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= .
U = potential energy
change
= interatomics force
constant
u = maximum displacement
Gaya pada pegas:
F=-.u=- ;F=m.a
2 2
Maka . + 2 = 0 atau + =0
2
Solusi persamaan: =
Substitusikan u(t) sehingga diperoleh
2 = , = Natural frequency
The displacement occurs only in small
region.
Elastic properties are described
considering a crystal as a homogenaous
continuum, rather than a periodic array of
atoms
Applied forcess described in terms of stress
Displacement described in terms of strain
Elastic constant C relates stress and strain
so that = C.
Stress has meaning of local applied pressure
Applied force F(Fx, Fy, Fz) Stress component ij (i, j = 1, 2, 3 x, y, z)
Similar to stress, we introduce
displacement vector u = uxx + uyy +uzz
Hookes law:
For cubic crystal, due to symmetry, there are existed only 3 constants:
C11 = C22 = C33; C12 = C21 = C13 = C31 = C23 = C32; C44 = C55 = C66
2
2 = (2 +1 1 )
Assume the wave: , = (+)
Substitute to find
2 = ( + 2)
=
2 2 2 cos
4
2 = ( )
2
2
= 0
2
4
0 =
< < <<
2 2 2
From Heisenberg Uncertainty principle we
can only measure position or speed at a
time.
We can not distinguish u(k) and u(k+2)
Phase velocity:
= /
Group velocity:
= =
2
At small k, sin =
2 2
So that = = =
2
1 2 = 2 +1 1
2 + 1
2 = 2+1 +2
2
And
= 1 (+) , + 1 = 2 ((+1)+)
In matric form
<<
2 2
Acoustic branch:
1 1 1 1 2 2
2 = + + 4
1 2 1 2 1 2
If k=0, 0=0, A1=A2
Optical branch:
1 1 1 1 2 2
2 = + + 4
1 2 1 2 12
1 1
If k=0, 0 = 2 + , m1A1+m2A2=0
1 2
Acoustics vibration have lower energy,
and thus lower frequencies than optical
vibration.
Optical vibration frequencies are infrared
optical branch.
At boundaries, the wave becomes
standing waves in mono-atomic (k=0).