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9/26/2008

MSE 280: Introduction to Engineering Materials

Mechanical Properties
Why mechanical properties?

Reading: Chapter 7

Need to design materials that can withstand applied load


e.g. materials used in
building bridges that can
hold up automobiles,
pedestrians

materials for
skyscrapers
in the Windy
City

NASA

materials for
space
exploration
materials for and designing
MEMs and NEMs

Space elevators?

2007, 2008 Moonsub Shim, University of Illinois

MSE280

Issues to address
Stress and strain
Elastic behavior
Plastic behavior
Strength, ductility, resilience, toughness,
hardness
Mechanical behavior of different classes
of materials
Design/safety factors
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Stress and Strain


Stress: Pressure due to applied load.
tension, compression, shear, torsion, and
combination.

stress = =

force
area

Strain: response of the material to stress (i.e. physical


deformation such as elongation due to tension).

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Tension

Shear
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Compression

Torsion

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COMMON STATES OF STRESS


Simple tension: cable

Ao = cross sectional
Area (when unloaded)

Ao

Ski lift

(photo courtesy P.M. Anderson)


From Callister 6e resource CD.

2007, 2008 Moonsub Shim, University of Illinois

MSE280

COMMON STATES OF STRESS


Simple compression:

Ao

Canyon
y Bridge,
g Los Alamos, NM
(photo courtesy P.M. Anderson)

Balanced Rock, Arches


National Park

(photo courtesy P.M. Anderson)

F
Ao

Note: compressive
structure member
( < 0 here).
From Callister 6e resource CD.

2007, 2008 Moonsub Shim, University of Illinois

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COMMON STATES OF STRESS


Hydrostatic compression:

Fish under water

<
h 0

(photo courtesy
P.M. Anderson)

From Callister 6e resource CD.

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MSE280

Tension and Compression


Tension

Engineering stress = =

F
Ao

Engineering strain = =

li lo l
=
lo
lo

Ao = original cross sectional area


li = instantaneous length
lo = original length
Note: strain is unitless
unitless.

Compression
Same as tension but in the opposite direction (stress and strain defined
in the same manner).
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By convention, stress and strain are negative for compression.
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Shear

Pure shear stress = =

F
Ao

Pure shear strain = = tan

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Elastic Deformation
1. Initial

2. Small load

3. Unload

bonds
stretch
return to
initial

Elastic means reversible!


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Linearelastic

Non-Linearelastic
From Callister 6e resource CD.

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Plastic Deformation
1. Initial

2. Small load
bonds
stretch
& planes
shear

3. Unload
p lanes
still
sheared
plastic

elastic + plastic

F
F
Plastic means permanent!

linear
elastic

From Callister 6e resource CD.

linear
elastic

plastic

2007, 2008 Moonsub Shim, University of Illinois

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MSE280

Stress-strain test

tensile stress,

Elastic+Plastic
at larger stress

Elastic
initially
permanent (plastic)
after load is removed

engineering strain,

From Callister 6e resource CD.

p lastic strain
Figure 6.3 Callister

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Elastic Deformation
-a non-permanent deformation where the material completely
recovers to its original state upon release of the applied stress.

= E

Hookes Law:

strain

stress

Modulus of elasticity (Youngs modulus)

Measure of materials resistance


to elastic deformation (stiffness).
E = slope in the linear region
For metals, typically E ~ 45 400 GPa

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MSE280

Recall back to bonding Energy vs. r curve


E
Steeper slope near ro leads to larger
Elastic modulus.
r
Bond
B
d
energy

tension

compression
Equilibrium bond length = ro

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S co (s
Silicon
(single
g e ccrystal)
ysta )
Glass (pyrex)
SiC (fused or sintered)
Graphite (molded)
High modulus C-fiber
Carbon Nanotubes

120
0 - 190
90 (depe
(depends
ds o
on ccrystallographic
ysta og ap c d
direction)
ect o )
70
207 - 483
~12
If we normalize to density: ~20 times
400
that of steel wire.
~1000
Density normalized strength is ~56X
15
that of steel wire.
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Elastic deformation: example problem

100 inches
1 inch

Steel car hanger: How many


VW Beetles must we hang
from a 100 inch long bar of
steel in order to stretch it by
1%?
Ao = 1 in2
E = 30 x 106 psi

MATSE 101 Materials in Todays World


Tim Spila, 2002

I. Robertson, Ken Bratland 1999, 2000

Will this be an elastic deformation?


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Poisson Ratio
So far, weve considered stress only along one dimension
Along
g z: tension

z =

l
lo

Along x: compression

z
x

do

x =

lo

lo+l

Isotropic x and y: =
y
x

do+d

Poisson ratio =
Compression

d
do

y
x
=
z
z

Elongation

Relation between elastic and shear moduli: E = 2G(1+)


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MSE280

Poisson Ratio
Poisson Ratio has a range 1 1/2
Look at extremes w /w = l /l
No change in aspect ratio:
w /w
=
= 1

l /l

Volume (V = AL) remains constant: V =0 or lA = - A l


Hence, V = (l A+A l) = 0.
In terms of width, A = w2,
and A = w2 - ((w+w))2 = 2w w + w2
then
A/A = 2 w/w + w2/w2
in the limit of small changes,
w / w
( 1 l / l)
A/A = 2 w/w
=
= 2
= 1/ 2
then
l / l
l / l
2 w/w = -l/l
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Poisson Ratio: materials specific


Metals: Ir

W
0.26

Ni
0.29

Cu
0.31

Al
0.34

Ag
0.34

Au
0.38

0.42

generic value ~ 1/3

Solid Argon: 0.25


Covalent Solids:
Ionic Solids:

Si
0.27
MgO

Ge
0.28

Al2O3
0.23

TiC
0.19

generic value ~ 1/4

0.19

Silica Glass: 0.20


Polymers: Network (Bakelite) 0.49
Elastomer:

Chain (PE) 0.40

Hard Rubber (Ebonite) 0.39

(Natural) 0.49
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MSE280

Poisson Ratio: Example problem


Calculate the force necessary to produce change
of - 2.5 x 10-3 mm in diameter of a 10mm diameter
brass rod
rod.

z
x

do=10 mm

d = -2.5 x 10-3 mm
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Plastic Deformation
Simple tension test:
Elastic+Plastic
at larger stress

tensile stress,
stress

Elastic
initially
permanent (plastic)
after load is removed

engineering strain,

From Callister 6e resource CD.

p lastic strain

A permanent deformation (usually considered for T<Tm/3).


Atoms break bonds and form new ones.
In metals, plastic deformation occurs typically at strain 0.005.
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Tensile properties
A. Yield strength (y): the strength required to produce
a very slight yet specified amount of plastic deformation.
Whatt iis th
Wh
the specified
ifi d amountt off strain?
t i ?
Strain offset method
1. Start at 0.002 strain (for most metals).
2. Draw a line parallel to the linear region.
3. y = where the dotted line crosses
the stress-strain curve.

P = proportional limit (beginning of


deviation from linear behavior.
behavior
Mixed elastic-plastic behavior
0.002

Elastic region

For materials with nonlinear elastic region:


y is defined as stress required to produce
specific amount of strain (e.g. ~0.005 for
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most metals).

2007, 2008 Moonsub Shim, University of Illinois

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Tensile properties
Yield point phenomenon occurs when elastic-plastic
transition is well-defined and abrupt.
p

No offset methods required here.

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Fig. 6.10 Callister

2007, 2008 Moonsub Shim, University of Illinois

MSE280

Yield strengths of different materials


Metals/
Alloys

Graphite/
Ceramics/
Semicond

Composites/
fibers

Polymers

20 00

300

Yield strenggth,

200

Ti (5Al-2.5Sn) a
W (pure)
Cu (71500) cw
Mo (pure)
Steel (4140) a
Steel (1020) cd
Al (6061) ag
Steel (1020) hr
Ti (pure) a
Ta (pure)
Cu (71500) hr

100
70
60
50
40

Al (6061) a

30
20
Tin (pure)

dry

PC
Nylon 6,6
PET
humid
PVC
PP
HDPE

Harrd to measure,

700
600
500
400

LDPE

10 Moonsub Shim, University of Illinois


2007, 2008

in ceramic matrix and ep


poxy matrix composites, since
in tension, fracture u
usually occurs before yield.

10 00

Hard
d to measure ,
since in tension, fracture usually occurs before yield.

y (MPa))

Steel (4140) qt

y(ceramics)
>>y(
y(metals))
>> y(polymers)
Room T values
Based on data in Table B4,
Callister 6e.
a = annealed
hr = hot rolled
ag = aged
cd = cold drawn
cw = cold worked
qt = quenched & tempered

From Callister 6e resource CD.

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Tensile Properties
B. Tensile Strength (TS): stress at the maximum of
stress-strain curve.

TS

P = proportional limit
y = yield strength
TS = tensile strength
M = max. stress
F = fracture point

0.002

Elastic region

Note: For most engineering materials, strength should be


specified by yield strength (not tensile strength). Why? 25

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MSE280

Necking

engineering
stress

TS

Adapted from Fig. 6.11,


Callister 6e.
6e

Typical response of a metal

strain
Necking: at maximum stress, a small constriction (a neck)
appears.
Subsequent deformation is confined to this neck.
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True stress and strain


engineering
g
stress

TS

Notice that past maximum stress


point, decreases.
Does this mean that the
material is becoming weaker?
Typical response of a metal

Necking leads to smaller cross


sectional area!

strain

Recall: Engineering Stress = =


True Stress = T =

F
Ai

True Strain = T = ln

li
lo

F
Ao

Original cross sectional area!

Ai = instantaneous area
li = instantaneous length
If no net volume change (i.e. Ai li = Ao lo)

T = (1 + )
T = ln(1 + )

2007, 2008 Moonsub Shim, University of Illinois

Only true at the onset of


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necking

MSE280

Example problem
Calculate/determine the
following for a brass
specimen
i
th
thatt exhibits
hibit
stress-strain behavior
shown on the left.
1) Modulus of elasticity.
2) Yield strength.
3) Maximum load for a
cylindrical specimen
with d = 12.8mm.
4) Change in length at
345MPa if the initial
length is 250mm.

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Tensile properties
C. Ductility: measure of degree of plastic deformation that
has been sustained at fracture.
Ductile materials can undergo significant plastic
deformation before fracture.
Brittle materials can tolerate only very small plastic
deformation.

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Measure of ductility
% elongation =

% reduction in area =

l f lo
lo

100%

Ao A f
Ao

Lo

Ao

Af

Lf

100%
Ao and lo are initial.
Af and lf are at
fracture.

N
Note:
t %AR and
d %EL are often
ft comparable.
bl
--Reason: crystal slip does not change material volume.
--%AR > %EL possible if internal voids form in neck.
Typically, materials are considered: brittle if %EL < 5%
ductile if %EL > 5%

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Example Problem: ductility & true stress

engineering
stress

TS

Typical response of a metal

Steel specimen with


do = 12.8 mm
Fracture at f = 460 MPa
Cross sectional diameter at
fracture = 10.7 mm

strain

A) Calculate ductility in terms of percent reduction in area.


B) The true stress at fracture.

Example problem 6.4 Callister 6e

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MSE280

Note: most metals are ductile at RT, but can become


brittle at low T

Ductile failure

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Brittle failure

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Tensile properties
D. Resilience: the capacity to absorb energy when
deformed elastically and to have the absorbed energy
recovered upon unloading.
Modulus of Resilience =U

= d
0

Ur =

y2
2E

Resilient materials have large


yield strength and small elastic
modulus.

Ur = area under
the elastic region
y

If the elastic region


is perfectly linear
(i.e. E is
independent of ):

E. Toughness: the ability of a material to absorb energy


up to its fracture point.
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Elastic recovery after plastic deformation

This behavior is exploited


to increase yield strengths
of metals: strain
hardening (also called
cold working).

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Hardness
Resistance to permanently indenting the surface.
Large hardness means:
--resistance to p
plastic deformation or cracking
g in
compression.
--better wear properties.
e.g.,
10mm sphere

apply known force


(1 to 1000g)

measure size
of indent after
removing load

Smaller indents
mean larger
hardness.

Indentation will depend not only on the material being


tested but also indenter composition and geometry.
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Hardness scales

Indentation with
diamond pyramid tip
Indentation with
spherical hardened
steel and conical
diamond (for
hardest materials)

Indentation with spherical


hardened steel or tungsten
carbide tip.

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Qualitative scale

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Correlation between hardness and tensile strength

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Both tensile strength and


hardness indicate a
materials resistance to
plastic deformation.
these two properties are
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roughly proportional.

MSE280

Mechanical properties - Ceramics


Recall tensile tests for stress-strain behavior

Most ceramics (brittle):


need to apply large stress
(but very little strain till
fracture)
Most metals: can
get elastic
modulus, yield
strength tensile
strength,
strength etc

In fact, if the testing apparatus is mainly made of metal, how do we


test for ceramics with larger fracture strength?
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3-point bend test

This is similar to tensile test. Why?


Look at point of max stress (where is it?).

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MSE280

3-point bend test


b

Elastic modulus is proportional to F/

F L3

4bd 3
F L3

=
4R 4

Erectt . =
Ecirc.

Flexural strength: strength at fracture


Sl
Slope
= F/

fs = 2
fs =

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3F f L

4bd 2
Ff L

R 3

Rectangular
Circular

Ff = force at fracture

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Example 1: 3pt bend test


F
Glass specimen
5 mm
10 mm
45 mm
a)) Calculate
C l l t fl
flexurall strength
t
th if th
the lload
d att ffracture
t
iis 290 N
N.
b) Calculate the maximum deflection at F = 266 N

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MSE280

Example 2: 3pt bend test


F
Sample A

A
R2 = d2

L
F

Sample B

L
Compare the ratio of flexural strengths
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Polymer stress-strain behavior


Brittle
Plastic
Highly elastic

Plastic polymers
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MSE280

Polymer stress-strain behavior


Modulus of elasticity ~7MPa to 4GPa.
Tensile strength up to ~100MPa.
Plastic elongation can be >100%.
Typically highly T sensitive mechanical properties.

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Polymer stress-strain behavior


Metal (Iron)

Polymer (PMMA)

As T increases:
E decreases
TS decreases
Ductility increases
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MSE280

Semicrystalline polymer
Upper
yyield p
pt

Neck formation
(chains become
aligned in the neck)

Elongation via neck propagation


lower yield pt
Elastic region

Compare to metals where


neck forms and
subsequent deformation is
at the neck.
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Viscoelastic deformation
Amorphous polymers may act like:
- Glass at low T (T < Tg Glass transition temperature).
- Rubbery solid (Tm > T > Tg).
- Viscous
Vi
liliquid
id (T > Tm).
)
Viscoelasticity: mechanical characteristics exhibiting both viscous
flow and elastic deformation (rubbery solid).

Elastic

Instantaneous
response w/
complete
recovery.
y

Delayed
response.
Viscous Not reversible.

Viscoelastic

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MSE280

Viscoelastic relaxation modulus


Recall Elastic Modulus:

= E

The modulus can be both time and temperature dependent.


(t)
1. At a constant T, apply small stress () to
achieve initial strain (o).
2. Adjust to maintain o.
3. Repeat at different T.
(t)
For each T: Relaxation Modulus

E r (t ) =

(t )
o
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Viscoelastic relaxation modulus


Plot as a
function
of T at a
fixed t.

Polystyrene (t = 10s)
3 orders of magnitude
change
Glass transition

Fig. 15.6 Callister

2007, 2008 Moonsub Shim, University of Illinois

Fig. 15.7 Callister

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Viscoelastic relaxation modulus


Glassy region:
Initially independent of T.
Rigid & brittle (molecular chains
f
frozen
in
i place).
l
)
Glass transition region:
Time-dependent deformation.
Incomplete recovery upon release
of load.
Rubbery region:
Both viscous and elastic.
elastic
Low relaxation modulus -> easy
to deform.
Viscous flow region:
High viscosity liquid.
Completely viscous deformation.
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Viscoelastic relaxation modulus


Molecular structure effect

Polystyrene

Crystalline isotactic PS

Highly crosslinked PS

Amorphous PS
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MSE280

Viscoelastic creep
Time dependent deformation when stress is kept
constant (as opposed to constant strain for viscoelastic
rela ation)
relaxation).
Creep modulus:

E c (t ) =

o
(t )

Similar to relaxation modulus, creep modulus is


dependent on T and structure.
In general: Ec(t) decreases with increasing T
Ec(t) increases with increasing crystallinity.
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MSE280

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Example problem
crystalline
crosslinked

amorphous

Which behavior will polystyrene exhibit if it is:


1) amorphous and deformed at 120oC?
2) amorphous and deformed at 180oC?
3) crystalline and deformed at 70oC?
4) crosslinked and deformed at 180oC?
2007, 2008 Moonsub Shim, University of Illinois

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MSE280

Concepts to remember

Tensile, compressive, shear, and torsional stress. Strain.


Elastic vs. Plastic deformation.
Modulus of elasticity.
Yield and tensile strengths.
Poisson ratio.
True vs. Engineering stress and strain.
Necking.
Ductility, Resilience, Toughness, Hardness.
Polymer stress-strain behavior.
Viscoelastic relaxation and creep.

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2007, 2008 Moonsub Shim, University of Illinois

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