Professional Documents
Culture Documents
Martin Larter
Exam 4b
Name
May, 2013
Multiple Choice
(24 points)
Page 5
(22 points)
Page 6
(26 points)
Page 7
(22 points)
Total
(94 points)
Percent
(100 %)
All work must be shown to receive credit. Give all answers to the correct number of significant
figures
Avogadros number 6.022 x 1023 /mol
kw = 1.0 x 10-14 M2
Specific heat of ice = 2.09 J/g C ,
Specific heat of water = 4.18 J/g C ,
Specific heat of water vapor = 1.84 J/g C ,
Hfus = 0.334 kJ/g ,
Hvap = 2.259 kJ/g
Grossmont College
Periodic Table
VIIA
IA
1
H
1.008
3
Li
6.941
11
Na
23.00
19
K
39.10
37
Rb
85.47
55
Cs
132.9
87
Fr
(223)
IVA
6
C
12.01
14
Si
28.09
32
Ge
72.59
50
Sn
118.7
82
Pb
207.2
VA
7
N
14.01
15
P
30.97
33
As
74.92
51
Sb
121.8
83
Bi
209.0
VIA
8
O
16.00
16
S
32.06
34
Se
78.96
52
Te
127.6
84
Po
(209)
1
H
1.008
9
F
19.00
17
Cl
35.45
35
Br
79.90
53
I
126.9
85
At
(210)
68
Er
167.3
100
Fm
(257)
69
Tm
168.9
101
Md
(258)
70
Yb
173.0
102
No
(259)
71
Lu
175.0
103
Lr
(260)
IIA
4
Be
9.012
12
Mg
24.30
20
Ca
40.08
38
Sr
87.62
56
Ba
137.3
88
Ra
226.0
IIIB
IVB
VB
VIB
VIIB
VIII
VIII
VIII
IB
IIB
21
Sc
44.96
39
Y
88.91
57
La
138.9
89
Ac
227.0
22
Ti
47.90
40
Zr
91.22
72
Hf
178.5
104
Rf
(261)
23
V
50.94
41
Nb
92.91
73
Ta
180.9
105
Db
(262)
24
Cr
52.00
42
Mo
95.94
74
W
183.9
106
Sg
(263)
25
Mn
54.94
43
Tc
(99)
75
Re
186.2
107
Bh
(262)
26
Fe
55.85
44
Ru
101.1
76
Os
190.2
108
Hs
(265)
27
Co
58.93
45
Rh
102.9
77
Ir
192.2
109
Mt
(266)
28
Ni
58.70
46
Pd
106.4
78
Pt
195.1
110
??
(269)
29
Cu
63.55
47
Ag
107.9
79
Au
197.0
30
Zn
65.38
48
Cd
112.4
80
Hg
200.6
IIIA
5
B
10.81
13
Al
27.00
31
Ga
69.72
49
In
114.8
81
Tl
204.4
58
Ce
140.1
90
Th
232.0
59
Pr
140.9
91
Pa
231.0
60
Nd
144.2
92
U
238.0
61
Pm
(147)
93
Np
(237)
62
Sm
150.4
94
Pu
(244)
63
Eu
152.0
95
Am
(243)
64
Gd
157.3
96
Cm
(247)
65
Tb
158.9
97
Bk
(247)
66
Dy
162.5
98
Cf
(251)
67
Ho
164.9
99
Es
(252)
Lanthanide series
Actinide series
NOBL
E
GASE
S
2
He
4.002
10
Ne
20.18
18
Ar
39.95
36
Kr
83.80
54
Xe
131.3
86
Rn
(222)
Multiple Choice (24 points) Give the best answer for each of the following questions.
1. At which temperature would CO2 gas be least soluble?
a.
10. oC
20. oC
b.
c.
30. oC
d.
40. oC
2. Which of the following will increase the rate of dissolving of a solid in a solution?
a. raise the solution
temperature
CO2
CH3OCH3
b. sulfuric acid
c. sulfurous acid
d. dihydrogen monosulfide
e. hydrogen sulfide
5. A solution is formed at room temperature by dissolving enough of the solid solute so that some solid remains at the
bottom of the solution. Which statement below is true?
a) The solution is unsaturated.
b) The solution is supersaturated.
c) The solution is saturated.
d) The solution is hydrated.
e) none of the above
6. The conjugate base of NH3 is ________.
a.
OH-
b.
H3O+
c.
H2O
d.
NH2-
e.
NH4+
8. A solid has a relatively low melting point, is soft, its structure is held together by intermolecular forces, and is an
electrical insulator. The solid is most likely a(n) ______ solid.
a. ionic
b. molecular
c. metallic
d. covalent network
b. proton acceptor.
e. amphoteric
b. greater than
c. equal to
d. 7
Problems:
1. (8 points) Calculate the total heat in kJ when a 55.0 g sample of ice is cooled from 0.00 C to 45.0 C under 1 atm
of pressure.
2.
(4 points) Calculate the mass percent of potassium oxalate (166.22 g/mol) in a solution prepared by dissolving
2.58 g of K2C2O4 in 35.00 g of H2O.
3.
(4 points) A students needs to prepare a solution that contains 0.38 moles of KNO3. A 2.50% (m/m) NaNO3
solution is available. How many grams of the 2.50% (m/m) NaNO3 solution are needed?
4.
(6 points) An aqueous solution of nitric acid is 32.0 % HNO3 by mass. The density of this solution is 1.164 g/mL.
Determine the molarity of the solution.
5. (6 points) What volume of a 0. 840 M HClO4 solution is needed to reach the endpoint in a titration of a 25.00 mL
sample of a 0.175 M Ba(OH)2 solution? The balanced molecular equation for the reaction is given below:
Ba(OH)2 (aq) + 2 HClO4 (aq)
Ba(ClO4)2 (aq)
+ 2 H2O (l)
6. A 0.0750 M solution of benzoic acid, a weak acid used commonly in preservatives has a pH of 2.667.
a. (6 points) What are the molar concentrations of hydronium ion and hydroxide ion in this solution?
b. (4 points) How does the pH of 0.0750 M solution of benzoic acid compare to that of a 0.0750 M solution of nitric
acid which is 1.125? Why are the two different?
c. (4 points) If a 15.00 mL sample of this solution were removed and diluted to a total volume of 250.00 mL,
what would be the molarity of K3PO4 in the diluted solution?
8.
(22 points) 4.500 g of potassium carbonate are dissolved in 250.0 mL of solution. To this solution are added
70.00 mL of 0.4185 M Barium Chloride solution. Use ICE Method
Write the complete and balanced equation for the reaction. (If you need help with the balanced chemical equation come
see me and I will sell it to you for 2 points.)
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