TRNG I HC NNG LM TP.

H CH MINH
B MN CNG NGH HO HC
-

BI BO CO NHM

MN: TH NGHIM HA L
GVHD: NGUYN BO VIT

LP DH08HH

Nhm thc hin :

1. Trn Phc Sn MSSV 08139234
2. Trn Th Mai Tho MSSV 08139260
3. Phan Vn Tun MSSV 09139221
4. L Vn Ho MSSV 09139045
5. Nguyn Th Trc Phng MSSV 08139211

Thng 1/2011
 THY PHN ESTER BNG KIM

I. Yu cu
Sinh vin cn nm vng cc vn sau :
- Xc nh phn ng thy phn ester trong mi trng kim l phn ng bc 2.
- Nm vng ngha ca nng lng hot ha v nh hng ca nhit ln
hng s tc ca phn ng qua h thc Arrhenius.
- S dng phng php chun ngc xc nh nng NaOH
- Hiu l do phi un hon lu hn hp phn ng.
II. L thuyt
Phn ng gia ester acetat etyl v NaOH xy ra nh sau :
CH3COOC2H5 + NaOH CH3COONa + C2H5OH
t=0 a b 0 0
t ax bx x x
vi : a, b l nng u ca ester v NaOH
(a x) v (b x) l nng ca ester v NaOH thi im t
y l phn ng bc 2, biu thc hng s tc c dng :
k / t = [1 / (a b)] . ln {[b.(a x)] / [a .(b x)]}
(7.1)
Gi no , nt , n l th tch NaOH cn trong hn hp phn ng cc thi
im t = 0 , t , (phn ng han ton thi im t )
Nng NaOH cc thi im s t l vi cc th tch . Cn nng ester
thi im u v thi im t s t l tng ng vi (no - n) v (nt - n).
Do : CoNaOH = b = A . no
Coester = a = A . (no - n)
Ct NaOH = b x = A . nt
Ct ester = a x = A . [(no - n) no nt)] = A . (nt - n)
vi : A - l hng s t l.
Thay cc gi tr trn vo (7.1)
 1 A.n0 . A.(nt n )
kt . ln
A.( n0 n ) A.n0 A.nt . A.(n0 n )

1 n .(n n )
kt . ln 0 t
An nt .( n0 n )
1 n .( n n )
kt . ln t 0 (7.2)
An n0 .( nt n )

Tm hng s A trong biu thc (7.2) :

Dung dch NaOH c nng ng lng N/100. Vy s ng lng NaOH
c trong 25ml hn hp phn ng (hay trong no ml NaOH) l :
1000 1/100 } n x 1/100 x 1/1000 = s ng lng NaOH/ 25ml
o

no ?
Nng ng lng ca NaOH trong mu th s l :
CoNaOH = no x (1/100) x (1/1000) x (1000/25) = no / 2500
m CoNaOH = A . no.
Suy ra : A = 1/2500
* nh hng ca nhit n hng s tc
Phng trnh Arrhenius m t s ph thuc ca tc phn ng vo nhit :
k = ko . e-E / RT
(7.3)
vi : ko l tha s tn s hay tha s Arrhenius, khng ph thuc nhit
E - l nng lng hot ha ca phn ng.
Ly logarit 2 v : lnk = lnko - (E / RT)
Nh vy, ng biu din lnk = f(1/T) l ng thng c dc E/R
Gi k1, k2 l hng s tc cc nhit T1, T2 , khi :
Ln (k2 / k1 ) = - (E/R) . ( 1/T2 1/T1) (7.4)
Da vo (7.4) c th tm nng lng hot ha ca phn ng khi bit hng s
tc hai nhit khc nhau.

III. Thc nghim

1- Dng c v ha cht
* Ha cht :
- CH3COOC2H5 M/200
- NaOH M/100
- HCl M/100
- Phenolphtalein
* Dng c :
- 3 erlen nt nhm 500 ml
- 6 erlen 250 ml
- 2 becher 100 ml
- 1 nhit k 100C
- 2 eprouvette 250 ml
- 2 pipette 25 ml
- 2 burette 25 ml
- 1 ng ngng hi bu
- 1 Qu bp cao su
- 1 bnh xt nc ct
- 2 b iu nhit
2- Cch tin hnh
Thc hin qu trnh thy phn ester hai nhit :
a) Nhit phng T1
- Dng ng ong ly 150 ml DD NaOH M/100 v 150 ml ester M/200 cho
vo 2 bnh tam gic 500 ml khc nhau. y nt kn.
- Chun b 6 bnh tam gic, mi bnh cha 12,5 ml DD HCl M/100
- nhanh DD NaOH vo ester (ghi thi im t = 0), y np lc mnh.
- c nhit T1 ca DD phn ng (nhng nhit k sch vo DD).
Sau 5, 10, 20, 30, 40, 50 pht dng pipette ht 25 ml hn hp phn ng cho
vo bnh cha 12,5 ml acid.
Chun HCl tha bng DD NaOH M/100, dng ch th phenolphtalein (2
git). (Ch trnh chun tha, im tng ng t mu hng nht bn
trong khong 30 giy).
Sau pht 50, un hon lu cch thy hn hp phn ng cn tha n 70C,
gi t trong 30 pht. ngui ti nhit phng, sau ly mu v chun
 nh trn. 70 phn ng xy ra rt nhanh nn sau 30 pht c th coi phn ng
hon tt v d kin thu c khi chun NaOH ln ny ng vi thi im t =
.
b) Nhit bnh iu nhit T2
Lng DD TN ging nh trn. Ngm 2 bnh ng ester v NaOH trong bnh
iu nhit trong t nht 20 pht (thc hin vic ny sm, ngay t giai on o
nhit phng), t nhit khong 38C - 45C (ghi nhit chnh xc theo
bnh iu nhit) ri mi bt u cho phn ng.
Tin hnh TN tng t trn.
I. Kt qu th nghim
1. Kt qu th:

Nhit Thi im
5 10 20 30 40 50 x
T1 27.5 27.8 27.9 28 28.5 29 30
T2 30.1 30.5 30.6 30.8 31 31.1 45

2.Kt qu tnh:
Thi V NaOH chun V NaOH trong
Nhit (0C) im (ml) mu th (ml) K
27.5 0 4.8 7.7 0
27.5 5 5.2 7.3 4.545E-06
27.8 10 6 6.5 1.593E-05
27.9 20 6.6 5.9 2.737E-05
28 30 7 5.5 3.707E-05
28.5 40 8.5 4 1.074E-04
29 50 9 3.5 1.654E-04
T1=3 v
0 30 cng 9.7 2.8 2.776E-03
trung bnh 3.917E-04
30 0 4 8.5 0
30.1 5 4.6 7.9 7.161E-06
30.5 10 5 7.5 1.294E-05
30.6 20 6.1 6.4 3.560E-05
30.8 30 6.8 5.7 5.971E-05
31 40 7.4 5.1 9.471E-05
31.1 50 7.6 4.9 1.126E-04
v
T2=45 45 cng 8.4 4.1 1.655E-03
trung
bnh 4.610E-05

Tnh kT1 v kT2 theo phng php bnh phng cc tiu, ta c cc th sau
T bng s liu trn, p dng cng thc (*) ta tnh c nng lng hot ha E:

T1 (K) T2 (K) k1 k2 E (Calo)

303 318 2.776E-03 1.655E-03 6570.095
 CN BNG LNG - RN

I. Yu cu :
Sinh vin cn nm vng cc vn :
- Nm c nguyn tc phng php phn tch nhit
- p dng quy tc pha gii thch dng cc ng cong ngui lnh
- Thit lp gin nhit - thnh phn khi lng ca h hai cu t kt tinh
khng to hp cht ha hc hay DD rn.

II. L thuyt :
Phng php phn tch nhit t trn c s nghin cu s thay i nhit ca
mt h ngui hoc nng dn theo thi gian.
p sut nht nh, nhit kt tinh ca mt nguyn cht c gi tr khng i
v gi nguyn trong sut qu trnh kt tinh. i vi DD, nhit bt u kt tinh
ph thuc thnh phn DD v trong qu trnh kt tinh mt cu t, nhit gim
dn cho ti khi xut hin cu t th hai cng kt tinh th nhit gi nguyn Te
(ng vi nhit eutecti ) cho ti khi qu trnh kt tinh kt thc. Sau nhit
tip tc gim.
Trn hnh 4.1, ng ngui (1) v (5) ng vi A v B nguyn cht. ng (2)
v (4) ng vi hn hp c gi tr %B tng dn. ng (3) ng vi hn hp c
thnh phn bng ng thnh phn eutecti.
Trn ng (1) v (5) cc on thng nm ngang ng vi qu trnh kt tinh A
v B nguyn cht.
Trn ng (2), (3), (4) on nm ngang b, c, e ng vi qu trnh kt tinh
eutecti, cn cc im b,c ng vi im bt u v kt tinh mt cu t no (cc
hn hp 2, 4). Nhng im ny xc nh d dng v dc ca ng biu
din thay i do tc gim nhit trc v trong khi kt tinh khng ging
nhau. Trong thc nghim vic xc nh im eutecti rt quan trng nhng li rt
kh. Thng dng phng php Tamman - nu iu kin ngui lnh han ton
nh nhau th di ca on nm ngang (thi gian kt tinh) trn ng cong
ngui lnh s t l vi lng eutecti. Nh vy nu t trn on ad thnh phn v
trn trc tung l di cc on nm ngang ca ng ngui lnh tng ng ni
cc u mt li., ta s c tam gic aId. nh I ca tam gic ng vi thnh phn
eutecti. Tam gic aId gi l tam gic Tamman.
 Gin nhit - thi gian Gin nhit - thnh phn

III. Thc hnh :

1- Dng c v ha cht :
* Dng c :
- 8 ng nghim
- 1 bp in
- 8 nhit k ru 100C
- 8 a khuy vng
- 1 becher 500 ml
- 1 chu nha
- 8 nt cao su

* Ha cht :
- Hn hp Naptalen Diphenylamin pha sn theo cc thnh phn nh sau :
ng nghim 1 2 3 4 5 6 7 8
Naptalen (g) 10 8 6 4.5 3 2.5 1 0
Diphenylamin 0 2 4 5.5 7 7.5 9 10
(g)

2- Cch tin hnh :

- un cch thy ng nghim ti khi hn hp va chy lng han ton. Ch
khng un qu lu, cht rn thng hoa s bm thnh ng.
- Ly ng nghim ra lau kh ngoi ng. Theo di s h nhit theo thi gian, c
sau 1 pht ghi nhit mt ln. Lin tc khuy nh v u tay cho ti khi thy vt
tinh th u tin xut hin (ghi nhit ny) th ngng khuy. (C th kim tra
cho chc chn bng cch nhng ng nghim vo nc nng tr li cho hn hp
chy lng v ghi li nhit bt u kt tinh)
- Sau tip tc theo di (khng khuy) v ghi nhit hn hp ngui dn, cho
ti khi hn hp hon ton ng c.
 Ch : Khi nhit cc ng nghim ngui n khong 40C th s dng ng bao
khng kh bn ngoi ng nghim v nhng vo hn hp nc + 1 t nc
(nhit nc lm lnh khng di 20C) v tip tc ghi nhit cho n khi
nhit gim xung n 28C th ngng TN.

3- Kt qu
a) Kt qu th : Ghi li nhit hn hp tng thi im ca 8 ng nghim.
b) Kt qu tnh:
- V th nhit - thi gian (ng cong ngui lnh) ca h. Xc nh nhit
bt u kt tinh ca tng hn hp. (nh du trn th)
- V th nhit - thnh phn ca h diphenylamin naptalen v xc nh
nhit eutecti, thnh phn eutecti ca h.

Bi lm:
nhit
thi nhit nhit nhit nhit nhit nhit nhit
gian(ph ng ng ng ng
t) ng 1 2 3 ng 4 ng 5 6 7 ng 8
1 80 76 68.5 72 55.4 64 56 62
2 78 71 63.8 66 52.5 62 52 58
3 78 70 62 60 48 56 49 54.5
4 77 68 62.5 53 44 50 46 53.5
5 77 67 62 49.5 41.3 47 45 53
6 77 66 62 47 36 44 46 53
7 76.5 64 61 45 30 42 45.8 53.5
8 75.5 63 59 44.5 28 38 45 52.7
9 74 61.5 57.5 44 30 44.5 52.7
10 73 60 57 44 33 44.5 52.7
11 71 59 55 42.8 32 44 52.7
12 70 58 53 40.5 28 43 52.7
13 68 55 51.5 40 42.8 52.7
14 67.5 53 49.8 38 42.5 52.7
15 65 50 48.8 35.5 42.5 52.2
16 48 48 33.5 44 52
17 46.5 32 43.5 51.2
18 45 42.5 50.2
19 43 42 49.1
20 41.5 41.7 47
21 40 40.8 42.5
22 38 40 40.5
23 35 38 38
24 33.5 36 34.5
25 30 34 30
26 32
27 31.8
28 30
29 29.8
30 29.8
Nhn vo th ta c ,thnh phn hn hp eutecti tng ng vi thnh phn hn
hp ca ng 6: 2.5 g naptalen, 7.5 g Diphenyl amin
Nhit ca eutecti l 30.
nbviet@hcmuaf.edu.vn
 HP PH TRN RANH GII LNG - RN

I. Yu cu
Sinh vin cn nm vng cc vn sau :
- Nm vng nh ngha hp ph, ng ng nhit hp ph
- Kho st s hp ph acid acetic trong DD nc trn than hot tnh v thit
lp cc ng ng nhit hp ph tng ng.

II. L thuyt
Hp ph l hin tng c mt cht (dng phn t, nguyn t hay ion) tp
trung, cht cha trn b mt phn chia pha no (kh / rn, lng / rn, kh /
lng)
Trong trng hp cht hp ph rn, thng l cht c b mt ring (tng din
tch trn 1 gam cht rn) rt ln, c gi tr vo khong 10 1000 m2/g. Cc cht
hp ph cht rn thng dng l : than hot tnh, silicagel (SiO2), alumin (Al2O3),
zeolit
Trong s hp ph cc cht trn b mt ct hp ph rn, nguyn nhn ch yu
ca s hp ph l do nng lng d b mt trn ranh gii phn chia pha rn kh
hay rn - lng. Cc lc tng tc trong hp ph ny c th l cc lc Van der
Waals (hp ph vt l) hay cc lc gy nn do tng tc ha hc (hp ph ha
hc) hay so c hai loi tng tc trn cng tc dng.
Lng cht b hp ph trn b mt cht hp ph tu thuc vo nhiu yu t
nh :
- Bn cht ca cht hp ph v cht b hp ph
- Nng ca cht b hp ph
- Nhit , v.v
Thc hin TN nhit khng i, ta c th o c s mol cht b hp ph
trn 1 g cht hp ph rn ( hp ph ) cc nng cht b hp ph khc
nhau (C). ng biu din C gi l ng ng nhit hp ph.
 Mt s phng trnh thc nghim v l thuyt c s dng biu th cc
ng ng nhit hp ph : Freundlich, Langmuir, BET, v.v
1- Phng trnh Freundlich
y l phng trnh thc nghim, p dng cho s hp ph cht kh hay cht
ha tan trong DD.
= k . C1/n (13.1)
Trong : k v 1/n l nhng hng s khng c ngha vt l
C - l nng DD khi hp ph t cn bng

Vit di dng logarit :

ln = 1/n lnC + lnk
Nh vy nu biu th ln theo lnC, ta s c 1 ng thng c h s gc 1/n
v tung gc l lnk.
Phng trnh freundlich thng thch hp khong nng (hay p sut)
trung bnh, v nng thp thng t l thun vi C v nng cao
thng t ti 1 tr s gii hn v do c lp vi C.
2- Phng trnh Langmuir
y l phng trnh l thuyt, p dng cho hp ph n lp (hp ph ha hc)
= / = kC / ( 1 + kC ) (13.2)
vi : - che ph b mt
k - hng s
- s mol cht b hp ph ti a trn 1g cht rn trong n lp.
C th vit li phng trnh trn di dng :
C / = ( C / ) + ( 1 / k )
Vy nu biu th C / theo C ta oc mt ng thng c h s gc 1 /
v tung gc 1 / k
T phng trnh Langmuir, c th xc nh c b mt ring So ca cht hp
ph theo cng thc :
So = . N . Ao ( m2/g)
Trong : N s Avogadro = 6,023.1023
Ao - din tch chim ch trung bnh ca 1 phn t cht b hp ph
Phn t Aragon NH3 C6H6 CO2 CO C 2 H6 Krypton
Ao(A2) 14.2 14.6 40 19.5 16.3 20.5 19.5

Phn t n-butan n-hexan N2 O2 H2 O CH3COOH Xenon

Ao(A2) 14.2 14.6 40 19.5 16.3 20.5 19.5

III. Thc nghim

1- Dng c - Ha cht
* Ha cht:
- CH3COOH 0,2 N
- NaOH N / 20
- Phenolphtalein
- Than hot tnh
* Dng c :
- 9 erlen 125 ml
- 6 becher nha 250 ml
- 6 nt cao su
- 6 da nha cn
- 2 becher 100 ml
- 2 burettre 25 ml
- 1 pipette 10 ml
- 1 pipette 5 ml
- 6 phu lc
- 6 vng phu lc
- 1 nhit k 100C
- 1 bnh xt nc ct
- 1 qu bp cao su
- Giy lc
Trong phn TN ny chng ta s kho st s hp ph ca CH3COOH trong DD
nc trn than hot tnh nhit phng.
2- Cch tin hnh
- Dng acid acetic CH3COOH 0,2M v nc ct cha trong burette, pha cc
DD sau trogn 6 bnh nn c nt nhm :
 Bnh 1 2 3 4 5 6
CH3COOH 50 40 30 20 10 5
(ml)
Nc ct 0 10 20 30 40 45
(ml)
- Lc u cc bnh va pha
- Cn 6 mu than hot tnh trong cc da nha, mi mu 1g.
- Cho vo mi bnh cha DD CH3COOH mt mu than, y nt, lc mnh
trong vi pht. yn 10 pht ri lc mnh vi pht. yn 30 pht. Xong em
lc. Ghi nhit TN. Nc qua lc nh phn bng DD NaOH 0,1 N vi ch th
phenolphtalein.
Vi bnh 1, 2, 3 nh phn 3 ln, mi ln dng 5ml mc qua lc
Bnh 4,5 3 ln, mi ln dng 10 ml
6 2 ln, mi ln dng 20 ml
3- Kt qu
a) Kt qu th : lp thnh bng ghi cc gi tr thu c khi nh phn bng dung
dch NaOH

Th tch NaOH V trung

Nhit (
Bnh o ( ml) bnh
C)
Ln 1 Ln 2 Ln 3
1 31 8.6 8.5 8.75 8.6167
2 31 7 6.9 6.75 6.8833
3 30.5 5.1 5.1 5.2 5.1333
4 30 6.6 6.7 6.55 6.617
5 30 2.95 3.2 3 3.0500
6 31 2.5 2.45 2.6 2.5167

a) Kt qu tnh: ghi theo bng

no(mol)
Bnh Co (mol/l C (mol/l) Ln C (mol/c ln C/
m2)
1 0.01 0.2 0.1723 -1.758 0.0091 - 18.85
 4.695
4 28 8
-
2 0.0073 4.918 18.82
0.008 0.16 0.1377 -1.983 1 28 8
-
3 0.0054 5.205 18.71
0.006 0.12 0.1027 -2.276 9 43 2
-
4 0.0033 5.702 19.82
0.004 0.08 0.066 -2.716 4 28 0
-
5 0.0017 6.380 17.99
0.002 0.04 0.031 -3.490 0 07 4
-
6 0.0007 7.197 16.81
0.001 0.02 0.013 -4.375 5 66 5

dd ban u l CH3COOH 0.2M

Bnh 1 cha 50ml dd CH3COOH ,t suy ra s mol CH3COOH cha trong bnh 1
l: no1=0.2*0.05=0.01(mol);
Tng t:
no2= 0.2*0.04=0.008 ; no3=0.2*0.03=0.006(mol); no4=0.2*0.02=0.004(mol);
no5=0.2*0.001=0.002(mol); no6=0.2*0.005=0.001(mol);
tnh C0
C01; C02; C03 =n01;02;03/5ml
C04;C05=n0/10ml; c06=n06/20ml
Tnh hp ph:
=s mol cht b hp ph trn 1 g cht hp ph rn
Hay hp ph T = s mol u - s mol sau khi hp ph
=n01-nNaOH; tnh tng t hp ph ca bnh 2,3,4,5,6
Vi: n NaOH= (0.1x Vtb)
C= nCH3COOH/ V CH3COOH
Bnh 1 2 3 4 5 6
Th
tch 0.005 0.005 0.005 0.01 0.01 0.02
Cm 0.1723 0.1377 0.1027 0.066 0.031 0.013

C1=nNaOH/V1=0.1*Vtb1/0.005=0.1*8.6167/0.005=0.1723
Tnh tng t cho nhng bnh khc
Dng phng php bnh phng cc tiu vit phng trnh cc ng
biu din :
- V th ln lnC suy ra hng s k, 1/n

T th trn ta suy ra :
1/n= 0.955
ln k= -3.035
k= 0.048075
- V th C / theo C suy ra k,

1/T = 10.86
T =0.09208
k =10.86*1/17.09=0.635459
 So = . N . Ao ( m2/g)=0.09208*6.023*10^23*20.5=1.13694E+24(m2/g)
Vi : = 0.09208
Ao = 20.5
N s Avogadro = 6,023.10^23
Nhn xt: biu th ln theo lnC c chnh xc cao hn ( R2=0.9998) V th ng
ng nhit Freundlich ph hp hn. Vy phng trnh ph hp vi qu trnh hp ph
acid acetic bng than hot tnh l phng trnh ln T theo lnC.
 BI S 3
TNH TAN HN CH CA CHT LNG
NHM: 3 Th 3, ngy 05, thng 04, nm 2016
Mao c Huy.
Nguyn Duy Khnh.
Tm tt:

I. Gii thiu.

II. Phng php thc nghim.

1. Xy dng ging tn tan ca h Phenol nc.

Bc 1: Cho nc v phenol vo 6 ng nghim nu phenol dng rn phi nhng l phenol

vo cc nc nng khong 40-50oC cho phenol chy. (Tuyt i khng un trc tip
phenol trn bp v bng phenol rt nguy him.)
Bc 2: Ly ln lt vo 6 ng nghim c nh s t 1 n 6 cc hn hp c thnh phn
xc nh. ( bi ging thc hnh ha l,trang 40)
Bc 3: Nhng ng nghim 1 vo cc nc un nng, khuy nh v u tay, quan st s
thay i nhit v s bin i ca hn hp, ghi nhit khi h bt u trong sut T1.
Bc 4: Kim tra kt qu bng cch ly ng nghim ra, khuy nh, quan st nhit v
hin tng, ghi nhit khi hn hp xut hin vt c T 2, (2 nhit T1 v T2 chnh nhau
khng qu 1oc th chp nhn, nu qu th lm li, gi tr trung bnh 2 nhit chnh l
nhit ti c cn bng ng th v d th)
Bc 5: Tin hnh tng t vi cc ng nghim khc. (Mi ng nghim lm 3 ln.)

STT Nhit oC Ttb = (T1 + T2 + T3)/3

Ln T1 T2 T= (T1 + T2)/2
1 90 1
2
3
2 85 1
2
 3
3 75 1
2
3
4 50 1
2
3
5 40 1
2
3
6 30 1
2
3

Bc 6: v ging s ph thuc ca nhit ha tan hon ton phenol v nc vo thnh phn

hn hp v tm nhit ha tan ti hn km nhn xt.

2. Xy dng ging ha tan tng h ca h nc axit axetic cloroform.

2.1. Xy dng ging ha tan tng h ca h nc - axit axetic

Bc 1: Cho cloroform, axit axetic v nc ln lt vo 3 buret c 50 ml (hoc 25 ml). Ly vo 4
bnh nn c nt nhm c 100 ml nhng hn hp c thnh phn nh sau:

Cht/ bnh. 1 2 3 4
Nc (ml) 9 7.5 6 4
Axit axetic (ml) 1 2.5 4 6

Bc 2: y np bnh li, lc cho hn hp trn u vi nhau.

Bc 3: Ly cloroform vo microburet. (Cho cloroform xung tng git mt. Mi ln c mt git
ri xung li y np li, lc cho tan ht.)
Bc 4: Tip tc n khi bt u thong thy xut hin c (khng nn cho qu n ni cht lng
tch thnh lp). Ghi ly lng cloroform thm vo.
Nh vy ta xc nh c mt im thc nghim trn ng cong tnh tan.

Bc 5: Tin hnh vi 3 bnh cn li. (nhm xc nh c thm 4 im na trn gin ).

II.2. Xy dng ging ha tan tng h ca h axit axetic cloroform.

Bc 1: Ly vo 4 bnh nn nhm c 100 ml cc hn hp c thnh phn sau:
Cht/ bnh. 5 6 7 8
 Axit axetic (ml) 1 2.5 4 6
Cloroform (ml) 9 7.5 6 4

Bc 2: y np, lc u cc bnh, dng microburet thm nc vo tng git mt, y nt, lc

cho tan ht, tip tc n khi thong c.Ghi ly lng nc cho vo.
Bc 3: Tin hnh vi 4 bnh. (nhm xc nh c thm 4 im na trn gin tnh tan).

Phng php tnh ton:

Bc 1: tin hnh i tt c ml ra s gam theo cng thc: m = d * v
Trong :
m : l gam dung dch. (g).
d : khi lng ring (g/cm3 ); dH2O = 1.00; dCH3COOH = 1.05; dCH3Cl = 1.48.
v : th tch dung dch (ml).
Bc 2: tnh thnh phn phn trm theo khi lng ca 3 cht trong hn hp tng ng. ( in kt
qu vo bng)

STT bnh Nc Axit axetic Cloroform

1
2
3
4
5
6
7
8

Bc 3: V ging tan tng h ca h 3 cu t.

III. KT QU V THO LUN.

IV. KT LUN.