S GIO DC V O TO K THI CHN HC SINH GII LP 12 CP TNH

NG NAI NM HC 2013 2014

MN: HA HC
CHNH THC Thi gian lm bi: 180 pht (khng k thi gian giao )
Ngy thi: 11/10/2013
( thi ny gm 02 trang, c 05 cu)

Cu I: (3,0 im)
1/Vit cu hnh electron ca nguyn t c c im sau:
a/ C in tch ht nhn l 19+
b/ C tng electron cc phn lp s trong nguyn t l 5
c/ C tng electron cc phn lp p trong nguyn t l 15
d/ C 5 electron phn lp 3d
e/ C 3 lp cha electron v c 3 electron c thn trng thi c bn
2/ X, Y l hai phi kim. Trong nguyn t X v Y c s ht mang in nhiu hn s ht khng
mang in ln lt l 14 v 24. Trong phn t XYn th:
- X chim 7,1101% v khi lng.
- Tng s proton l 190
- Tng s ntron l 246
a/ Xc nh s khi v tn nguyn t X, Y
b/ V cng thc cu to ca XYn v cho bit kiu lai ha ca nguyn t trung tm.
Cu II: (6,0 im)
1/Hon thnh cc phng trnh phn ng:
a/ Fe3O4 + (B) (C) + (D) + (E)
b/ (C) + Ba(OH)2 (F)+BaSO4
c/ (D) + KOH (G) + (H)
d/ (C) + KMnO4 + (B) (D) + MnSO4 + (H) + (E)
e/ (F) + O2 + (E) (G)
f/ (D) + KI (C) + (H) + I2
g/ (G) + HNO3 (K) + (E)
h/ (K) + Fe (M)
k/ (M) + (N) (K) + (O)
l/ (N)(O)+NO2+O2
2/ Xt 250C. Cho dung dch HCOOH 0,1M (dung dch X).
a/ Tnh pH ca dung dch X. Bit: HCOOH c Ka=1,77.10-4.
b/ Cho vo dung dch X trn mt lng axit H2SO4 x(M) c cng th tch, thy pH
dung dch gim 0,385 n v so vi pH khi cha cho H2SO4 vo. Tnh x. Bit H2SO4
c hng s axit i vi nc phn li th hai l Ka2=1,20.10-2, gi thit khi pha trn th
tch dung dch mi thu c bng tng th tch cc dung dch ban u.
3/ Ch dng thm mt thuc th, hy nhn bit cc l dung dch mt nhn cha ring bit
cc dung dch sau: Zn(NO3)2, AgNO3, ZnCl2, AlCl3, CH3CHO, C2H5OH. (Lu : khng
dng phng php nhit phn mui, ch cn nu cch lm v hin tng, khng cn ghi
phn ng gii thch).
Cu III: (6,0 im)
1/ T than , vi (cc cht v c v iu kin phn ng c ), hy vit cc phng
[CH2 -CH(CN)]n
trnh iu ch t olon (poliacrilonitrin: ), polibutaien.

Trang 1/2
2/ Hy gii thch: Khi n sn (khoai m) b ng c, ngi ta thng gii c bng nc
ng hoc nc ma (dung dch ng saccaroz)?
3/ Cho cc cht: CO(NH2)2; CH3-CH2-CH2-NH2; CH2=CH-CH2-NH2; p-metylanilin; anilin;
p-nitroanilin. Sp xp cc cht trn theo th t tng dn lc baz. Gii thch ngn gn.
4/ Hn hp X gm mt ankin v hai hidrocacbon l ng ng lin tip nhau (khng cha
ni ba u mch). Chia 2,24 lt hn hp X (ktc) thnh hai phn bng nhau:
- Phn 1: Cho tc dng vi lng d dung dch AgNO3/NH3 thu c 2,4 gam kt ta
v thy th tch hn hp gim 20%.
- Phn 2: em t chy hon ton ri cho sn phm chy vo 5,0 lt dung dch
Ca(OH)2 0,02M, n khi phn ng xy ra hon ton thu c 7,0 gam kt ta.
Tm cng thc phn t cc cht c trong X.
Cu IV: (2,0 im)
Cho 0,08 mol hn hp hai este n chc E, F (u c dng RCOOR, khng c nhm chc
no khc) tc dng vi 150ml dung dch KOH 1M, sn phm thu c gm hai mui hu
c X, Y c khi lng l 12,22 gam (t l phn t lng ca X:Y = 49:73) v mt ancol Z.
Ancol Z khng bn chuyn thnh andehit, gi thit ton b Z chuyn thnh andehit th khi
lng andehit thu c l 2,9 gam. trung ha ht lng KOH d cn dng 200ml dung
dch HCl 0,2M.
a/ Xc nh cng thc phn t ca Z.
b/ Xc nh cng thc phn t, cng thc cu to ca hai este E, F.
Cu V: (3,0 im)
1/ t chy 2,24 gam Fe trong V lt kh clo ( iu kin tiu chun), ri cho ton b lng
cht rn ha tan vo nc ch thu c dung dch X (th tch l 500ml). Cho lng dung
dch X trn tc dng vi lng dung dch AgNO3 d thu c 16,155 gam kt ta. Tm V
v nng mol (mol/l) cht tan trong dung dch X. Xem cc phn ng xy ra hon ton,
b qua s thy phn ca nc.
2/ Cho tan hon ton 4,0 gam hn hp X gm FeS v FeS2 trong 200 ml dung dch HNO3,
ch thu c kh NO (sn phm kh duy nht ca N+5) v dung dch Y (khng cha SO2).
tc dng ht vi cc cht trong dung dch Y, cn 250 ml dung dch Ba(OH)2 0,5M thu
c kt ta. em lng kt ta to thnh ra sch v em nung ngoi khng kh n
khi lng khng i c 16,015 gam cht rn Z.
a/ Tnh phn trm khi lng cc cht trong X
b/ Tnh nng mol (mol/lt) dung dch HNO3 dng.

Cho: H=1; C=12; N=14; O=16; S=32; Cl=35,5; Na=23; Al=27; K=39; Ca=40; Fe=56;
Cu=64; Zn=65; Ag=108; Ba=137
250C, tch s ion ca nc l Kw=1,00.10-14
Th sinh c s dng bng h thng tun hon cc nguyn t ho hc.

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Trang 2/2
S GIO DC V O TO HNG DN CHM THI V BIU IM
NG NAI K THI CHN HC SINH GII LP 12 CP TNH
NM HC 2013 2014
MN: HA HC
Ngy thi: 11/10/2013

Cu I (3,0 im)
1/
1,5 a/ 1s2 2s2 2p6 3s2 3p6 4s1 0,25x6
b/ 1s2 2s2 2p6 3s1
c/ 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p3
d/ 1s2 2s2 2p6 3s2 3p6 3d5 4s1 hoc 1s2 2s2 2p6 3s2 3p6 3d5 4s2
e/ 1s2 2s2 2p6 3s2 3p3
2/
1,5 Z +nZ =190
X Y

e=> N X +nNY =246

(ZX +N X ) 7,1101
=
(ZX +N X )+n(ZY +NY ) 100
Z +N X =31
=> X
n(ZY +NY )=405
ZX =15
Ma t khac: 2ZX -N X =14=>
N X =16 0,25
X laP (photpho)
=>
A X =31 0,25
nZY =175 Z 35
=> => Y =
nNY =230 NY 46
Ma t kha
c: 2ZY -N Y =24
ZY =35

=> NY =46
0,25
n=5
Y laBr (bro
m)
=>
A Y =81
0,25
Phn t PBr5 c cu to lng thp tam gic
Br
Br

Br P
0,25
Br
Br

Trong PBr5, P trng thi lai ha sp3d

0,25
Trang 3/2
Trang 4/2
Cu II (6,0 im)
1/ a/ Fe3O4 + 4H2SO4 FeSO4 + Fe2(SO4)3 + 4H2O 0,25x1
2,5 b/ FeSO4 + Ba(OH)2 Fe(OH)2 + BaSO4 0
c/ Fe2(SO4)3+6KOH2Fe(OH)3+3K2SO4
d/ 10FeSO4 + 2KMnO4 + 8H2SO4 5Fe2(SO4)3 + 2MnSO4 + K2SO4 + 8H2O
e/ 4Fe(OH)2 + O2 + 2H2O4Fe(OH)3
f/ Fe2(SO4)3 + 2KI 2FeSO4 + K2SO4 + I2
g/ Fe(OH)3 + 3HNO3 Fe(NO3)3 + 3H2O
h/ 2Fe(NO3)3+Fe3Fe(NO3)2
k/ Fe(NO3)2+AgNO3Fe(NO3)3 +Ag
l/ AgNO3Ag+NO2+1/2O2
2/ a/
2,0 HCOOH HCOO- +H+ (1)
[ ] (0,1-a) a a
a.a
(1)=> =1,77.10-4
0,1-a 0,25
-3
=>a=4,12.10
=>pH=-lg(4,12.10-3)=2,385
0,25
b/pHs=2,385-0,385=2,00=>[H+]s=10-2M
0,1.1
CHCOOH = =0,05M
2
x.1 0,25
CH2SO4 = =0,5xM
2

HCOOH
HCOO- +H+ (2)
H2SO
4 H++HSO4- (3)
HSO
-
4 H++SO2-
4 (4)

V Ka2>Ka>>Kw=> b qua s in li ca nc, [HCOOH]0,05M (*)

[H+].[HCOO- ] 1,77.10-4.[HCOOH] 0,25
(2)=> =1,77.10-4 =>[HCOO- ]= (**)
[HCOOH] [H+]
[H+].[SO2-
4] -2 - [H+].[SO2-
4]
(4)=> -
=1,20.10 =>[HSO4 ]= -2
(***) 0,25
[HSO4 ] 1,20.10

p dng nh lut bo ton proton cho cc qu trnh (2, 3, 4) 0,25

[H+]=[HCOO- ]+[HSO-4 ]+2[SO42- ] (****)
0,25
[SO4 ]=3,2171.10 M
2- -3

(*)(**)(***)(****)=> - -3
[HSO4 ]=2,6809.10 M 0,25
=>0,5x=[SO2- -
4 ]+[HSO4 ]=>x=1,1796.10
-2

3/ Zn(NO3)2 ZnCl2 AgNO3 AlCl3 CH3CHO C2H5OH 0,25x6

1,5 Cho t Kt ta Kt ta Kt ta Kt ta Khng Khng
Trang 5/2
 t dung keo trng, keo en, tan keo hin hin
dch tan trong trng, trong trng, tng tng
NH3 n NH3 d tan NH3 d khng
d vo trong tan
NH3 d trong
NH3 d
Dung Khng Kt ta
dch hin trng
AgNO3 tng
Dung Kt ta Khng
dch Ag hin
AgNO3 tng
trong
NH3 v
un
nng
nh

Cu III (6,0 im)

1/ CaCO3
0
1000 C CaO+CO2 0,25x8
2,0 0
CaO+3C 2000 C CaC2 +CO

CaC2 +2H2O Ca(OH)2 +C2H2
CH CH+HCN xt
CH2 =CH-CN
0
nCH2 =CH-CN
xt,P,t
[CH2 -CH(CN)]n
2CH CH
NH4Cl,CuCl
t0
CH2 =CH-C CH
CH2 =CH-C CH+H2
Pd
t0
CH2 =CH-CH=CH2
0
nCH2 =CH-CH=CH2
Na,P,t (CH2 -CH=CH-CH2 )n

2/ Khi n sn (khoai m) b ng c l do n phi HCN c trong sn. gii c

1,0 ngi ta dng cht chuyn ha HCN thnh cht khng c. Do , ngi ta
c th s dng nc ng (nc ma) gii c. 0,25
Khi ung nc ng vo, saccaroz b thy phn ( d dy) cho glucoz.
C12H22O11 + H2O C6H12O6 (glucoz) + C6H12O6 (fructoz) 0,25
Glucoz s phn ng vi HCN
HOCH2[CHOH]4CH=O+HCNHOCH2[CHOH]4CH(OH)CN 0,25
Trong mi trng axit ca d dy, HOCH2[CHOH]5CN b thy phn sinh ra
cht khng c
HOCH2[CHOH]5CN+2H2O HOCH2[CHOH]5COONH4 0,25
3/ (A) CO(NH2)2 <(B) p-O2NC6H4-NH2 < (C)C6H5-NH2 < (D) p-CH3-C6H4-NH2 0,5
1,0 < (E) CH2=CH-CH2-NH2 < (F) CH3-CH2-CH2-NH2
- Mnh nht l (F) do c gc ankyl y e (+I)
- Yu nht l (A) do c nhm C=O ht e mnh (-I) ng thi c hiu ng lin
hp p- gia CO vi cp e ca N (-C) lm gim mnh mt e ca nguyn
t N.

Trang 6/2
 - Gc ankenyl ht e yu hn so vi vng benzen nn (E) > (B), (C), (D)
- Nhm NO2 ht e gp thm phn lm gim mt e ca N cn nhm CH3 y
e lm hn ch s gim mt e ca N nn (B) < (C) < (D) 0,5
4/ Goi CT cua ankin laCnH2n-2 (2a mol)
2,0 trong 2,24 lt ho
n hp
CT cua 2 hidrocacbon co n lai laCxHy (2b mol)
2,24
e
=>2a+2b= =0,1mol (*)
22,4
CnH2n-2 +xAgNO3+xNH
3 CnH2n-2-xAgx +xNH4NO3(1)
a a 0,25

0,1
a= .20%=0,01mol (**)
(1)=> 2
a(14n-2+107x)=2,4
a=0,01

=> b=0,04
14n+107x=242

x 1 2
n 9,6 2
4
Chn x=n=2=> ankin l C2H2 0,25
C2H2
+O2
2CO2(2)
0,01 0,02
CxH
y xCO2(3)
0,04 0,04x
(3)(4)=>nCO2 =0,02+0,04x 0,25
nCa(OH)2 =5.0,02=0,1mol

e
=> 7
nCaCO3 = 0,07mol
100
*TH1: Ca(OH)2 d
CO2 +Ca(OH)
2 CaCO3+H2O(4)
0,07 0,07
(4)=>0,02+0,04x=0,07=>x=1,25<2 0,25
Vay mot trong hai hidrocacbon co
n lai laCH4
=>hidrocacbon o
ng a
ng lie
n tie
p laC2H6 0,25

*TH2: Ca(OH)2 pha

n
ng v
i CO2 tao hai muo
i
CO2 +Ca(OH)
2 CaCO3 +H2O(5)
0,07 0,07 0,07

Trang 7/2
 2CO2 + Ca(OH)
2 Ca(HCO3)2(6) 0,25
0,06 (0,1-0,07)
(5)(6)=>0,02+0,04x=0,07+0,06=>x=2,75

=>S cacbon ca hai hidrocacbon cn li l 2 v 3. 0,25

Vi hidrocacbon c 2C (khng c ni ba u mch) ch c hai trng hp 0,25
+ Cht ny l C2H6 (ankan)=> ng ng cn li l C3H8
+ Cht ny l C2H4 (anken)=>ng ng cn li l C3H6 (anken)

Cu IV (2,0 im)
nKOH=0,15.1=0,15 mol
nKOH d=nHCl=0,2.0,2=0,04 mol
=>nKOH xph= 0,15-0,04=0,11 mol
n 0,11
=>1< KOH(xph) = <2
nhh este 0,08

=> trong hn hp 2 este n chc c mt este phn ng vi KOH theo t l mol

1:2 v este ny c dng R-COO-Ar (Ar l gc c cha vng thm v nhm R-
COO- lin kt trc tip vi C ca vng thm )
Phn ng x phng ha hn hp hai este ch cho hai mui m trong c mui 0,25
Ar-OK=> gc hidrocacbon ca axit c trong hai este phi ging nhau
Gi E l R-COO-Ar (a mol) v F l R-COO-R (b mol)
R-COO-Ar + 2KOH R-COOK + Ar-OK (1)
a 2a a a
R-COO-R + KOH R-COOK + R-OH (2)
B b b b

a+b=0,08

2a+b=0,11

1 2 => (a+b)(R+83)+a(Ar+55)=12,22
R+83 49 Ar+55 49
= hay =
Ar+55 73 R+83 73
Ar 77
a=0,03
b=0,05
Ar: C7H7
=> =>
Ar=91 R:CH3 0,25
R=15

R"OH R'CHO(3)
a a
2,9
(3)=>R'+29= =58=>R'=29
0,05

=> R l C2H5
=>Andehit l CH3CH2CHO=> Ancol Z c CTPT: C3H6O (CH3CH=CHOH) 0,25

Trang 8/2
CTPT ca E: C5H8O2
CTPT ca F: C9H10O2 0,25
CTCT ca E:
CH3 COO CH3 CH3 COO H
C C C C 0,5
H H H CH3

CTCT ca F:
CH3 CH3 0,5
CH3 COO CH3 CH3 COO CH3 COO

Trang 9/2
Cu V (3,0 im)
1/ 2,24
nFe = =0,04mol
1,5 56
a=nCl2 em phan
ng
Goi
b=nAg
Fe Fe3+ + 3e (1)
0,04mol 0,12mol 2 phn
ng
Cl + 1e Cl - (2) ng
2amol 2amol 2amol cho
Ag+ + 1e Ag (3) 0,25
(0,25x2
bmol bmol
)
Ag +
+ Cl
-
AgCl (4)
2amol 2amol
(1,2,3)=>2a+b=0,12
(3,4)=>108b+143,5.2a=16,155
a=0,045
=>
b=0,03
=>V=0,045.22,4=1,008

Ag+ + Fe2+ Ag + Fe3+(5) 0,25
0,03mol 0,03mol
0,25
(5)=>nFeCl2 /X =nFe2+ =0,03mol
lbt Fe: nFeCl3 /X =nFe3+/X =nFe -nFe2+ /X =0,04-0,03=0,01mol
0,03
CM(FeCl2 /X) = =0,06M
0,5
=>
0,01
CM(FeCl3 /X) = =0,02M 0,25
0,5

0,25

Trang 10/2
2/ a=nFeS 2
1,5 trong 4,0 gam X=>88a+120b=4,0(g) (*) phng
b=nFeS2
trnh
x=nNO ng
y=nH+ trong Y cho
0,25

FeS+4H2O Fe3++SO2-4 +8H++9e (1)
(0,25x3
a a a 8a 9a )

FeS2 +8H2O Fe +2SO +16H++15e
3+ 2-
4 (2)
b b 2b 16b 15b

4H++NO3- +3e NO+2H2O (3)
4x 3x x

H++OH
-
H2O (4)
y y
Fe 3+
+ 3OH
-
Fe(OH)3 (5)
(a+b) 3(a+b) (a+b)
SO 2-
4 + Ba 2+
BaSO4 (6)
(a+2b) (a+2b) (a+2b)
0
2Fe(OH)3 t
Fe2O3 (7)
(a+b) 0,5(a+b)
(5,6)=>0,5(a+b).160+(a+2b).233=16,015 (g) (**)

0,025.88.100%
%mFeS = =55,0%
a=0,025 4
(*)(**)=> =>

b=0,015 %m =0,015.120.100% =45,0%
FeS2
4
0,25
nBa(OH)2 =0,25.0,5=0,125 mol
(6)=>nBa2+p =a+2b=0,055<nBa(OH)2 =>Ba2+ d=>OH- he
t
(4)(5)=>y+3(a+b)=nOH- =2nBa(OH)2 =0,25=>y=0,13

(1)(2)(3)=>3x=9a+15b=>x=0,15
(1)(2)(3)=>nHNO3b =4x+y-8a-16b=0,29 0,25
0,29
=>CM(HNO3 ) = =1,45M
0,2

0,25

Lu :
*Th sinh lm cch khc ng cho im ti a phn bi tng ng

Trang 11/2
*Chm theo thang im 20,0
*Sau khi chm xong chia i im s ghi vo bi
*Cch lm trn im cui cng:
0,1250,25
0,3750,5
0,61250,75
0,8751,0

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