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DEFINITION

All

De-broglie wavelength

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Diagram

De Broglie's wavelength is the wavelength associated with a massive


particle,hypothesized by De Brogliethat explains Bohr's quantised orbits
by bringing in the wave-particle duality. It is written as
h
=

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mv

Definition
Example

(de broglie wavelength)

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Heisenberg uncertainty principle

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The position and momentum of a particle cannot be simultaneously


measured with arbitrarily high precision.

Formula

Also Practice This Chap


2

DEFINITION

Solve questions and clear all go


master this chapter.

Photons and Photoelectric Effec

xp >
2

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Stopping Potential and Einstein

E t >
2

Terms

Dual Nature
3

FORMULA

+ 1 more Goal

Uncertainty in position or momentum

Practice All Goals

xp >
2

wherex is the uncertainty in position,


p is the uncertainty in momentum and
is the reduced Planck's constant

DIAGRAM

Intensity of X-rays

DIAGRAM

Variation of photocurrent with potential for different intensity of


incident light

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DIAGRAM

Variation of photocurrent with potential for different frequencies of


incident light

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Terms

EXAMPLE

Solve problem on cathode ray tube


Example: A cathode ray tube has a potential difference of V volt between
the cathode and the anode. Find the speed of cathode rays.
Solution:
The kinetic energy of electrons is:
1
E =

mv

The potential between cathode and anode is V hence,


1
mv

= eV

2
v

2eV
=
m
19

2 1.6 10
=

31

9.1 10
v

12

= 0.35 10

5
v = 0.35 10 V
5

v = 5.9 10 V
5

v 6 10 V ms

EXAMPLE

Mass of a particle using de-Broglie wavelength


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The de-Brogliewavelength associated with a particle movingwith a


velocity of 10 m/s is 6.6 10 m.Then the mass of the particle is
2

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24

=
mv
34

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m =

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6.6 10
=

24

6.6 10

12

= 10

kg

10

DEFINITION

Photocell

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A photocell is a technological application of the photoelectric effect.A


photocellconsists of a semi-cylindrical photo-sensitive metal plate C
(emitter) and a wire loop A(collector) supported in an evacuated glass or
quartz bulb. It is connected to the externalcircuit having a high-tension
battery B and microammeter (A).When light of suitable wavelength falls
on theemitter C, photoelectrons are emitted. Thesephotoelectrons are
drawn to the collector A.A photocell converts a change in intensity
ofillumination into a change in photocurrent.

10

DEFINITION

Particle and wave nature of light


Dual nature of light:
Sometimes it behaves like a particle (called a photon), which explains
how light travels in straight lines
Sometimes it behaves like a wave, which explains how light bends (or
diffracts) around an object
Light also shows interference properties, for example the formation of
dark and bright fringes in Young's Double Slit experiment illustrates this
fact. Light alsoexhibits polarization. Natural light coming from the sky is
partially polarised but it can be made fully polarised by passing through a
polaroid.

11

DEFINITION

Understand the difference between continuous and characteristic Xrays

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At certain sharply defined wavelengths, the intensity of X-rays is very large


as marked K , K in figure. These X-rays are called characteristic X-rays.
At other wavelengths the intensity varies gradually and theses X-rays are
called continuous X-rays.

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Photoelectric current is zero when the stopping potential is sufficient to


repel even the most energetic photoelectrons with the maximum kinetic
energy K
so that K
= eV
For a given frequency of the incident radiation, the stopping potential is
independent of its intensity.
max

13
ONLI N E COACHING

Effect of potential on photocurrent

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DEFINITION

max

DEFINITION

Moseley's law and Bohr model


Moseley's Law:

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= a(Z b)

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where a and b are constants


and is frequency of X-rays
According to Bohr's model, the energy released during the transition from
n = 2 to n = 1 is given by

Terms

E = h = Rhc(Z b)

so that

14

1
(

3Rc

=
(Z b)

DEFINITION

Einstein's photoelectric equation


Einstein's photoelectric equation :
hc
Kmax =

= h

The kinetic energy of the photoelectron coming out may be anything


between zero and (E ) where E
individual electrons.

hc
=

is the energy supplied to the

Kmax = E

15

DEFINITION

Stopping potential
The smallest magnitude of the anode potential which just stops the
photocurrent is called the stopping potential.
hc
V0 =

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DEFINITION

Factors affecting stopping potential

The stopping potential V depends on the wavelength of light and the


work function of the metal. It doesn't depend on the intensity of light.
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FORMULA

Energy and momentum of photoelectrons


Energy:

DOUBTS

hc

E = h =

Momentum:

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p =

E
=

Example: A radiation of wave length 2500 A is incident on ametal plate


whose work function is 3.5 eV. Thenthe energy and momentum of
thephotoelectrons emitted by the surface is(h = 6.63 10
Js and
c = 3 10 m/s)
Given:
0

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10

= 2500 10

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6.63 3 10
E =

DISCUSS

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m
19

10

= 7.95 10

2500 10

p =

E
c

19

7.9510

310

27

= 2.65 10

kg. m. s

18

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Saturation current

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Terms

If the potential of the anode is increased gradually, a situation arrives


when the effect of the space charge becomes negligible and any electron
that is emitted from the cathode is able to reach the anode. The current
then becomes constant and is known as the saturation current.Further
increase in the anode potentiaal does not change the magnitude of the
photocurrent.

19

DEFINITION

Photoelectron
Whenlightof suitable frequencyshines upon a metal surface electrons are
emitted from the surface. These electrons are called photoelectrons.

20

DEFINITION

Bound and conduction electrons


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The electrons which are in orbits close to the nucleus are called the bound
electrons because they are tightly bound to the nucleus by the strong
attractive force between the positive charge of the nucleus and the
negative charge of electrons.
When large number of atoms come together to form a solid, the loosely
bound electrons of the outermost orbit leave their individual atom and
become free to move inside the solid. These electrons remain within the
solid. They are called conduction electrons.

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21

DEFINITION

frequency vs potential

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The maximum kinetic energy of the photoelectrons varies linearly with the
frequency of incident radiation, but is independent of its intensity.
For afrequency of of incident radiation, lower than the threshold
frequency no photoelectric emission is possible even if the intensity is
large.
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22

DEFINITION

Work function
The minimum amount of energy required to emit electrons from a metal
surface is called the work function. It is characteristics of a metal. Work
function for some metals are as follows:
Platinum

6.2

Tungsten

4.52

Chromium 4.37
Zinc

4.24

Sodium

2.3

From above table it's evident that the alkali metals have low work
function.

23

DEFINITION

Thermionic Emmision
The emission of electrons from a metal surface when heat energy is
imparted to it is called the thermionic emission.Thermionic emissionis
the thermally induced flow ofcharge carriersfrom a surface or over a
potential-energy barrier. This occurs because the thermal energy given to
the carrier overcomes thework functionof the material. After emission, a
charge that is equal in magnitude and opposite in sign to the total charge
emitted is initially left behind in the emitting region. But if the emitter is
connected to a battery, the charge left behind is neutralized by charge
supplied by the battery as the emitted charge carriers move away from
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the emitter, and finally the emitter will be in the same state as it was
before emission.
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24

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Work function of metals

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From the graph shown, the value of Work function ifthe stopping
potential, V , and frequency of theincident light, , are on y and x- axes
respectivelyis:
hv = h0 + K . E

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at stopping potential K . E =eV


h = h0 + eV

h
V =

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( 0 )

from the graph for = 0


work function = h =

25

3eV

DEFINITION

Factors affecting the rate of thermionic emission

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The number of electrons emitted per second from a surface depends on


the following three factors:
1. The nature of the metal surface: Lower the work function of the metal,
greater is the rate of emission of electrons from its surface.
2. The temperature of the surface: Higher the temperature of the surface,
greater is the rate of emission of electrons from the surface.
3. The surface area of the metal: Larger the surface area of the metal
emitting the electrons, greater is the rate of emission of electrons.

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26

DEFINITION

Decay of X-Rays in a medium


X-rays travelling through a medium suffers decay with distance as they
travel.
x

I = Io e

where,
I : Intensity after travelling a distance x in the medium.
I : Incident intensity.
: Absorption coefficient.
o

27

EXAMPLE

Einstein's photoelectric equation example

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Three metals have work functions in the ratio 2:3:4.Graphs are drawn for
all between the stoppingpotential and the incident frequency. The
graphshave slopes in the ratio:
Here equation is
V = (h )/e

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or V

h
=

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or comparing with

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we get m = h/ec = /e
So, slope (m) = h/e
which is a constant.
So, ratio is 1:1:1.

y = mx + c

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28

DEFINITION

Principle and construction of cathode ray tube

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The essential parts of a cathode ray tube makeuse of the following three
processes:
1. Thermionic emission
2. Deflection of electron beam by the electric and magnetic fields
3. Fluorescence produced by the electron beam on a fluorescent screen
Construction: It consists of a long hollow evacuated glass tube containing
the three main components: 1. The electron gun 2. The deflecting system
3. The fluorescent screen.

29

DEFINITION

Explain the properties of X rays


1. They have a very short wavelength (about the same size as the
diameter of an atom).
2. They cause ionisation (adding or removing electrons in atoms and
molecules).
3. They affect photographic film in the same way as visible light (turning it
black).
4. They are absorbed (stopped) by metals and bones.

30

EXAMPLE

Problem on variation of energy and wavelength of X-rays


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Example:
The voltage applied to an X-ray bulb increases to1.5 times the initial
voltage. The short wavelengthlimit of continuous X-ray spectrum shifts
by25 pm. Then find the original wavelength.
Solution:

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hc
=

eV
2hc
25 =

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3eV

3
=

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25

2 = 3 75

= 75 pm

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Working of the electron gun, the deflecting system and the


fluorescent screen in hot cathode ray tube
1. The electron gun: It is the part of cathode ray tube which gives out a fine
beam of electrons. By varying the negative potential on the grid, the
number of electrons striking the screen can be changed which changes
the brightness of the pattern on the screen.
2. The deflecting system: It is the part of cathode ray tube which deflects
the electron beam.
3. Deflection of electrons by the electric fields: When an electric field is
produced between the two plates, the electron beam on entering the
space between the plates, gets deflected towards the positive plate.

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DEFINITION

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EXAMPLE

Terms

Maximum velocity of photoelectrons


hc
Kmax =

then v

mvmax
2

hc

)
2(

=
m

max

The work function of a metal surface is 1 eV. Alight of wavelength 3000A


is incident on it. Themaximum velocity of the photoelectrons is found as:
The maximum K.E with which electrons comes out,

hc

1
1eV =

mv

2
19

2 3.14 1.6 10

31

10

= v

9.1
v

12

= 1.10461 10
6

v = 1.05 10
6

v = 10

33

DEFINITION

Deflection of electrons by electric field and magnetic field


Deflection of electrons by the electric field: When an electric field is
produced between two plates, the electrons beams on entering the space
between the plates, gets deflected towards the positive plate in the
influence of electric field.
Deflection of electrons by the magnetic field: On entering the magnetic
field, the electrons of the electron beam get deflected in a direction given
by the Fleming's left hand rule.

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34

DEFINITION

Methods of electron emission


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Different methods of electron emission are:


1. Thermionic Emission: By suitably heating, sufficient thermal energy can
be imparted to the freeelectrons to enable them to come out of the metal.
2. Field Emission: By applying a very strong electric field (of the order of
10 V /m ) to a metal, electrons can be pulled out of the metal.
3. Photo-electric Emission: When light of suitable frequency illuminates a
metal surface, electrons are emitted from the metal surface.

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35

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DEFINITION

Uses of a cathode ray tube

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A cathode ray tube is used mainly to convert electrical signal into a visual
signal by applying the electric signal on the deflecting plates. Some of its
usage are given below:
1. To determine the unknown frequency of an alternating potential by
applying it on one pair of deflecting plates and comparing it with the
known frequency of other alternating potential applied on other pair of
plates.
2. To check the wave form of a varying electrical signal.
3. To measure a short time interval.
4. In television as a picture tube.

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36

DEFINITION

Maximum frequency of X-rays

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Terms

X-ray frequency,

eV
=
h

This shows that the maximum frequency is directly proportional to the


accelerating voltage.
The maximum frequency of X-rays produced in an
X-ray tube at an operating voltage of 25kV is
(h=

34

6.63 10

J s and c

= 3 10

m/s)

Operating voltage =
e

operating voltage e
=
h

25 10

19

1.6 10

34

6.63 10

=6.08 10 H z
18

37

EXAMPLE

Photocurrent for a given intensity


Let the intensity of the incident photons be I and frequency be .
Then, the incident power is P = I A where A is the area of the conductor.
Energy of one photon, E

hc
p

Then, number of photons incident per unit time is given by, n

P
=
Ep

Since, each photon emits one electron, number of electrons emitted is n.


Photocurrent is given by I = ne where e : charge of an electron.
p

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38

DIAGRAM

Plot of stopping potential v/s frequency


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Plot of stopping potential v/s frequency for incident light is shown in the
attached figure. Some salient characteristics of plot are:
1. x-intercept gives the threshold frequency of the material.
2. y-intercept obtained by interpolationis the work-function of the
material in eV.
3. Slope of the graph is given by h/e. Hence, it can be used to calculate
the value of Planck's constant.

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39

EXAMPLE

Problems on Millikan's drop experiment

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In Millikan's oil drop experiment a fine mist of oil droplets was sprayed
into a chamber above the plates. The oil was of a type usually used in
vacuum apparatus and was chosen because it had an extremely low
vapour pressure. Ordinary oil would evaporate under the heat of the light
source causing the mass of the oil drop to change over the course of the
experiment. Some oil drops became electrically charged through friction
with the nozzle as they were sprayed. Alternatively, charging could be
brought about by including an ionising radiation source (such as an X-ray
tube). The droplets entered the space between the plates and, because
they were charged, could be made to rise and fall by changing the voltage
across the plates. It was found that the charge on an oil droplet was
always an integral multiple of an elementary charge, 1.602 10 C .
Thus, it was established that electric charge is quantized and from the
values of charge (e) and specific charge (e/m, the mass (m) of the electron
could be determined.
19

Example: In a Millikans oil drop experiment, an oil drop ofmass


0.64 10
kg , carrying a charge 1.6 10
C remains stationary
between two platesseparated by a distance of 5 mm. Given
g = 9.8m/s ; find the voltage that must be applied between theplates.
14

19

Solution:
Let the voltage applied by V ,
According to equilibrium eqn.,
0

14

0.64 10

16

9.8 = 1.6 10

V0
5

0.64 5 9.8 10

1.6

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= V0

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V0 = 1960volts

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DEFINITION

Photon
The particles of light are photons. Its properties are:
A photon always travel at a speed c = 3 10 ms in vaccum.
The rest mass of a photon is zero.
Each photon has a definite energy and linear momentum.
8

hc
E = h =

COMPARE

p =

E
=

FRIE N D S

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During collisions, the number of photons may not be conserved.


If the intensity of a given wavelength is increased, there is an increase
in the number of photons crossing a given areain a given time. The
energy of each photon remains the same.

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41

FORMULA

Energy of a photon
hc
E = h =

ONLI N E COACHING

Example: Consider a parallel beam of light of wavelength 600 nm and


intensity 100 W m . Then energy of each photon is :

15

hc
E =

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(4.14 10

eV s) (3 10 ms

1)
= 2.07eV

600 10

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42

EXAMPLE

Bragg's law and its application

Suppose, and X-ray bean is incident on a solid, making an angle with the
planes of the atoms. These X-rays are diffracted by different atoms and
the diffracted rays interfere. In certain directions, the interference is
constructive and we obtain strong reflected X-rays. The analysis shows
that there will be a strong reflected X-ray beam only if
2d sin = n

where n is an integer. this equation is known as Bragg's law.


Example: X-rays are known to be electromagnetic radiation with
wavelength of the order of 1A . They are produced when accelerated
electrons strike target inside an evacuated tube. It is well known that
when an electron is accelerated through a potential difference of V it
acquires energy eV. If all this energy is used in producing one quantum of
X-radiation, then hf = eV . It is likely that the electron may have lost
some of its acquired energy before producing the quantum of radiation.
The f gives the maximum possible frequency of X-radiation emitted and
that corresponds to the short wavelength limit of the emitted spectrum. In
general, therefore, X-ray spectra consist of a continuous spectrum upon
which is superposed a line spectrum that is characteristic of the element
used as target. For some time after the discovery of X-rays, there was
considerable speculation about the nature of X-rays. Max Von Laue found,
in 1912 that if X-rays are passed through a crystal they get diffracted. As
Laue
patterns are difficult to interpret, Bragg worked out a simple equation

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that predicts the conditions under which diffracted X-rays beams from a
crystal are possible. In its simplest form, Bragg's Law is given by
= 2d sin where d is the perpendicular distance between the planes
contining atoms and is the glancing angle at which the X-rays fall on the
crystal. is known, the distance may be found from experimental
measurements. This is the basis for the field of X-ray crystallography in
which the structure of crystals is determined by using X-rays. Find the
photon is the order of energy associated with an x-ray.

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Solution:
Using the equations

hc

DOUBTS

E =

E = eV

COMPARE

and equating we get:


34

hc
V =

FRIE N D S

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6.63 10
=

10

10

3 10

= 12, 413V 10K eV (order)

19

1.6 10

DEFINITION

Davisson and Germer experiment


Davison and Germer observed the diffraction of electrons by crystals. The
setup consists of an electron gun firing electron beam onto a nickel target
inside a vaccum chamber. The diffracted electrons are observed by the
galvanometer.The experiment was performed by varying the voltage from
44V to 68V. It was observed that a strong peak appeared when the voltage
was 54V at a scattering angle of 50 due to constructive interference
effects of the electrons. The wavelength of the matter waves was found to
be 0.168 nm from diffraction measurements which matches that of deBroglie wavelength at 54 V thus verifying the wave nature of electrons.
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Terms

44

DEFINITION

Threshold frequency
The minimum frequency (characteristic of the metal)below which no
photoelectric emission takes place, no matter how large the intensity may
be.
c
0 =

where is the threshold frequency, is thethreshold wavelength, is


the work function and h is the planck's constant.
0

45

DEFINITION

Photoelectric effect

When lightof suitable frequencystrikes upon a metal surface electrons


are emitted from the surface. This phenomenon is called photoelectric
effect.
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46

EXAMPLE

Calculate the de broglie wavelength of an electron accelerated by a


given potential

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Example: An electron of charge e and mass m is acceleratedfrom rest by a


potential difference V. Find the de-Brogliewavelength.
Solution:
1
2

DOUBTS

mv

= eV

mv = 2eV m

So de-broglie wavelength
h

COMPARE

=
mv

FRIE N D S

LEAD E R B OARD

h
=

2meV

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EXAMPLE

Planck's constant using de-broglie equation


If U.V. light of wavelengths 800 A and 700 A canliberate electrons with
kinetic energies of 1.8eV and 4eV respectively from hydrogen atom in
groundstate, then the value of Planck's constant is found as follows :
From first eqn of photoelectric effect,
0

DISCUSS

ONLI N E COACHING

hc
(

10 ) W = 1.8
8

---------------(I)

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From second equation of photoelectric effect,


8

hc 10

W = 4
7

-----------------(II)

Solving (I) and (II) simultaneously we get,


h = 4.10625 10
eV
15

Converting this h in terms of J s we get,


1915

h = 4.10625 1.6 10
34

h = 6.57 10

J s

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