S GD&T NG NAI K THI HC SINH GII CP TNH

NM HC 2014 2015
CHNH THC MN THI: HA HC 12
BNG B
Thi gian lm bi 180 pht (khng k thi gian giao )
Ngy thi: 06/02/2014

S th t S phch
H tn v ch k gim th (do gim th ghi) (do Ch tch hi ng
chm ghi)
Gim th 1 Gim th 2

Th sinh ghi y thng tin vo cc mc di y

1.Tnh/TP: ......

2. Hi ng thi: ......

3.Phng thi: ......

4.H v tn th sinh: ....

5.Hc sinh trng: ...

6.Ngy sinh: //

7.S bo danh: ....

8.Ch k th sinh: ....

HNG DN:

1. thi gm 14 trang, trong c 30 cu trc nghim v 05 cu t lun, th sinh kim tra s trang v
thi trc khi lm bi.
2. Th sinh lm bi trc tip vo thi (dng bt ch en t en p n cu trc nghim tng ng vo
phiu tr li trc nghim phn trc nghim, ghi cu tr li phn t lun vo phn trng di cu hi,
nu khng ch th ghi vo phn cui sau phn tr li ca cu V). Khng c vo lm bi vo trang
1 v 2 v y l phch s ct mt.
3. Th sinh gi gn cn thn bi lm. Khng ghi tn v lm k hiu ring t trang th 3 tr i.
4. Nu th sinh lm bi sai, dng thc gch, khng dng bt ty (mu trng). Th sinh ch c dng
bt mt mu xanh hoc en hay tm lm bi t lun. Khng dng mc mu .
5. Gim th khng gii thch g thm.
6. Th sinh c s dng bng h thng tun hon cc nguyn t ha hc.
7. Cho nguyn t khi ca nguyn t (u): H=1; C=12; N=14; O=16; S=32; Cl=35,5; Na=23; Al=27;
K=39; Ca=40; Fe=56; Cu=64; Zn=65; Ag=108; Ba=137

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Trang 2
 S GD&T NG NAI K THI HC SINH GII CP TNH
NM HC 2014 2015
CHNH THC MN THI: HA HC 12
BNG B
Thi gian lm bi 180 pht (khng k thi gian giao )
Ngy thi: 06/02/2014

S th t S phch
im bi thi H tn v ch k gim kho (do gim th ghi) (do Ch tch hi
ng chm ghi)
im bng s im bng ch Gim kho 1 Gim kho 2

I.TRC NGHIM:
Cu 1: Cho cc pht biu sau:
(I) Fructoz v glucoz u c kh nng lm mt mu nc brm
(II) Lng d dung dch saccaroz v fructoz u ha tan c Cu(OH)2 to dung dch mu xanh
thm (xanh lam) nhit thng
(III) Tinh bt l mt loi polime thin nhin
(IV) Xenluloz v glucoz u thuc loi hp cht cacbohidrat.
Pht biu ng l
A. (I) v (III). B. (I), (II) v (IV). C. (II), (III) v (IV). D. (I), (III) v (IV).
Cu 2: H2SO4 c, nng, d c th phn ng ti a vi bao nhiu cht trong cc cht rn: FeO, Fe(OH) 2,
FeCl2, FeCl3, Fe3O4, FeS, CuO, Cu, NaNO3, FeSO4?
A. 10 B. 9 C. 6 D. 8
Cu 3: i n phn (vi i n cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau m t thi gian thu
c dung dch Y vn cn mu xanh, c khi lng gim 8,0 gam so vi dung dch ban u. Cho 16,8
gam b t Fe vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l
A. 2,25 B. 1,25 C. 3,25 D. 1,5
Cu 4: Hn hp X cha Na, Ba (ng mol). Cho m gam hn hp X tan ht trong H 2O, thu c dung
dch Y v 6,72 lt kh H2 (iu kin tiu chun). Cho vo dung dch Y mt lng dung dch cha 0,2 mol
HNO3; 0,02 mol AlCl3 v 0,05 mol Al2(SO4)3 thu c m gam kt ta. Bit cc phn ng hon ton. Gi
tr ca m l
A. 52,30 B. 37,58 C. 58,22 D. 41,19
Cu 5: Cho cc cn bng sau
(I) 2HI(k) H2(k) + I2(k) (II) CaCO3(r) CaO(r) + CO2(k)
(III) FeO(r) + H2(k) Fe(r) + H2O(k) (IV) 2SO3(k) 2SO2(k) + O2(k)
S cn bng khng b chuyn dch cn bng khi thay i p sut ca h l
A. 1 B. 2 C. 3 D. 4
Cu 6: Cho:
(I) Dung dch KMnO4 trong mi trng H2SO4
(II) Dung dch K2Cr2O7 trong mi trng H2SO4
(III) Nc brom
(IV) Kh clo
(V) Dung dch hidrosunfua
Dung dch FeSO4 phn ng c vi
A. ch c (I), (II) B. ch c (I), (II), (III)
C. ch c (I), (II), (III), (IV) D. ch c (I), (II), (III), (V)
Cu 7: C ti a bao nhiu anken th kh (s C<5) khi hp nc (H +,t0) ch thu c mt ancol duy
nht?
Trang 3
 A. 4 B. 3 C. 5 D. 2
Cu 8: Cho hn hp X gm H 2, buta-1,3-ien, axetilen, propenal, anehit oxalic, trong hp cht hu
c chim 50% v s mol. Cho 0,3 mol hn hp X qua bt Ni, nung nng, sau mt thi gian thu c
hn hp Y. Bit t khi ca Y so vi X bng 1,2. Y phn ng hon ton vi lng d nc brm. S mol
brom phn ng vi Y l
A. 1,20 B. 1,00 C. 0,25 D. 0,50
Cu 9: Ho tan va ht MO trong dung dch H 2SO4 9,8% th thu c dung dch cha mui MSO 4 (duy
nht) c nng 14,18%. Vy cng thc ca MO l
A. CuO B. MgO C. ZnO D. FeO
Cu 10: Cho cc pht biu sau:
(I) T visco, t xenluloz axetat u thuc loi t tng hp.
(II) Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng ngng.
(III) T nilon6,6 c iu ch t hexametyleniamin v axit axetic.
(IV) Si bng, t tm thuc loi polime thin nhin.
(V) T nitron c tng hp t vinyl xianua
S pht biu ng l
A. 2 B. 3 C. 4 D. 5
Cu 11: Cho cc pht biu sau:
(I) Natri isopropylat vo nc thu c dung dch X. Dung dch X c pH>7
(II) Tnh axit tng dn theo th t C2H5OH, H2O, HCOOH, CH3COOH
(III) Oxi ha ancol bc mt bng CuO (to) thu c xeton
(IV) Alanin v phenol u to kt ta trng khi tc dng vi nc brom
(V) Toluen tham gia phn ng th d hn benzen
(VI) Stiren khng lm mt mu dung dch thuc tm ngay c khi un nng nhit cao
S pht biu ng l
A. 4 B. 2 C. 3 D. 5
Cu 12: in phn dung dch cha x mol NaCl v y mol CuSO 4 vi in cc tr, mng ngn xp n
kh nc b in phn c 2 in cc th ngng. Th tch kh anot sinh ra gp 1,5 ln th tch kh
catot cng iu kin nhit v p sut. Hiu sut cc phn ng 100%. Quan h gia x v y l
A. y = 1,5x B. x = 6y C. x = 1,5y D. x = 3y
Cu 13: Cho 0,1 mol -aminoaxit X (X c mch cacbon khng phn nhnh) tc dng va vi dung
dch cha 0,2 mol NaOH. Mt khc, 2,66 gam X tc dng vi HCl (va ) cho 3,39 gam mui. Vy
cng thc ca X l
A. HOOCCH2CH(NH2)COOH B. CH3CH2CH(NH2)COOH
C. HOOC[CH2]3CH(NH2)COOH D. HOOC[CH2]2CH(NH2)COOH
Cu 14: Gi thit trong tinh th cc nguyn t Fe l nhng hnh cu chim 74% th tch tinh th, phn
cn li l cc khe rng. Cho bit nguyn t khi ca Fe l 55,85, khi lng ring ca Fe l 7,87 g/cm 3.
Tnh bn knh gn ng ca Fe (Bit NA=6,02.1023)
A. 1,44.10-8 cm B. 1,22.10-8 cm C. 1,97.10-8 cm D. 1,28.10-8 cm
Cu 15: Cho V lt C5H12 thc hin phn ng tch thu c hn hp X gm cc hidrocacbon mch h:
C5H10, CH4, C3H8, C2H4, C2H6, C3H6,C4H8, H2 v C5H12 cn d. Hn hp X c t khi so vi hidro bng
x. Hiu sut phn ng tch theo x l
x (36 x) x (72 x)
A. .100% B. .100% C. .100% D. .100%
36 x 72 x
Cu 16: X l hn hp 2 este mch h ca cng 1 ancol no, n chc v 2 axit no, n chc ng ng
k tip nhau. t chy hon ton 0,1 mol X cn 6,16 lt O 2 (iu kin tiu chun). un nng 0,1 mol X
vi 50 gam dd NaOH 20% n phn ng hon ton, ri c cn dung dch sau phn ng thu c m gam
cht rn khan. Gi tr ca m l
A. 37,5 B. 7,5 C. 13,5 D. 15,0
Cu 17: Tripeptit M v tetrapeptit Q u c to ra t mt amino axit X phn t c mt nhm NH 2.
Phn trm khi lng ca N trong X l 18,667%. Thy phn khng hon ton m gam hn hp M,Q (t
l mol 1:1) trong mi trng axit thu c 0,945 gam M; 4,62 gam ipeptit v 3,75 gam X. Bit tt c
cc cht trn u mch h. Gi tr ca m l
A. 8,389 gam B. 5,580 gam C. 9,315 gam D. 58,725 gam

Trang 4
Cu 18: Cho V lt hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc
H+) thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H 2SO4 c 1400C thu c 10,65
gam hn hp Y gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Bit kh o iu kin tiu
chun. Cng thc phn t ca 2 olefin v gi tr ca V l
A. C2H4, C3H6, 4,48 lt B. C3H6, C4H8, 4,48 lt
C. C4H8, C5H10, 5,6 lt D. C2H4, C3H6, 5,60 lt
Cu 19: Cho cc pht biu
(I) Axit hu c (X) n chc, no, mch h c cng thc tng qut l CnH2n+1COOH. (X) c
(3n+3) lin kt n trong phn t axit ny
(II) CnH2nO2 (X) l hp cht n chc, mch h th X ch c th l axit hay este
(III) S lin kt pi trong cc cht: benzen, vinylaxetilen, cumen, phenol, phenylamin u bng 3
(IV) Nu t chy hon ton mt este thu c s mol CO 2 v nc bng nhau th este l este n
chc.
(V) nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ngi ta c th dng nc brom
(VI) p-crezol l ng ng ca phenol
S pht biu ng l
A. 4 B. 3 C. 6 D. 5
Cu 20: Hp cht hu c X mch h c cng thc C aHbO. Khi t chy hon ton x mol X thu c y
mol CO2 v z mol H2O. Bit (y z)=3x. Khi hidro ha hon ton 0,1 mol X th th tch H2 (iu kin tiu
chun) cn ti thiu l
A. 8,96 lt B. 2,24lt C. 6,72 lt D. 4,48 lt
Cu 21: Cho cc th nghim sau:
(I) Sc kh HCl d vo dung dch natri aluminat.
(II) Cho dung dch NH3 d vo dung dch AlCl3.
(III) Sc kh H2S vo dung dch CuCl2.
(IV) Cho dung dch Ba(OH)2 d vo dung dch Al2(SO4)3.
(V) Cho Al2S3 vo nc.
(VI) Cho dung dch NH3 d vo dung dch ZnCl2.
(VII) Sc kh SO2 vo nc clo.
(VIII) Cho dung dch Fe(NO3)2 vo dung dch AgNO3.
S trng hp thu c kt ta sau phn ng l
A. 7 B. 6 C. 4 D. 5
Cu 22: Chn pht biu ng
A. Trong cc baz: metylamin, phenylamin, benzylamin th benzylamin c lc baz yu nht
B. H2N-CH2-COOH l hp cht hu c no
C. C7H9N ch c 4 ng phn cu to cha vng benzen
D. Cc peptit u cho phn ng mu biure (tr ipeptit)
Cu 23: Hai kim loi X, Y v cc dung dch mui ca chng c cc phn ng ha hc sau:
X + 2Y3+ X2+ + 2Y2+
Y + X2+ Y2+ + X
Pht biu ng l
A. Kim loi X c tnh kh mnh hn kim loi Y B. Ion Y3+ c tnh oxi ha mnh hn ion X2+
C. Ion Y2+ c tnh oxi ha mnh hn ion X2+ D. Kim loi X kh c ion Y2+
Cu 24: t chy hon ton 10,33 gam hn hp X gm axit acrylic, axit aipic. axit propanoic v ancol
etylic (trong s mol axit acrylic bng s mol axit propanoic) thu c hn hp Y (gm kh v hi).
Dn ton b Y vo dung dch c cha 0,35 mol Ca(OH)2 thu c 27 gam kt ta v nc lc Z. un
nng nc lc Z li thu c kt ta. Nu cho 10,33 gam hn hp X trn tc dng vi 100 ml dung
dch KOH 1,2M, sau phn ng c cn dung dch (ch xy ra s bay hi ca cht lng) th thu c khi
lng cht rn khan thu c l
A. 12,77 B. 13,76 C. 12,21 D. 10,12
Cu 25: Trn 250ml dung dch hn hp gm HCl 0,08M v H 2SO4 0,01M vi 250ml dung dch
Ba(OH)2 aM thu c m gam kt ta v 500ml dung dch c pH = 12. (Xem H 2SO4, Ba(OH)2 u in li
hon ton c hai nc). Gi tr m v a ln lt l
Trang 5
A. 5,8250 v 0,06 B. 5,8250 v 0,60 C. 0,5825 v 0,60 D. 0,5825 v 0,06

Trang 6
Cu 26: Cho dung dch cha ring bit cc cht sau: FeCl 3, NaNO3, K2S, KHCO3, CH3COOK, NaAlO2,
NaHSO4, HNO3, ZnCl2. C bao nhiu dung dch c pH<7?
A. 5 B. 4 C. 3 D. 6
Cu 27: X l mt axit cacboxylic, Y l mt este hai chc, mch h (c to ra khi cho X phn ng vi
ancol n chc Z). Cho 0,2 mol hn hp gm X v Y phn ng hon ton vi dung dch KHCO 3 ly d,
thu c 0,11 mol CO2. Mt khc, t chy hon ton 0,2 mol hn hp trn, thu c 0,69 mol CO 2 v
m gam H2O. Gi tr ca m l
A. 6,21 B. 10,68 C. 8,82 D. 14,35
Cu 28: Trong cc cht sau, cht c nhit si cao nht l
A. HF B. HI C. HBr D. HCl
-18
Cu 29: Cho nguyn t nguyn t X c in tch ht nhn l +4,8.10 C. X l nguyn t
A. s B. p C. d D. f
Cu 30: Phn ln nc trn tri t cha cc nguyn t hidro c nguyn t khi l 1. Nhng nguyn t
ny c xem l hidro nh. Trong nc nng, hu ht nguyn t hidro c s khi l 2. ng v nng ca
hidro c gi l teri (D) v cng thc ca nc nng c th vit l D2O.
Bng so snh mt vi c im ca nc nng (D2O) v nc nh (H2O)
Tnh cht D2O H2O
im ng bng (C) (Nhit ng c) 3,82 0,0
im si (C) (Nhit si) 101,4 100,0
1,105 0,998
Khi lng ring ( 20C, g/ml)
6 2
Nhit c khi lng ring ln nht (C) 11,6 4,0
3
Khi lng ring ca nc (g/cm ) ( im ng 1,011 0,916
bng) 7 7
Nhn xt no sau y ng?
A. ng c t nc nh s chm trong nc nng, nhng ni trn nc nh
B. ng c t nc nng s ni trn nc nng, nhng chm trong nc nh
C. ng c t nc nng s chm trong nc nng, nhng ni trn nc nh
D. ng c t nc nh s ni trn nc nng, nhng chm trong nc nh

PHIU TR LI TRC NGHIM

*Ch c dng bt ch t en p n cn chn ng vi cu hi pha trn

01. ; / = ~ 09. ; / = ~ 17. ; / = ~ 25. ; / = ~

02. ; / = ~ 10. ; / = ~ 18. ; / = ~ 26. ; / = ~

03. ; / = ~ 11. ; / = ~ 19. ; / = ~ 27. ; / = ~

04. ; / = ~ 12. ; / = ~ 20. ; / = ~ 28. ; / = ~

05. ; / = ~ 13. ; / = ~ 21. ; / = ~ 29. ; / = ~

06. ; / = ~ 14. ; / = ~ 22. ; / = ~ 30. ; / = ~

07. ; / = ~ 15. ; / = ~ 23. ; / = ~

08. ; / = ~ 16. ; / = ~ 24. ; / = ~

Trang 7
 II.T LUN: (14,0 im)
Cu I: (3,0 im)
Cu I.1: nhit cao, canxi phn ng c vi kh nit v photpho to hp cht A, B. Cho A, B vo
nc thu c hai kh X, Y.
a/ Vit phng trnh phn ng xy ra, gi tn X, Y.
b/ So snh (c gii thch) tnh tan trong nc, tnh baz v tnh kh ca X, Y.
Cu I.2: Tnh pH dung dch HCN (axit hidrocyanic) 1,0.10-5M.
Bit hng s cn bng ca nc l 1,0.10-14; HCN c hng s axit Ka=6,2.10-10.

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 Cu II: (4,0 im)
Cu II.1: Vit phng trnh phn ng xy ra khi:
a/Cho hn hp natri bromat, natri bromua vo dung dch H2SO4 long
b/Cho toluen vo dung dch KMnO4, H2SO4 un nng
c/Cho kh NO2 vo dung dch thuc tm.
d/Cho kh CO vo dung dch [Ag(NH3)2]OH.
e/ lu dung dch HI trong khng kh.
f/Hn hp Na2O2 v KO2 (t l mol 1:2) tc dng vi CO2
Cu II.2: Hon thnh s phn ng sau: (mi mi tn l mt phn ng khc nhau, ghi r iu kin
nu c)
FeS2 (1)
SO2 (2)
H2SO 4
(3)

FeSO 4
(4) FeCl

3 (5) HCl (6) HNO3 (7) KNO3

(8)

O2 (9)

Fe(OH)3 (10)
FeI 2

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 Cu III: (2,0 im)
Cho 23,3 gam hn hp X gm Zn, Fe lu ngoi khng kh thu c 29,7 gam hn hp Y gm kim
loi v nhiu oxit. Cho V lt dung dch Z (cha HCl 3,0M v HNO3 2,0M) tc dng va lng Y trn
thu c 2,24 lt kh NO (o iu kin tiu chun, sn phm kh duy nht ca N+5) v dung dch T.
Dung dch T khng phn ng c vi dung dch HNO3 long.
a/ Tnh phn trm khi lng mi cht trong hn hp X
b/ C cn dung dch T (xem ch xy ra qu trnh bay hi nc) thu c bao nhiu gam cht rn khan?

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 Cu IV: (3,0 im)
Cu IV.1: Hon thnh s phn ng sau: (mi mi tn l mt phn ng khc nhau, ghi r iu kin
nu c)
Phenol (1) C6H OH (2)
11 C6H
10
(3)
C6H 6 (4) C6H 5 NO2
(5)
C6H5NH3Cl (6) C6H 5NH 2
Cu IV.2: Hn hp X gm 2 este E, F n chc, ng phn mch h.
- Cho 2,58 gam hn hp X tc dng hon ton vi dung dch KOH va thu c dung dch Y. C cn
dung dch Y thu c 2,80 gam mui khan ca hai axit hu c l ng ng lin tip ca nhau. Mt
khc cho lng dung dch Y trn tc dng hon ton vi lng d dung dch AgNO3/NH3 un nng thu
c hn 6,48 gam bc.
- t chy hon ton 1,462 gam hn hp X thu c 1,5232 lt CO2 ( iu kin tiu chun).
Tm cng thc cu to ca E, F

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Cu V: (2,0 im)
t chy hon ton 0,448 lt hn hp X gm hai hidrocacbon mch h (s nguyn t C mi cht b hn
5) cn dng va 8,400 lt khng kh (cha 20% th tch oxi, cn li l nit) thu c 0,400 mol hn
hp kh v hi. Tm cng thc phn t ca cc hidrocacbon trong X. Bit th tch cc kh o iu kin
tiu chun.
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--- HT ---
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S GD&T NG NAI K THI HC SINH GII CP TNH

NM HC 2014 2015
Trang 17
 P N CHNH THC MN THI: HA HC 12
BNG B

I.TRC NGHIM:
Cu hi p n Cu hi p n Cu hi p n Cu hi p n
1 C 9 D 17 A 25 D
2 A 10 A 18 D 26 B
3 B 11 B 19 C 27 C
4 D 12 B 20 A 28 A
5 B 13 A 21 D 29 C
6 C 14 D 22 D 30 B
7 B 15 B 23 B
8 C 16 C 24 A
II.T LUN: (14,0 im)
Cu I: (3,0 im)
Cu I.1: nhit cao, canxi phn ng c vi kh nit v photpho to hp cht A, B. Cho A, B vo nc
thu c hai kh X, Y.
a/ Vit phng trnh phn ng xy ra, gi tn X, Y.
b/ So snh (c gii thch) tnh tan trong nc, tnh baz v tnh kh ca X, Y.
(1,5 im) im
3Ca N t0
Ca N 0,25
2 3 2
t0
3Ca 2P Ca3P2
Ca3N2 6H2O
2 2NH3
3Ca(OH) 0,25
Ca3P2 6H2O 2 2PH3
3Ca(OH)
NH3 amoniac 0,25
PH3 photphin
*NH3 tan trong nc tt hn PH3 do phn t NH3 phn cc hn v c kh nng to lin kt 0,25
hidro vi nc
H H
... H N ... H O ... H N ... H O ...
H H H H
*Tnh baz ca NH3 c tnh baz mnh hn PH3 do lin kt N-H phn cc mnh hn lin kt 0,25
P-H, lm cho nguyn t N trong phn t NH3 giu electron hn, d nhn proton hn v cng
do ion NH4+ bn hn ion PH4+.
*Tnh kh ca PH3 mnh hn so vi NH3 do P l phi kim c m in nh hn N v phn t 0,25
PH3 km bn hn so vi phn t NH3
Cu I.2: Tnh pH dung dch HCN (axit hidrocyanic) 1,0.10-5M.
Bit hng s cn bng ca nc l 1,0.10-14; HCN c hng s axit Ka=6,2.10-10.
(1,5 im) im
Goi x=[H ]
HCN
H++CN- K a =6,2.10-10(1)
x.[CN- ] x.[CN- ]
(1)=> =K a=> =K a
[HCN] CHCN -[CN- ]
C .K 0,25
=>[CN- ]= HCN a
x+K a

Trang 18

H2O H++OH- K w =1,0.10-14(2)
(2)=>x.[OH ] K w
Kw
[OH ] 0,25
x
nh luat ba
o toa n tch: [H+]=[OH- ]+[CN-
n ie
K C .K
x w HCN a 0,25
x x Ka
x3 x2.K a x(K w CHCN .K a ) K w.K a 0
0,25
x3 x2.6,2.1010 x(1014 105.6,2.1010) 6,2.1010.1014 0
x 1,272.107 0,25
pH lg(1,272.107) 6,896 0,25
Cu II: (4,0 im)
Cu II.1: Vit phng trnh phn ng xy ra khi:
a/Cho hn hp natri bromat, natri bromua vo dung dch H2SO4 long
b/Cho toluen vo dung dch KMnO4, H2SO4 un nng
c/Cho kh NO2 vo dung dch thuc tm.
d/Cho kh CO vo dung dch [Ag(NH3)2]OH.
e/ lu dung dch HI trong khng kh.
f/Hn hp Na2O2 v KO2 (t l mol 1:2) tc dng vi CO2
(1,5 im) im
a/ 5NaBr + NaBrO3 + 3H2SO4 3Na2SO4 + 3Br2 + 3H2O 0,25x6
b/ 5C6H5-CH3+6KMnO4+9H2SO4 5C6H5-COOH+3K2SO4+6MnSO4+14H2O
c/ KMnO4 + 5 NO2 + H2O KNO3 + Mn(NO3)2 + 2 HNO3
d/ CO + 2[Ag(NH3)2]OH 2Ag + (NH4)2CO3 + 2NH3
e/ 4HI + O2 2H2O + 2I2
f/ Na2O2 + 2KO2 + 2CO2 Na2CO3 + K2CO3 + 2O2
Cu II.2: Hon thnh s phn ng sau: (mi mi tn l mt phn ng khc nhau, ghi r iu kin nu c)
FeS2 (1)
SO2 (2) H2SO 4
(3)

FeSO 4 (4) FeCl
3 (5) HCl (6) HNO3 (7) KNO3

(8)

O2 (9)

Fe(OH)3 (10)
FeI 2
(1,5 im) im
(1) 4FeS2 +11O2 t0
8SO2+2Fe2O3 0,25x8

(2) SO2 +Cl2 +2H2O H2SO4+2HCl

(3) H2SO4(l) +Fe FeSO4 +H2
(4) 6FeSO4 +3Cl
2 2FeCl3+2Fe2(SO4 )3
t0
(5) 2FeCl3+3H2SO4 ac 6HCl+Fe2(SO4 )3
(6) HCl+AgNO
3 AgCl+HNO3
(7) HNO3+KOH KNO3+H2O
0
(8) 2KNO3 t
2KNO2 +O2

(9) O2 +4Fe(OH)2 +2H2O 4Fe(OH)3
(10) 2Fe(OH)3+6HI 2FeI 2 +I 2 +6H2O
Cu III: (2,0 im)
Cho 23,3 gam hn hp X gm Zn, Fe lu ngoi khng kh thu c 29,7 gam hn hp Y gm kim loi v
nhiu oxit. Cho V lt dung dch Z (cha HCl 3,0M v HNO 3 2,0M) tc dng va lng Y trn thu c 2,24
lt kh NO (o iu kin tiu chun, sn phm kh duy nht ca N+5) v dung dch T. Dung dch T khng phn
ng c vi dung dch HNO3 long.
a/ Tnh phn trm khi lng mi cht trong hn hp X
Trang 19
b/ C cn dung dch T (xem ch xy ra qu trnh bay hi nc) thu c bao nhiu gam cht rn khan?
(2,0 im) im
a nFe
Goi trong 23,3 gam ho
n hp =>56a+65b=23,3(*1)
b nZn

Fe Fe3 3e(1)
a a 3a
2

Zn
Zn 2e(2)
b b b 0,25

O + 2e O2 (3)
x 2x x
4H NO3 3e
NO 2H2O(4)
2,24
0,4 0,1 0,3 0,25
22,4
16x 23,3 29,7
(1,2,3,4) (*2) 0,25
3a 2b 2x 0,9

a 0,3
0,25
(*1,*2) b 0,1
x 0,4

0,3.56
%mFe 23,3 .100% 72,1%
0,25
%m 0,1.65.100% 27,9%
Zn
23,3
O2 2H

H2O(5)
x 2x 0,25
(4,5) nH 2x 0,4 1,2mol
3V 2V 3nHCl 2nHNO3 1,2
0,25
V 0,24
nCl /CR nHCl 0,24.3 0,72mol

nNO3 /CR nHNO3 nNO 0,24.2 0,1 0,38mol
m' 56.nFe3 65.nZn2 35,5.nCl /CR 62.nNO /CR
3
0,25
=56.0,3+65.0,1+35,5.0,72+62.0,38=72,42
Cu IV: (3,0 im)
Cu IV.1: Hon thnh s phn ng sau: (mi mi tn l mt phn ng khc nhau, ghi r iu kin nu
c)
Phenol (1) C6H OH (2)
11 C6H
10
(3)

C6H 6 (4) C6H 5 NO2
(5)
C6H 5NH3Cl (6) C6H 5NH 2
(1,5 im) im

Trang 20
 OH OH
6x0,25
Ni,t0
+ 3H2

OH

xt,t0
+ H2 O

xt,t0
+ 2H2
NO2

0
H2SO4,t
+ HNO3 + H2O

NO2 NH3Cl

+ 3Fe + 7HCl t0 +3 FeCl2 + 2H2O

NH3Cl NH2

+ NaOH + NaCl + H2O

Cu IV.2: Hn hp X gm 2 este E, F n chc, ng phn mch h.

- Cho 2,58 gam hn hp X tc dng hon ton vi dung dch KOH va thu c dung dch Y. C cn
dung dch Y thu c 2,80 gam mui khan ca hai axit hu c l ng ng lin tip ca nhau. Mt
khc cho lng dung dch Y trn tc dng hon ton vi lng d dung dch AgNO3/NH3 un nng thu
c hn 6,48 gam bc.
- t chy hon ton 1,462 gam hn hp X thu c 1,5232 lt CO2 ( iu kin tiu chun).
Tm cng thc cu to ca E, F
(1,5 im) im
Goi CTTQ cu a E, F laCnH2n2kO2(n 3)
a=n25,8gX a(14n 2k 32) 25,8(*1)
O2
CnH2n2kO
2 nCO2(1)
a an
26,88
(1)=>an= 1,2mol(*2)
22,4
32 7,5n
k
2

Chn n=4, k=1=>CTPT ca E, F l C4H6O2 0,25

Goi CTTQ 2 este laR-COO-R' vaRCH2 -COO-R"
CTTB: R-COO-R'
n2,58gX =0,03mol

R-COO-R'+KOH R-COOK+R'OH(2)
0,03 0,03
2,8
(2)=>R+83= =>R=10,33
0,03
=>R<10,33<R+14
0,25
Chon R=1 (H)=>hai muo
i laHCOOK vaCH3COOK

Trang 21
 H-COO-C3H5 x mol
=>X
CH3-COO-CH=CH2 y mol
x+y=0,03
x=0,01
=> 1.x+15y =>
0,25
0,03 =10,333 y=0,02

t0
CH3-COO-CH=CH2 +KOH CH3COOK+CH3-CHO(3)
0,02 0,02
0
H-COO-C3H5+KOH t
H-COOK+C3H5OH(4)
0,01 0,01 0,01
t0
CH3CHO+2AgNO3 +3NH3+H2O CH3COONH 4+2Ag+NH 4NO3(5)
0,02 0,04
t0
H-COOK+2AgNO3+3NH3+H2O NH 4KCO3+2NH 4NO3+2Ag(6) 0,25
0,01 0,02
(3,4,5,6)=>mAg(5,6) =108.(0,04+0,02)=6,48
Ma
t kha
c: mAg (e)>6,48
=>sa
n pha
m pha
n
ng thu
y pha
n pha
i co1 cha
t n
a ta
c dung v
i AgNO3 /NH3 tao Ag.
0,25
=>C3H5OH laancol kho
ng be
n chuye
n tha
nh anhdehit
HO-CH=CH-CH
3 CH3-CH2 -CHO+H2O
t0
CH3-CH2 -CHO+2AgNO3+3NH3 +H2O CH3-CH2 -COONH4 +2Ag+NH4NO3
Vay CT u
ng cu
a H-COO-C3H5 laH-COO-CH=CH-CH3
H-COO-CH=CH-CH3 c ng phn hnh hc
HCOO H HCOO CH3
0,25
C C C C
H CH3 H H

Cu V: (2,0 im)
t chy hon ton 0,448 lt hn hp X gm hai hidrocacbon mch h (s nguyn t C mi cht b hn 5) cn
dng va 8,400 lt khng kh (cha 20% th tch oxi, cn li l nit) thu c 0,400 mol hn hp kh v hi.
Tm cng thc phn t ca cc hidrocacbon trong X. Bit th tch cc kh o iu kin tiu chun.
(2,0 im) im
8,4 nO2 =0,375.1:5=0,075mol
nkk = =0,375mol=>
22,4 nN2 =0,375.4:5=0,3mol
x=nCO2
Goi tao tha
nh
y=nH2O
x+y+0,3=0,4
=>
2.x+1.y=2.0,075(lbt O)
x=0,05
=> 0,25
y=0,05
solien ke
t pi tb=1

Trang 22
 CnH2n CnH2n+2
=>ho
n hp X go
m 2 cha
t hay
CmH2m CmH2m+2-2k (4 k>1)
0,448 0,05 0,25
=>nX
e 0,02mol soC tb= 2,5
22,4 0,02
CnH2n
*TH1: X ch
a
CmH2m
n 2 C2H4
=>X 0,25
m 3 C3H6
=>2 n<2,5<m 4 =>
n 2 C2H4
X
m 4 C4H8 0,25

CH
*TH2:X n 2n+2
CmH2m+2-2k (k>2)
m=2 CnH2n2 a mol
+Neu m<n=>2 m<2,5<n 4=> X
k=2 C2H2 b mol
a b 0,02
0.a 2.b C3H8

1 n 3 X
0,25
0,02 C2H2
n.a 2b 0,05
u n<m=>1 n<2,5<m 4
+Ne
CH4 a mol
*n 1 X
CmH2m 22k (4 k 1) b mol
a b 0,02
0.a k.b

1 m 1 1,5k
0,02
1.a m.b 0,05
k2 CH4
nha
n =>X 0,25
m 4 C4H6
k4
loai
m 7
C2H6 a mol
*n 2 X
CmH2m 22k (4 k 1) b mol
a b 0,02
0.a k.b

1 m 1 1,5k
0,02
2.a m.b 0,05
k2 C2H6
nha
n =>X 0,25
m 3 C3H 4
k4 C2H6
nha
n =>X 0,25
m 4 C4H2
Hc sinh lm cch khc ng vn cho im ti a
Trang 23