Bi tp hu c hay v kh

Cu 1 : Este A to bi 2 axitcacboxylic X Y u mch h khng phn nhnh

v ancol Z. X phng ha hon ton a gam A bng 140ml dd NaOH tM cn
dng 80ml dd HCl 0,25 M trung ha va lng NaOH d thu c dd
B. C cn B th thu c b gam mui khan N. Nung N trong NaOH khan d
c thm CaO thu c cht rn N v hn hp kh K gm 2 RH v c t khi
vi oxi l 0,625. Dn K li qua nc brom thy c 5,376 lt 1 kh thot ra ,
cho ton b R vi axit H2SO4 long d thy c 8,064 l kh CO2 sinh ra ,
bit rng t chy hon ton 2,76 gam Z cn dng 2,352 l oxi sinh ra
nc , CO2 c t l khi lng l 6:11. Gi tr a gn nht vi :

A 26 B 27. C 28. D 29

Cu 2 : Hn hp P gm ancol A v axitcacboxylic B ( u no, n chc ,

mch h ) v este C c to ra t A v B . t chy hon ton m gam P cn
va 0,18 mol O2 , sinh ra 0,14 mol CO2 . Cho m gam P trn vo 500ml
dd NaOH 0,1M un nng , sau khi kt thc cc phn ng th thu c dd Q .
C cn dd Q thi cn li 3,68 gam cht rn trn ri nung nng trong bnh kn (
chn khng ) , sau khi phn ng xy ra hoang ton th thu c a gam kh .

A 0,85 B 1,25 C 1,45 D 1,05

Cu 3 : Hn hp X gm glixerol ( C3H8O3) , CH3OH, C2H5OH, C3H7OH

v H2O . Cho X tc dng vi Na d thu c 3,36 lt kh H2 (ktc) . t
chy hon ton m gam X thu c 11,34 gam H2O . Bit trong X chim
25% v s mol , gi tr m gn nht vi

A 10 B 11 C 12 D 13

Cu 4 : un nng 0,045 mol hn hp A cha 2 peptit X,Y ( c s lin kt

peptit hn km nhau 1 lin kt ) cn va 120ml KOH 1M, thu c hn
hp Z cha 3 mui ca Gly , Ala , Val trong mui ca Gly chim
33,832% v khi lng . Mt khc t chy hon ton 13,68 gam A cn
dng 14,364 lt O2( ktc) thu c hn hp kh v hi trong tng khi
lng ca CO2 v H2O l 31,68 gam . Phn trm khi lng mui ca Ala

A 45% B 50% C 55% D 60%

Cu 5 : Hn hp kh X gm 0,5 mol H2 v 0,3 mol buta 1,3 ddien. Nung
X mt thi gian vi xc tc Ni thu c hn hp Y c t khi so vi H2
bng 21,5. Dn hn hp Y qua dd brom d , sau khi phn ng xy ra hon
ton th khi lng brom tham gia phn ng l

A 8g B 16g C 32g D 24g

Cu 6 : X l hn hp cha 3 ancol v m gam X c s mol l 0,34 mol. Cho

Na d vo m gam X th thy thot ra 13,44 lt kh H2 thot ra ktc . Mt
khc, t chy m gam X th thu c 52,8 gam CO2. Bit cc phn ng xy
ra hon ton . Gi tr ca m l

A 36,68 B 34,72 C 38,72 D 32,68

Cu 7 : Tripeptit X v tetrapeptit Y u mch h. Khi thy phn hon ton

hn hp X v Y ch to ra c 1 aminoaxit duy nht H2NCnH2nCOOH.
t chy 0,01 mol X trong oxi d cho sn phm chy vo dd Ba(OH)2 d
thu
c m gam kt ta . t chy 0,05 mol Y trong oxi d th thu c N2 v
36,3 gam hn hp CO2 v H2O. Bit cc phn ng u xy ra hon ton.
Gi

A 17,73 g B 23,61 C 11,84 D 29,52

Cu 8 : Chia 14,2 gam hn hp X gm hai andehit n chc thnh 2 phn

bng nhau . t hon ton phn 1 thu c 15,4 gam CO2 v 4,5 gam H2O.
Cho phn 2 tc dng vi lng d AgNO3 trong NH3 thu c 43,2 gam
bc . Tng s nguyn t trong cc phn t ca X l

A 11 B 12 C 13 D 14

Cu 9 : Cho hn hp X gm 1 este n chc v 1 ancol bn, u mch h v

c cng s nguyn t cacbon. t chy hon m gam X th thu c 10,08 lit
CO2 (ktc) v 7,2 gam H2O. Mt khc cho m gam X tc dng vi NaOH d
thu c 0,1 mol ancol. Gi tr ca m l

A 9,4 B 9,7 C 9,0 D 8,5

Cu 10 : Cho X v Y l 2 axitcacboxylic n chc, no, mch h ( MX

<MY); T l este hai chc to bi X,Y v mt ancol no mch h Z. t chy
hon ton 8,85 gam hn hp E gm X,Y,T bng mt lng va O2 , thu
c 7,168 lit CO2 v 5,22 gam nc . Mt khc , 8,85 gam E tc dng vi
dd AgNO3/NH3 d thu c 17,28 gam Ag. Khi lng cht rn thu c
khi cho cng lng E trn tc dng vi 150ml dd NaOH 1M l

A 12,08 B 11,04 C 13,08 D 9,06

Cu 11: t chy hon ton 29,16 gam hn hp X gm RCOOH,

C2H3COOH v (COOH)2 thu c m gam nc v 21,952 lit CO2 (ktc).
Mt khc 29,16 gam hn hp X tc dng hon ton vi NaHCO3 d thu
c 11,2 lit kh CO2 (ktc). Gi tr ca m l

A 10,08 B 9,0 C 12,6 D 8,1

Cu 12: Hn hp X cha 4 hidrocacbon u th kh c s nguyn t

cacbon lp thnh mt cp s cng v c cng s nguyn t hidro. Nung
nng 6,72 lit hn hp E cha x v H2 c mt Ni lm xc tc thu c hn
hp F c t khi so vi He l 9,5. Dn ton b F qua bnh ng dd brom thy
khi lng brom phn ng l a mol; ng thi khi lng bnh tng ln l
3,68 gam. Kh thot ra khi bnh (hh kh T) c th tch l 1,792 lit ch cha
cc hidrocacbon. t chy ton b T th thu c 4,32 gam nc. Cc kh
iu o ktc. Gi tr ca a l

A 0,12 mol B 0,14 mol C 0,13 mol D 0,16 mol

Cu 13 :Hn hp A gm mt axit n chc ,mt ancol n chc v 1 este

n chc (cc cht trongA u c nhiu hn 1C trong phn t).t chy
hon ton m (g) A ri hp th sn phm chy vo bnh dng dd Ca(OH)2 d
thy c 135g kt ta xut hin .ng thi khi lng dd gim 58.5 g.Bit s
mol ancol trong m (g) A l 0,15.Cho Na d vo m (g)A thy c 2,8 lt kh
(ktc) thot ra. Mt khc m(g) A tc dng va dd cha 12g NaOH.Cho m

(g) A vo dd nc brom d.Hi s mol Brom phn ng ti a l :

A 0,4 B 0,6 C 0,75 D 0,7

Cu 14: Hn hp A gm mt axit no,h,n chc v hai axit khng

no,h,n chc(gc hirocacbon cha 1 lien kt i),k tip nhau trong dy

ng ng .Cho A tc dng hon ton vi 150ml dd NaOH 0,2 M. trung

ha va ht lng NaOH d cn them vo 100ml dd HCL 1M c dd D.C

cn cn thn D thu c 22.89g cht rn khan.Mt khc t chy hon ton

A ri cho ton b sn phm chy hp th ht vo bnh ng lng d dd

NaOH c,khi lng bnh tng them 26,27 g. Phn trm khi lng ca

axit khng no c phn t nh hn trong hn hp A l

A 35,52% B 40,82% C 44,24% D 22,78%

Cu 15: Hn hp X cha 0.08 mol axetandehit; 0.09mol vinylaxetylen v

0.016mol hiro.Nung X vi xc tc Ni sau mt thi gian th thu c hh Y

c t khi so vi hiro l 21,13.Dn Y i qua dd AgNO3 / NH3 d phn

ng xy ra hon ton th thu c m (g)Z gm 4 kt ta c s mol bng

nhau,hn hp kh thot Sau phn ng lm mt mu va ht 30ml dd brom

0,1M.Ga tr ca m gn gi tr no nht sau y

A 27 B 29 C 26 D 25

Cu 16: Hn hp X gm 3 peptit A,B,C u mch h tng khi lng l m

v c t l s mol l nA : nB : nC = 2:3:5 .Thy phn hon ton X thu c

60g glyxin ; 80,1g Alanin; 117g Valin.Bit s lien kt peptit trong C,B,A

theo th t to nn 1 cp s cng c tng bng 6.Ga tr ca m l :

A 226,5 B 262,5 C 256,2 D 252,2

Cu 17: Thy phn hon ton m g hn hp 2 este n chc mch h

A,B(MA<MB) trong 700ml dd KOH 1M thu c dd x v hn hp Y gm 2

ancol l ng ng lien tip .Thc hin tch nc Y trong H2SO4 c

1400C

thu c hn hp Z .Trong z tng khi lng ca cc este l 0,84g(hiu sut

este ca cc ancol u l 60%).C cn dd X c 54.4 g cht rn,Nung cht

rn ny vi CaO cho n khi phn ng xy ra hon ton,thu c 6,72 lt

hn hp kh T(ktc).Phn trm khi lng ca A trong hn hp ban u l :

A 66,89% B 48,96% C 49,68% D 68,94%

Cu 18: Cho hh A cha hai peptit X,Y u c to bi glyxin v

alanin.Bit rng tng s nguyn t O trong A l 13.Trong X hoc Y u c

s lien kt peptit ln hn 4.un nng 0,7 mol A trong KOH th thy 3,9 mol

KOH phn ng v thu c m (g) mui .Mt khc t chy hon ton

66,075g A ri cho sn phm hp th hon ton vo bnh cha Ca(OH)2

d.Thy khi lng bnh tng 147,285g.Ga tr ca m l

A 560,1 B 470,1 C 520,2 D 490,6

Cu 19: t chy hon ton 0,13 mol hh X gm mt anehit v mt ancol

u h mch cn nhiu hn 0,27mol O2 thu c 0,25mol CO2 V

0,19mol

H2O..Mt khc cho X phn ng hon ton vi dd AgNO3 /NH3 d thu c

m (g) kt ta .Bit rng s nguyn t H trong phn t ancol nh hn 8 .Ga

A 40,02 B 58,68 C 48,48 D 52,42

Cu 20: Hn hp X gm mt anehit no n chc mch h v mt anehit

khng no n chc mch h(trong phn t cha mt lien kt i C=C).Khi

cho X qua dd brom d n phn ng hon ton thy c 2,4 g brom phn ng

.t chy hon ton X th thu c 7,7 g CO2 v 2,25 H2O .Nu cho hn

hp X tc dng vi dd AgNO3 d trong NH3 n phn ng hon ton thu

c m (g) cht rn. Ga tr m l :

A 16,2 B 27 C 32,4 D 21,6

Cu 21: Cho X,Y l hai axit cacbonxylicn chc mch h (MX <MY );T l

estehai chc to bi X,Y v ancol no mch h Z.t chy hon ton 6,88g

hh E gm X,Y,T bng mt lng O2 thu c 5,6 lt CO2 (ktc) v 3,24g

nc .Mt khc 6,88 g E tc dng vi dd AgNO3 /NH3 d thu c 12,96 g

Ag.Khi lng rn khan thu c kh cho cng lng E tc dng vi 150ml

A 10,54g B 14,04g C 12,78g D 13,66g

Cu 22: Hn hp X gm metan,propan,etilen,buten c tng s mol l 0,57

mol tng khi lng l m .t chy hon ton m (g)X cn 54,88 lt O2

(ktc).Mt khc cho m (g) X qua dd brom d th thy s mol brom phn ng

l 0,35mol.Ga tr ca m l

A 22,28 B 22,68 C 24,24 D 24,4

Cu 23 : Dng 19,04 lt khng kh (ktc) (O2 chim 20% v N2 chim

80%

th tch) t chy hon ton 3,21g hh A gm hai amoniaxit no,n chc

k tip nhau trong dy ng ng .Hn hp thu c sau phn ng em lm

kh (hh B) ri dn qua nc vi trong d thu 9,5 g kt ta .Nu cho B vo

bnh dd 2 lt ,nhit 1270C th p sut trong bnh lc ny l P (atm).Bit

amoni axit khi chy sinh ra N2 .Ga tr ca P gn nht vi

13 B 14 C 15 D 16

Cu 24: Hn hp X gm mt peptit mch h A,mt peptit mch h B v mt

peptit mch h C(mi peptit c cu to t mt loi aminoaxit,tng s

nhm CO-NH- trong 3 phn t A,B,C l 9 ) vi t l s mol nA :nB

:nC=2;1;3.bit s lien kt peptit trong A,B,C u ln hn 1 .Khi thy phn

hon ton m (g)X thu c 33,75g glyxin, 106,8 g alanin, 263,25 g Valin.

A 349,8 B 348,9 C 384,9 D 394,8

Cu 25: t chy hon ton 26,46g mt hp cht hu c X cha hia kim

loi nhm chc cn 30,576 lt O2 (ktc).Thu c H2O, N2 v 49,28g CO2

.Bit rng trong phn t X ch cha 1 nguyn t N .Mt khc cho KOH d

tc dng vi 26,46g X thu c hh Y cha 2 ancol Z .T l ng ng lin

tip v m (g) mui .Bit rng MZ<MY v khi lng trung bnh ca Y l

A 31,22 B 34,24 C 30,18 D 28,86

Cu 26: Hn hp M gm ancol no,n chc X v axit cacboxylic n chc

Y u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5

mol(s mol ca Y ln hn s mol X ).Nu t chy hon ton M th thu

c26g kh CO2 v 25,2g H2O .Mt khc ,nu un nng M vi H2SO4
c

thc hin phn ng este ha (hiu sut l 75%) th s g este thu c l

A 17,10 B18,24 C 25,65 D 30,40

Cu 27: t chy hon ton 38,5 g hh X cha andehitaxetic,propanol

,propan-1,2 iol v etanol(trong s mol ca propanol v propan- 1,2 iol

bng nhau).Ngi ta hp th hon ton sn phm chy vo bnh dng dd

Ca(OH)2 d thy xut hin 170g kt ta trng v khi lng bnh tng m

A 114,4 B 116,2 C 115,3 D 112,6

Cu 28 :t chy hon ton 29,064g hh gm HOC CHO, axit acrylicvinyl

axetat v metyl metacrylat ri cho ton b sn phm chy vo bnh 1 ng

dd H2SO4 c,bnh 3 ng dd Ba(OH)2 d thy khi lng bnh1 tng

13,608g ,bnh 2 xut hin m (g) kt ta .Ga tr ca m l

A 318,549 B 231,672 C 220,64 D 232,46

Cu 29 : t chy hon ton 5,16g hh X gm cc CH3OH, C2H3OH ,

C3H7OH ,C4H7OH bng mt lng kh O2 (va )thu c 12,992 lt hh

kh v hi dktc.Sc ton b lng kh v hi trn vo bnh ng dd

Ca(OH)2 d thy khi lng dd trong bnh gim m (g).Ga tr ca m l

A 7,32 B 6,46 C 7,48 D 6,84

Cu 30: Ba cht hu c X,Y,Z (50<Mx<My<MZ) u c thnh phn nguyn

t C ,H ,O.Hn hp T gm X,Y,Z ,trong n X=4(n Y +n Z).t chy hon

ton m (g) T thu c 13,2 g CO2 .Mt khc ,m (g)T phn ng va vi

0,4 lt dd KHCO3 0,1M.Cho m (g) T phn ng hon ton vi lng d dd

Ag NO3 trong NH3 thu c 56,16g Ag.Phn trm khi lng ca Y trong

A 22,26% B 67,90% C 74,52% D 15,85%

Cu 31:t chy hon ton 24,4 g hh X gm C3H6,C3H8.C4H10

,CH3CHO.CH2=CH-CHO cn va 49,28 lt kh O2 (ktc) .Sau phn ng

thu c 28,8g H2O.Mt khc ly ton b lng X trn sc vo dd AgNO3

/NH3 d thy xut hin m (g) kt ta (cc phn ng xy ra hon ton ).Ga
tr

A 21,6 B 32,4 C 43,2 D 54,0

Cu 32 : Hn hp A gm mt amin n chc ,mt anken,mt ankan.t

chy hon ton 12,95g hh cn V lt O2 (ktc).thu c 19,04 lt CO2 (ktc)

0,56 lt N2 (ktc) v m (g) H2O.Ga tr m l

A 18,81 B 19,89 C 19,53 D 18,45

Cu 33 t chy hon ton 0,2 mol mt amin no ,mch h X bng O2 va

thu c 1,4 mol hh kh v hi c tng khi lng m (g).Ga tr m

A 34,2 B 37,6 C 38,4 D 33,8

Cu 34 .un nng hh gm 1 mol HCOOH, 1 mol CH3 COOH, v 2 mol

C2H3OH t 0C(trong bnh kn dung tch khng i )n trng thi can

bng
th thu c HCOOC2H5 v 0,4 mol CH3COOC2H5 .Nu un nng hn
hp

gm 1 mol HCOOH, 4 mol CH2COOH v a mol C2 H5OH (ktc) nh trn

n trng thi cn bng th thu c 0,8 mol HCOOC2H5 .Ga tr a l

A 12,88 mol B 9,97 mol C 12,32 mol D 6,64 mol

Cu 35;Hn hp X gm glixerol.CH3OH ,C2H5OH, C3H7OH, H2O.Cho m

(g)

X tc dng vi Na d thu c 3,34 lt kh H2 (ktc).t chy hon ton m

(g) X thu c 11,34g H2O .Bit trong X glixerol chim 25%v s mol.Ga

tr ng ca m gn nht vi

A 10 B 11 C 12 D 13

Cu 36:Hn hp X gm nhiu ancol,andehit v axit u h mch ,Cho

NaOH d vo m (g)X thy c 0,2 mol NaOH phn ng.Nu cho Na d vo

m (g) X th thy c 12,32 lt kh H2(ktc) bay ra.Cho m (g) X vo dung dch

g NO3/NH3d thy c 43,2 g kt ta xut hin .Mt khc ,t chy hon

ton m (g) X thu c 57,2 g CO2.Bit cc phn ng xy ra hon ton tng

s mol cc ancol trong X l 0,4 mol ,trong X khng cha HCHO v

HCOOH .Ga tr ng ca m gn nht l

A 40 B 41 C 2 D 43

Cu 37: Hn hp M gm hai peptit mch h X v Y (mi peptit c cu

t l nX:nY=1:3. khi thy phn hon ton m gam M thu c 81gam Gly v
42,72 gam Ala. Gi tr ca m l

A 104,28 B 116,28 C 109,5 D 110,28

- aminoaxit , tng s lin kt peptit trong X v Y l 5) vi

Cu 38: Khi chng ct nha than , ngi ta thu c 1 phn on l hh

cha phenol v anilin ha tan trong ankylbenzen (gi l dd A). sc kh

hidroclorua n d vo 100ml dd A th thu c 1,295 g kt ta. Nh t t

nc brom vo 100 ml dd A v lc k cho ti khi ngng to kt ta trng th

thy ht 300g nc brom 3,2%, bit cc phn ng xy ra hon ton. Nng

mol/l ca phenol trong hh A l

A 0,2 M B 0,1M C 0,6M D 0,3M

Cu 39: Cho mt cht hu c X c cng thc C2H10N2O3. Cho 11g X tc

dng vi c cha 12g NaOH, un nng phn ng xy ra hon ton th

thu c hh Y gm 2 cht kh u c kh nng lm i mu qu tm m v

dd Z. C cn X thu c m gam cht rn khan. Gi tr ca m l

A 24,6 B 10,6 C 14,6 D 28,4

Cu 40: Cho 0,05 mol mt aminoaxit X H2NCnH2n-1(COOH)2 vo 100ml

dd

HCl 1M th thu c dd Y. Cho Y tc dng va vi mt lng dd Z c

cha ng thi dd NaOH 1M v KOH 1M, th thu c mt dd T, c cn T

th thu c 16,3g mui, bit cc phn ng xy ra hon ton. Phn trm v

khi lng cacbon trong hh X l

A 32,65 B 36,09 C 24,49 D 40,81

Cu 41: Cho ankan X c cng thc C7H16, crackinh hon ton X thu c
hh

kh Y ch gm ankan v anken. T khi hi ca Y so vi H2 nm trong

A 10 n 25 B 12,5 n 25 C 25 n 50 D 10 n 12,5

Cu 42: Mt loi kh thin nhin X c thnh phn v phn trm v th tch

nh sau : 85% metan; 10% etan; 2% nit; 3% cacbonddioxxit. Bit rng, khi

t chy 1mol metan v 1mol etan th lng nhit ta ra tng ng l 880 kJ

v 1560 kJ. nng 1ml nc ln thm 1 C cn 4,18J. Th tch kh X

ktc dng un nng 100 lit nc t 20C ln 100C l

A 985,6 lit B 982,6 lit C 828,6 lit D 896 lit

Cu 43: Hn hp X gm mt anehit, mt axitcacboxylic v mt este (trong

axit v este l ng phn ca nhau). t chy hon ton 0,2 mol X cn

0,625 mol oxi, thu c 0,525 mol CO2 v 0,525 mol nc. Tnh phn trm

v khi lng andehit c trong X

A 26,29% B 21,6% C 32,4% D 23,07%

Cu 44: Hn hp X gm ancol A v hai sn phm hp nc ca propen. T

khi hi ca X so vi H2 l 23. Cho m gam X i qua ng s ng CuO d

nung nng. Sau khi cc phn ng xy ra hon ton thu c hn hp Y gm

3 cht hu c v hi nc, khi lng cht rn trong ng s gim 3,2g. Cho

Y tc dung hon ton vi dd AgNO3/NH3 to ra 48,6 gam kim loi Ag. Phn

trm s mol ca ancol bc hai trong X l

A 37,5% B 62,5% C 48,9% D 51,1%

Cu 45: Cho hn hp X gm cht Y (C2H10O3N2) v cht Z (C2H7NO2).

Cho

14,85 gam X phn ng va vi lng dd NaOH n nng thu c dd M

v 5,6 lit (ktc) hh T gm 2 kh u lm xanh qu tm m. C cn dd M thu

c m gam mui khan. Gi tr ca m l

A 12,5 B 11,8 C 10,6 D 14,7

Cu 46: t chy ht 16,4 gam hh M gm 2 axitcacboxylic n chc X,Y v

1 este n chc Z thu c 0,75 mol CO2 v 0,5 mol H2. Mt khc, 24,6
gam

hh M trn tc dng ht vi dd NaOH 10%. Sau khi cc phn ng xy ra ht

thu c N. C cn ton b dd N thu c m gam cht rn khan CH3OH v

146,7 gam nc. Coi nc bay hi khng ng k trong phn ng vi dd

NaOH. Gi tr ca m l

A 31,5 B 33,1 C 36,3 D 29,1

Cu 47: Oligopeptit mch h X c to thnh t cc

CT dng H2NCxHyCOOH. t chy 0,05 mol X cn va 1,875 mol oxi

ch thu c N2 ; 1,5 mol CO2; 1,3 mol H2O. Mt khc, thy phn ht

0,025mol X bng 400ml dd NaOH 1M v un nng thu c dd Y. C cn

ton b Y th thu c m gam cht rn khan. S lin kt peptit trong X v

A 9 v 27,75 C 9 v 33,75

B 10 v 33,75 D 10 v 27,75

Th thut khi thi trc nghim

Cu 48: Hn hp X gm etanol; propan-1-ol; butan-1-ol; pentan-1-ol. Oxi

ha khng hon ton mt lng X bng CuO nung nng, sau mt thi gian

thu c H2O v hh Y gm 4 andehit tng ng v 4 ancol d. t chy ht

Y cn va 1,875 mol oxi thu c 1,35 mol kh CO2 v nc. Mt khc,

cho ton b lng Y trn tc dng ht vi lng d AgNO3/NH3 , un nng.

Sau khi cc phn ng xy ra ht thu c m gam Ag. Gi tr ca m l

A 64,8 B 27 C 32,4 D 43,2

Cu 49: Hn hp T gm 3 cht X, Y, Z (50<MX<MY<MZ v u to t cc

nguyn t C,H,O). t chy ht m gam T th thu c nc v 2,688 lit

(ktc). Cho m gam T phn ng vi dd NaHNO3 d, thu c 1,568 lit kh

CO2 (ktc). Mt khc, cho m gam T phn ng ht vi lng d dd

AgNO3/NH3 thu c 1,8 gam Ag. Gi tr ca m l

A 4,6 B 4,8 C 5,2 D 4,4

Cu 50: X phng ha ht 1 este no, n chc, mch h E bng 26g dd MOH

28% (M l kim loi kim). C cn hh sau phn ng thu c 24,72g cht

lng X v 10,08g cht rn Y. t chy ht Y th thu c sn phm gm CO2;

H2O v 8,97g mui cacbonat khan. Mt khc, cho X tc dng vi Na d, thu

- amino axit u c

c 12,768 lit kh H2 (ktc). Phn trm khi lng mui trong Y c gi tr

A 67,5 B 85 C 80 D 97,5

Cu 51: ung nng 0,16 mol hh E gm 2 peptit X

Cu 52: Ancol X (MX=76) tc dng vi axit cacboxylic Y thu c hp cht

Z mch h (X v Y u ch c 1 laoij nhm chc). t chy ht 17,2 g Z cn

va 14,56 lit O2 (ktc) thu c CO2 v H2O theo t l mol tng ng l

7:4. Mt khc, 17,2 g Z li phn ng va vi 8g NaOH trong dd. Bit Z

c CTPT trng vi CTGN. S CTCT tha mn ca Z l

A1B3C2D4

Cu 53: Mt loi kh gas dng trong sinh hot c hm lng phn trm theo

khi lng nh sau: butan 99,40% cn li l pentan. Nhit nng chy ca

cc cht ln lt l 2654kJ v 3,6.106 J v nng nhit ca 1g nc

(D=1g/ml) ln 10 cn 4,16 J. Khi lng gas cn dng un si 1lit nc

ni trn t 250C n 1000C l

A 5,55 B 6,66 C 6,81 D 5,81

Cu 54: Hn hp A gm 2 ancol ng ng lin tip. t chy ht A thi thu

c 0,5 mol CO2. Mt khc oxi ha A thu c hh B gm cc axit v

andehit tng ng ( bit 60% khi lng ancol bin thnh andehit v phn
cn li bin thnh axit). Cho B vo dd AgNO3/NH3 d thu c m gam Ag.

A38,88 B 60,48 C 51,84 D 64,08

Cu 77: Hn hp X gm ancol metylic , ancol anylic, glixerol, etylenglicol.

Cho m gam hn hp X tc dng vi Na d thu c 10,752 lit H2 (ktc).

t

chy m gam hn hp X trn th cn 37,856 l O2 (ktc) thu c 30,6 gam

nc. Phn trm khi lng ancol anlylic trong hn hp X l

A 28,29% B 29,54% C 30,17% D 24,7%

Cu 78: Hn hp X gm Gly v Ala. Ngi ta ly m gam X tc dng vi

lng va KOH thu c 13,13 gam hn hp mui. Mt khc, cng t

lng X trn iu kin thch hp ngi ta iu ch c hn hp Y th

c m gam hn hp gm nc v peptit. t chy hon ton m gam hn

hp peptit trn cn 7,224 lit O2 (ktc). Gi tr ca m gn nht vi

A 7 B 8 C 9 D 10

Cu 79: Thy phn hon ton m gam hn hp gm 2 peptit X v Y bng dd

NaOH thu c 151,2 g hn hp gm cc mui natri ca Gly, Ala v Val.

Mt khc t chy hon ton m gam hn hp X,Y trn cn 107,52 lit

kh O2 (ktc) v 64,8 gam nc. Gi tr ca m l

A 102,4 B 97 C 92,5 D 107,8

Cu 80: t chy hon ton 5,4 gam hh X gm axit cacboxylic no ,n chc

v mt ancol n chc Y, thu c 0,2 mol CO2 v 0,3 mol H2O. Thc hin

este ha 5,4 g X vi hiu sut 80% thu c m gam este. Gi tr ca m l

A 2,04 B 2,55 C 1,86 D 2,20

Cu 81: Hn hp X gm 1 anken v hai amin ( no, n chc, mch h v

ng ng k tip nhau). t chy hon X cn va 15,12 lit kh O2 (ktc)

thu c H2O, N2 v 7,84 lit kh CO2 (ktc). Tn gi ca amin c phn t

khi ln hn trong hh X l

A etylamin B propylamin C butylamin D

Cho hh X gm CH3-CO-CH3,CH3;CCHCHO3OOH;CHCCCv

32OOHCHCCCHC

CO2 v 18,36 gam H2O. Phn trm khi lng ca CH3-CO-CH3 trong X
l

A 20,803% B 16,643% C 14,562% D 18,723%

Cu 83 : Hn hp X gm C2H2; C3H6; C4H10 v H2. Cho 11,2 lit (ktc)

hh X

qua bnh ng brom d thy c 64 gam brom phn ng. Mt khc t chy

hon ton 11,2 lit (ktc) hh X thu c 55g CO2 v m gam nc. gi tr ca

A 31,5 B 27 C 24,3 D 22,5

Cu 84: Hn hp X gm C2H2; C3H6; C4H10 v H2. Cho 7,64 gam hh X

qua

bnh ng brom d thy c 41,6 gam brom phn ng. Mt khc t chy

hon ton 13,44 lit (ktc) hh X thu c 47,52g CO2 v m gam nc. gi tr
A 21,24 B 21,06 C 20,7 D 20,88

Cu 85:Hn hp A gm C3H6O,C4H6O,C4H4O2 v C5H6O2.t chy

hon

ton 36,5 A cn 45,92 lit kh O2(ktc).Hp th hon ton sn phm chy qua

bnh ng dd Ba(OH)2 d thy KL dd trong bnh gim 262,35 g .Khi

lng ca C3H6O trong 36.5 g A l:

A.3,48g B.2,09g C.4,35g D.4,64g

. t chy 27,88 gam hh X thu c 64,24 gam

Cu 86:Hn hp A gm 1 axit no, h,n chc v 2 axit ko no,h,n

chc(gc hiddrocacbon cha 1 lin kt i),k tip nhau trong dy ng

ng.Cho A tc dng hon ton vi 150 ml dd NaOH 2M. trung ha va

ht lng NaOH d cn thm vo 100 ml dd HCl 1 M c dd D.C cn cn

thn dd D thu c 22,89 g cht rn khan.Mt khc t chy hon ton A ri

cho ton b sn phm chy hp th ht vo bnh ng lng d dd NaOH

c,khi lng bnh tng thm 26,72 g.Phn trm khi lng ca axit khng

no c khi lng phn t nh hn trong hn hp A l:

A.35,52% B.40,82% C.44,24% D.22,78%

Cu 87:Chia 0,6 mol hn hp gm 1 axit n chc v 1 ancol n chc

thnh 2 phn bng nhau.
Phn 1 t chy hon ton ,thu c 39.6g CO2
Phn 2 un nng vi H2SO4 c,thu c 10,2g este E(H=100%).t chy
ht lng E thu c 22,0 g CO2 v 9g H2O.Nu bit s mol axit nh hn
s mol ancol cng thc ca axit l:

A.C3H7COOH B.CH3-CH C.C2H3COOH D.HCOOH

Cu 88:Axit cacboxylic X hai chc(c phn trm khi lng oxi nh hn

Y v Z l 2 ancol ng ng k tip (My<Mz).t chy hon ton 0.2 mol

hn hp X,Y,Z cn va 8.96 l kh oxi(ktc),thu c 7.84 l CO2(ddktc)

v 8.1 g H2O.% khi lng cuarY trong hn hp trn l:

A.12.6% B.29.9% C.29.6% D.15.9%

Cu 89:Hn hp X gm HCOOH,CH3COOH(t l mol 1:1),hn hp Y gm

CH3OH,C2H5OH(t l mol 2:3).Ly 16.96 g hh X tc dng vi 8.08 g hh

Y(xc tc H2SO4 c) thu c m g este(hiu sut cc phn ng este ha

u bng 80%).Gi tr m l:

A12.064 g B.20,4352 g C.22,736 g D.17,728 g

Cu 90:X;Y l 2 hp cvhaats hu c,mch h c hn nhau 1 nguyn t

cacbon,thnh phn ch gm C,H,O.Mx>My.t chy hon ton 0.34 mol

hn hp Q gm X v Y ri cho sn phm chy hp th ht vo 1 dd cha 0.3

mol Ba(OH)2; 0,1 mol KOH sau hp th thu c 39,4 g kt ta.Khi cho

0,34 ol hn hp Q vo mt dd cha 0,35 mol KOH n phn ng hon ton

,thu c dd khng cn bazo.T khi ca X v Y nhn gi tr no sau y:

A.1,438 B.2,813 C.2,045 D.1,956

Cu 91:Hn hp X gm CC2H3N v 2 hidrocacbon ng ng lin tip.t

chy hon ton 100 ml hh X bng mt lng O2 va thu c 550 ml Y

gm kh v hi nc.Nu cho Y qua axitsufuric c d th cn li 250 ml

kh cipt ca 2 hidrocacbon:

A.CH4 v C2H4 B.C2H4 v C3H4 C.C2H4 v C3H3 D.C3H6 v

Cu 92:Hn hp kh X gm CH4 v C2H2 c Mx=23,5.Trn V(lit)X vi

V1(lit) hidrocacbon Y thu c 107,5g hh kh Z.Trn V1(lit)X vi

V(lit)hidrocacbon Y thu c 91,25g hh kh F.Bit V1-V=11.2(lit)(cc kh

o ktc).Cng thc ca Y l:

A.C3H4 B.C3H6 C.C4H6 D.C2H6

Cu 93:Mt bnh kn cha hn hp X gm 0.05 mol axetilen ;0.09 mol

vinyhoxetilen Y ;0.16 mol H2 v mt t bt Ni.Nung hh X thu c hh Y

gm 7 hidrocacbon(khng cha but-I-in)c t khi hi i vi H2 l

328/15.Cho ton b hhY qua bnh ng dd AgNO3,NH3 d ,thu c m g

kt ta vng nht v 1,792 lit hh kh Z thot ra khi bnh. lm b hon

ton hh Z cn dng 50 ml dd Br2 1M.Cc phn ng xy ra hon ton .Gi tr

A.28,71 g B.14,37 g C.13,56 g D.15,18 g

Cu 94:t hon ton 0,5 mol hh 2 ankin ng ng k tip,sn phm chy

em hp th hon ton vo bnh ng dd cha 0,846 mol Ca(OH)2 th thu

c kt ta v khi lng dd khng thay i.Mt khc cho 0,5 mol hh vo

dung dch AgNO3 d /NH3 th thu c m gam kt ta .Gi tr m l:

A.110,7 g B.96,75 g C.67,9 g D.92,1 g

Cu 95:Oxi ha 1 ancol n chc bng oxi c mt cht xc tc thu c hh

X.Chia X thnh 3 phn bng nhau .Phn 1 tc dng ht vi Na thu c 8,94

lit H2(ktc) v hh Y,lm kh Y thu c 48,8 g cht rn khan.Phn 2 tc

dng vi NaHCO3 d thu c 4,48 lit kh CO2 (ktc).Phn 3 tc dng

AgNO3/NH3 d thu c 21,6 g bc.CTCT ca ancol a dng l:

A.C2H2CH2OH B.C2H4OH C.C2H4CH2OH D.CH2OH

Cu 96:Cho m g hh X gm 2 ancoln chc X1,X2 ng ng k tip

(Mx1<Mx2),phn ng vi CuO nung nng ,thu c 0.25 mol H2O v hh Y

gm 2 anehit tng ng v 2 ancol d.t chay hon ton Y thu c 0.5

CO2 v 0.65 mol H2O.Mt khc,cho ton b lng Y trn tc dng vi

lng d AgNO3 trong NH3 un nng ,kt thc cc phn ng thu c 0.9

mol Ag.Hiu sut to anehit ca X1,X2 ln lt l;

A.50% v 66.67% B.33.33% v 50%

C.66.67% v 33.33% D.66.67% v 50%

Cu 97:Chia 0.16 mol hh X gm 2 anddehit n chc A v hai chc B

(MA<MB) thnh 2 phn bng nhau.Hidro ha phn 1 cn va 3,584 lit

H2(ktc).Cho phn 2 tc dng vi 1 lng d dd AgNO3/NH3 thu c

25.92 g Ag v 8.52 g hh 2 mui amoni ca 2 axit hu c.Cc phn ng xy

Thnh phn % khi lng A trong hh X l

A.49.12% B.50.88% C.34.09% D.65.91%

Cu 98:Hn hp X gm 1 anehit,1 axit cacboxylic v 1 este(trong axit

v este l ng phn ca nhau).t chy hon ton 0.2 mol X cn 0.625 mol

O2,thu c 0.525 mol CO2 v 0.525 mol H2O.Nu em ton b lng

anhit trong X cho phn ng hon ton vi 1 lng d dd AgNO3 trong

NH3 th khi lng Ag to ra l:

A.21.6 g B.54 g C.32.4 g D.16.2 g

Cu 99:Hn hp X gm 2 axit cacboxylic no,mch h Y v Z( phn t khi

ca Y nh hn Z).t chy hon ton a mol X,sau phn ng thu c a mol

nc.Mt khc,nu cho a mol X tc dng vi lng d dd NaHCO3 th thu

c 1.6a mol CO2.Thnh phn % theo khi lng ca Y trong X l:

A.35.41 B.40 C.25.41 D.46.67

Cu 100:Hn hp X gm 1 axit v 1 ru u no,n chc,mch h.t

chy hon ton 12.88 g X thu c 0.54 mol CO2 v 0.64 mol H2O.Khi un

nng 12.88 g X vi H2SO4 c th thu c m g este vi hiu sut 80%.Gi

A.10.2 g B.11.22 g C.8.16g D.12.75 g