ng I: ESTE - LIPID TRC NGHIM ESTE - LIPID

TEN:________________________________________________________________________________
LP 12A5
CHNG I: ESTE LIPID

TRAC NGHIEM ESTE-

LIPIT
1. Thy phn hon ton hn hp X gm 2 este n chc A, B cn dng 100 ml dung dch NaOH 1M thu c 8,2 gam
mui duy nht v 4,04 gam hn hp 2 ru l ng ng lin tip nhau. Cng thc cu to ca 2 este l:
A. HCOOCH3 v HCOOC2H5 B. CH3COOCH3 v CH3COOC2H5
C. CH2=CH-COOCH3 v CH2=CH-COOC2H5 D. p n khc.
2. Thy phn hon ton 0,1 mol este E (mch h v ch cha mt loi nhm chc) cn dng va 100 gam dung dch
NaOH 12%, thu c 20,4 gam mui ca mt axit hu c v 9,2 gam mt ru.Vy cng thc ca E l :
A. C3H5(COOC2H5)3 B. (HCOO)3C3H5 C. (CH3COO)3C3H5 D. C3H5(COOH)3.
3.Gi s trong iu kin thch hp, ngi ta thc hin c phn ng este ha va gia 12,4 gam etylenglicol vi m
gam hn hp hai axit hu c n chc no mch h ng ng k tip, thu c 32 gam hn hp ba este a chc. Cng
thc hai axit hu c em dng l:
a) HCOOH, CH3COOH b) CH3COOH, CH3CH2COOH
c) CH3CH2COOH, CH3CH2CH2COOH d) C3H7COOH, C4H9COOH
4.Hn hp E gm 3 este a chc ca axit oxalic v hai ru n chc, no, mch h, ng ng k tip. Thc hin phn
ng x phng ha hon ton 4,8 gam hn hp E bng dung dch xt va th thy dng ht 19,48 ml dung dch
NaOH 11% (c khi lng ring 1,12 g/ml). Cng thc ca hai ru to nn hn hp E l:
a) CH3OH, C2H5OH b) C4H9OH, C5H11OH
c) C2H5OH, C3H7OH d) C5H11OH, C6H13OH
5. A l mt cht hu c cha mt loi nhm chc. A khng tc dng kim loi kim. t chy a mol A thu c 4a mol
CO2 v 3a mol H2O. a mol A tc dng va dung dch c ha tan 2a mol NaOH, thu c mt mui v mt ru. A l:
a) Este ca axit oxalic b) Este ca etylenglicol
c) Este a chc hai nhm chc este d) (a) hoc (b)
6. A l mt este c cng thc thc nghim (C3H5O2)n. Mt mol A tc dng va hai mol KOH trong dung dch, to
mt mui v hai ru hn km nhau mt nguyn t cacbon trong phn t. A l:
a) Metyl etyl malonat b) Metyl Vinyl malonat
c) Vinyl alyl oxalat d) Metyl etyl aipat
7.Cho 2,76 gam chat hu c A cha C, H, O tac dung vi dung dch NaOH va u, sau
o chng kho th phan
bayhi ch co nc, phan chat ran khan con lai cha hai muoi cua natri chiem
khoi lng 4,44 gam. Nung nong
hai muoi nay trong oxi d, sau khi phan ng hoan toan, ta thu c 3,18 gam Na 2CO3
2,464 lt kh CO2 (ktc) va
0,9 gam nc. Biet cong thc n gian cung la cong thc phan t. Cong thc
cau tao thu gon cua A la:
A. HCOOC6H5 B. C6H5COOH C. CH3COOC6H5 D. HCOOC6H4OH
8. Hon hp E gom hai chat hu c A, B co cung chc hoa hoc. un nong 13,6 gam
hon hp E vi dung dch
NaOH d thu c san pham gom mot muoi duy nhat cua mot axit n chc, khong
no hon hp hai ru n
chc, no ke tiep nhau trong day ong ang. ot chay hoan toan 27,2 gam hon hp
E phai dung het 33,6 lt kh oxi

1 Ngun: Tp th hc sinh 12 A 5 L Hng Phong 2010 - 2011

 ng I: ESTE - LIPID TRC NGHIM ESTE - LIPID

thu c 29,12 lt kh CO2 va hi nc (cac kh o cung ieu kien tieu chuan).

Cong thc phan t cua A, B co
the la:
A. C4H6O2 va C5H8O2 B. C4H8O2 va C5H10O2 C. C2H2O2 va C3H4O2 D. C3H4O2 va C4H6O2
9. (C, H, O) mach thang, ch cha mot loai nhom chc tac dung va het 152,5 ml
dung dch NaOH 25%. Co
d=1,28 g/ml. Sau khi sau phan ng xay ra hoan toan thu c dung dch A cha mot
muoi cua axit hu c, hai
ru n chc, no ong ang lien tiep e trung hoa hoan toan dung dch A can
dung 255ml dung dch HCl 4M.
Co can dung dch sau khi trung hoa th thu c hohp hai ru co t khoi so vi H 2
la 26,5 va 78,67 gam hon hp
muoi khan. Hp chat X co cong thc cau tao la:
A. C3H7OOC-C4H8-COOC2H5 B. C3H7OOC- C2H4-COO C2H5
C. CH3OOC- C3H6-COO C3H7 D. C2H5OOC-C4H8-COOC2H5
10. A l mt cht hu c mch thng cha mt loi nhm chc m mui natri ca n khi em nung vi vi ti xt th
thu c kh metan. B l mt ru mch h m khi cho a mol B tc dng ht vi Na th thu c a/2 mol H 2. a mol B
lm mt mu va dung dch c ha tan a mol Br2. t a mol B thu c 3a mol CO2. A tc dng B th thu c
mt hp cht hu c a chc X. X l cht no?
a) CH3COOCH2CH2CH2OOCCH3 b) CH3CH2CH2OOCCH2COOCH2CH2CH3
c) CH3COOCH2CHCHOOCCH3 d) CH2CHCH2OOCCH2COOCH2CHCH2
11.Hn hp X gm hai este no,n chc,mch h.t chy hon ton mt lng X cn dng va 3,976 lt kh O 2
(ktc),thu c 6,38 gam CO2.Mt khc,X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng
ng k tip. Cng thc phn t ca hai este trong X l:
A.C2H4O2 v C5H10O2 B.C2H4O2 v C3H6O2
C.C3H4O2 v C4H6O2 D.C3H6O2 v C4H8O2
12. Cho hn hp X gm 2 este n chc mch h tc dng ht vi dung dch KOH thu c 1,96
gam mt mui v
1,02 gam hn hp 2 anehit no, ng ng k tip. Cho lng 2 anehit ny tc dng ht vi
bc nitrat trong dung
dch NH3 th thu c 4,32 gam Ag. Cng thc ca 2 este trong X l
A. CH3-COO-CH=CH-CH3 v CH3-COO-CH=CH-CH2-CH3.
B. CH3-COO-CH=CH2 v CH3-COO-CH=CH-CH3.
C. H-COO-CH=CH-CH3 v H-COO-CH=CH-CH2-CH3.
D. H-COO-CH=CH2 v H-COO-CH=CH-CH3.
13. Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C,
tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6
lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu
sut l 80%) th s gam este thu c l
A. 34,20. B. 27,36. C. 22,80. D. 18,24.
14. Cho 0,05 mol hn hp X gm 2 este n chc tc dng va vi 120ml dd NaOH 0.5M, thu c hh Y gm
2 mui v mt ancol . Mt khc, khi t chy han tan 0,1 mol hh X trn thu c 14,08g CO 2 . CTCT ca este
l :
A.CH3COOC2H5;C2H5COOC2H5 B. HCOOCH 3;HCOOC6H4CH3
C. CH3COOCH3;CH3COOC6H5 D. HCOOCH3;HCOOCH2C6H5
15. Cho 3.52g mt este no, n chc X phn ng va ht vi 40ml dd NaOH 1M, thu c hai cht hu c A v B. Nu
t chy 0.6g cht B th thu c 1.32g CO2. Khi oxi ha trong iu kin thch hp, cht B cho sn phm l 1 andehit Y.
Xc nh CTCT ca X, A, B, Y. Gi s hiu sut phn ng l 100%.
16. un nng hn hp gm 30g axit axetic v 34,5g etanol vi H2SO4 m c. Tnh lng este thu c v
hiu sut phn ng. Bit nhit trn, phn ng co hng s cn bng l 1/4.
A. 17,776g ; 40,4% B. 17,776g ; 66,67% C. 44g ; 40,4% D. 44g ; 40,4%
17. X tc dng c NaOH, nhit v cho phn ng trng gng. 3.7g X c th tch bng th tch 1.6g O2 (cng iu
2 Ngun: Tp th hc sinh 12 A 5 L Hng Phong 2010 - 2011
 ng I: ESTE - LIPID TRC NGHIM ESTE - LIPID

kin).t 1g X thu VCO2 > 0.7L(ktc). S ng phn tp cht, mch h ca X:

A. 4 B.5 C.6 D.7
18. Este (E) c to bi ancol a chc (X) v axit n chc (Y). Bit 8.9g (E) tc dng va vi 0.3 lt dd
NaOH 0.1M thu c ancol (X) v 9.18 g mui ca axit Y. T khi hi ca (E) so vi heli bng 222.5. (E) l:
A. glixerol tripanmitat (tripanmitin) B. glixerol tristearat (tristearin)
C. glixerol trioleat (triolein) D. glixerol trioxalat
19. Thc hin phn ng este ho 1 mol CH3COOH v 1 mol ru etylic, lng este ln nht thu c l 2/3 mol. t
hiu sut cc i l 90% (theo axit) khi tin hnh este ho 1 mol CH 3COOH th cn s mol C2H5OH l bao nhiu (cho
bit cc phn ng este ho thc hin cng nhit )
A.2,925 B.0,456 C.2,412 D.0,342
20. Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75
gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u
bng 80%). Gitr ca m l (cho H = 1, C = 12, O = 16)
A. 10,12. B. 6,48. C. 8,10. D. 16,20.
21.Thy phn han tan Este X trng mi trng axit thu c hai cht hu c A v B. Oxi ha A cho ra B. X
khng th l cht no sau y:
A. Etyl axetat B.Vinyl axetat C. Etylen oxalat D. Isopropyl propionat
22. X l este khng no, mch h, t khi so vi Oxi l 3,125. X phng ha X c mt andehit v mt mui ca axit
hu c. X c th c bao nhiu cng thc cu to:
A.4 B.5 C.6 D.7
23. X l 1 este n chc. Thu phn 0,01 mol X vi 300ml dd NaOH 0,1M n khi p.ng xy ra hon ton thu c dd
Y. C cn Y thu c phn hi (ch c nc) v 2,38g cht rn khan. S CTCT c th c ca X l:
A.1 B. 2 C. 3 D.4
24. un a gam hn hp hai cht X v Y l ng phn cu to ca nhau vi 200ml dd NaOH 1M (va ) n
khi phn ng hon ton thu c 15g hh hai mui ca hai axit no, n chc, l ng ng k tip nhau v
mt ancol. Gi tr ca a v CTCT ca X,Y ln lt l:
a. 12g CH3COOH v HCOOCH3
b. 14,8g CH3COOCH3 v CH3CH2COOH
c. 14,8g HCOOC2H5 v CH3COOCH3
d. 9g CH3COOH v HCOOCH3
25. 100 ml dd cha 2 este A, B n chc c nng mol chung l 0,8M. Cho hn hp ny tc dng vi 150 ml
dd NaOH 1M. Sau phn ng thu c 2 mui hu c C v D c khi lng l 10,46g (t l MC : MD = 41 :65)
ng thi thu c 1 ancol E c khi lng l 2,9g ancol ny khng bn bin thnh anehyt sau phn ng phi
dng 200 ml dd HCl 0,2M trung ho NaOH d. Xc nh CTCT ca A, B.
26. E l hn hp ca hai ng phn este c to ra t axit no , n chc v ancol no , n chc. cng nhit
v p sut 1 lt hi E nng gp 2 ln 1 lt kh CO2 . Thu phn 35,2(g) E bng 4 lt dd NaOH 0,2 M c dd
A . C cn dd A c 44,6 (g) cht rn khan. Xc nh CTCT v tnh % s mol ca 2 este.
A. HCOOC3H7 ( 75%) , CH3COOC2H5 ( 25%)
B. HCOOC3H7 (87,5%) , C2H5 COOCH3 (12,5 %)
C. A v B ng
D. A v B sai
27. 1.Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s
mol cn cho phn ng chy) 139,9 C, p sut trong bnh lc ny l 0,8 atm. t chy hon ton X sau a
v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l:
A. C4H8O2 B. C3H6O2 C. CH2O2 D. C2H4O2
28.Cho 0,1 mol mt este G1 tc dng va vi 100ml dung dch NaOH 2M, thu c hh 2 mui ca 2 axit
hu c mch h G2, G3 u n chc v 6.2g mt ancol G4. Axit hu c G2 no khng tham gia phn ng trng
gng. Axit G3 khng no, ch cha lin kt i C=C, c mch cacbon phn nhnh. t chy ht hn hp hai
mui thu c trn to ra Na2CO3, CO2 v H2O. Cho hon ton CO2, H2O sinh ra i qua bnh ng Ca(OH)2
d, thu c 100g kt ta. Cng thc cu to ca ancol G4 v este G1 l:
A.CH2OH-CH2OH v CH3-COO-CH2-CH2-OOC-(CH3)C=CH2

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B.CH2OH-CHOH-CH2OH v CH3-COO-CH2-CH2-OCO-CH3
C.CH2OH-CH2OH v CH3-COO-CH2-CH2-OCO-CH=CH2
D.CH2OH-CH2OH v CH3-CH2-COO-CH2-CH2-OCO-CH=CH2
29. Thc hin phn ng eate ha 1mol CH3COOH v 1 mol C2H5OH c hng s cn bng
K= 2,25 . Vy nu
tin hnh phn ng este ha 1 mol CH3COOH v a mol C2H5OH t hiu sut l 90%
th gi tr a cn l :
a. 5,4 b. 4,5 c. 3,6 d. 2,4
30. Hai cht X,Y c cng cng thc phn t C2H4O2.Cht X phn ng c vi kim loi Na v tham gia phn
ng trng bc.Cht Y phn ng c vi kim loi Na v ha tan c CaCO3.Cng thc ca X ,Y ln lt l.
A.CH3COOH,HOCH2CHO B.HCOOCH3,HOCH2CHO
C.HCOOCH3,CH3COOH D.HOCH2CHO,CH3COOH
31.un nng 21,8 g cht X vi 1lt dd NaOH 0,5 M thu c 24,8 g mui ca axit mt ln axit v mt ru B .
nu cho lng bay hi kc chim th tch l 2.24 lt . Lng NaOH d c trung ha ht bi 2 lt dd HCl
0,1 M.Cng thc cu to ca A l:
a. (HCOO)3C3H5 b.(C2H5COO)5C3H5 c.(CH3COO)3C3H5 d.(CH3COO)2C2H4 e.kt qu khc
32. Chia hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip thnh 3 phn bng nhau. Phn
1 tc dng vi dung dch NaHCO3 d thu c 2,24 lt kh CO2 (ktc). Phn 2 t chy hon ton X thu c
6,272 lt CO2 (ktc). Phn 3 tc dng va vi etylen glycol thu c m gam hn hp 3 este khng cha
nhm chc khc. Tm m.
33. Cho 300ml dd NaOH 1M tc dng va vi hn hp X gm 2 cht hu c n chc, sau phn ng thu
hn hp Y gm 1 ancol v 2 mui ca 2 axit cacboxilic. Cho ancol trn tc dng vi Na d, thu 0.896 l H2 0
C, 3 atm. Hn hp X cha:
A. 1 ancol v 1 este B.1 axit v 1 este C.2 este cng gc ancol D. 1 axit v 1 ancol
34. X l este ca 1 Axit n chc v mt ancol n chc. Thy phn han tan 6,6 g lng cht X dng 90
ml dd NaOH 1M, lng NaOH ny d 20% so vi lng NaOH cn dng cho phn ng. Dd sau phn ng c
cn thu rn 5,7g. Cng thc X l:
A. HCOOC3H7 B.HCOOC3H5 C.CH3COOC2H5 D.C2H5COOCH3
35. Cho cht hu c A ch cha 1 loi nhm chc tc dng vi 1 lt dd NaOH 0,5M thu c a gam mui v 0,1 mol
ancol. Lng NaOH d c th trung ha ht 0,5 lt dd HCl 0,4M. Cng thc tng qut ca A l:
a)R-COO-R b) (R-COO)2R c) (R-COO)3R d) R(COO-R)3
36. un 1 lng d axit axetic vi 13,8g ancol etylic ( c H2SO4 c lm xc tc). n khi phn ng dng li thu c
11g este. Hiu sut phn ng este ha l:
a)75% b)62,5% c)60% d)41,67%
37. Mt este A ( khng c chc khc) c to bi axit no, mch thng (c 2 nhm cacboxyl) vi glixerol. %
khi lng C trong A l 56,03%. Axit to thnh A l :
a/ Axt Oxalic b/Axt Malonic c/ Axt Aipic d/ Axt Succinic
38.t 0,2 mol hn hp gm etyl axetat v metyl acrylat thu c CO2 v H2O trong : s mol CO2 s
mol H2O =0,08 mol. Nu un 0,2 mol hn hp X trn vi 400ml dung dch KOH 0,75M v c cn thu c m
gam cht rn khan. m c gi tr l :
A. 26,4 gam B. 26,64 gam C. 20,56 gam D. 26,16 gam
39. Axit acrylic tc dng vi ancol n chc X thu este Y. un nng 7,74g este Y vi dd HCl ( gi s H+
trong dd axit khng ng k). Trung ha dd thu c cn 200ml dd NaOH 1,5M. X phng ha lng este
cn li phi dng thm mt th tch gp i NaOH ni trn. X c tn l:
A. ancol anlylic B. ancol metylic C. ancol propylic D. ancol etylic
40. Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100
gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca
X l

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A. CH3OOC(CH2)2COOC2H5. B. CH3COO(CH2)2COOC2H5.
C. CH3COO(CH2)2OOCC2H5. D. CH3OOCCH2COOC3H7.
41. Lm bay hi 15.3gam mt este A thu c mt th tch ca 4.2gam nito cng iu kin. S cng thc
cu to c th c ca A l:
A.8 B.9 C.10 D.11
42. Este ho ancol n no A v axit n no B (MA = MB) thu este D tho iu kin: tng phn t lng ca A, B gp 2
ln khi lng cacbon c trong MD. Nhn xt no sau y sai:
A. A hn B mt nguyn t cacbon.
B. Ancol A c 2 ng phn cng chc.
C. B c 1 ng phn n chc khc chc.
D. B + Cl2 (xt nh sng) cho sn phm hu c E c tnh axit yu hn B.
43. Cho 0.1 mol A (C8H12O5) tc dng va vi dung dch NaOK, sau c cn dung dch c 1 ancol 3 chc &
17.6g hn hp cht rn gm mui ca 2 axit n chc (s nguyn t C hn km nhau 1 C).
CTCT thu gn ca A:
A. (HCOO)(CH3COO)C5H7OH B. (C2H5COO)(CH3CHOO)C3H3OH
C.(HCO)(C2H5COO)C4H5OH D.(CH3COO)(C2H3COO)C3H5OH
44.t a mol X l este 3 ln este ca glixerol v 3 axit n chc thu c b mol CO2 v c mol H2O, bit b-c=4a. Hiro
ha m gam X cn 5,6 lt H2 ktc thu c 32 gam X. Nu un m gam X vi dung dch NaOH va thu c bao
nhiu gam mui khan?
A. 35,5 gam B. 39,6 gam C. 30,2 gam D. 40,6 gam
45. X phng ho hon ton 26.4g este etyl oxalat bng dd NaOH, thu hh ancol A, B. Ete ho hh ancol tren thu
m (g) hh 3 ete. Cho hiu sut phn ng to ete ca ancol nh v ln theo th t l 60% v 70 %. Tm m:
A. 7,94 B. 5,6 C. 12 D. 9,74
46. t chy hon ton 2,76g hn hp X gm CXHYCOOH, CXHYCOOCH3 v CH3OH thu c 2,688 lt CO2
(ktc) v 1,8g H2O . Mt khc, cho 2,76g X phn ng va vi 30 ml dd NaOH 1M, thu c 0,96g CH3OH.
Cng thc ca CXHYCOOCH3 l :
A. C2H5COOCH3 B. CH3COOCH3 C. C2H3COOCH3 D. C3H5COOCH3

HT

5 Ngun: Tp th hc sinh 12 A 5 L Hng Phong 2010 - 2011