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PROCEDURE
3+
3+
2+
Kinetic Masking
- a case in which a metal
ion does
not effectively enter into the
complexation reaction because of
its kinetic inertness
- difference in rates of reaction with
EDTA of metal cations are utilized
**For this case, the slow reaction of
chromium (III) with EDTA makes it
possible to titrate the other metal
ion which is Fe (III) without
interference from Cr (III).
Fe3+
+
Cr3+
+
CHEMICAL EQUATIONS,
COMPUTATIONS INVOLVED
Pb2+
+
Fe (III) content (VEDTA and VPbNO3 are
from 1st addition):
%Fe 3+
Cr
Vsolution
REFERENCES: