Cu 33.

Hn hp X gm Al2(SO4)3 v Na2SO4 (trong s nguyn t oxi chim 20/31 tng s

nguyn t c trong hn hp). Ha tan m1 gam X vo lng nc d thu c dung dch Y. Cho BaCl2
n d vo Y, thu c m2 gam kt ta. T l m1 : m2 c gi tr gn nht l.
A. 0,5
B. 1,6
C. 1,5
D. 0,6
Gii
Chn n cc nguyn t trong X = 31 nO = 20 nS = 5 nAl + nNa = 6
H: 2a + 2b = 6; BTS 3a + b = 5 a = 1; b = 2
BTS nBaSO4 = 5 m1 : m2 = 0,54
Cu 34. Thy phn hon ton m gam hn hp X gm peptit Y (C6H11O4N3) v peptit Z (C11H20O5N4)
cn dng 300 ml dung dch NaOH 1M, thu c dung dch T c cha 6,255 gam mui ca valin. Gi
tr m l.
A. 20,52 gam B. 25,02 gam C. 22,05 gam D. 22,50 gam
Gii
Y: Gly3: y
Z: Gly3Val
nVal-Na = 0,045 nZ = 0,045 nY = (0,3 - 0,045.4):3 = 0,04
m = 20,52
Cu 35. Hp th hon ton 0,2 mol kh CO2 vo dung dch cha Ba(OH)2 v 0,2 mol NaOH, thu c
m gam kt ta v dung dch X gm cc mui. Cho t t dung dch cha HCl 0,4M v H2SO4 0,2M
vo dung dch X, thy hot ra 0,08 mol kh CO2; ng thi thu c dung dch Y. Cho Ba(OH)2 d
vo dung dch Y, thu c 22,75 gam kt ta. Gi tr ca m l.
A. 11,82 gam B. 5,91 gam
C. 9,85 gam
D. 7,88 gam

Na : 0,2
Na

2
Ba(OH)2
HCO3
BaCO3
Ba(OH)2
HCl:2y
CO2
BaCO3 CO3

CO

H2 SO4 :y

NaOH : 0,2
2

Cl : 2y
BaSO4 : y

0,2
0,08
x
HCO
3

SO2 : y
4

BTC nHCO3-trong Y = 0,12 - x nBaCO3 = 0,12 - x

mkt = 22,75 197 (0,12 - x) + 233.y = 22,75
BTT cho Y 0,2 = 0,12 - x + 4y
x = 0,04 m = 7,88
Cu 36. Theo gi ca thy To Mnh c
Thc hin s phn ng sau (ng vi t l mol cc cht)
t0

2X1 + X2 + 2H2O
(1) X + 2NaOH
(2) 2X1 + H2SO4 2X3 + Na2SO4
t0

(NH4)2CO3 + 2NH4NO3 + 2Ag

(3) X3 + 2AgNO3 + 4NH3 + H2O
xt,t 0

Nilon-6,6 + 2nH2O
(4) nX2 + nX4
iu khng nh no sau y l sai?
A. X2, X3, X4 u c cu trc mch khng phn nhnh.
B. Trong X3, s nguyn t hiro bng s nguyn t oxi.
C. X c cng thc phn t l C6H14O4N2.
D. Trong X2, s nguyn t hiro l s chn.
Gii
X2: H2N-(CH2)6-NH2
X4: HOOC-(CH2)4-COOH
X3: HCOOH
X1: HCOONa
X: HCOONH3-(CH2)6-NH3OOCH CTPT X: C8H20O4N2
Cu 37. Cho 3,68 gam hn hp gm Mg v Fe vo dung dch cha FeCl3 0,4M v CuCl2 0,6M. Kt
thc phn ng, thu c dung dch X v 4,48 gam rn Y. Cho dung dch NaOH d vo X (khng c
mt oxi) thu c 14,44 gam kt ta. Lc ly kt ta, nung ngoi khng kh n khi lng khng i
thu c x gam rn khan. Gi tr ca x l.
A. 20,0 gam
B. 12,0 gam
C. 18,4 gam
D. 10,4 gam

M n
M n
Mg
FeCl3 : 4a

NaOH
nung

ddX

xg ran

Fe
CuCl
:
6a
Cl
:
24a
OH
:
24a

4,48g

2
3,68

14,44g

BTKL 3,68 + 4a.56 + 64.6a = 4,48 + 14,44 - 17.24a a = 0,015

Nu Cu2+ ht mCu = 0,09.64 = 5,76 > 4,48 Cu2+ d Y ch c Cu: 0,07

Mg2 : x
2
Mg FeCl3 : 0, 06
Fe : y 0, 06

Cu : 0, 07 ddX 2

Fe
CuCl
:
0,
09

Cu : 0, 02
2
Cl : 0,36
3,68

24x + 56y = 3,68

BTT 2x + 2y = 0,2
x = 0,06; y = 0,04

MgO : 0, 06

Fe2 O3 : 0, 05 x 12
CuO : 0, 02

Cu 38. Thy phn hon ton m gam hn hp X gm peptit Y (C6H11O4N3) v peptit Z (C11H20O5N4)
cn dng 300 ml dung dch NaOH 1M, thu c dung dch T c cha 6,255 gam mui ca valin. Gi
tr m l.
A. 20,52 gam B. 25,02 gam C. 22,05 gam D. 22,50 gam
Gii
Y: Gly3: y
Z: Gly3Val
nVal-Na = 0,045 nZ = 0,045 nY = (0,3 - 0,045.4):3 = 0,04
m = 20,52
Cu 39. Hn hp X cha ba este mch h, u c to bi t mt ancol no, n chc v cc axit
cacboxylic c mch cacbon khng phn nhnh. t chy hon ton 8,58 gam X cn dng 0,395 mol
O2, thu c 4,5 gam nc. Mt khc hiro ha hon ton 8,58 gam X cn dng 0,1 mol H2 (xc tc
Ni, t0) thu c hn hp Y cha este u no. un nng ton b Y vi dung dch NaOH va , thu
c hn hp gm hai mui, trong c a gam mui A v b gam mui B (MA < MB). T l gn nht
ca a : b l.
A. 1,0
B. 0,8
C. 1,2
D. 0,6
Gii
BTKL nCO2 = 0,38
BTO nCOO = 0,11
npi gc = nH2 = 0,1 npi X = 0,11 + 0,1 = 0,21
nCO2 - nH2O = npi X - nX nX = 0,08
COOtb = 1,375 c c este n chc v este hai chc

R1COO : 0, 05
2
R (COO)2 : 0, 03 0,05k1 + 0,03k2 = 0,1 k1 = 2; k2 = 1
C H
m 2m 1 : 0,11
BTC 0,05 (n1 + 1) + 0,03(n2 + 2) + 0,11m = 0,38
n1 = 2; n2 = 2; m = 1
A: C2HCOONa: 0,05; B: C2H4(COONa)2: 0,03 a : b = 0,946
Cu 40. Ha tan ht hn hp gm 7,44 gam Mg v 4,86 gam Al trong dung dch cha 1,44 mol
HNO3 v 0,12 mol NaNO3, sau khi kt thc phn ng, thu c dung dch X ch cha cc mui v
hn hp kh Y gm hai kh khng mu, khng ha nu ngoi khng kh. C cn dung dch X, thu
c hn hp mui Z, Nung Z n khi lng khng i, thu c phn rn c khi lng gim

67,76 gam so vi khi lng ca Z. T khi ca Y so vi He c gn tr gn nht vi gi tr no sau

y?
A. 9
B. 10
C. 8
D. 11

Mg(NO3 )2 : 0,31
NO
Al 2 O3 : 0, 09 2

Mg : 0,31 HNO3 :1, 44

N
Al(NO3 )3 : 0,18
O
t0

Y 2

MgO : 0,31 2

Al : 0,18 NaNO3 : 0,12

NaNO : 0,12 N 2 O
N 2 O NH 4 NO3
2

NaNO : 0,12
H O

3
2
mrn gim = 0,31.148 + 0,18.213 + 0,12. 85 + 80x - 0,09.102 - 0,31.40 - 0,12.69 = 67,76
x = 0,04
nN2 = a; nN2O = b
BTN 1,56 = 2a + 2b + 0,31.2 + 0,18.3 + 0,04.2 + 0,12
BTE 0,31.2 + 0,18.3 = 10a + 8b + 0,04.8
a = 0,02; b = 0,08
d = 10,2