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2.
m
of the permeability m and permittivity e is:
e
(a) [RT2]
(b) [R2T1]
(c) [R2]
(d) [R2T2]
The initial speed of a bullet fired from a rifle is 630 m/s. The
rifle is fired at the centre of a target 700 m away at the same
level as the target. How far above the centre of the target ?
(a) 1.0 m
(b) 4.2 m
(c) 6.1 m
(d) 9.8 m
A body of mass 5 kg under the action of constant force
3.
F = Fx i + Fy j
has
velocity
5.
6.
at
3 4
(b) - i + j N
5 5
3 4
i - j N
5 5
A small ball of mass m starts at a point A with speed vo and
moves along a frictionless track AB as shown. The track BC
has coefficient of friction m. The ball comes to stop at C after
travelling a distance L which is:
(c)
4.
( -3j + 4j) N
( 3i - 4j) N
2h vo2
+
m 2mg
(b)
h v2o
+
m 2mg
(c)
h v2o
+
2m mg
(d)
v2
h
+ o
2m 2mg
The force
F is:
(a)
(a)
(d)
L l o L2
2 4M
(b)
L lo L2
+
3 8M
L l o L2
2L l o L2
+
(d)
3 4M
3
6M
From a sphere of mass M and radius R, a smaller sphere of
R
radius
is carved out such that the cavity made in the
2
original sphere is between its centre and the periphery (See
figure). For the configuration in the figure where the distance
between the centre of the original sphere and the removed
sphere is 3R, the gravitational force between the two sphere
is:
(c)
7.
3R
(a)
41 GM 2
3600 R 2
(b)
41 GM 2
450 R 2
2
(c)
8.
9.
10.
11.
12.
13.
59 GM 2
(d)
GM 2
450 R 2
225 R 2
The bulk moduli of ethanol, mercury and water are given as
0.9, 25 and 2.2 respectively in units of 109 Nm2. For a given
value of pressure, the fractional compression in volume is
DV
DV
. Which of the following statements about
for these
V
V
three liquids is correct ?
(a) Ethanol > Water > Mercury
(b) Water > Ethanol > Mercury
(c) Mercury > Ethanol > Water
(d) Ethanol > Mercury > Water
A tank with a small hole at the bottom has been filled with
water and kerosene (specific gravity 0.8). The height of water
is 3m and that of kerosene 2m. When the hole is opened the
velocity of fluid coming out from it is nearly: (take g = 10 ms
2
and
density
of
water
= 103 kg m3)
(a) 10.7 ms1
(b) 9.6 ms1
1
(c) 8.5 ms
(d) 7.6 ms1
An air bubble of radius 0.1 cm is in a liquid having surface
tension 0.06 N/m and density 103 kg/m3. The pressure inside
the bubble is 1100 Nm2 greater than the atmospheric
pressure. At what depth is the bubble below the surface of
the liquid? (g = 9.8 ms2)
(a) 0.1 m
(b) 0.15 m
(c) 0.20 m
(d) 0.25 m
A hot body, obeying Newtons law of cooling is cooling
down from its peak value 80C to an ambient temperature of
30C. It takes 5 minutes in cooling down from 80C to 40C.
How much time will it take to cool down from 62C to 32C?
(Given In 2 = 0.693, In 5 = 1.609)
(a) 3.75 minutes
(b) 8.6 minutes
(c) 9.6 minutes
(d) 6.5 minutes
During an adiabatic compression, 830 J of work is done on 2
moles of a diatomic ideal gas to reduce its volume by 50%.
The change in its temperature is nearly: (R = 8.3 JK1 mol1)
(a) 40 K
(b) 33 K
(c) 20 K
(d) 14 K
An ideal monoatomic gas is confined in a cylinder by a spring
loaded piston of cross section 8.0 103 m2. Initially the gas
is at 300 K and occupies a volume of 2.4 103 m3 and the
spring is in its relaxed state as shown in figure. The gas is
heated by a small heater until the piston moves out slowly
by 0.1 m. The force constant of the spring is 8000 N/m and
the atmospheric pressure is 1.0 105 N/m2. The cylinder
and the piston are thermally insulated. The piston and the
spring are massless and there is no friction between the
piston and the cylinder. The final temperature of the gas will
be:
(Neglect the heat loss through the lead wires of the heater.
The heat capacity of the heater coil is also negligible).
(a) 300 K
(b) 800 K
(c) 500 K
(d) 1000 K
14. The angular frequency of the damped oscillator is given by,
k
r2
w=
m 4m 2 where k is the spring constant, m is the
r2
is 8%, the change in time period compared to the
mk
undamped oscillator is approximately as follows:
(a) increases by 1%
(b) increases by 8%
(c) decreases by 1%
(d) decreases by 8%
15. Two factories are sounding their sirens at 800 Hz. A man
goes from one factory to other at a speed of 2m/s. The velocity
of sound is 320 m/s. The number of beats heard by the person
in one second will be:
(a) 2
(b) 4
(c) 8
(d) 10
16. A cone of base radius R and height h is located in a uniform
ratio
electric field
E parallel to its base. The electric flux entering
the cone is:
1
EhR
(b) E h R
2
(c) 2 E h R
(d) 4 E h R
A parallel plate capacitor is made of two plates of length l,
width w and separated by distance d. A dielectric slab
(dielectric constant K) that fits exactly between the plates is
held near the edge of the plates. It is pulled into the capacitor
(a)
17.
U
where U is the energy of the capacitor
x
when dielectric is inside the capacitor up to distance x (See
figure). If the charge on the capacitor is Q then the force on
the dielectric when it is near the edge is:
by a force F = -
x
l
d
(a)
(c)
Q 2d
2wl2 eo
Q 2d
2wl 2 e o
(b)
( K - 1)
(d)
Q 2w
2dl 2 e 0
Q2w
2dl 2 e o
( K - 1)
K
(c)
21.
5W
20 W 10 W
50 V
30 V
22.
5W
I2 = 20 A
23.
24.
5 cm
3 cm
25.
I = 10 A
26.
27.
A P, B F, C D
(d) A F, B P, C D
A coil of circular cross-section having 1000 turns and 4 cm2
face area is placed with its axis parallel to a magnetic field
which decreases by 102 Wb m2 in 0.01 s. The e.m.f.
induced in the coil is:
(a) 400 mV
(b) 200 mV
(c) 4 mV
(d) 0.4 mV
An electromagnetic wave of frequency 1 1014 hertz
is propagating along z-axis. The amplitude of electric field is
4 V/m. If e0 = 8.8 1012 C2/N-m2, then average energy
density of electric field will be:
(a) 35.2 1010 J/m3
(b) 35.2 1011 J/m3
12
3
(c) 35.2 10 J/m
(d) 35.2 1013 J/m3
An object is located in a fixed position in front of a screen.
Sharp image is obtained on the screen for two positions of a
thin lens separated by 10 cm. The size of the images in two
situations are in the ratio 3 : 3. What is the distance between
the screen and the object?
(a) 124.5 cm
(b) 144.5 cm
(c) 65.0 cm
(d) 99.0 cm
Two monochromatic light beams of intensity 16 and 9 units
are interfering. The ratio of intensities of bright and dark
parts of the resultant pattern is:
16
4
(a)
(b)
3
9
7
49
(c)
(d)
1
1
In a compound microscope the focal length of objective
lens is 1.2 cm and focal length of eye piece is 3.0 cm. When
object is kept at 1.25 cm in front of objective, final image is
formed at infinity. Magnifying power of the compound
microscope should be:
(a) 200
(b) 100
(c) 400
(d) 150
A photon of wavelength l is scattered from an electron,
which was at rest. The wavelength shift Dl is three times of
l and the angle of scattering q is 60. The angle at which the
electron recoiled is f. The value of tan f is : (electron speed
is much smaller than the speed of light)
(a) 0.16
(b) 0.22
(c) 0.25
(d) 0.28
A radioactive nuclei with decay constant 0.5/s is being
produced at a constant rate of 100 nuclei/s. If at t = 0 there were
no nuclei, the time when there are 50 nuclei is:
4
2ln s
3
(a) 1s
(b)
(c) ln 2 s
4
(d) ln s
3
4
28.
4 kW
IL
IZ
10 V = VZ
60 V
RL = 2kW
(A)
29.
List I
Doublet of
sodium
III Wavelength
emitted by
atomic
hydrogen in
interstellar
space
K2
R
G
S
(B)
K1
K2
S
G
R
(C)
30.
K1
List II
(A) Visible
radiation
II Wavelength
(B) Microwave
corresponding
to temperature
associated with
the isotropic
radiation filling
all space
K2
K1
S
R
K2
G
(D)
K1
RS
(a) Circuit A with G = ( R - S)
PART B : CHEMISTRY
38.
2h
( lo - l )
m
(b)
2hc
( lo - l )
m
(c)
2hc lo - l
m ll o
(d)
2h 1 1
m l o l
39.
40.
1
1
DE = -2.0 10 -18 J
n2 n 2
2
1
d [O2 ]
d [ NO 2 ]
= k [ N 2 O5 ]
d [ N 2 O5 ]
dt
41.
(a)
3 Li
(b)
9 F 35 Br
increases
(c)
42.
6 C 32 Ge
= k [ N 2 O5 ] and
dt
k and k are related as:
(a) k = k
(b) 2k = k
(c) k = 2k
(d) k = 4k
36. In some solutions, the concentration of H3 O+ remains
constant even when small amounts of strong acid or strong
base are added to them. These solutions are known as:
(a) Ideal solutions
(b) Colloidal solutions
(c) True solutions
(d) Buffer solutions
37. Given
Fe3+ (aq) + e Fe2+ (aq); E0 = + 0.77 V
Al3+ (aq) + 3e Al(s); E0 = 1.66 V
Br2(aq) + 2e 2Br; E0 = + 1.09 V
Considering the electrode potentials, which of the following
represents the correct order of reducing power?
(a) Fe2+ < Al < Br
(b) Br < Fe2+ < Al
(c) Al < Br < Fe2+
(d) Al < Fe2+ < Br
(a)
(b)
O -2 > O 2 > N 2
(c)
43.
44.
6
45.
46.
47.
48.
50.
51.
C
O
NH2
O
C
CH3
A is:
(a) CH3CH = C CHO
CH3
CH3
Potassium
tetracyanoplatinate (II)
(2) [Mn(CN)5 ]
Pentacyanomagnate (II)
ion
Potassium diammine
tetrachlorochromate (III)
(c)
CH3 CH2 C = C = O
CH3
(d) CH 3 CH2 C C = O
55.
56.
CH 2H
In allene (C3H4), the type(s) of hybridization of the carbon
atoms is (are) :
(a) sp and sp3
(b) sp2 and sp
2
(c) only sp
(d) sp2 and sp3
Chlorobenzne reacts with trichloro acetaldehyde in the
presence of H2SO4.
O
Cl + H C CCl3
H2SO4
OH
Cl
+ HCl + HCN
52.
CH
49.
OH
CH
Formula
C
O
CH3COOH
(1) K2 [Pt(CN)4 ]
NH3
CH
OH
Anhyd.
ZnCl2
C Ph
Ph
H
Cl
C=C
Cl
Cl
CHO
is known as:
(a) Perkin reaction
(b) Gatterman-Koch Formylation
(c) Kolbes reaction
(d) Gattermann reaction
The reagent needed for converting
Ph C
(a)
Cl
(b) Cl
Cl
CH2Cl
H
Ph
(c)
Cl
CH
CCl3
Cl
7
(a)
(d) Cl
CH
Cl
Cl
57. Tischenko reaction is a modification of:
(a) Aldol condensation
(b) Claisen condensation
(c) Cannizzaro reaction
(d) Pinacol-pinacolon reaction
58. Which one of the following is used as Antihistamine?
(a) Omeprazole
(b) Chloranphenicol
(c) Diphenhydramine
(d) Norethindrone
59. Which one of the following statements is not correct?
(a) Alcohols are weaker acids than water
(b) Acid strength of alcohols decreases in the following
RCH2OH > R2CHOH > R3COH
(c) Carbon-oxygen bond length in methanol, CH3OH is
shorter than that of C O bond length in phenol.
64.
65.
in methanol is 108.9.
C
H
60. The gas liberated by the electrolysis of Dipotassium
succinate solution is:
(a) Ethane
(b) Ethyne
(c) Ethene
(d) Propene
3
+2 3
2
(b)
3
- +2 3
2
66.
67.
3
3
-2 3
(d) - - 2 3
2
2
62. If z1, z2 and z3, z4 are 2 pairs of complex conjugate numbers,
then
(c)
z
arg 1
z4
z2
+ arg equals:
z3
(a) 0
(c)
63. If
2
3p
2
a and
(b)
p
2
68.
(d) p
b
4 lnk
are
roots
of
the
x - 4 2 kx + 2e
- 1= 0 for some k, and
then a3 + b3 is equal to:
equation,
a2 +
b2 = 66,
(c) -32 2
(d) -280 2
Let A be a 3 3 matrix such that
(a)
3 1 2
3 0 2
1 0 1
(c)
0 1 3
0 2 3
1 1 1
(b)
3 2 1
3 2 0
1 1 0
(d)
1 2 3
0 1 1
0 2 3
A ( x ) = p 2 ( x ) p 2 ( x ) p 2 ( x )
p3 ( x ) p3 ( x ) p3 ( x )
PART C : MATHEMATICS
(a)
280 2
Then A1 is:
11p
is equal to:
Then f(x) at x = 6
(b)
1 2 3 0 0 1
A 0 2 3 = 1 0 0
0 1 1 0 1 0
248 2
69.
(1000 )!
(50 )!( 950 )!
(b)
(1000 )!
( 49 )!( 951)!
(c)
(1001)!
( 51)!( 950 )!
(d)
(1001)!
(50 )!( 951)!
8
70.
If
lim
tan ( x - 2 ) x 2 + ( k - 2 ) x - 2k
72.
(a) 4
x 2 - 4x + 4
then k is equal to:
(a) 0
(b) 1
(c) 2
(d) 3
Let f(x) = x|x|, g(x) = sin x and h(x) = (gof) (x). Then
(a) h(x) is not differentiable at x = 0.
(b) h(x) is differentiable at x = 0, but h(x) is not continuous
at x = 0
(c) h(x) is continuous at x = 0 but it is not differentiable at
x= 0
(d) h(x) is differentiable at x = 0
For the curve y = 3 sin q cosq, x = e q sin q,
0 q p, the tangent is parallel to x-axis when q is:
x 2
71.
} = 5,
(a)
3p
4
(b)
p
2
73.
p
p
(d)
6
4
Two ships A and B are sailing straight away from a fixed
point O along routes such that AOB is always 120. At a
certain
instance,
OA = 8 km, OB = 6 km and the ship A is sailing at the rate of
20 km/hr while the ship B sailing at the rate of 30 km/hr. Then
the distance between A and B is changing at the rate (in km/
hr):
(a)
(b)
37
80
260
37
(d)
75.
(b)
-1 1 - x
1
2
3
2
l
2
3
l
2
79. The base of an equilateral triangle is along the line given by
3x + 4y = 9. If a vertex of the triangle is (1, 2), then the length
of a side of the triangle is:
(d) a circle of radius
(a)
2 3
15
(b)
4 3
15
4 3
2 3
(d)
5
5
80. The set of all real values of l for which exactly two common
tangents can be drawn to the circles
x2 + y2 4x 4y + 6 = 0 and
x2 + y2 10x 10y + l = 0 is the interval:
(a) (12, 32)
(b) (18, 42)
(c) (12, 24)
(d) (18, 48)
81. Let L1 be the length of the common chord of the curves x 2 +
y2 = 9 and y2 = 8x, and L2 be the length of the latus rectum
of y2 = 8x, then:
(a) L1 > L2
(b) L1 = L2
(c) L1 < L2
(d)
L1
= 2
L2
p
, be two distinct points on the hyperbola
2
(a)
11
3
(b)
11
3
x
y
+ F , for some function F, is given by y ln |cx| =
x
y
(c)
13
2
(d)
13
2
77.
x2 y2
= 1 . Then the ordinate of the point of intersection
9
4
of the normals at P and Q is:
76.
3 is:
8
3p
3
(d) 2p
(a)
(d)
(c)
80
37
37
The volume of the largest possible right circular cylinder
(c)
74.
260
1
4
78. A stair-case of length l rests against a vertical wall and a
floor of a room. Let P be a point on the stair-case, nearer to
its end on the wall, that divides its length in the ratio 1 : 2. If
the stair-case begins to slide on the floor, then the locus of
P is:
(c) 4
(c)
1
4
(b)
y =
9
83. Let A (2, 3, 5), B ( 1, 3, 2) and C (l, 5, m) be the vertices of a
DABC. If the median through A is equally inclined to the
coordinate axes, then:
(a) 5l 8m = 0
(b) 8l 5m = 0
(c) 10l 7m = 0
(d) 7l 10m = 0
84.
87.
(c)
x -1 y - 2 z - 3
=
=
and
The plane containing the line
1
2
3
x y z
parallel to the line = = passes through the point:
1 1 4
(a) (1, 2, 5)
(b) (1, 0, 5)
(c) (0, 3, 5)
(d) ( 1, 3, 0)
88.
c . -7i + 2j + 3k is:
(a)
4 2
89.
(d) 12
(c)
1
2
(b)
63
128
(d)
p
3
1
2
(b) 2
11
46
(d)
2
5
The angle of elevation of the top of a vertical tower from a
point P on the horizontal ground was observed to be a.
After moving a distance 2 metres from P towards the foot of
the tower, the angle of elevation changes to b. Then the
height (in metres) of the tower is:
(a)
64
127
31
128
(d)
(c)
(c) 24
(d) 12 2
86. A set S contains 7 elements. A non-empty subset A of S and
an element x of S are chosen at random. Then the probability
that x A is:
(a)
p
2
If 2cos q + sin q = 1 q ,
2
(c)
90.
2 sin a sin b
sin ( b - a )
2sin ( b - a )
sin a sin b
(b)
(d)
sin a sin b
cos ( b - a )
cos ( b - a )
sin a sin b
(b) q
(d) : q
10
2.
5.
-1
630ms
For vertical motion,
Here, u = 0
h =
=
10
sec
9
E=
1 2
gt
2
1
10
10
9
2
500
m = 6.1 m
81
Therefore, the rifle must be aimed 6.1 m above the centre
of the target to hit the target.
(a) From question,
Mass of body, m = 5 kg
Velocity at t = 0,
6.
7.
1
103 (9)2
2
1
103 81 = 4.05 104 J
2
(c)
(a) Volume of removed sphere
3
4 R
4
1
Vremo = p = pR 3
3 2
3
8
u = (6i - 2 j) m/s
Velocity at t = 10s,
4 3 4 31
pR - pR
3
3
8
4 37
pR
3
8
Therefore mass of sphere carved and remaining sphere
v = + 6 j m/s
Force, F = ?
v -u
t
1
7
M and M.
8
8
Therefore, gravitational force between these two sphere,
are at respectively
6 j - (6i - 2 j) -3i + 4 j
=
m/s2
10
5
Force, F = ma
=
F=
( -3i + 4 j )
= ( -3i + 4 j ) N
5
(b) Initial speed at point A, u = v0
Speed at point B, v = ?
v2 u2 = 2gh
v2 = v20 + 2gh
Let ball travels distance S before coming to rest
= 5
4.
1
mv2
2
=
2
Acceleration, a =
= [M2L4T6A4 ] = [R2]
(c) Let t be the time taken by the bullet to hit the target.
\ 700 m = 630 ms1 t
700m
v02
2 gh
h v02
+
= +
2mg 2mg
m 2mg
100
m = 1 m3
100
As we know, density of water,
d = 103 kg/m3
Therefore, mass of this volume of water
M = d v = 103 1 = 103 kg
Average terminal velocity of rain drop
v = 9 m/s (given)
Therefore, energy transferred by rain,
[MLT -2 A -2 ]
Dimensions of m
=
Dimensions of [M -1L-3 T 4 A 2 ]
t=
3.
v 2 + 2 gh
v2
S=
= 0
2mg
2mg
8.
GM m
r2
7M 1
M
7 GM 2
8 8
=
64 9 R 2
(3R )2
41 GM 2
3600 R 2
1
Bulk modulus
As bulk modulus is least for ethanol (0.9) and maximum
(a) Compressibility =
11
for mercury (25) among ehtanol, mercury and water.
9.
10.
DV
Hence compression in volume
V
Ethanol > Water > Mercury
(b) According to Toricellis theorem,
Velocity of efflex,
830 =
DT =
13.
14.
15.
2 6 10 -2
10-3
16.
980
= 0.1 m
9800
(b) From Newtons law of cooling,
17.
18.
q - q0
1
log e 2
k
q1 - q0
From question and above equation,
t=
1
(40 - 30)
log e
(80 - 30)
k
1
(32 - 30)
log e
k
(62 - 30)
Dividing equation (2) by (1),
And, t =
1
log e
t k
=
5 1
log e
k
12.
19.
(a)
I1 = 30 A
I = 10 A
I2 = 20 A
3 cm
5 cm
...(2)
(32 - 30)
(62 - 30)
(40 - 30)
(80 - 30)
mR (T1 - T2 )
g -1
2 2 800
= 10
320
(b) Electric flux, f = E (ds) cos q
= E (hR) cos 0 = EhR
(c)
(a) Current through 50 V and 30 V batteries are respectively
2.5 A and 3 A.
...(1)
V
Q l =
f
h=
5=
2 2 4
- - =
l l l
2 2
= 320
800
11.
830 0.4
= 20 K
2 8.3
(c)
(b) The change in time period compared to the undamped
oscillator increases by 8%.
(d) Given: Frequency of sound produced by siren, f = 800
Hz
Speed of observer, u = 2 m/s
Velocity of sound, v = 320 m/s
No. of beats heard per second = ?
No. of extra waves received by the observer per second
= + 4l
\ No. of beats/ sec
2s
r
2 8.3( DT ) 2 8.3(DT )
=
1.4 - 1
0.4
20.
12
21.
parts
I Bright
I Dark
25.
DB
= N
A cos q
Dt
= 400 mV
10-2
(c) Given: Amplitude of electric field,
E0 = 4 v/m
Absolute permitivity,
e0 = 8.8 1012 c2/N-m2
Average energy density uE = ?
Applying formula,
=
22.
1000 10-2 4 10 -4
I1 3
=
I2 2
1
1
1
=
1.2 v0 ( -1.25)
1
1
1
=
v0 1.2 1.25
26.
27.
(b)
(b) Let N be the number of nuclei at any time t then,
dN
= 100 lN
dt
N
1
N
log (100 - lN )]0 = t
[
l
log (100 l N) log 100 = lt
3 ( D + 10)2
=
2 ( D - 10)2
100 - lN
= e -lt
100
a1 = 4; a2 = 3
Therefore the ratio of intensities of bright and dark
100 - l N
= lt
100
log
I1 16 a12
= =
I 2 9 a22
dN
(100 - lN ) = dt
0
0
I1 ( D + d )2
=
I 2 ( D - d )2
24.
v0 D
u0 f e
30 25
(Q D = 25 cm least
1.25 3
distance of distinct vision)
= 200
Hence the magnifying power of the compound
microscope is 200
or
3 D + 100 + 20 D
= 2
2
D + 100 - 20 D
3D2 + 300 60D = 2D2 + 200 + 40D
D2 100D + 100 = 0
On solving, we get D = 99 cm
Hence the distance between the screen and the object
is 99 cm.
(d) Intensity (amplitude)2
49
1
1
1 1
= f 0 v0 u0
M = -
uE =
23.
(4 - 3)
v0 = 30 cm
Magnification at infinity,
1
e0 E 2
4
1
8.8 10 -12 (4) 2
4
= 35.2 1012 J/m3
(d) Given: Separation of lens for two of its position, d = 10
cm
Ratio of size of the images in two positions
(a1 - a2 )
(4 + 3) 2
-d f
dt
(a1 + a2 )2
1-
lN
= e -lt
100
100
(1 - e -l t )
l
As, N = 50 and l = 0.5/sec
N=
100
(1 e0.5t)
0.5
Solving we get,
50 =
4
t = 2ln sec
3
13
28.
VZ
10
=
= 5 mA
RL 2 103
34. (d)
1
1
\ pH = 7 + pK a + log c where pka = - log K a
2
2
V - VZ
Current through R, I = i
R
30.
G=
RS
R-S
35. (b)
hc hc 1 2
=
+ mv
l l0 2
32. (d)
33. (d)
37. (d)
38. (a)
\ k = 2k
Solutions which resist the change in the value of pH
when small amount of acid or base is added to them are
known as buffers.
Reducing character decreases down the series. Hence
the correct order is
Al < Fe2+ < Br
According to Boyles law
V1 P2 750 360
;
=
=
V2 P1 V2
840
39. (b)
V2 = 1750 ml = 1.750 L
Given, Cp = 10 cals at 1000 K
T1 = 1000 K. T2 = 100 K
m = 32 g
DS = ?
at constant pressure
T
DS = C p ln 2
T
1
2hc l 0 - l
v =
m ll 0
2
v=
= 2.303 Cp log
2hc l 0 - l
m ll 0
1 d [ N 2 O5 ] 1 d [ NO2 ]
=
2
dt
4
dt
k k
=
2 4
l - l
= hc 0
ll 0
or
= log 105 = 5
1
1
k [ N 2O5 ] = k [ N 2 O5 ]
2
4
1 2 hc hc
mv =
2
l l0
5 1
2 2
= 9.0
log c = log 101 = 1
Rate of disappearance of reactant = Rate of appearance
of products
-
36. (d)
CHEMISTRY
31. (c)
= 7+
50
=
= 12.5 mA
4 103 4 103
Fom circuit diagram,
I = IZ + IL
12.5 = IZ + 5
IZ = 12.5 5 = 7.5 mA
(d) Wavelength emitted by atomic hydrogen in interstellar
space - Part of short radio wave of electromagnetic
spectrum.
Doublet of sodium - visible radiation.
(d) The correct circuit diagram is D with galvanometer
resistance
29.
60 - 10
dSO 2
dO
= -2 2
dt
dt
= 2 2.5 104
= 5 104 mol L1 s1
Sodium acetate is a salt of strong base and weak acid.
\-
dO
1 dSO2
1 dSO3
=- 2 =
2 dt
dt
2 dt
= 2.303 10 log
T2
T1
100
1000
1
1
DE = -2.0 10 -18 2 - 2
2
1
-18 -3
= -2.0 10
4
= 1.5 1018
14
DE =
hc
l
41. (c)
42. (c)
43. (d)
44. (c)
45. (d)
\
48. (b)
49. (a)
Co3+ + 6NH3
Co ( NH3 )6
Lewis
acid
50. (b)
Lewis
base
3+
adduct
51. (b)
52. (c)
3
Ph C C Ph
Ph
Birch reduction
53. (a)
54. (c)
H
C=C
H
Ph
On reduction with Zn and HCl, C6H5N2Cl forms aniline
as the main product.
Given compound A is CH 3 - CH 2 - C = C = O
|
CH3
Reactions given are as following :
NH
3
CH 3 - CH 2 - C = C = O
|
CH3
CH 3 - CH 2 - C = C - O -
CH3
CH 3 - CH 2 - C = C - OH
|
|
CH3 NH 2
n=
F
Br
F
47. (c)
2HNO3(aq) + [Ag(NH3)2]+ + Cl
AgCl ( s )
When nitric acid is added to amine solution, solution is
made acidic and the complex ion dissociates and liberate
silver ion to recombine with chloride ion. This is the
+2NH 4 + 2NO3-
O
||
CH 3 - CH 2 - CH = C - NH 2
|
CH3
H O
2
CH 3 - CH 2 - C = C = O
|
CH3
CH 3 - CH 2 - CH - COOH
|
CH3
CH COOH
3
CH 3 - CH 2 - C = C = O
|
CH3
15
O
O
||
||
CH 3 - CH - CH - C - O - C - CH 3
|
CH 3
sp 2 sp sp2
C=C=C
55. (b)
56. (c)
136 pm
Phenol
60. (c)
H
H
Chloral on reaction with chlorobenzene in the presence
of a catalytic amount of sulphuric acid forms DDT
(dichlorodiphenyl Trichloro ethane).
CH2COOK
ionization
CH2COOK
CH2COO
CH2COO
+ 2K
Pot. Succinate
ionization
Cl
2OH - + 2H +
2H 2O
At anode :
Cl
CH2COO
Cl3C C = O +
Trichloro
acetaldehyde
CH2COO
Cl
61.
(c)
-11p
p
p
f
6 = 3sin - 2 p - 6 + 4cos - 2p - 6
and
cos(
-q
)
=
cos
q
90%
p
p
-11p
\ f
= -3sin 2p - - 4cos 2p -
6
6
6
p
p
-11p
f
= +3sin - 4cos
6
6
6
1
3
-11p
f
= 3 - 4
6
2
2
H
C
-11p 3
or f
= -2 3
6 2
O
H
Methanol
-11p
p
p
f
6 = 3sin -2p + 6 + 4cos -2p + 6
+ 2CO2
-11p
-11p
-11p
3sin
+ 4cos
f
=
6
6
6
50 60, 4 hr
142 pm
CH2COO
CH2
Mathematics
58. (c)
59. (c)
CH2
2H + + 2e -
[ 2H ]
H2
C6H5CH2ONa
CH2COO
At cathode :
Cl
DDT
2e
Unstable
Cl3C CH
57. (c)
62.
(a)
z
z
Consider arg 1 + arg 2
z4
z3
16
= arg( z1 ) - arg( z4 ) + arg( z2 ) - arg( z3 )
3 1 2
3 0 2
= A1 I = A1
I
1 0 1
z2 = z1 &
given
z4 = z3
arg( z3 ) = - arg( z3 )
(d)
Hence, A1
65.
(a)
x 2 - 4 2kx + 2e 4 ln k - 1 = 0
or, x 2 - 4 2kx + 2k 4 - 1 = 0
a2
b2
32k2
= (4 2k )
+
+ 2ab =
2
66 + 2ab = 32k
66 + 2 (2k4 1) = 32k2
66 + 4k4 2 = 32k2 4k4 32k2 + 64 = 0
or, k4 8k2 + 16 = 0 (k2)2 8k2 + 16 = 0
(k2 4) (k2 4) = 0 k2 = 4, k2 = 4
k= 2
Now, a3 + b3 = (a + b) (a2 + b2 ab)
(a +
b3
= (4 2( -2))[66 - 2( -2) - 1]
\ a3 + b3 = -280 2
64.
(a)
2a2 x + b2
2a3 x + b3
a1x 2 + b1x + c1
a2 x 2 + b2 x + c2
a3 x 2 + b3 x + c3
a3 + b3 = ( -8 2) (66 32 + 1) = ( -8 2) (35)
2a1x + b1
a1 x 2 + b1x + c1 a2 x 2 + b2 x + c2
B(x) = 2a1 x + b1
2a2 x + b2
2a
2a2
1
\ A(x) = a2 x 2 + b2 x + c2
a3 x 2 + b3 x + c3
3 1 2
3 0 2
=
1 0 1
66.
(d)
0 0 1
1 2 3
Given A 0 2 3 = 1 0 0
0 1 0
0 1 1
Applying C1 C3
a3 x 2 + b3 x + c3
2a3 x + b2
2a3
2a1x + b1
2a2 x + b2
2a3 x + b3
2a1
2a2
2a3
3 2 1
1 0 0
3 2 0
0 0 1
=
A
1 1 0
0 1 0
Again Applying C2 C3
1 and 8
7 7!
3 1 2
1 0 0
3 0 2
0 1 0
=
A
0 0 1
1 0 1
2 and 7
3 and 6
7 7!
7 7!
4 and 5
7 7!
2a1
2 a2
2a3
1 0 0
0 1 0
0 0 1
67.
(d)
17
S = (1 + x)1000 + x (1 + x)999 + x2 (1 + x)998 + ...
+ ... + x1000
Put 1 + x = t
S = t1000 + xt999 + x2 (t)998 + ... + x1000
This is a G.P with common ratio
x
t
Now, Sn =
x 1001
t1000 1 -
S=
x
1t
20
[2 11 + (20 1) 20]
2
S20 = 10 [22 + 19 20]
S20 = 10 402 = 4020
\ S20 = 4020
S20 =
x 1001
(1 + x)1000 1 -
1 + x
=
x
11+ x
70.
(d)
(c)
lim
-1
a (r
(r
or
-5
-1
- 1)
a (r - 1) ( r
-1
a (r
-5
- 1) ( r - 1)
or k + 2 = 5
71.
(c)
(1 - r 5 ) (1 - r ) r
a2r4
= 49
a2r4
k=3
Let f (x) = x|x| = x|x|, g(x) = sin x
and h (x) = gof (x) = g[f (x)]
= 49
72
ar 2 = 7
x0
x<0
2
2 x cos x , x 0
Now, h (x) =
2
-2 x cos x , x < 0
Since, L.H.L and R.H.L at x = 0 of h (x) is equal to
0 therefore h (x) is continuous at x = 0
Now, suppose h (x) is differentiable
= 49
a 2 (1 - r 5 ) (1 - r ) r 5
tan h
= 1
Q lim
h0 h
(k + x ) = 5
1 xlim
2
2
sin x ,
\ h(x) =
2
- sin x ,
- 1)
=5
(k + x )( x - 2 )
tan( x - 2)
lim ( x - 2) lim
=5
x 2
x 2
( x - 2 )
= 49
-1
( x - 2) 2
- 1)
=5
tan( x - 2){x 2 + kx - 2 x - 2 k}
x2
(1001)!
50!(951)!
According to Question
S
5' = 49 {here, S5 = Sum of first 5 terms
S5
and S5 = Sum of their reciprocals)
a(r - 1)
(r - 1)
x2 - 4 x + 4
x 2
...(1)
Also, given, S1 + S3 = 35
a + ar2 = 35
...(2)
Now substituting the value of eq. (1) in eq. (2)
a + 7 = 35
(b)
tan( x - 2){x 2 + (k - 2) x - 2k }
lim
69.
lim
=
(1 + x )1001
68.
n
[2a + ( n - 1) d ]
2
a = 28
Given n = 20; S20 = ?
Series (1) 3, 7, 11, 15, 19, 23, 27, 31, 35, 39, 43, 47,
51, 55, 59...
Series (2) 1, 6, 11, 16, 21, 26, 31, 36, 41, 46, 51, 56,
72.
(c)
2
2
2
2(cos x + 2 x ( - sin x ), x 0
\ h(x) =
2
2
2
2( - cos x + 2 x sin x ), x < 0
Since, L.H.L and R.H.L at x = 0 of h (x) are different
therefore h (x) is not continuous.
h(x) is not differentiable
our assumption is wrong
Hence h(x) is not differentiable at x = 0.
Given, y = 3 sin q.cos q
dy
= 3[sin q(- sin q) + cos q(cos q)]
dq
18
(OA)2 = (OB)2 + (AB)2
dy
= 3[cos 2 q - sin 2 q] = 3 cos 2q
dq
and x = eq sin q
...(1)
dx
= eq cos q + sin q eq
dq
dx
= eq (sin q + cos q)
dq
Dividing (1) by (2)
...(2)
3(cos 2 q - sin 2 q)
dy
3cos 2q
= q
= q
dx
e (sin q + cos q)
e (sin q + cos q)
2
( 3)
h2
h2
2
+ r2 r = 3 4
4
Now, volume of cylinder = pr2h
dy
=0
dx
h2
V = p3 - h
4
3(cos q - sin q)
q
e
or cos q sin q = 0 cos q = sin q
(a)
V1 =
120
Let OA = x km, OB = y km, AB = R
(AB)2 = (OA)2 + (OB)2 2 (OA) (OB) cos 120
62 + 82 + 6 8 = 2 37
Differentiating equation (1) with respect to t
dx
dy dy
dx
dR
= 2 + 2y + x + y
dt
dt
dt dt
dt
1
[2 8 20 + 2 6 30 + (8 30 + 6 20)]
=
2R
1
260
dR
[1040] =
=
2
2
37
37
dt
74.
(c)
h2
p
3
=
h = p (6 - 2) = 4p
4
...(1)
R=
dV
3
= 3 p - ph 2
4
dh
3 2
3
or 3p - ph = 0 3p = p h 2
4
4
h2 = 4 h = 2
Now, volume (V) of the cylinder
1
R2 = x2 + y2 2 xy - = x 2 + y 2 + xy
2
R at x = 6 km, and y = 8 km
ph 3
...(2)
4
Now, for largest possible right circular cylinder the
volume must be maximum
dV
\ For maximum volume,
=0
dh
Now, Differentiating eq. (2) w.r.t. h
tan p
p
q=
4
4
...(1)
V = 3 ph -
2R
h
2
= +r
2
3=
73.
3(cos q - sin q)
dy
=
dx
eq
tan q = 1 tan q =
0=
h/2
75.
(a)
Let I =
\I=2
x cos
-1
IIx .tanI
1 - x2
dx
1 + x2
-1
x dx
d
-1
I = 2 tan x xdx - (tan x xdx)dx
dx
x2
x2
1
-1
dx + c
I = 2 2 tan x -
1 + x 2 2
19
x2
1 x2 + 1 - 1
-1
dx + c
I = 2 2 tan x - 2 2
x +1
x2
1 x2 + 1
1
1
-1
dx +
dx + c
I = 2 2 tan x - 2 2
2 1 + x2
x +1
dx
dv
=
x
1
f
v
or,
x2
1
1
-1
-1
2
I = 2 tan x - 2 1.dx + 2 tan x + c
dx
=
x
x2
x 1
-1
-1
I = 2 2 tan x - 2 + 2 tan x + c
But, given y =
or I = - x + ( x 2 + 1) tan -1 x + c
e
(c)
Pn =
(log x )
so that
\ P10 =
. e dt
1
e dt and P8 =
78.
8 t
e dt
10 t
tI
0
(b)
Y
1
e dt - 90 t 8et dt
II
B (0, b)
P (h, k)
P10 90 P8
1
1 9 t
1 8 t
10 t
P10 90 P8 = t e - 100 t e dt - 900 t e dt
0
P10 90 P8 =
1
1
1
d 9 t
e - 10 t 9 et dt -
(t ) e dt - 90 t 8et dt
dt
0
0
0
1 8 t
1 8 t
P10 90 P8 = e - 10 e - 90 t e dt - 900 t e dt
A(a, 0)
\ P10 - 90 P8 = -9e
(d)
dy y
y
= + f
Given
x
dx x
...(1)
h=
2(0) + 1(a )
a
=
1+ 2
3
k=
2(b ) + 1(0) 2b
=
3
3
or
dy
dv
= x +v
dx
dx
a = 3h and b =
Now, a 2 + b 2 = l2
y
Let = v so that y = xv
x
9 h2 +
...(2)
8 t
8 t
P10 90 P8 = e - 10e + 90 t e dt - 90 t e dt
77.
x
y
1
-1
= 2 i.e. f(2) = - = - =
x
2
4
y
Let point A (a, 0) is on x-axis and B (0, b) is on
y-axis.
when
10 t
dv
1
f
v
n t
x
1
-1
y2
f =
f
=
v
y
v2
x2
x
1
=
= ln|cx| =
v
y
x
is the general solution
ln | cx |
dx
\ Pn =
dv
dv
ln x + c =
1
1
f
f
v
v
I = x 2 tan -1 x + tan -1 x - x + c
76.
dv
1
+ v = v + f
v
dx
9k 2
= l2
4
3k
2
20
h2
l
3
k2
2l
3
r1 = 50 - l , r2 = 2
For exactly two common tangents we have
=1
l2
9
1- 2 =
9 4l
Now e =
1-
1
3
=
4
2
(b)
81.
P (1, 2)
50 - l - 2 < 3 2 < 50 - l + 2
50 - l - 2 < 3 2 or 3 2 < 50 - l + 2
50 - l < 4 2 or 2 2 < 50 - l
50 - l < 32 or 8 < 50 - l
l > 18 or l < 42
Required interval is (18, 42)
3
.
2
79.
(c)
y2 = 8x
x2 + y 2 = 32
3x + 4y = 9
We have
x2 + (8x) = 9
x2 + 9x x 9 = 0
x (x + 9) 1 (x + 9) = 0
(x + 9) (x 1) = 0
x = 9, 1
ax1 + by1 - c
by = c is d =
a2 + b2
Now shortest distance of P (1, 2) from 3x + 4y = 9
is
3(1) + 4(2) - 9
PC = d =
for x = 1, y = 2 2 x = 2 2
L1 = Length of AB
2
5
32 + 42
Given that DAPB is an equilateral triangle
Let 'a' be its side
a
2
Now, In DPCB, (PB)2 = (PC)2 + (CB)2 (By Pythagoras
theorem)
then PB = a, CB =
a
2
a2 = +
5
4
(b)
82.
(d)
x2
y2
a 2 x b2 y
+
= a2 + b2
x1
y1
a 2 b2
therefore equation of normal to the hyperbola
a2 -
a4
4
3a 2
4
=
=
4
25
4
25
32
a2 =
16
a=
75
32 x
22 y
+
= 32 + 22
3sec q 2 tan q
x2
16
4
3 4 3
=
=
75 5 3
15
3
(2 2 + 2 2) 2 + (1 - 1) 2 = 4 2
L2 = Length of latus rectum = 4a = 4 2 = 8
L1 < L2
Let the coordinate at point of intersection of normals
at P and Q be (h, k)
Since, equation of normals to the hyperbola
=
4 3
5
and x + y - 4 x - 4 y + 6 = 0
C1 = centre of (1) = (5, 5)
C2 = centre of (2) = (2, 2)
d = distance between centres
= C1C2 = 9 + 9 = 18
y2
22
3 x cos q + 2 y cot q = 32 + 22
...(1)
...(1)
...(2)
x2
32
y2
22
32 x
22 y
+
= 32 + 22
3sec f 2 tan f
3 x cos f + 2 y cot f = 32 + 2 2
...(2)
21
Given q + f =
p
p
f = - q and these passes
2
2
through (h, k)
\ From eq. (2)
p
3 x cos - q + 2 y cot - q = 32 + 22
2
2
3h sin q + 2k tan q = 32 + 2 2
...(3)
...(4)
84.
(b)
A (2, 3, 5)
l 7
= 10l - 7m = 0
m 10
Equation of the plane containing the line
85.
(d)
i.e,
l - 5
2
2
l - 5
m - 8
+ 1 +
2
2
....... (i)
....... (ii)
....... (iii)
a
b
c
=
=
= k (let)
8 - 3 3 - 4 1- 2
\ a = 5k, b = k, c = k
On putting the value of a, b and c in equation (i),
5(x 1) (y 2) (z 3) = 0
5x y z = 0
....... (iv)
when x = 1, y = 0 and z = 5; then
L.H.S. of equation (iv) = 5x y 2
=5105
=0
= R.H.S. of equation (iv)
Hence coordinates of the point (1, 0, 5) satisfy the
equation plane represented by equations (iv),
Therefore the plane passes through the point (1,0,5)
Let, cr = ai + bj + ck
r
Given, cr (i + 2 j + 5k) = 0
x y z
= =
1 1 4
\
a.1 + b.1 + c.4 = 0
i.e., a + b + 4c = 0
From (ii) and (iii),
m + 2
l -1
D=
, 4,
2
2
l -5 m -8
, 1,
2
2
Since median AD is equally inclined with coordinate
axes, therefore direction ratios of AD will be equal,
l - 5
m - 8
+ 1 +
2
2
x -1 y - 2 z - 3
is
=
=
1
2
3
a (x 1) + b (y 2) + c (z 3) = 0
where a.1 + b.2 + c.3 = 0
i.e.,
a + 2b + 3c = 0
Since the plane (i) parallel to the line
-13
2
If D be the mid-point of BC, then
C
(l , 5, )
Then
at P and Q is
l = 7, 3 and = 10, 6
If l = 7 and = 10
-13
2k = 13 k =
2
Hence, ordinate of point of intersection of normals
B
(1, 3, 2)
m - 8
2k tan q - 2 k + 2k tan q = 13
(c)
l - 5
m - 8
+ 1 +
2
2
l - 5
m - 8
=1 =
2
2
83.
1
2
j k
a b c
1 2 5
r
= 0
22
Squaring both sides, we get
5b 2c = 0; 5a c = 0; 2a b = 0
or 5b = 2c; 5a = c; 2a = b
r
Also given | c |2 = 60 a 2 + b 2 + c 2 = 60
Putting the value of b and c in above eqn., we get
a 2 + (2a)2 + (5a) 2 = 60
2
2
2
a + 4a + 25a = 60 30a2 = 60
a2 = 2
a= 2;b= 2 2;c= 5 2
r
Now, c = ai + bj + ck
r
\ c = 2i + 2 2 j + 5 2k
r
Value of c . ( -7i + 2 j + 3k) is
)(
(
86.
(b)
2i + 2 2 j + 5 2k . -7i + 2 j + 3k
-3
-3
= tan q = sec 2 q - 1 =
4
4
Q tan q = sec 2 q - 1
9
-3
2
sec q - 1 = =
4
16
= -7 2 + 4 2 + 15 2 = 12 2
Let S = {x1, x2, x3, x4, x5, x6, x7}
Let the chosen element be xi.
Total number of subsets of S = 27 = 128
No. of non-empty subsets of S = 128 1 = 127
We need to find number of those subsets that
contains xi.
sec2q =
9
25
5
+1 =
sec q =
16
4
16
or cos q =
4
5
2 2 2 2 1 2 2
Now,
87.
(b)
sin2q
cos2q
sin2q +
4
16 9
2
=
= 1 sin q = 1 5
25 25
sin q =
3
5
...(2)
4
3 28 18 46
+6 =
+ =
5
5 5 5
5
Let AB be the tower of height 'h'.
= 7
89.
(a)
n!
p 2 (1 - p )n
n!
p 3 (1 - p ) n
.
.
=
2!(n - 2)! (1 - p )2
3!(n - 3)! (1 - p )3
1 p
1
= .
n - 2 3 1- p
3 (1 p) = p (n 2)
3 3p = np 2p
np = 3 p
E(X) = mean = 3 p
(Q mean of B (n, p) = np)
Given 2 cos q + sin q = 1
88.
(d)
4
2
= 1 sin q + = 1
5
3
3
64
127
Since X has a binomial distribution, B (n, p)
\ P (X = 2) = nC2 (p)2 (1 p)n2
and P (X = 3) = nC3 (p)3 (1 p)n3
Given P (X = 2) = P (X = 3)
nC2 p2 (1 p)n2 = nC3 (p)3 (1 p)n3
...(1)
2
x1 x2 ------- xi ---- x7
For those subsets containing xi, each element has 2
choices.
i.e., (included or not included) in subset,
However as the subset must contain xi, xi has only
one choice. (included one)
So, total no. of subsets containing
xi = 2 2 2 2 1 2 2 = 64
Required prob =
a
2m
Given : In DABP
tan a =
AB
PB
23
Putting the value of x in eq. (2) to eq. (1), we get
sin a
h
=
cos a
x+2
(x + 2) sin a = h cos a
or
h=
x sin a + 2sin a
cos a
...(1)
AB
BC
sinb
h
h cos b
= x=
x
cosb
sin b
...(2)
h=
90.
(c)
2sin a.sin b
sin (b - a )
Given ~ ( p ~ q) ~ ( p q)
(~ p q) (~ p ~ q )
~ p (q ~ q)
~ p