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Abstract
Brine viscosities are an important property in sand control and
coil tubing operations. Viscosities are used to calculate sand
settling rates for gravel packing and frictional pressure losses.
Due to limited brine viscosity data, viscosites were determined
for conventional completion fluids using an Oswald
viscometer. Then three dimension equations were determined
as a function of density and temperature for calcium chloride,
calcium bromide, calcium chloride and calcium bromide,
calcium bromide and zinc bromide, three salt mixture of
calcium chloride, calcium bromide and zinc bromide, and
sodium bromide solutions. All equations had an average
deviation from the measured values of less than 10%.
Introduction
Viscosities for water and low density brines are readily
available even at elevated pressures.1-2 However, very little
work has been done on brines above 10.0 ppg. One source
provided brine viscosities in chart form at densities up to 16.5
ppg and at temperatures ranging from 40 to 500F.3 However,
interpolating within these brine densities are difficult but were
the best the industry had available. Since these viscosities
were established using an Ostwald-Cannon-Fenske viscometer, measuring these brine viscosities above 250F is
impossible due to boiling of these brines. Obviously, the brine
viscosities were extrapolated from the measured data above
the boiling point. Since no experimental data was provided,
the accuracy of these brine viscosities is questionable. Also
brine viscosities above 16.5 ppg are needed.
The purpose of this work is to provide brine
viscosities in equation form and to report the accuracy of these
equations from the experimental data.
Experimental
The various densities of the calcium chloride brines were
achieved by mixing 11.6 ppg calcium chloride with water until
the desired density was reached. The densities of the calcium
chloride, calcium bromide brines were achieved by combining
11.6 ppg calcium chloride with 15.1 ppg calcium bromide,
calcium chloride (two salt blend) until the chosen density was
attained. The densities of the calcium chloride, calcium
bromide and zinc bromide brines were made by adding 15.1
ppg calcium chloride, calcium bromide to 19.2 ppg calcium
bromide, zinc bromide (three salt blend) until the desired
densities were achieved. The densities of the sodium bromide
fluids were reached by diluting 12.5 ppg sodium bromide with
water. The specific gravity of the fluid was then measured.
The brines were then cooled to around 35oF. The viscosities
for the calcium chloride brines were measured using a Cannon
Instrument Company Viscosity Tube model number 50 Y 991.
All of the other viscosities were measured using a Cannon
Instrument Company Viscosity Tube model number 150 433 I.
The different fluids were placed in the tube, and the amount of
time for the fluid to go from the top line on the tube to the
bottom line of the tube was measured using a standard
stopwatch. This was done three times, and an average was
taken of the three times in seconds. After the 35F run was
completed, the brine was heated in the viscosity tube using a
Fisher Scientific Isotemp 2150 heater and a 4000 mL beaker
of water. The same procedure regarding the viscosity tube and
the stopwatch was repeated. The brines were heated to 198oF
in increments of 20oF. The brines were allowed to heat for
fifteen minutes to confirm that the temperature of the brine
was the same as the temperature of the water in the beaker.
Equation 1 was used to calculate the viscosities at
temperature.
SPE 86506
References
1.
Kestin J., Khalifa, H. E., Ro, S. T., and Wakeham, W., A.,
"Preliminary Data on the Pressure Effect on the Viscosity
of Sodium Chloride-Water Solutions in the Range 10
40C, J. of Chemical and Engineering Data, Vol. 22,
No. 2 (1977) 207.
Conclusions
2.
3.
4.
Nomenclature
= the coefficient of the viscometer
= the brines density, ppg at temperature
t = the time in seconds
T = the temperature in degrees Farhenheit
Table 1
Brine Viscosity Equations
Density Range
Viscosity Equation
-5
Average % Deviation
6.51
0.9954
8.58
0.9992
1.70
0.9965
7.00
0.9919
5.32
0.9966
2.73
SPE 86506
25
25
20
20
15
15
10
10
0
19
175
18
Densit 17
y, ppg
16
15
14 25
Viscosity, cp.
Viscosity, cp.
15
12 0
100 5
, F
75
rature
e
p
50
m
Te
Brine Viscosities
70.00
60.00
50.00
40.00
30.00
20.00
10.00
0.00
0.00
10.00
60.00
70.00
SPE 86506
Density
ppg
Time
sec.
16.5
64.4
88.1
108
127.9
148.1
167.9
188
198
11.18
11.06
11.00
10.95
10.90
10.84
10.78
10.71
10.68
142
44
34
29
25
22
20
18.7
18
Viscosity
cp.
Measured
6.21
1.90
1.46
1.24
1.06
0.93
0.84
0.78
0.75
% Dev
Temp.
F
Density
ppg
Time
sec.
-0.05
12.96
11.52
1.51
-6.38
-12.36
-17.11
-21.33
-22.19
36.5
70.6
88.5
108.1
128.2
147.9
168.1
188.1
198
13.14
13.02
12.96
12.90
12.83
12.76
12.70
12.63
12.60
85
68.3
56.7
47
40
34
31
27.7
26
Density
ppg
Time
sec.
37.6
72.3
88.4
108.1
128
148
167.7
188
198
11.53
11.44
11.40
11.34
11.29
11.23
11.17
11.10
11.07
59
44
38
32
27
24
22
20
19
Viscosity
cp.
Measured
2.66
1.97
1.69
1.42
1.19
1.05
0.95
0.86
0.82
Density
ppg
Time
sec.
40.5
68.7
88.5
108.1
128.1
148
167.9
187.9
198
12.07
11.99
11.93
11.87
11.81
11.75
11.69
11.62
11.59
65.3
48.3
42
35
30
26.7
24
22
21
Viscosity
cp.
Measured
3.08
2.26
1.96
1.62
1.38
1.22
1.09
0.99
0.94
Viscosity
cp.
Predicted
4.40
3.80
3.05
2.36
1.86
1.53
1.30
1.15
1.09
% Dev
Viscosity
cp.
Predicted
8.18
7.55
5.60
4.34
3.43
2.81
2.40
2.12
2.01
% Dev
Viscosity
cp.
Predicted
13.31
10.58
8.21
6.49
5.32
4.54
4.00
3.80
% Dev
0.74
9.23
6.18
-0.13
-6.87
-9.30
-14.75
-15.31
-14.08
% Dev
Temp.
F
Density
Ppg
Time
sec.
-1.83
12.21
6.90
-1.19
-6.87
-13.52
-18.85
-20.91
-20.74
44.7
62.5
88.5
108
127.9
147.9
167.9
187.9
198.1
14.37
14.30
14.20
14.12
14.05
13.98
13.90
13.83
13.80
144.7
132
98.6
80
66
56
48
42
39
Viscosity
cp.
Measured
4.37
3.47
2.87
2.36
2.00
1.69
1.53
1.36
1.27
Viscosity
cp.
Measured
8.13
7.37
5.46
4.41
3.61
3.05
2.59
2.26
2.09
0.59
2.35
2.43
-1.44
-5.00
-7.61
-7.51
-6.22
-3.98
% Dev
Temp.
F
Density
Ppg
Time
sec.
-0.23
18.74
8.03
1.05
-6.34
-13.05
-16.92
-19.55
-19.82
69.7
88.5
108
127.9
148
167.9
187.8
197.9
15.18
15.10
15.02
14.94
14.86
14.79
14.71
14.67
233.7
178
138
110
90
75
64
59
Viscosity
cp.
Measured
13.85
10.49
8.08
6.40
5.20
4.31
3.66
3.36
-3.92
0.87
1.59
1.35
2.13
5.24
9.48
12.94
SPE 86506
Table A-2
Calcium Chloride Solutions
8.5 ppg CaCl2
Temp.
F
Density
ppg
Time
sec.
44.4
67.8
88.1
108.2
127.9
147.9
168.1
188.1
199
8.56
8.54
8.51
8.48
8.44
8.39
8.34
8.28
8.25
446
277.3
218.7
179
149
127
112
98.7
93.7
Viscosity
cp.
Measured
1.92
1.19
0.93
0.76
0.63
0.53
0.47
0.41
0.39
% Dev
Temp.
F
Density
ppg
Time
sec.
-3.11
-0.12
-3.66
-4.87
-3.75
-2.58
-2.85
-1.35
-1.65
43.5
67.2
88.1
108.2
128
148.1
168.1
188.1
199.7
10.01
9.96
9.92
9.87
9.83
9.78
9.72
9.67
9.64
682
457
360
295
249
214
186
166
157
Density
ppg
Time
sec.
44.8
69.3
88.9
108.2
128
148
168.2
188.1
199.9
9.06
9.03
9.00
8.96
8.92
8.88
8.82
8.77
8.73
479.3
307
251
205.3
173.7
148.7
130
114
109
Viscosity
cp.
Measured
2.18
1.39
1.13
0.92
0.78
0.66
0.57
0.50
0.47
Density
ppg
Time
sec.
43.9
67.6
88.3
108.1
128.1
148.3
168
188.3
199.7
9.54
9.50
9.46
9.42
9.38
9.33
9.28
9.22
9.19
531.3
367.3
294
240
201.3
174
151
134
126
Viscosity
cp.
Measured
2.55
1.75
1.39
1.13
0.94
0.81
0.70
0.62
0.58
Viscosity
cp.
Predicted
3.83
2.49
1.91
1.56
1.32
1.14
1.01
0.90
0.85
% Dev
Viscosity
cp.
Predicted
7.55
3.41
2.77
2.31
1.97
1.71
1.50
1.42
% Dev
Viscosity
cp.
Predicted
17.76
7.04
5.51
4.44
3.66
3.09
2.72
2.55
% Dev
11.66
9.11
6.50
6.78
7.77
9.39
11.42
12.64
12.70
% Dev
Temp.
F
Density
ppg
Time
sec.
6.60
7.14
2.08
2.62
2.73
4.11
5.21
7.81
6.45
42.3
88.2
106.9
126.8
146.9
167.1
188.5
198.4
11.05
10.93
10.88
10.82
10.77
10.71
10.65
10.62
1344.3
665
546.7
452.7
382
329
284.7
267.7
Viscosity
cp.
Measured
7.46
3.64
2.98
2.45
2.06
1.76
1.51
1.42
1.26
-6.26
-6.86
-5.92
-4.32
-2.75
-0.69
0.24
Viscosity
cp.
Measured
3.43
2.28
1.79
1.46
1.22
1.04
0.90
0.80
0.75
Viscosity
cp.
Predicted
3.00
1.95
1.50
1.22
1.03
0.89
0.79
0.70
0.66
% Dev
Temp.
F
Density
ppg
Time
sec.
17.75
11.47
7.32
8.07
9.45
10.13
12.81
14.27
15.09
42.8
88.7
107.7
127.7
148.7
169.8
187.9
197.7
11.75
11.62
11.56
11.50
11.44
11.37
11.32
11.29
2885
1203
979.7
773
626
523.6
458
442
Viscosity
cp.
Measured
17.03
7.00
5.67
4.45
3.58
2.97
2.59
2.49
4.31
0.58
-2.90
-0.26
2.18
3.90
5.03
2.34
SPE 86506
Table A-3
Calcium Chloride / Calcium Bromide / Zinc Bromide Standard Blends
17.0 ppg CaCl2 / CaBr2 / ZnBr2
Density
ppg
Time
sec.
72.1
88.1
108.5
128.1
148.3
168.4
188.1
198.3
15.52
15.46
15.38
15.31
15.23
15.15
15.07
15.03
830
627
435.3
319
243
191
155
141
Viscosity
cp.
Measured
50.32
37.83
26.10
19.02
14.40
11.25
9.07
8.23
Viscosity
cp.
Predicted
51.22
37.20
26.27
19.68
15.13
11.97
9.71
8.78
% Dev
Temp.
F
Density
ppg
Time
sec.
1.80
-1.66
0.64
3.50
5.10
6.41
7.04
6.66
74.9
88.3
108.2
128.1
148
168
188.1
198.1
16.99
16.93
16.84
16.76
16.67
16.59
16.50
16.46
521.3
417.3
301
228
178.3
144
118
108
Density
ppg
Time
sec.
76.3
88.3
108
127.7
147.7
167.7
188.3
198.8
220.7
16.00
15.95
15.87
15.79
15.71
15.63
15.55
15.51
15.42
675
540
380
281
216
171
138
125
102.3
Viscosity
cp.
Measured
42.17
33.61
23.51
17.28
13.21
10.39
8.33
7.52
6.12
Viscosity
cp.
Predicted
40.60
32.11
22.94
17.14
13.21
10.45
8.40
7.57
6.1716
Density
ppg
Time
sec.
70
88.3
108.1
128.2
148
168
188.3
198.5
16.53
16.46
16.37
16.29
16.21
16.12
16.04
16.00
650.3
456
331
248
193
153.7
124
113
Viscosity
cp.
Measured
41.99
29.29
21.13
15.74
12.17
9.63
7.72
7.02
Viscosity
cp.
Predicted
42.98
29.70
21.19
15.75
12.17
9.63
7.77
7.02
Viscosity
cp.
Predicted
36.73
28.21
20.09
14.98
11.56
9.15
7.39
6.69
% Dev
-6.22
-2.34
-1.65
-0.68
0.05
1.44
2.23
2.98
Temp.
F
Density
ppg
Time
sec.
3.72
4.48
2.45
0.81
0.00
-0.55
-0.75
-0.55
-0.91
76.4
88.3
108.1
128.1
148
168
188.1
198.3
220.7
17.51
17.45
17.36
17.27
17.18
17.09
17.00
16.95
16.85
490.3
394
291
221
173.3
140.7
116
103.7
86
Viscosity
cp.
Measured
34.58
27.57
19.77
14.88
11.57
9.28
7.56
6.90
Viscosity
cp.
Measured
33.51
26.83
19.70
14.87
11.59
9.35
7.66
6.82
5.62
Viscosity
cp.
Predicted
33.55
26.58
18.96
14.12
10.89
8.62
6.97
6.29
5.11
% Dev
-0.10
0.93
3.74
5.04
5.97
7.76
9.04
7.76
9.06
Temp.
F
Density
ppg
Time
sec.
-2.34
-1.42
-0.26
-0.10
0.01
0.01
-0.55
-0.03
77.3
88.2
108.1
128.1
148.1
168
188.1
198.4
18.02
17.97
17.87
17.78
17.68
17.59
17.49
17.44
438.3
364.3
272.7
210.7
167
134.3
111
102
Viscosity
cp.
Measured
30.83
25.54
19.00
14.59
11.49
9.18
7.54
6.91
Viscosity
cp.
Predicted
30.56
24.72
17.60
13.10
10.10
8.00
6.46
5.84
% Dev
0.89
3.22
7.38
10.19
12.11
12.84
14.26
15.49
SPE 86506
Density
ppg
Time
sec.
75.7
88.9
108.5
128.7
148.3
168.2
188.1
198.4
18.44
18.37
18.27
18.17
18.07
17.97
17.87
17.82
348
285
220
173
139
114
97
87
Viscosity
cp.
Measured
25.05
20.43
15.67
12.24
9.77
7.96
6.73
6.02
Viscosity
cp.
Predicted
29.33
22.65
16.24
12.06
9.35
7.41
6.00
5.42
% Dev
Temp.
F
Density
ppg
Time
sec.
-17.08
-10.89
-3.61
1.46
4.32
6.92
10.86
9.97
76
88.3
107.7
128.1
148.3
167.6
187.6
198.1
19.11
19.04
18.94
18.83
18.73
18.62
18.52
18.46
323
270.3
200
152
120
99
82
75
Viscosity
cp.
Measured
24.10
20.09
14.77
11.15
8.74
7.17
5.90
5.37
Viscosity
cp.
Predicted
25.01
19.66
14.11
10.44
8.03
6.40
5.18
4.66
% Dev
Viscosity
cp.
Predicted
20.50
16.59
12.22
9.35
7.33
5.90
4.90
4.51
% Dev
Viscosity
cp.
Predicted
30.55
22.68
16.53
12.44
9.64
7.66
6.25
5.70
% Dev
Viscosity
cp.
Predicted
40.01
30.59
21.75
16.15
12.33
9.63
7.76
7.00
% Dev
-3.78
2.14
4.46
6.37
8.21
10.64
12.20
13.22
Table A-4
Calcium Chloride / Calcium Bromide Blends
12.0 ppg CaCl2 / CaBr2
.5 ppg CaCl2 / CaBr2
Temp.
F
Density
ppg
Time
sec.
80.5
88.3
108.1
128.1
148.2
167.9
187.8
198.2
11.94
11.92
11.86
11.80
11.74
11.68
11.62
11.59
192
167.3
129.7
103.7
85
71
60.7
56
Viscosity
cp.
Measured
8.95
7.78
6.00
4.77
3.88
3.22
2.74
2.52
Viscosity
cp.
Predicted
9.43
8.35
6.27
4.83
3.85
3.21
2.79
2.63
% Dev
Temp.
F
Density
ppg
Time
sec.
-5.29
-7.32
-4.53
-1.38
0.80
0.41
-1.72
-4.36
75.8
88.2
108.3
128
148
168.1
188.1
198.2
13.46
13.41
13.35
13.28
13.21
13.15
13.08
13.04
397
320
235.3
181
142.7
115
96
88
Density
ppg
Time
sec.
79.8
89.2
108.3
128.2
148.1
167.9
188.1
198.3
12.44
12.41
12.35
12.29
12.23
12.16
12.10
12.07
234
206
159
124.7
101
83
70.3
65
Viscosity
cp.
Measured
11.36
9.98
7.66
5.97
4.80
3.92
3.30
3.05
Density
ppg
Time
sec.
71.1
88.1
108.2
128
148
168.1
188.3
198.2
12.95
12.89
12.83
12.76
12.70
12.63
12.57
12.54
326.7
257
191.7
149
119
97
81.3
75.3
Viscosity
cp.
Measured
16.52
12.93
9.59
7.41
5.88
4.76
3.97
3.66
1.73
0.96
0.19
0.13
0.14
-0.40
-0.50
-1.25
% Dev
Temp.
F
Density
ppg
Time
sec.
-2.46
-0.72
0.52
1.61
2.74
1.71
0.24
-1.38
72.5
88.4
108.1
128.1
148
168
188
198.1
14.01
13.96
13.89
13.82
13.75
13.68
13.61
13.57
583.3
425.3
305.3
229.3
178
143
117
107.3
Viscosity
cp.
Measured
20.86
16.75
12.24
9.36
7.34
5.88
4.88
4.46
Viscosity
cp.
Measured
31.92
23.16
16.53
12.34
9.52
7.60
6.18
5.65
4.29
2.09
0.01
-0.78
-1.22
-0.72
-1.08
-0.79
% Dev
Temp.
F
Density
ppg
Time
sec.
-1.99
1.75
1.52
1.93
2.37
1.77
0.63
-0.16
75.3
88.5
108.3
128.1
148.1
168.3
188.1
198.5
14.47
14.42
14.35
14.27
14.20
14.13
14.06
14.02
695
550.7
388
287.7
220
174
140
126
Viscosity
cp.
Measured
39.26
30.99
21.70
16.00
12.16
9.56
7.64
6.86
-1.89
1.29
-0.21
-0.97
-1.38
-0.80
-1.54
-2.04
SPE 86506
Density
ppg
Time
sec.
76.4
88.5
108.3
128.1
148.2
168.2
188
198.3
15.07
15.02
14.95
14.87
14.80
14.72
14.65
14.61
1067
819
557.7
400
299
231.7
186
167
Viscosity
cp.
Measured
62.79
48.01
32.50
23.17
17.21
13.26
10.58
9.47
Viscosity
cp.
Predicted
64.08
47.68
32.25
23.20
17.25
13.22
10.43
9.31
% Dev
-2.05
0.68
0.76
-0.13
-0.19
0.29
1.45
1.73
Table A-5
Sodium Bromide Solutions
9.0 ppg NaBr
Temp.
F
Density
ppg
Time
sec.
72.5
88.2
108
128.2
148.3
168.1
188.4
199.1
9.02
8.99
8.96
8.91
8.86
8.81
8.75
8.72
33.7
27
23
20
18
16
15
14
Viscosity
cp.
Measured
1.19
0.95
0.80
0.69
0.62
0.55
0.51
0.47
% Dev
Temp.
F
Density
ppg
Time
sec.
2.40
-0.83
2.01
2.77
3.92
1.94
4.25
1.78
73.9
88.3
108.1
128.3
148.3
168.2
188.4
199.1
11.97
11.94
11.90
11.86
11.83
11.81
11.78
11.77
43.7
36
29.7
25
22
19.7
18
17
Density
Ppg
Time
sec.
74.5
88.1
108
127.9
147.8
167.9
187.4
199.1
9.96
9.93
9.89
9.85
9.80
9.75
9.70
9.67
34
27
23
20
17.7
16.3
15
14
Viscosity
cp.
Measured
1.32
1.05
0.89
0.77
0.67
0.62
0.57
0.53
Density
Ppg
Time
sec.
69.2
88.1
108
128.1
147.8
167.9
187.7
199.1
11.04
11.00
10.96
10.92
10.88
10.84
10.80
10.78
42
33
27
24
21
19
17.6
17.3
Viscosity
cp.
Measured
1.81
1.42
1.15
1.02
0.89
0.80
0.74
0.72
Viscosity
cp.
Predicted
1.93
1.62
1.34
1.15
1.01
0.91
0.83
0.79
% Dev
Viscosity
cp.
Predicted
2.01
1.66
1.43
1.26
1.13
1.03
0.98
% Dev
5.26
3.19
2.92
0.67
-0.17
-1.05
-0.79
-1.87
% Dev
Temp.
F
Density
Ppg
Time
sec.
3.05
-3.84
-0.80
-0.18
-0.69
1.09
1.43
-0.59
88.3
108.1
127.8
148
167.9
188.1
199.1
12.41
12.37
12.34
12.32
12.30
12.28
12.28
41
34
28
24
22
19
18
Viscosity
cp.
Predicted
1.77
1.40
1.15
0.99
0.87
0.78
0.71
0.68
% Dev
Viscosity
cp.
Measured
2.04
1.68
1.38
1.16
1.01
0.90
0.82
0.78
2.48
1.50
0.48
3.44
1.83
1.99
3.26
6.25
Viscosity
cp.
Measured
1.99
1.64
1.35
1.15
1.05
0.91
0.86
-1.36
-1.08
-6.03
-9.53
-7.84
-13.70
-14.37