Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

CLB gia s Bch khoa

Chuyn :NHM HALOGEN V HP CHT

I/. KIN THC C BN:
1/Khi nim v cu to:
Nguyn t halogen c 7 electron lp ngoi cng ns2np5, bn knh nguyn t nh, c m in ln
d nhn e, halogen c tnh oxi ha mnh v l phi kim in hnh.
Ion halogenua X- c mc oxi ha thp nht nn th hin tnh kh.
I2 Br2 Cl2 F2
Tnh oxi ha tng dn
2I 2Br 2Cl 2F
Tnh kh gim dn
2/. L tnh:
Halogen
F2
Cl2
Br2
I2
Trng thi
Kh
Kh
Lng
Rn
Mu sc
Xanh nht
Vng lc
nu
Tm than
3/. Tnh oxi ha ca halogen:
Tc dng vi
Chu y
V d
Kim loi
Oxi ha kim loi n ha
2Fe + 3Cl2 2FeCl3
tr cao tr Iot
Fe + I2 FeI2
Phi kim
Tr N2, C, O2.
H2 + Cl2 2HCl
2P + 3Cl2 PCl3 hay PCl5
Halogen tnh
y halogen c tnh oxi
Cl2 + 2NaBr Br2 + 2NaCl
oxi ha yu
ha yu ra khi dung dch
Br2 + 2NaI I2 + 2NaBr
mui.
Cht kh
H2S, Fe2+, Na2SO3, SO2
FeCl2 + Cl2 2FeCl3
Br2 + SO2 + H2O H2SO4 + 2HBr
4Cl2 + H2S + 4H2O H2SO4 + 8HCl
Dung dch
Long ngui hoc c
2KOH + Cl2 KCl + KClO + H2O
kim
nng
, to
6KOH + 3Cl
5KCl + KClO3 + 3H2O
2
2Ca(OH)2 + Cl2 CaCl2 + Ca(ClO)2 + 2H2O
H2O
F2 phn hy H2O.
2F2 + 2H2O 4HF + O2
I2 khng phn ng.
Cl2 + H2O HCl + HClO
4/. Tnh cht ha hc ca cc Halogenua:
a/. Cc phn ng chng minh kh nng kh gim dn t I- n FCht phn ng
HI
HBr
HCl
HF
MnO2
I2
Br2
Cl2
H2SO4 c
I2 (H2S, S)
Br2 (SO2)
FeCl3
I2
b/. Da vo tnh kh ca X- ta c phng php iu ch halogen
Cl2: c th oxi ha Cl- bng KMnO4 hoc MnO2 or K2Cr2O7 trong mi trng axit.
2KMnO4 + 16HCl 2MnCl2 + 2KCl + 5Cl2 + 8H2O
MnO2 + 4HCl MnCl2 + Cl2 + 2H2O
K2Cr2O7 + 14HCl 2CrCl3 + 3Cl2 + 2KCl + 7H2O
Br2: oxi ha Br- bng MnO2 trong mi trng axit.
MnO2 + 2KBr + 2H2SO4 Br2 + K2SO4 + MnSO4 + 2H2O
MnO2 + 4HBr MnBr2 + Br2 + 2H2O
I2: oxi ha I- bng MnO2 trong mi trng axit.
MnO2 + 2KI + 2H2SO4 I2 + K2SO4 + MnSO4 + 2H2O
F2: nhit phn nng chy KF, vi anot bng than ch vo katot bng thp.
o
NaCl + H2SO4 ()
250 C NaHSO4 + HCl
2NaBr + 2H2SO4 () Na2SO4 + Br2 + SO2 + 2H2O
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Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

CLB gia s Bch khoa

2NaI + 2H2SO4 () Na2SO4 + I2 + SO2 + 2H2O

II/. KIN THC B SUNG:
1/. Hp cht cha oxi ca clo:
Trong hp cht, clo c nhiu s oxi ha khc nhau, ch yu l cc s oxi ha l (-1, +1, +3, +5, +7).
a/. Nc Javen: L dung dch thu c khi cho kh clo qua dung dch NaOH
2NaOH + Cl2 NaCl + NaClO + H2O
Nc Javen c tnh oxi ha mnh dng ty trng, st trng.
NaClO l mui ca axit yu, trong khng kh tc dng vi kh CO2 to dung dch axit hipoclor l axit
km bn v c tnh oxi ha mnh.
NaClO + CO2 + H2O NaHCO3 + HClO
b/. Clorua vi: Cng thc cu to: Cl Ca O Cl
Cht bt mu trng ca mui clo, c iu ch bng cch cho kh clo tc dng vi vi sa
Cl2 + Ca(OH)2 CaOCl2 + H2O
CaOCl2 l mui ca 2 axit: HClO v HCl. Trong khng kh, clorua vi tc dng vi CO2 to dung
dch axit hipoclor l axit km bn c tnh oxi ha mnh.
2CaOCl2 + CO2 + H2O CaCO3 + CaCl2 + 2HClO
c/. Kali clorat: Tinh th mu trng, c iu ch bng cch cho kh clo qua dd KOH d nhit khong 70oC
, to
6KOH + 3Cl
5KCl + KClO3 + 3H2O
2
Nhit phn KClO3 c xc tc MnO2, phn ng d dng:
o
2KClO3 t
2KCl + 3O2
Cht oxi ha mnh, n d dng phn ng khi nung vi S hoc C:
o
2KClO3 + 3S t
2KCl + SO2
o
2KClO3 + 3C t
2KCl + 3CO2
d/. Cc axit Clorua Oxi ca clo:
Cc axit clorua oxi ca clo gm: axit hipoclor HClO, axit clor HClO2, axit clorit HClO3, axit
peclorit HClO4.
Tnh axit trong dung dch tang dan va tnh oxi hoa giam dan theo th t: HClO, HClO2,
HClO3, HClO4.
HClO: axit yeu kem ben:
NaClO + CO2 + H2O NaHCO3 + HClO
2HClO 2HCl + O2
HClO2: axit trung bnh, kem ben
3HClO2 2HClO3 + HCl
HClO3: axit manh, kem ben khi nong o > 50%
3HClO3 HClO4 + ClO2 + H2O
HClO4: axit manh nhat trong cac axit vo c, kem ben khi un nong vi P2O5
o
2HClO4 t
Cl2O7 + H2O
2/. Gii ton lin quan n halogen:
a/. Nhn bit X- bng dd AgNO3
ClBrIFAgNO3
AgF tan
AgCl (trng)
AgBr (vng nht)
AgI (vng)
3+
3+
2+
Ring I sau khi oxi ho bng Fe : 2Fe + 2I 2Fe + I2
Iot sinh ra lm h tinh bt c mu xanh thm.
b/. Cc halogen X2 (trong dung dch) khi c cn s b bay hi.
Ch : + 2 mui halogenua tc dng vi AgNO3 c to kt ta (c th 2 hoc 1 mui to kt ta)
+ Cho halogen X tc dng vi mui halogenua NaY, c th gp trng hp X2 thiu, Y2 b y ra
khng hon ton
III/. BI TP NG DNG:
Cu 1. Cc nguyn t halogen c cu hnh lp e ngoi cng l:
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Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

A. ns2
B. ns2np3
C. ns2np4
Cu 2/. Halogen c th rn (iu kin thng), c tnh thng hoa l:
A. flo
B. clo
C. brom
Cu 3/. Th t tng dn m in ca cc halogen l:
A. F<Cl<Br<I

B. Br<Cl<F<I

C. I<Cl<Br<F

CLB gia s Bch khoa

D. ns2np5
D. iot
D. I<Br<Cl<F

Cu 4/. Th t tng dn bn knh nguyn t ca cc halogen l:

A. F<Cl<Br<I B. Br<Cl<F<I C. I<Cl<Br<F D. I<Br<Cl<F

Cu 5/. C 7e lp ngoi cng, cc tnh cht chung ca cc halogen l:

A. tnh kh mnh, d nhng 1e.
B. Tnh kh mnh , d nhn 1e.
C. Tnh oxi ho mnh d nhn 1e.
D. tnh oxi ho mnh, d nhng 1e.
Cu 6/. Trong cc hp cht clo c nhng s oxi ho no ?
A. -1, 0, +1, +5
B. -1, 0, +1, +7
C. -1, +3, +5, +7
D. -1, +1, +3, +5, +7
Cu 7/. Chn halogen c phn ng mnh nht vi H2
A. Cl2
B. F2
C. Br2
D. I2
Cu 8/. Trong phn ng: Cl2 + H2O HCl + HClO, kh clo th hin tnh
A. oxi ho
B. Kh
C. Kh v oxi ho
D. axit
Cu 9/. Chn phn ng trong halogen c tnh kh:
A. Br2 + SO2 + 2H2O 2HBr + H2SO4
B. H2 + Cl2 2HCl
C. 4Cl2 + H2S + 4H2O H2SO4 + 8HCl
D. Br2 + 5Cl2 + 6H2O HBrO3 + 10HCl
Cu 10/. Chn kim loi phn ng vi Clo v HCl cho cng mt mui:
A. Ag
B. Cu
C. Fe
D. Ca
Cu 11/. Trong phng th nghim , kh clo thng c iu ch t:
A. NaCl + H2SO4 (c)
B. HCl + KMnO4
C. NaCl (Nhit phn)
D. F2 + KCl
Cu 12/. Xt v tnh oxi ho kh, axit clohidric
A. clo c tnh kh
B. Clo c tnh oxi ho
C. Clo c tnh oxi ho v tnh kh
D. Khng c tnh Oxi ho v tnh kh.
Cu 13/. Phn ng no di y khng xy ra ?
A. NaCl + AgNO3 AgCl + NaNO3
B. HCl + AgNO3 AgCl + HNO3
C. 2HCl + Cu CuCl2 + H2
D. 2HCl + FeS FeCl2 + H2S
Cu 14/. Trong phng th nghim ngi ta iu ch HCl bng phn ng:
A. NaCl r + H2SO4 c
B. BaCl2 + H2SO4
C. H2 + Cl2
D. Cl2 + HBr
Cu 15. Nhn xt no ng v tnh oxi ha-kh ca nhm halogen ?
A. Clo, brom v iot ch co tnh oxi hoa manh.
B. Tnh kh giam dan theo th t clo, brom, iot.
C. Tnh oxi hoa tang dan theo th t la flo, clo, brom, iot.
D. Flo ch co tnh oxi hoa, con clo, brom, iot co ca tnh kh va tnh oxi hoa.
Cu 16/ Thc hin phn ng gia 0,03g H2 vi 0,71g Cl2. Nu hiu sut phn ng t 40% th th tch kh
sinh ra sau phn ng ktc l :
A. 0,448 lt
B. 0,1344 lt
C. 0,1792 lt
D. 0,672 lt
Cu 17/. Cho a mol kh HCl vo 92,7g H2O c dd A. Ly 1/5 dd A tc dng vi AgNO3 d c 5,74g
kt ta. Nng % ddh A l
A. 7,3%
B. 3,65%
C. 3,94%
D. 7,87%
Cu 18/. Axit halogenhidric no c th n mn thu tinh?
A. HF
B. HCl
C. HBr
D. HI
Cu 19/. S oxi ho ca Clo trong clorua vi l:
A. +1
B. -1
C. +1 v -1
D. 0
Cu 20 Clorua vi v nc Javen th hin tnh oxi ho l do:
A. Cha ion ClO-, gc ca axit c tnh oxi ho mnh.
B. Cha ion Cl-, gc ca axit clohidric in li mnh.
C. nc clo u l sn phm ca cht oxi ho mnh Cl2 vi kim.
D. Trong phn t c cha cation kim loi mnh.
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Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

CLB gia s Bch khoa

Cu 21/. Chn cu ng
A. Cc ion F-, Cl-, Br-, I- u to kt ta vi Ag+.
B. Cc ion Cl-, Br-, I- u cho kt ta mu trng vi Ag+.
C. C th nhn bit ion Cl-, F-, I- ch bng dd AgNO3.
D. Trong cc ion halogenua, ch c ion Cl- mi to kt ta vi Ag+.
Cu 22/. Dy axit no c xp theo th t tnh axit gim dn ?
A. HCl, HBr, HI, HF

B. HI, HBr, HCl, HF

C. HCl, HI, HBr, HF

D. HF, HCl, HBr, HI

Cu 24/. Chat nao co the kh c FeCl3 ?

A. KBr
B. NaCl
C. KI
D. NaF
Cu 25/. Cho 19g mui MgX2 (X: halogen) tc dng vi dd AgNO3 d c 57,4g kt ta. Cng thc ca
mui l :
A. MgI2
B. MgCl2
C. MgBr2
D. MgF2
Cu 26/. Cho 0,03mol hh 2 mui NaX vo NaY (X, Y l 2 halogen thuc 2 chu k lin tip) tc dng vi
AgNO3 d c 4,75g kt ta. X v Y l:
A. F v Cl
B. Cl v Br
C. Br v I
D. I v At
Cu 27/. Cho 5,6g Fe v 6,4g Cu vo dung dch HCl d. Th tch kh thu c ktc l:
A. 2,24 lt
B. 3,36 lt
C. 4,48 lt
D. 5,60 lt
Cu 28/. Phn ng no sau y c th xy ra c?
A. Br2 + 2NaCl 2NaBr + Cl2
B. Cl2 + 2NaI 2NaCl + I2
C. I2 + 2NaBr 2NaI + Br2
D. 3I2 + 6FeCl2 4FeCl3 + 2FeI3
Cu 29/. Dn 0,15mol kh clo qua V lt dung dch NaBr 0,1M, phn ng kt thc thu c 8g Br2. Gi tr
V l :
A. 0,5
B. 1,0
C. 1,5
D. 2,0
Cu 30/. Chn mt hp cht phn bit cc dd NaNO3, HCl, NaCl v AgNO3
A. phenolphtalein
B. dung dch NaOH
C. Qu tm
D. dung dch H2SO4
Cu 31/. Cho 200ml dd HCl 0,75M vo bnh cha 5,30g Na2CO3 th thy c kh khng mu bay ln. Th
tch kh thot ra ktc l:
A. 1,12 lt
B. 1,68 lt
C. 3,36 lt
D. 6,72 lt
Cu 32/. Chn cu sai:
A. C th iu ch Brom bng phn ng gia Cl2 vi NaBr.
B. Mui AgBr khng bn b phn tch khi c nh sng.
C. C th iu ch HBr bng phn ng NaBr vi H2SO4 c.
D. iu kin thng Br2 c th lng mu nu, d bay hi.
Cu 33/. Mui Iot l mui c cha Iot o dng no :
A. I2
B. MgI2
C. CaI2
D. KI
Cu 34/. Nu phn bit 2 dd NaBr, NaI ta c th dng
A. AgNO3
B. AgNO3, h tinh bt
C. FeCl3, ho tinh bt
D. H tinh bt
THI TUYN SINH CAO NG NM 2007
Cu 1: Khi cho 100ml dd KOH 1M vo 100ml dd HCl thu c dd c cha 6,525 gam cht tan. Nng
mol (hoc mol/l) ca HCl trong dd dng l (Cho H = 1; O = 16; Cl = 35,5; K = 39)
A. 0,75M.
B. 1M.
C. 0,25M.
D. 0,5M.
Cu 2: Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi dung dch HCl c
mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M c th l
A. Mg.
B. Zn.
C. Al.
D. Fe.
Cu 3: Cc kh c th cng tn ti trong mt hn hp l
A. NH3 v HCl.
B. H2S v Cl2.
C. Cl2 v O2.
D. HI v O3.
Cu 4: Ho tan hon ton hh X gm Fe v Mg bng mt lng va dd HCl 20%, thu c dd Y. Nng
ca FeCl2 trong dd Y l 15,76%. Nng phn trm ca MgCl2 trong dd Y l
A. 24,24%.
B. 11,79%.
C. 28,21%.
D. 15,76%.
THI TUYN SINH CAO NG NM 2009
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Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

CLB gia s Bch khoa

Cu 1: Cht dng lm kh kh Cl2 m l

A. Na2SO3 khan.
B. dung dch NaOH c.
C. dung dch H2SO4 m c .
D. CaO .
Cu 2: Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l:
A. NaHCO3, MgO, Ca(HCO3)2.
B. NaHCO3, ZnO, Mg(OH)2.
C. NaHCO3, Ca(HCO3)2, Al2O3.
D. Mg(OH)2, Al2O3, Ca(HCO3)2.
Cu 3: t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp
kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hh kh phn ng l 5,6 lt ( ktc).
Kim loi M l A. Mg.
B. Ca.
C. Be.
D. Cu.
Cu 4: Dy no sau y ch gm cc cht va tc dng c vi dd HCl, va tc dng c vi dd
AgNO3?
A. Fe, Ni, Sn.
B. Al, Fe, CuO.
C. Zn, Cu, Mg.
D. Hg, Na, Ca.
Cu 5: Nung nng 16,8 gam hh gm Au, Ag, Cu, Fe, Zn vi mt lng d kh O 2, n khi cc phn ng
xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dd HCl 2M va phn ng vi cht rn X
l
A. 400 ml.
B. 200 ml.
C. 800 ml.
D. 600 ml.
THI TUYN SINH I HC, CAO NG NM 2007, Khi A
Cu 1: Cho t t dd cha a mol HCl vo dd cha b mol Na 2CO3 ng thi khuy u, thu c V lt kh
( ktc) v dd X. Khi cho d nc vi trong vo dd X thy c xut hin kt ta. Biu thc lin h gia V
vi a, b l:
A. V = 22,4(a - b).
B. V = 11,2(a - b).
C. V = 11,2(a + b). D. V = 22,4(a + b).
Cu 2: Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng ng
l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li)
A. y = 100x.
B. y = 2x.
C. y = x - 2.
D. y = x + 2.
Cu 3: Trong phng th nghim, ngi ta thng iu ch clo bng cch
A. in phn nng chy NaCl.
B. cho dung dch HCl c tc dng vi MnO2, un
nng.
C. in phn dung dch NaCl c mng ngn.
D. cho F2 y Cl2 ra khi dung dch NaCl.
THI TUYN SINH I HC, CAO NG NM 2008, khi A
Cu 1: ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s
mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l
A. 0,23.
B. 0,18.
C. 0,08.
D. 0,16.
Cu 2: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra
A. s kh ion Cl-.
B. s oxi ho ion Cl-.
C. s oxi ho ion Na+.
D. s kh ion
Na+.
Cu 3: Cho 2,13 gam hh X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi thu c
hh Y gm cc oxit c khi lng 3,33 gam. Th tch dd HCl 2M va phn ng ht vi Y l
A. 57 ml.
B. 50 ml.
C. 75 ml.
D. 90 ml.
Cu 4: Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn
ng c vi dung dch HCl, dung dch NaOH l
A. 4.
B. 5.
C. 7.
D. 6.
Cu 5: Cho cc phn ng sau:
4HCl + MnO2 MnCl2 + Cl2 + 2H2O.
2HCl + Fe FeCl2 + H2.
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O.
6HCl + 2Al 2AlCl3 + 3H2.
16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O.
S phn ng trong HCl th hin tnh oxi ha l
A. 2.
B. 1.
C. 4.
D. 3.
Cu 6: Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y.
Dung dch Y c pH l
A. 4.
B. 3.
C. 2.
D. 1.
THI TUYN SINH I HC, CAO NG NM 2009, khi A

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Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

CLB gia s Bch khoa

Cu 1: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d

dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l
A. KMnO4.
B. MnO2.
C. CaOCl2.
D. K2Cr2O7.
Cu 2: Dy gm cc cht u tc dng c vi dung dch HCl long l:
A. KNO3, CaCO3, Fe(OH)3.
B. FeS, BaSO4, KOH.
C. AgNO3, (NH4)2CO3, CuS.
D. Mg(HCO3)2, HCOONa, CuO.
Cu 3: dd X cha hh gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dd HCl
1M vo 100 ml dd X, sinh ra V lt kh (ktc). Gi tr ca V l
A. 4,48.
B. 3,36.
C. 2,24.
D. 1,12.
Cu 4: Ho tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt
kh H2 ( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l
A. 2,80 lt.
B. 1,68 lt.
C. 4,48 lt.
D. 3,92 lt.
THI TUYN SINH I HC, CAO NG NM 2007, Khi B
Cu 1: Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100oC. Sau khi phn ng xy ra
hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l (cho Cl = 35,5; K = 39)
A. 0,24M.
B. 0,48M.
C. 0,4M.
D. 0,2M.
Cu 2: Cho 1,67 gam hh gm hai kim loi 2 chu k lin tip thuc nhm IIA (PNC nhm II) tc dng
ht vi dd HCl (d), thot ra 0,672 lt kh H 2 ( ktc). Hai kim loi l (cho Be = 9, Mg = 24, Ca = 40, Sr = 87,
Ba = 137)

A. Be v Mg.
B. Mg v Ca.
C. Sr v Ba.
D. Ca v Sr.
Cu 3: Nung 13,4 gam hh 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v kh X.
Lng kh X sinh ra cho hp th vo 75 ml dd NaOH 1M, khi lng mui khan thu c sau phn ng
l:
A. 5,8 gam.
B. 6,5 gam.
C. 4,2 gam.
D. 6,3 gam.
Cu 4: Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo chiu
tng ca in tch ht nhn nguyn t th
A. tnh phi kim gim dn, bn knh nguyn t tng dn.
B. tnh kim loi tng dn, m in tng dn.
C. m in gim dn, tnh phi kim tng dn.
D. tnh kim loi tng dn, bn knh nguyn t gim dn.
THI TUYN SINH I HC, CAO NG NM 2008, khi B
Cu 1: Cho bit cc phn ng xy ra sau: 2FeBr2 + Br2 2FeBr3; 2NaBr + Cl2 2NaCl + Br2
Pht biu ng l:
A. Tnh kh ca Cl- mnh hn ca Br -.
B. Tnh oxi ha ca Br2 mnh hn ca Cl2.
C. Tnh kh ca Br- mnh hn ca Fe2+. D. Tnh oxi ha ca Cl2 mnh hn ca Fe3+.
Cu 2: Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc
phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr
ca m l
A. 9,75.
B. 8,75.
C. 7,80.
D. 6,50.
Cu 3: Cho cc phn ng: Ca(OH)2 + Cl2 CaOCl2 + H2O
2H2S + SO2 3S + 2H2O
2NO2 + 2NaOH NaNO3 + NaNO2 + H2O
o
4KClO3 t
KCl + 3KClO4
O3 O2 + O
S phn ng oxi ho kh l
A. 5.
B. 2.
C. 3.
D. 4.
Cu 4: Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi dung
dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l :
A. Na.
B. K.
C. Rb.
D. Li.
Cu 5: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung
dch:
A. NaOH (d).
B. HCl (d).
C. AgNO3 (d).
D. NH3(d).
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Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

CLB gia s Bch khoa

o

Cu 6: Cho cc phn ng:

(1) O3 + dung dch KI

(2) F2 + H2O t
o
(3) MnO2 + HCl c t
(4) Cl2 + dung dch H2S
Cc phn ng to ra n cht l:
A. (1), (2), (3).
B. (1), (3), (4).
C. (2), (3), (4).
D. (1), (2), (4).
Cu 7: Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l
A. 1.
B. 3.
C. 2.
D. 4.
THI TUYN SINH I HC, CAO NG NM 2009, khi B
Cu 1: Cho cc phn ng sau:
(a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O.
(b) HCl + NH4HCO3 NH4Cl + CO2 + H2O.
(c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O.
(d) 2HCl + Zn ZnCl2 + H2.
S phn ng trong HCl th hin tnh kh l:
A. 2.
B. 3.
C. 1.
D. 4.
Cu 2: Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong
t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3
(d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l
A. 58,2%.
B. 41,8%.
C. 52,8%.
D. 47,2%.
THI TUYN SINH I HC, CAO NG NM 2011, khi A
Cu 1: Pht biu no sau y l sai?
A. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo.
B. m in ca brom ln hn m in ca iot.

C. Tnh kh ca ion Br ln hn tnh kh ca ion Cl .

D. Tnh axit ca HF mnh hn tnh axit ca HCl.
Cu 2: Trong cc th nghim sau:
(1) Cho SiO2 tc dng vi axit HF.
(2) Cho kh SO2 tc dng vi kh H2S.
(3) Cho kh NH3 tc dng vi CuO un nng.
(4) Cho CaOCl2 tc dng vi dung dch HCl c.
(5) Cho Si n cht tc dng vi dung dch NaOH.
(6) Cho kh O3 tc dng vi Ag.
(7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng.
S th nghim to ra n cht l
A. 7.
B. 6.
C. 5.
D. 4.
Cu 3: Khng kh trong phng th nghim b nhim bi kh clo. kh c, c th xt vo khng kh
dung dch no sau y?
A. Dung dch NaOH.
B. Dung dch NaCl.
C. Dung dch NH3.
D. Dung dch H2SO4 long.
Cu 4: Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d) thu c dung dch
Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta
A. Fe(OH)3.
B. Fe(OH)2 v Cu(OH)2.
C. Fe(OH)2, Cu(OH)2 v Zn(OH)2.
D. Fe(OH)3 v Zn(OH)2.
THI TUYN SINH I HC, CAO NG NM 2011, khi B
Cu:1 Trong t nhin clo c hai ng v bn:

37
17

Cl chim 24,23% tng s nguyn t, cn li l

35
17

Cl .

37

Thnh phn % theo khi lng ca 17 Cl trong HClO4 l:

A. 8,92%
B. 8,43%
C. 8,56%
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D. 8,79%
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Ti liu n thi H-C 2010-2011

Chuyn : Nhm halogen v hp cht ca chng

CLB gia s Bch khoa

Cu 2: Cho dy cc cht sau: Al, NaHCO 3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C bao nhiu
cht trong dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH?
A. 2
B. 3
C. 4
D. 5
Cu 3: Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch FeCl2 l:
A. Bt Mg, dung dch NaNO3, dung dch HCL
B. Bt Mg, dung dch BaCl2, dung dch HNO3
C. Kh Cl2, dung dch Na2CO3, dung dch HCL
D. Kh Cl2, dung dch Na2S, dung dch HNO3
Bi ging c bin son v tng hp bi CLB Gia S Bch Khoa
Mi ng gp ,thc mc ca bn c xin gi v a ch :
giasubachkhoa09@gmail.com
Hoc lin h vi trng nhm gia s Nguyn Gia Huy 0904532035

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