 + nCH3NH2 = 0,12 ny = 0,06 My = 8,28 gam Mz = 19,8 gam nz = 0,15 mol
Cho 28,08 gam X tc dng vs HCl thu c cc cht hu c theo s :
H4NOOC COOH3NCH3
(COOH)2 + NH4Cl + CH3NH3Cl
H2N-CH2CO-NH-CH2COOH + H2O + 2HCl
2 ClH3N-CH2COOH.
( lu : NH4Cl ) khng phi l hp cht hu c.
m= m(COOH)2 + m CH3NH3Cl + m cht hu c
= 0,06.90 + 0,06.67,5 + 0,3 . 111,5 = 42.9 gam
Cu 46 : p n D
gi s hn hp 2 anhit n chc khng cha HCHO :
RCHO 2Ag
nRCHO = 1/2 nAg =0,5
MRCHO =

52, 4
= 52,4 R= 23,4
2.0,5

2 anhit lin tip l CH3CHO (x mol )

v C2H5CHO (y mol)
x + y = 0,5 (1) v 44x +58 y =

52, 4
= 26,2 (2)
2

x= 0,2 ; y= 0,3
Y gm 2 ancol C2H5OH (0,2 mol) v C3H7OH (0,3 mol).
Theo bi ton hiu sut ca Y l 60% v ca Z bng H%
0,12 mol C2H5OH v a mol C3H7OH to este
meste = 0,12.46 +60a (0,12+a)/2.18 = 12,09 a= 0,15
= 50%
Cu 47: p n A
nhh= 0,3 + 0,5 +0,8 = 1,6 mol,
mhh= 0,3.26 + 0,5.52 8,8.2 = 35,4 = mx
nx =

35, 4
= 1 mol
17, 7.2

nH2 phn ng = n gim = nhh nx= 0,6 mol

Cho X td vi dd AgNO3 kh Y thot ra : 0,45 mol.
s mol kh tc dng vi dd AgNO3/NH3 =
kh tc dng vi AgNO3/NH3 = nX ny = 1 0,45 = 0,55
CH CH
(x mol)

D CH C-CH=CH2 (y mol)
CH C-CH2-CH3 (z mol)
x + y + z = 0,55 (1)
nAgNO3 = 2x + y + z=0,7 (2)
* Ta c tng mol lk pi trong hh u =
2nC2H2 + 3nC4H4 = 2,1 mol.
* s mol lk pi phn ng = nH2 p + nBr2 p = 0,6 + 0,1
mol lk pi trong (D) = 2x + 3y + 2z = 2,1-0,7 = 1,4 (3)

Trang 42

Gii (1), (2), (3) x

x=0,15; y=0,3; z=0,1
kt ta thu c gm 0,15 mol C2Ag2 ; 0,3 mol C4H3Ag v 0,1 mol C4H5Ag
m= 99,8 gam
1D
11A
21B
31D
41A
Cu 48 : p n C
2D
12C
22B
32D
42A
- Cng thc cc cht: axit acrylic C3H4O2; axit adipic
3B
13D
23C
33D
43B
C6H10O4; axit propanoic C3H6O2; glixerol C3H8O3. V s
4B
14B
24D
34A
44D
mol axit propanoic v axit acrylic bng nhau nn da
5B
15A
25D
35D
45B
vo cch quy di trong ha hu c ta c th thay 3 cht:
6A
16D
26D
36B
46C
axit acrylic C3H4O2; axit adipic C6H10O4; axit propanoic
7A
17A
27B
37D
47A
C3H6O2 bng cht mi c cng thc C3H5O2.
8D
18A
28A
38B
48D
hn hp gm:
C3H5O2 v C3H8O3.
9C
19B
29B
39C
49D
Gi x v y l mol 2 cht:
10C
20A
30C
40B
50C
mhh = 73x + 92y = 23,8 (1).
t chy hn hp qua dung dch Ba(OH)2 :
2CO2 + Ba(OH)2 Ba(HCO3)2 (v c kt ta v un dung dch li thu c kt ta na)
nco2 = nOH- - n = 2nBa(OH)2 nBaCO3 = 1,4- 0.5 = 0,9
=> nCO2= 3x + 3y = 0,9
(2).
Gii ra: x = 0,2 v y = 0,1
- Cho X tc ng vi KOH ch c C3H5O2 phn ng:
nKOH phn ng = x = 0,2 mol = nH2O
cht rn thu c gm mui C3H4O2K v 0,1 mol KOH d
mrn = 111.0,2 = 56.0,1 = 27,8
Cu 49. p n C
V1 lt dung dch axit c pH = 5 nH = 10-5 V1
V2 lt dung dch baz c pH = 9 pOH = 5
nOH- = 10-5 V2.
Trn 2 dung dch xy ra phn ng:
H+ + OH- H2O
V dung dch thu c c pH = 8
nOH- d = 10-6(V1+ V2) = 10-5V2- 10-5V1
0,1V1 + 0,1V2= V2 - V1 11V1= 9V2 V1:V2= 9:11.
Cu 50. p n A
Ta c:
nAl = 0,l mol , nFe2O3 = x mol; nFe3O4 = y mol 160x + 232y = 20 (1).
Nhn thy sau cc phn ng Al chuyn thnh Al3+ v Fe trong cc oxit chuyn thnh Fe3+ nn bo ton e ta c:
3.0,1 + y = 0,36 (2).
T (1) v (2)x = 0,038 v y = 0,06 mFe2O3 = 6,08 gam

P N 6
Cu 1 : p n D .Cc cp phn ng l :
BaCl2 +Na2CO3 ;
BaCl2+ NaHSO4;
NaHCO3+ NaHSO4; Na2CO3+ NaHSO4
Cu 2: p n D
linh ng ca nguyn t H trong cc HCHC khc nhm chc c sp xp nh sau :
Ait V C >Axit hu c >H2CO3>Phenol>H2O>Ru.
Nu so snh linh ng ca H ca cc hp cht cng nhm chc th :
+Cc HCHC lin kt vi cc gc ht in t th linh ng ca nguyn t H tng
+Cc HCHC lin kt vi cc gc y in t th linh ng ca nguyn t H gim
T trn suy ra : C2H5OH<H2O<C6H5OH<CH3COOH<HCOOH
Cu 3:p n B
Cc cu ng l :2,5,6,7
(1). Sai v d kin ca dng chng minh Glucozo c 5 nhm OH.

CH3

Trang 43

(3). Sai v v d: CH3 - C - CH2-OH

CH3
l ancol bc 1. Tuy nhin cacbon s 2 khng cn H nn khng c kh nng tch H2O to anken.
(4). Sai v SiO2 ch tan c trong axit HF hoc kim c.
Cu 4: p n B
Cho vo H2O th axit axetic v glixerol tan trong nc to dung dch trong sut .Cn triolein to lp phn cch
Nhn bit c triolein.
Cho qu tm vo th CH3COOH lm qu tm ha ,cn li l glixerol.
Cu 5 : p n B
2NaCl + CuSO4 Na2SO4+Cu+Cl2
V NaCl v CuSO4 cng s mol nn NaCl ht , d CuSO4, 2CuSO4 + 2H2O
in phn n khi cactot xut hin bt kh

2Cu+ O + 2H SO
2

ht mui ng anot thu c hai kh Cl2 v O2.

Cu 6: p n A
Cc cht tha mn khi cng phn ng vi HCl v Ba(OH)2 l :
+ cc cht lng tnh: CH3COONH4 , Al2O3 , Zn(OH)2, KHCO3, (NH4)2CO3 .
+ Al: Khng lng tnh nhng tan c trong HCl v Ba(OH)2
+ Na2CO3 nhng tc dng c vi HCl --> kh CO2 v tc dng Ba(OH)2 to kt ta BaCO3.
Cu 7: p n A
nFe2O3 =0,1. Nu phn ng xy ra hon ton th nFe =2nFe2O3 =0,2
( Nu sn phm sau khng c Al d th nH2 = nFe = 0,2).
Theo : nH2 =0,35 > 0,2 nn c Al d
Fe2O3 + 2Al --> 2Fe + Al2O3
0,1
0,2
0,1

2(0,35 0,2)
3
BTe: 2nH2 = 2nFe + 3nAld --> nAl d =
= 0,1

m= 8,1 gam

=> nAl u = 0,2 + 0,1 = 0,3 mol

Cu 8: p n D
Cc phn ng l :
1). Fe + 2 HCl FeCl2 +H2

3 FeCl
3). Fe +2AgNO Fe(NO ) +2Ag
4). FeCl + 3AgNO Fe(NO ) + Ag +2 AgCl
2). Fe + FeCl3

3 2

3 3

5). Fe(NO3)2 + HCl :

3Fe2+ +NO3 - + 4 H+
6). Fe(NO3)2 + AgNO3

3Fe3+ + NO + 2H2O

Fe(NO )

3 3

+ Ag

Cu 9: p n C
nCH3COOC2H5 = nCH3COOC6H5 = 0,02 ; nNaOH = 0,08
CH3COOC2H5 + NaOH CH3COONa + C2H5OH
0.02
0,02
0,02
CH3COOC6H5 + 2NaOH CH3COONa + C6H5ONa +H2O
0,02
0,04
0,02
0,02
Sau p cn NaOH d:
mRn = 0,02.40+0,04.82+0,02.116 = 6,4(gam)
Cu 10: p n C
Bo ton in tch: nHCO3 =0,7 .
Khi un nng dung dch X th ion HCO3- b nhit phn
2 HCO3- --> CO32- + CO2 + H2O
0,7
0,35

Trang 44

Ca2+ + CO32- --> CaCO3

0,15
0,15
0,15
Mg2+ + CO32- --> MgCO3
0,1
0,1
0,1
Trong ddB : Na+ : 0,8 mol ; Cl- : 0,6 mol v CO32- : 0,1 mol.
Khi nung n khi lng khng i th mui Na2CO3 khng b phn hy:
m rn = mion= 0,8.23 + 0,6.35,5 + 0,1.60 = 45,7 gam.
P to ta:

Cu 11: p n A
nNO= 0,12 mol ;nFe= 0,15 mol.
nNO3- to mui = 3nNO = 0,36 mol.
( Lu bi cho Fe tan ht --> chuyn mui).
mmui = mFe + mNO3- = 8,4+0,36. 62 =30,72
Cu 12: p n C
A mol cht bo X c th cng hp ti a vi 4a mol Br 2 nn trong cht bo X c tng s 4 lin kt

mch v 3 lin kt

trong nhm chc este COO ( tng k = 7)

nCO 2 nH 2O
ADCT: nX =
k 1
V
b
22, 4
-->
a
6

V
= 6a+b V=2,24(6a+b)
22, 4

Cu 13: p n D
Theo ta suy ra cng thc ca A l: (CH3)3NHNO3
(CH3)3NHNO3 + KOH (CH3)3N + KNO3 + H2O
0,09
0,09
0,09
0,09
Vy khi lng phn hi thu c l amin v hi nc:
m= 0,09.18 +0,09.59 =6,93(gam)
Cu 14: p n B
( Lu phn mng tinh th c gim ti)
Cu hi l thuyt n gin nhng kh nh v mng tinh th ca cc kim loi .
-Cc kim loi c dng lp phng tm khi : Li;Na;K;Ba;Cr ..
-cc kim loi dng lp phng tm din : Ca;Cu;Ag;Au;Al..
-Cc kim loi c dng lp phng lc phng : Be ;Mg;Zn
Cu 15: p n A
Cu 16. Chn D.
Da vo s ta xc nh c : p = e = 3, n = 4.
D sai v trong ht nhn s ht mang in l proton = 3.
Cu 17: p n A
Cc cht trong X u c CT chung l : (CH2O)n
CnH2nOn +n O2 nCO2 + nH2O
0,2
0,2
m =20(gam)
Cu 18. p n A
Cc polime trng hp l : poli vinylclorua ,thy tinh plexiglas, teflon, t nitron , cao su buna.
Cu 19: p n B
Cc cht l : FeCO3 ; Fe(NO3)2 ; FeS; FeS2 .
FeCO3 + 2HCl --> FeCl2 + CO2 + H2O
3Fe2+ + 4H+ + NO3- --> 3Fe3+ + NO + 2H2O
FeS + 2HCl --> FeCl2 + H2S
FeS2 + 2HCl --> FeCl2 + S + H2S

Trang 45

( CuS l kt ta bn khng tan trong axit)

Cu 20. Chn A
Cu 21 : Chn B
Cu hi n gin v cn bng ha hc
Phn ng thun ta nhit v lm gim p sut
li) phi h nhit v tng p sut

cn bng chuyn dch theo chiu thun ( lm ngc

Cu 22: p n B
B sai v t visco v t axetat l t nhn to
Cu 23: p n C
Cu 24 : p n D
Gi s s mol mi cht l 1 mol . Khi cho vo H2O thu c :

KOH : 2mol
NH Cl : 1mol

KHCO3 : 3mol
BaCl 2 : 1mol

KOH + KHCO3 K2CO3 +H2O

1
1
1
BaCl2 + K2CO3 BaCO3 +2KCl
1
1
2
KOH + NH4Cl KCl + NH3 + H2O
1
1
1
Nh vy dung dch thu c ch cha KCl
Cu 25: p n D
Cu 26: p n D
Cht c dng lm kh phi c kh nng ht nc v khng phn ng vi cht c lm kh .
Cu 27: p n B
V hp cht kh vi H l RH3 oxit cao nht ca R l R2O5
N

%mR =

2MR.100/(2MR+16.5) = 95,93%

MR=14 R l

Cu 28: p n A
Cho Ba vo nc to Ba(OH)2
Cc cht to kt ta l :
NaHCO3; CuSO4 ,(NH4)2CO3, MgCl2 v Na2SiO3.
Cu 29: p n B
Cc cu ng l : 1,5,6,7
(2) sai AgNO3 l cht oxi ha, Glucozo l cht kh nn phi gi l b oxi ha.
(3). Xenlulozo ch c cu trc dng thng, xon u.
(4). Saccarozo khng c nhm chc CHO nn khng lm mt mu nc brom.
Cu 30: p n C
Do c hai cht cng tc dng vi Na to H2
Cu 31. p n D
Cho X tc dng vi NaOH nn X l este hoc axit . Dung dch sau phn ng c cn thu cht rn thu hn hp v cht rn nn
X lag este v l este ca gc ancol khng bn . X 5 tc dng vi NaOH li thu X 2 l mui chng t este X c gc ancol v
gc axit c cng s nguyn t C.
Nn ch c p n D l CH2 =CH-OCOCH3
Cu 32: p n D.

Trang 46

(n mn in ha ) v bnh in phn cc in cc ngc nhau.

Cu 33. p n D
Nguyn t K: 1s22s22p63s23p64s1
Nguyn t Cr: 1s22s22p63s23p64s23d4 ----> ..... 3d54s1
Nguyn t Cu: 1s22s22p63s23p64s23d9 --> ...... 3d104s1
Cu 34: p n A
Quy i hn hp X v Na :x mol ,Ba:y mol v O:z mol
mhh = 23x + 137y +16z =107,9 (1)
Li c :mNaOH = 40x =28 x=0,7 (2)
BTe : 1.nNa + 2nBa = 2nO +2nH2
x +2y = 2z + 0,7
(3).
Kt hp (1), (2), (3) --> x = 0,7 ; y = z = 0,6
Ta c :

nOH- = nNa + 2nBa = 0,7 + 2.0,6 = 1,9(mol)

nSO2 = 0,08
Ta thy: t l nOH- / nSO2 > 2 --> nSO32- = nSO2 = 0,08 < nBa2+
Ba2+ + SO32- --> BaSO3
0,6
0,6
mBaSO3 = 0,6.217 =130,2 gam

Cu 35:p n D
C 1 kh ha nu trong khng kh nn kh l NO.
M

kh

5.18
= 37 --> MNO = 30 < 37 < MB
0.14

Vy hai kh l NO v N2O
p dng s ng cho nNO = nN2O = 0.07 (mol)
Gi nAl = x,nMg = y.
-Bo ton e ta c : 3x+2y=0,07.3+0,07.4,2=0,77(1)
Mhh 27x = 24y = 8,862 (2)

x 0.042(mol )
y 0.3229(mol )

%mAl =

0,042.27
=12,8%
8,862

Cu 36: p n B
( nSO2 =0,2; nKOH = 0,1 ; nK2CO3 = 0,16 )
CO2 +
2OH-
CO3 2+ H2O (1)
0,05
0,1 0,05
( sau (1) CO2 d = 0,2 -0,05 = 0,15 mol
CO32- = 0,16 + 0.05 =0,21
)
2CO2 +
CO3
+ H2O 2HCO3 (2)
0,15
0,15
(sau (2): Trong dung dch c 0,06 mol CO32- )
Cho tc dng BaCl2 d : nBaCO3 =0,06 mol.
Nung n khi lng khng i to thnh BaO.
BaCO3 BaO + CO2
0,06 0,06
m-BaO = 0,06 .153 =9,18 gam
Cu 37. p n D
Quy i hn hp v Fe: x mol vS: y mol
mhh = mFe + mS => 56x + 32y = 20,8
BTe: 3nFe + 6nS = nNO2 => 3x + 6y = 2,4

Trang 47

x 0, 2

y 0, 3

2Fe3+ --> Fe(OH)3 --> Fe2O3

0,2 mol
0,1 mol mRn =16(gam)
Cu 38: p n B
Gi nglu =a;nAla=b
( Glu v Ala u c 1 nhm NH2 nn tc dng vi HCl u theo t l 1: 1)
- Bo ton khi lng : mHCl = 11,68 --> nHCl = 0,32(mol)
=0,32 (l)
( Glu c 2 nhm COOH v ala c 1 nhm COOH ) nn khi tc dng vi NaOH t l mol ln lt l 1:2 v 1:1
ta c: nKOH =0,5 (mol) 2a + b=0,5 (2)
(1),(2) nglu =0,18 (mol) ,nAla =0,14(mol)
mx=147.0,18+0,14.89 =39,92(g)

a +b

Cu 39: p n C
n CO2= 0,012 mol = nFeCO3 mFeCo3= 2,32 gam
Cht rn thu c sau phn ng l Cu d = 22,4 gam./
Khi lng Cu phn ng = m u - mFeCO3 - mCu d
= 36,56 - 22,4 - 2,32 =11,84(gam) nCu p =0,185 mol
Mui thu c sau phn ng l: Cu(NO3)2 v Fe(NO3)2
( Lu sau phn ng c Cu d nn sp ca Fe to thnh l Fe(II)
mRn =mmui = 0,185.188+ 0,02.180 =39,38(gam)
Cu 40: p n B
* Phn 1: tc dng vi Na c hai cht u phn ng.
ta c: nH2=0,15 mol n hh= 0,3 mol
* Phn 2: Gi x l mol este to thnh.
CH3COOH + C3H7OH

CH3COOC3H7 + H2O.

x
x
x
x
Do png este ha bao gi cng xy ra khng hon ton.
Sau phn ng :
nCH3COOH d + nC3H7OH d = 0,3 - 2x
nH2O = x
Cho hn hp sau tc dng vi Na:
nH2 = (0,3 - 2x + x)/2 = 0,1
=> 0,3 - x = 0,2 => x = 0,1
Vy meste = 0,1. 102 = 10,2 gam.
Cu 41: p n A
(C : nKOH=0,2 mol, nAg=0,6 mol )
Gi x l mol este phn ng: x <nKOH = 0,2
RCOOR' + KOH --> RCOOK + R'OH
x
x
x
x
R'OH --> andehit --> Ag
x
0,06
* Nu andehit khng phi l HCHO : nAg = 2x < 0,4
V l.
* Suy ra andehit phi l: HCHO. B phi l CH3OH
nEste =x = nCH3OH = nHCHO = nAg/4 = 0,015 (mol).
Li c: mrn = mRCOOK + mKOH d
mRCOOK =19,3- 0,05.56 = 16,5(gam)
M RCOOK =110 R=27(C2H3)
Cng thc este: C2H3COOCH3.
m =0,15. 86 =12,9 (gam)
Cu 42. Chn A.

Trang 48

T l : Hai ng v l 23/2 ta suy ra ng.t khi trung bnh.

A Al

27.23 29.2
27,16
23 2

23
.100% 92%
23 2
ADCT tnh % khi lng ng v trong hp cht: Al2X3
x%.A. s ntu
92%.27. 2
27
33, 05%
%mKL 13 Al =
=
M hop chat
M Al2 X 3

27
13

Al =

M = 150,32 = 27,16.2 + Mx.3 => Mx = 32

Cu 43. Chn B.
Bo ton khi lng: nO2 p = 0,425 mol
nHCl p = 4nO2 = 1,7 mol.

Cu 44. Chn D.
nH2 = 0,85 => nHCl = nCl = 1,7 mol.
mmui = mKL + mCl = 24,1 + 1,7.35,5 = 84,45.
Cu 45: p n B
nKOH ln 1 =0,33mol ; nKOH ln 2 = 0,45 mol.
C hai trng hp u thu c kt ta nh nhau nn hai trng hp trn l trng hp min v max i vi Bi tp Hidroxit
lng tnh in hnh.
p dng cng thc:
nOH-min = 3n => 0,33= 3.a/78
nOH-max = 4nAl3+ - n => 0,45 = 4nAl3+ - a/78
Gii ra: nAl3+ = 0,14 mol. mAlCl3 =18,69 (gam)

Cu 46: p n C
nCO2=0,14 mol, nH2O=0,17 mol
( trong 3 cht cho ancol c k = 0 ; hai cht cn li c k =1)
nC2H5OH = nH2O - nCO2 = 0,03 mol.
Do ancol chim 50%

mol axit v anehit l : naxit anneh =0.03 mol

Gi s mol 2 cht ln lt l x v y

x y 0.03
x 0.02

y 0.01 m 3.3 gam

nCO2 3 x 2 y 2.0, 03 0.16

Ta c :

mhh = 3,2 gam c 0,01 mol CH3CHO

--> trong 13,2 gam hn hp c 0,04 mol CH3CHO
Vy mAg = 2.0,04.108 = 8,64 gam.
Cu 47: p n A
X (tetrapeptit) + 4 NaOH --> mui + H2O
a
4a
a

Y(tripeptit) + 3 NaOH
mui + H2O
3a
9a
3a
Bo ton khi lng:
316.a + 245.3a + 40.13a = 89,94 + 18.4a
Gii ra a = 0,06
mhh = 316.0,06 + 245.3.0,06 = 63,06 gam
Cu 48: p n D
nO2 = 0,1775 mol, nCO2 =0,145 mol = nH2O
Theo bo ton nguyn t O
n este = [( 2nCO2 + nH2O) -2n O2]/2 =0,04 mol
n =3,625 : 2 este C3H6O2 v C4H8O2.
Li c : M mui = 98

R= 15 (CH . thu hai ancol ng ng lin tip nn hai este cng l lin tip
3

Trang 49

 2 este l : CH COOCH
3

v CH3COOC2H5.

Cu 49: p n D
nH+ = 0,4 mol ; nCu2+ = 0,16 mol ; nNO3- = 0,32

1C
2D
3A
4C
5B
6C
7D
8A
9B
10C

11C
12B
13B
14B
15A
16A
17A
18B
19D
20B

21B
22A
23D
24B
25C
26C
27D
28A
29A
30D

31A
32A
33C
34C
35C
36D
37B
38A
39A
40B

41B
42D
43D
44B
45B
46A
47B
48B
49C
50C

( : nBa(OH)2 = 0.015 mol)

S mol HCl thm vo = 0,015 nBa(OH)2 d = 0,0075 mol
Ptpu: 2RCOOH + Ba(OH)2 (RCOO)2Ba + 2H2O
0,015
0,0075
0,0075
0,015

Sau phn ng thu c hn hp kim loi nn mui Fe

to thnh l mui Fe(II).
3Fe + 8H+ + 2NO3- --> 3Fe2+ + 2NO + 4H2O
0,15 0,4 0,1
0.1
Fe + Cu2+ --> Fe2+ + Cu
0,16 0,16
0,16
Ta c: mFe u + mCu to ra - mFe tan = m rn sau
a + 64.0,16 - 56( 0,15 + 0,16) = 0,8a
==> a = 35,6 gam
Cu 50: p n C

S mol Ba(OH)2 tc dng vi axit l 0,0075 mol

Ba(OH)2 + 2HCl BaCl2 + 2H2O.

0.0075
0,015
0,0075 0,015
: nRCOOH + nRCOOM = 0,035 mol
nRCOOM = 0,035 0,015 = 0,02 mol.
Sau khi c cn dung dch C: mmui = 5,4325 gam
Bo ton khi lng:
mhh + mBa(OH)2 + mHCl = mmui + mH2O
mhh + 0,015. 171 + 0,015.36,5 = 5,4325 + 0,03.18
mhh = 2,86 gam.
* Nu cho 50 ml dung dch A tc dng vi 0,02 mol NaOH.
RCOOH + NaOH RCOONa +H2O
0,015
0,015
0,015
0,015
Bo ton khi lng:
mhh + mNaOH = m rn + mH2O
mrn = 2,86 + 0,02.40 18.0,015 = 3,39 gam.

P N 7
Cu 1. Chn C.
Axit no ( k = 0), 2 chc ( k = 2) tng k = 2 ( mt 4 H)
4H
CnH2n+2O
CnH2n-2O4.
4
Cu 5 : Chn p n B
(2) Lm nht mu dung dch thuc tm. Loi C
(3) B hp th bi dung dch Ba(OH)2 d to kt ta trng.
Loi A vi D
Cu 8: Chn p n A
Cc hp cht hu c tc dng c vi dung dch NaOH c cng cng thc phn t C7H8O cht l phenol.
CH3

CH3

CH3

OH

OH
OH

Cu 9. Chn B.

Trang 50

i t F I bn knh nguyn t tng di lin kt HF HI tng kh nng phn tch H+ tng, tnh axit
tng.
Cu 10. Chn C
Xt cn bng ho hc:
2SO2 (k) + O2 (k) SO3 (k) H= -198kJ
T l SO3 trong hn hp lc cn bng s ln hn khi cn bng dch phi .Do phn ng thun ta nhit v s phn t kh
bn tri ln hn nn gim nhit v tng p sut s lm cn bng dch phi.
Cu 12. Chn B
R(COOR)2 + 2NaOH
R(COONa)2 + 2ROH
0,1
0,2

0,1
0,2 mol

M R OH

6,4
32 ancol CH3OH.
0,2

p dng nh lut bo ton khi lng ta c:

meste + mNaOH = mmui + mru

mmui meste = 0,240 64 = 1,6 gam.

13,56
meste
100
1,6 100
11,8 gam
meste =
13,56
mmui meste =

Meste = 118
R + (44 + 15)2 = 118 R = 0.
Vy cng thc cu to ca este l CH3OCOCOOCH3.
Cu 13. Chn B.
2NaOH + ZnSO4 Zn(OH)2 + Na2SO4 (1)
0,04
0,02
0,02
Sau phn ng (1). nNaOH d = 0,05 0,04 = 0,01
2NaOH + Zn(OH)2 Na2ZnO2 + H2O (2)
0,01
0,005
(2). nZn(OH)2 b tan = 0,005 nZn(OH)2 cn li = 0,015
m = 99.0,015 = 1,485 gam
Cu 15. Chn A.
Hnh 3: dng thu c cc kh khng tan c trong nc.
+ NH3 tan rt nhiu trong nc nn ta loi phng n D v B ngay.
( Nhiu hc sinh nhm C2H2 c phn ng vi H2O nn khng chn A.
C2H2 khng phn ng vi H2O iu kin thng, n ch phn ng vi H2O khi c xc tc l mui ca Hg2+).
Cu 16. Chn A.
n hh (CO H2 )

2,24
0,1 mol
22,4

Thc cht phn ng kh cc oxit l:

CO + O
H2 + O

Vy:

CO2
H2O.

n O n CO n H 2 0,1 mol .

mO = 1,6 gam.
Khi lng cht rn cn li trong ng s l: 24 1,6 = 22,4 gam.

Cu 17 : Chn A
Ch : Th tch ca bnh l 2 lt nn cn phi tnh li nng .
0, 6 0,12

Ta c :
2
2 4.104 mol / (l.s)
v
10.60
Cu 18 : Chn p n B
(1). C 5SO 2 2KMnO 4 2H 2 O K 2SO 4 2MnSO 4 2H 2SO 4 (2). C
4Cl 2 H2S 4H2O 8HCl H2SO4 .
1
(3). C 2NO 2 O 2 H 2 O 2HNO3 .
2
(4). Khng 3Na2CO3 2AlCl 3 3H2O 2Al(OH)3 3CO2 6NaCl (5).
3Fe2 NO3 4H 3Fe3 NO 2H2O
(6). C Fe 2 O3 6HI 2FeI 2 I 2 3H 2 O
Trang 51

Cu 19 : Chn D
S cht tc dng c vi dung dch NaOH long nhit thng l : CO2, NO2, CrO3, P2O5, Al2O3.
Cu 20 : Chn B
Chnh xc l: Cht bo l trieste ca glixerol v cc axit bo.
Cu 21 : Chn p n B
BaO + H2O Ba(OH)2
5
5
to ra 10 mol OHD thy ta c 10 mol OH- s p va vi
NH4HCO3 ( 4 mol) v NaHCO3 ( 2 mol)
OH- + HCO3- CO32- + H2O
6
6
6
OH- + NH4+ NH3 + H2O
4
4
Ba2+ + CO32- BaCO3
5
5
Dung dch cn 1 mol CO32- v 2 mol Na+
Cui cng dung dch Y ch cha mui Na2CO3
Cu 22: Chn A
Cht m 1 mol cht phn ng c ti a vi 2 mol NaOH l :
+ m-HOC6H4OH, (CH3NH3)2CO3, HOOCCH2CH(NH2)COOH, ClH3NCH(CH3)COOH
Cu 23: Chn D
Kim loi kim c kiu mng l p phng tm khi.
Cu 24: Chn B
Bao gm cc th nghim : (1), (3), (4).
Cu 25. Chn C
Axit cacbonxylic n chc c 2 nguyn t Oxi nn c th t l RO2. Vy:

n O ( RO2 ) n O (CO2 ) n O (CO2 ) n O ( H 2O)

0,12 + nO (p.) = 0,32 + 0,21

nO (p.) = 0,6 mol

nO2 0,3 mol

VO2 6,72 lt. (p n C)

Cu 26. Chn C.
Lu phi nm c kiu kin phn ng xy ra.
(1); H+ + HCO3- CO2 + H2O. (3) Mg2+ + 2OH- Mg(OH)2
(5). 2OH- + Zn2+ Zn(OH)2
(8).H++ AlO2- +H2O Al(OH)3

Cu 29: Chn p n A

0,5 0,1.2 0,1.2

0,2 0,1
n HCO

BTDT

2+

n HCO
3

0, 6

2+

Lu : nHCO > 2(nMg + nCa ) nc cng tm thi.

V: un si ta c

HCO3
2+

t0

CO32 : 0,3(mol)

0, 2

2+

Ton b ion Mg v Ca b loi khi dung dch do to ta.

Cu 30.Chn D.
Cu(OH)2 kt ta mu xanh.
Cu 31: Chn A
Gi s c 100 gam phn ( m KCl = 59,6 gam, mK2CO3 = 34,5 gam)

n KCl 0,8(mol)

n K 2CO3 0, 25(mol)

BTNT.K

n K 2O

0, 65

Vy dinh dng ca phn l : 0, 65.94 61,1%

Cu 32. Chn A.
nOH- = nNaOH + 2nBa(OH)2 = 0,55V
nH+ = 2nH2SO4 + nHNO3 = 1,2V'
Dung dch sau:
pH = 3 --> [H+] = 10-3 --> nH+ = 10-3(V+V')
nH+ = 1,2V' - 0,55V = 10-3(V+V')
=> V'(1,2-10-3) = V (0,55 + 10-3)
V
1, 2 103
2,17
=> 1
V2 0,55 103
Cu 33. Chn C.
Tin trnh (1).

Trang 52

Cu2+ : (0,25-a)
Mg2+: (0,05+a)
Cu(NO3)2: 0,25
NO3- : 0,6
AgNO3 : 0,1

Mg +

Mg + 2Ag+ Mg2+ + 2Ag

0,05 0,1
0,05 0,1
Mg + Cu2+ Mg2+ + Cu
a
a
a
a
Tin trnh (2).
Cu2+ : (0,25-a)
Fe
+
Mg2+:

8,4 gam
NO3- : 0,6
Fe + Cu2+ Fe2+ + Cu
0,25-a 0,25-a 0,25-a

Mgd
Ag
Cu
19,44 gam

rn

Mg2+
Fe2+ +
NO3-

Cu : a
Fed
9,36 gam

Bo ton khi lng cho tin trnh (2).

mFe + mCu2+ = mFe2+ + m rn sau.
8,4 + 64 ( 0,25 a ) = 56 ( 0,25 a ) + 9,36
a = 0,13
Bo ton khi lng cho tin trnh (1).
mMg + mAg+ + mCu2+ = mMg2+ + mCu2+ + m rn.
m + 108.0,1 + 64.0,25 = 64.0,12 + 24.0,18 + 19,44
m = 4,64
Cu 34: Chn p n C

5
0,19 ne 0,38(mol)
24
V M B 23 MH2 = 2 < 23 < MNO =30.

Ta c: nMg

( Da vo s ng cho v nhh = 0,08 )

NO : 0,06(mol)

H 2 : 0,02(mol)

BTE

Bo ton electron: 2nMg = 3nNO + 2nH2 + 8nNH4+

n NH
4

0,38 0,06.3 0,02.2

0,02(mol)
8

Ch : C kh H2 bay ra chng t trong dung dch khng cn

NO3

Bo ton mol N : nKNO3 = nNO + nNH4+ = 0,08 mol.

Mg 2 : 0,19(mol)

K : 0,08(mol)
Vy dung dch A c:

NH 4 : 0,02(mol)
SO 2 : a
BTDT 0,19.2 0,08 0,02
2a

BTKL

m(Mg

2
4

0, 24(mol)

, NH ,SO , K ) 31,08(gam)

Cu 35: Chn p n C
Quy i phn 1: thnh 3 nguyn t Al, Fe, O vi s mol tng ng l x, y, z.
27x + 56y + 16z = 14,49. (1)
Khi tc dng vi HNO3 d thu kh NO: 0,165 mol.
Bo ton electron: 3x + 3y 2z = 3nNO
3x + 3y 2z = 3.0,165 = 0,495 (2)
Quy i phn 2: Al, Fe, O vi s mol tng ng l:
kx, ky, kz
( V bi cho hai phn khng bng nhau)
Khi tc dng vi NaOH . Fe khng phn ng.
Bte: 3nAl 2nO = 2nH2
3kx 2kz = 0,03
(3)
Rn cn li l Fe: ky = 0,045
(4).
3x 2 z 2

Ly (3)/(4)
9x 2y 6z = 0 (4)
y
3
x = 0,15; y = 0,135 , z = 0,18
Cng thc oxit: y/z = 0,135 /0,18 = Fe3O4.
(4). K = 0,045/0,135 = 1/3
Vy : m u = m1 + m2 = m1 + m1/3 = 4m1/3 =
= ( 27.0,15 + 56.0,135 + 16.0,18).4/3 = 19,32 gam.
Cu 36. Chn D.

Trang 53

Nhn vo th ta thy
nBaCO3 t cc i khi = nBa(OH)2 = 0,6 y = 0,6
Ta li thy nCO2 = 1,6 th khng cn ta. Chng t khng cn CO32CO2 + 2OH- CO32- + H2O
CO2 + H2O + CO32- 2HCO3 cng : CO2 + OH- HCO3Khi : nCO2= nOH1,6 = 0,1 + x + 1,2 x = 0,3
* Tip tc ta thy: n = 0,2 nCO32- = 0,2
ADCT: z= nCO2 = nOH- - nCO32- = 1,6 0,2 =1,4
Cu 37: Chn B
X, Y, Z u tc dng vi Na nn X, Y, Z phi c H linh ng ( phi c nhm OH hoc COOH hoc c hai).
* X khng tc dng vi NaHCO3 nn X c nhm OH.
X trng Ag nn X c thm nhm CHO.
MX > 58 Cng thc ca X : HO-CH2-CHO ( M = 60)
hoc HO-C2H4-CHO. ( M = 74)
* Y tc dng vi NaHCO3 nn Y c nhm COOH , Y trang gng nn Y c nhm CHO.
MY < 78 Y ch c th l: HOC COOH ( M = 74)
* M MX < MY X ch c th l: HO-CH2-CHO ( M = 60)
Suy ra cng thc ca Z l: HO CH2 COOH ( M = 76 < 78)
Vy: Cc cht trong T l:

X : HO CH 2 CHO

Y : HOC COOH
Z : HO CH COOH
2

Cc cht trong T u c 2 cacbon.

Khi t chy : nCO2 = 2.0,25 = 0,5 mCO2 = 22 gam.
Cu 38: Chn A
Sau phn ng cn li kim loi: mCu d = 2,4 gam.
mhh phn ng = 58,8 gam.
Sau phn ng cn kim loi nn mui ca Fe to thnh l Fe(II).
Quy i 58,8 gam hn hp thnh Cu, Fe, O.
mhh = 64a + 56b + 16c = 58,8 (1)
BTe : 2Cu + 2Fe 2O = 3NO
2a + 2b 2c = 0.45 (2).
T CT oxit: b/c = 4b 3c = 0 (3)
a = 0.375 ; b = 0,45 , c = 0,6
Mui thu c: Cu(NO3)2 = 0.375 mol
mFe(NO3)2 = 0,45 mol
m = 151,5 gam
Cu 39. Chn A.
(RCOO)3C3H5 + 3NaOH 3RCOONa + C3H5(OH)3
0,06
0,02
BTKL: mxphng = 17,24 + 0,06.40 0,02.92 = 17,8 gam.
Cu 40. Chn B.
Hiu sut chung ca qu trnh H = 803/1002 = 51,2%
nP.E = 0,192 k.mol nCH4= 0,384 k.mol
Vkh thin nhin = (0,384.22,4).100/75 .100/51,2 = 22,4
Cu 41. Chn B.
Axit acrylic: CH2=CH-COOH.
Vinyl axetat: CH3COO-CH=CH2
Metyl acrylat: CH2 =CH-COOCH3
Cc cht trn u c cng cng thc phn t: CnH2n-2O2.
CnH2n-2O2 + O2 nCO2 + (n-1)H2O
14n + 30
n = 3,6
2,6
4.02 gam
0,18
0,13
n = 3,6
m bnh tng = mH2O = 0,13. 18 = 2,34
Cu 42. Chn D.
Meste = 100 CTPT : C5H10O2
neste= 15/100 = 0,15 mol.
nNaOH = 0,15 mol.
Ta thy: meste + mNaOH = 15 + 0,15.40 = 2,1 = mmui
Este ny l este vng.

Trang 54

 bi : Este khng phn nhnh Chn D.

Cu 43. Chn p n D
A. vinylaxetilen, glucoz, axit propionic.
Loi v c axit propionic
B. glucoz, imetylaxetilen, anehit axetic.
Loi v c imetylaxetilen ( CH3 - C C- CH3)
C. vinylaxetilen, glucoz, imetylaxetilen.
Loi v c imetylaxetilen
D. vinylaxetilen, glucoz, anehit axetic.
Tha mn.
Cu 44. Chn p n B
S cht trong dy phn ng c vi dung dch nc brom l : C2H2, C2H4, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol),
CH3CHO.
Cu 45. Chn A.

Gly :

mol
xt, to

Ala:

mol

Val:

mol

6Tripeptit + H2O

BTKL
Cng thc chung ca 3 aminoaxit: H2N-R-COOH
Tng mol a.a = 0,6 mol.
3 H2N-R-COOH H2N-R-CO-NH-R-CO-NH-R-COOH + 2H2O
0,6 mol
0,4 mol.
Bo ton khi lng: m 6tripeptit = tng ma.a - mH2O =
= (22,5 + 17,8 + 11,7) 18.0,4 = 44,8 gam

Cu 46. Chn A.
Cng thc chung ca axit bo t do: RCOOH.
Cng thc chung ca cht bo:
(RCOO)3C3H5.
* bi:
- Trung ha axit trong 1 gam cht bo cn
7 mg KOH.
Vy:
10 kg = 10000 gam ..cn 70000mgKOH
= 70 gamKOH
* Nhng bi ton ngi ta dng NaOH x phng ha.
( Dng NaOH hay KOH th s mol phn ng l nh nhau)
nNaOH = nKOH = 70/56 =1,25 mol.
mNaOH dng trung ha axit bo = 1,25.40 = 50 gam.
Phng trnh x phng ha:
RCOOH

+ NaOH
RCOONa + H2O
1,25 mol
1,25 mol

(1)

(RCOO)3C3H5 + 3NaOH 3RCOONa + C3H5(OH)3 (2)

33,75 mol
11,25 mol
HCl
0,5

+ NaOHd NaCl + H2O

0,5

(3).

nHCl = 0,5 nNaOH(3) = 0,5 mol.

nNaOH (1) tnh trn = 1,25 mol.
nNaOH = 1420 /40 = 35,5 mol.
nNaOH (2) = 35,5 0,5 1,25 = 33,75 mol.
T (2): mGlixerol = 1035 gam = 1,035 kg.
T (1), (2): Bo ton khi lng:
mbo + mNaOH(1),(2) = mRCOONa +mH2O + mglixerol
mRCOONa = 10000 + 40.(1,25 + 33,75) 18.1,25 -1035
= 10342,5 gam = 10,3425 kg.
Cu 47. Chn B.
CTCT ca X: CH3NH3NO3
CH3NH3NO3 + NaOH CH3NH2 + NaNO3 + H2O
0,1
0,1
0,1
mrn = mNaNO3 + mNaOH d = 85.0,1 + 40.0,1 = 12,5 gam.

Trang 55

Cu 48. Chn B.
C 3 nhn nh khng ng: (2), (4), (6).
(2) Keo h tinh bt c to ra bng cch ha tan tinh bt trong nc.
Khi nu tinh bt th mi thnh h tinh bt c ( cn phi c nhit )
(4) T lapsan c to ta t phn ng trng ngng.
(6) Cao su thin nhin khng dn in, c th tan trong benzen, trong xng v c tnh do.
Cao su thin nhin c tnh n hi.
Cu 49.Chn p n C
Gi a l mol ca a.a X
Ta xem nh ban u X cha phn ng vi H2SO4.
Trong dung dch Y gm X v H2SO4.
( Lu : X c 2 nhm COOH)
Tng mol H+ = 2nX + 2nH2SO4 = 2a + 0,2
- Phn ng trung ha: nH+ = nOH 2a + 0,2 = 0,4 a = 0,1
H+ + OH- H2O
0,4
0,4
0,4
Bo ton khi lng:
ma.a + mH2SO4 + mNaOH + mKOH = mmui + mH2O
ma.a = 36,7 + 18.0,4 98.0,1 40.0,1 56.0,3 = 13,3
Ma.a = 133
%N =

14
100% 10,526%
133

Cu 50. Chn p n C
Hn hp gm: Mg ( a mol) ; Cu(NO3)2 ( 0,25 mol)
Cu(NO3)2 :0,25
Mg : a

t0

CuO, Cu(NO3)2
Mg, MgO

+ NO2 + O2
0,45

NH4+ :b
H2 : 0,01
+ HCl ( 1,3 mol) Mg2+ :a
+
N2 : 0,04
CuO, Cu(NO3)2
Cu2+ :0,25
Cl- :1,3
+ H 2O
m?
c
( Da vo S C: tnh c mol H2 v N2. V c H2 sinh ra nn khng cn NO3- trong mui)
Mg, MgO

Bo ton in tch trong dung dch:

2a + b + 0,25.2 = 1,3 2a + b = 0,8 (1)
Bo ton mol H: 1,3 = 4b + 0,01.2 + 2c
4b + 2c = 1,28 (2)
Bo ton mol O:
nO ( trong Cu(NO3)2 u = molO(trongNO2+O2) + mol O ( trong H2O)

0,25.3.2 = 2.0,45 + c c = 0,6

a = 0,39 ; b = 0,02 , c = 0,6
Vy mmui = 24.0,39 + 18.0,02 + 64.0,25 + 35,5.1,3 =
= 71,87 gam

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