CHEMISTRY

(a) reduce to half (b) be doubled

(c) remain constant (d) increase four times
Time : 1 Hour M.M. 120 5. During complete combustion of one mole of butane, 2658 kJ of heat
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is released. The thermochemical reaction for above change is
Thermodynamics
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1. Thermodynamics is not concerned about______.
(a) energy changes involved in a chemical reaction.
(b) the extent to which a chemical reaction proceeds.
(c) the rate at which a reaction proceeds.
(d) the feasibility of a chemical reaction. 6. f U of formation of CH4(g) at certain temperature is 393 kJ
2. Which of the following statements is correct? mol1. The value of fHis
(a) The presence of reacting species in a covered beaker is an (a) zero (b) < U
f
example of open system.
(c) > U (d) equal to U
f f
(b) There is an exchange of energy as well as matter between the
7. In an adiabatic process, no transfer of heat takes place between
system and the surroundings in a closed system.
system and surroundings. Choose the correct option for free
(c) The presence of reactants in a closed vessel made up of copper
expansion of an ideal gas under adiabatic condition from the
is an example of a closed system.
following.
(d) The presence of reactants in a thermos flask or any other closed
(a) q = 0, T 0, w = 0 (b) q 0, T = 0, w = 0
insulated vessel is an example of a closed system.
(c) q = 0, T = 0, w = 0 (d) q = 0, T < 0, w 0
3. The state of a gas can be described by quoting the relationship
8. The pressure-volume work for an ideal gas can be calculated by
between___.
vs

(a) pressure, volume, temperature using the expression W pex dV . The work can also be calculated
Vt
(b) temperature, amount, pressure
from the pV plot by using the area under the curve within the
(c) amount, volume, temperature
specified limits. When an ideal gas is compressed
(d) pressure, volume, temperature, amount (a) reversibly or (b) irreversibly from volume Vi to Vf .choose the
4. The volume of gas is reduced to half from its original volume. The correct option.
specific heat will be ______. (a) w (reversible) = w (irreversible)
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 (b) w (reversible) < w (irreversible) (a) is always negative (b) is always positive
(c) w (reversible) > w (irreversible) (c) may be positive or negative (d) is never negative
(d) w (reversible) = w (irreversible) + pex. V
13. Enthalpy of sublimation of a substance is equal to
9. The entropy change can be calculated by using the expression S =
(a) enthalpy of fusion + enthalpy of vapourisation
qrev/T. When water freezes in a glass beaker, choose the correct
statement amongst the following : (b) enthalpy of fusion (c) enthalpy of vapourisation

(a) S (system) decreases but S (surroundings) remains the (d) twice the enthalpy of vapourisation

same. 14. Which of the following is not correct?

(b) S (system) increases but S (surroundings) decreases. (a) G is zero for a reversible reaction

(c) S (system) decreases but S (surroundings) increases. (b) G is positive for a spontaneous reaction

(d) S (system) decreases and S (surroundings) also decreases. (c) G is negative for a spontaneous reaction

10. On the basis of thermochemical equations (a), (b) and (c), find out (d) G is positive for a non-spontaneous reaction

which of the algebric relationships given in options (i) to (iv) is 15. Thermodynamics mainly deals with

correct. (a) interrelation of various forms of energy and their transformation

(a) C(graphite) + O2 (g) from one form to another.

CO2 (g) ; rH = x kJ mol1
(b) energy changes in the processes which depend only on initial and
(b) C(graphite) + 12 O2 (g)
CO (g) ; rH = y kJ mol1
final states of the microscopic systems containing a few molecules.
(c) CO(g) + 12 O2 (g)
CO2 (g) ; rH = z kJ mol1
(c) how and at what rate these energy transformations are carried
(a) z = x + y (b) x = y z
out.
(c) x = y + z (d) y = 2z x
(d) the system in equilibrium state or moving from one equilibrium
11. Consider the reactions given below. On the basis of these reactions
state to another quilibrium state.
find out which of the algebric relations given in options (i) to (iv) is
16. In an exothermic reaction, heat is evolved, and system loses heat to
correct?
the surrounding. For such system
CH4 (g); rH = x kJ mol
(a) C(g) + 4H(g) 1

(a) qp will be negative (b) rH will be negative

(b) C(graphite,s) + 2H2 (g) CH4 (g); rH = y kJ mol1
(c) qp will be positive (d) rH will be positive
(a) x = y (b) x = 2y (c) x > y (d) x < y
17. The spontaneity means, having the potential to proceed without the
12. The enthalpies of elements in their standard states are taken as zero.
assistance of external agency. The processes which occur
The enthalpy of formation of a compound
spontaneously are
(a) flow of heat from colder to warmer body.
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 (b) gas in a container contracting into one corner. 23. The enthalpy of combustion of methane, graphite and dihydrogen at
(c) gas expanding to fill the available volume. 298 K are, -890.3 kJ mol-1 -393.5 kJ mol-1, and -285.8 kJ mol-
1
(d) burning carbon in oxygen to give carbon dioxide. respectively. Enthalpy of formation of CH4(g) will be
18. For an ideal gas, the work of reversible expansion under isothermal (a) -74.8 kJ mol-1 (b) -52.27 kJ mol-1
condition can be calculated by using the expression w = nRT ln Vf/Vi (c) +74.8 kJ mol-1 (d) +52.26 kJ mol-1.
A sample containing 1.0 mol of an ideal gas is expanded isothermally 24. A reaction, A + B ! C + D + q is found to have a positive entropy
and reversibly to ten times of its original volume, in two separate change. The reaction will be
experiments. The expansion is carried out at 300 K and at 600 K (a) possible at high temperature
respectively. Choose the correct option. (b) possible only at low temperature
(a) Work done at 600 K is 20 times the work done at 300 K. (c) not possible at any temperature
(b) Work done at 300 K is twice the work done at 600 K. (d) possible at any temperature
(c) Work done at 600 K is twice the work done at 300 K. 25. In a process, 701 J of heat is absorbed by a system and 394 J of
(d) U = 0 in both cases. work is done by the system. What is the change in internal energy for
19. Choose the correct answer. A thermodynamic state function is a the process?
quantity (a) +701,-394,+307 (c) 594,+325, +701
(a) used to determine heat changes (b) 684,+308, +141 (d) 194,+807, +201
(b) whose value is independent of path 26. The reaction of cyanamide, NH2CN (s), with dioxygen was carried
(c) used to determine pressure volume work out in a bomb calorimeter, and U was found to be -742.7 kJ mol-1 at
(d) whose value depends on temperature only. 298 K. Calculate enthalpy change for the reaction at 298 K.
20. For the process to occur under adiabatic conditions, the correct NH2CN(g) + 3/2 O2(g) ! N2(g) + CO2(g) + H2O(l)
condition is: (i) -851.5 (b) -741.5 (c) -58.5 (d) -718.5
(a) T = 0 (b) p = 0 (c) q = 0 (d) w = 0 27. Calculate the number of kJ of heat necessary to raise the
21. The enthalpies of all elements in their standard states are: temperature of 60.0 g of aluminium from 35C to 55C. Molar heat
(a) unity (b) zero (c) < 0 capacity of Al is 24 J mol-1 K-1.
(d) different for each element (a)2.08 KJ (b)2.03 KJ (c)0.09 KJ (d)1.09 KJ
U0of combustion of methane is X kJ mol . The value of H is
-1
22. 28. Calculate the enthalpy change on freezing of 1.0 mol of water
(a) = U (b) > U (c) < U (d) = 0 at10.0C to ice at -10.0C. fusH = 6.03 kJ mol-1 at 0C.

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 Cp [H2O(l)] = 75.3 J mol-1 K-1
Cp [H2O(s)] = 36.8 J mol-1 K-1
(a) -6.415 KJ (b) -5.145 KJ (c) -7.258 KJ (d) -8.753 KJ
29. Enthalpy of combustion of carbon to CO2 is -393.5 kJ mol-1.
Calculate the heat released upon formation of 35.2 g of CO2 from
carbon and dioxygen gas.
(a) -485 KJ (b) -753 KJ (c) -315 KJ (d) -951 KJ
30. Enthalpies of formation of CO(g), CO2(g), N2O(g) and N2O4(g) are MATHS
-110, 393, 81 and 9.7 kJ mol-1respectively. Find the value of rH
Time : 1 Hour M.M.120
for the reaction: N2O4(g) + 3CO(g) ! N2O(g) + 3CO2(g)
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(a) -576 KJ (b) -778 KJ (c) -856 KJ (d) -475 KJ
Point & Straight line ,Circle, & Binomal
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CHEMISTRY 1. The intercept made by a line on y-axis is double to the intercept
Q. 1 2 3 4 5 6 7 8 9 made by it on x-axis. If it passes through (1, 2) then its equation
10 A. C C D C C B C B -
C C (a) 2x + y = 4 (b) 2x + y + 4 = 0
Q. 11 12 13 14 15 16 17 18 (c) 2x y = 4 (d) 2x y + 4 = 0
19 20 2. Orthocentre of the triangle whose sides are given by 4x 7y +
A. C C A B AB AB CD CD B 10 = 0, x + y 5 = 0 & 7x + 4y 15 = 0 is -
C (a) ( 1, 2) (b) (1, 2) (c) ( 1, 2) (d) (1, 2)
3. If the point (5, 2) bisects the intercept of a line between the
Q. 21 22 23 24 25 26 27 28
axes, then its equation is -
29 30
(a) 5x + 2y = 20 (b) 2x + 5y = 20 (c) 5x 2y = 20 (d) 2x 5y =
A. B C A D A B D A C
20
B 4 Equation of the line passing through the point (1, 1) and
perpendicular to the line 2x 3y = 5 is
(a) 3x + 2y 1 = 0 (b) 2x + 3y +
1=0
(c) 3x + 2y 3 = 0 (d) 3x + 2y +

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