LVN VN BN K THUT O LNG VIT NAM

LVN 274 : 2014

PHNG TIN O DN IN
QUY TRNH KIM NH

Electrolytic conductivity meters Verification procedure

H NI 2014

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LVN 274 : 2014

Li ni u:

LVN 274 : 2014 do Ban k thut o lng TC 17 Phng tin o Ho l bin

son. Vin o lng Vit Nam ngh, Tng cc Tiu chun o lng Cht lng
ban hnh.

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VN BN K THUT O LNG VIT NAM LVN 274 : 2014

Phng tin o dn in - Quy trnh kim nh

Electrolytic conductivity meters Verification procedure

1 Phm vi p dng
Vn bn k thut ny quy nh quy trnh kim nh ban u, kim nh nh k v kim
nh sau s a ch a phng tin o dn in c a cht l ng c phm vi o (0 500)
mS/cm v sai s ln nht cho php 5 % (gi tr c).

2 Gii thch t ng
Cc t ng trong vn bn ny c hiu nh sau:
2.1 : l kh nng c a mi trng nc cho php s di
chuyn c a cc ht in tch qua n khi c l c tc ng vo cc ht nh l c tnh
in c a in trng. S di chuyn ny to thnh dng in v c ch c a chuyn
ng ny ty thuc vo vt cht. dn in l nghch o c a in tr (Ohm).
2.2 Du u (s u u u :
l loi cht chun c ch ng nhn th l ng c dn in c nh.
2.3 v o:
- dn in:
1/Ohm = 1 Siemen (S) = 1.000 mili Siemen (mS) = 1.000.000 micro Siemen (S).
- dn in ring:
S/m; S/cm ; mS/cm; S/cm.

3 Cc php kim nh
Phi ln lt tin hnh cc php kim tra ghi trong bng 1.

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LVN 274 : 2014

Bng 1

Theo iu Ch kim nh
TT Tn php kim nh mc ca Sau
QTK Ban u nh k
s a cha
1 Kim tra bn ngoi. 7.1 + + +
2 Kim tra k thut. 7.2 + + +
3 Kim tra o lng. 7.3
3.2 - Kim tra sai s. 7.3.2 + + +
3.3 - Kim tra lp li. 7.3.3 + + +
3.4 - Kim tra n nh theo thi 7.3.4
+ + +
gian ( tri).

4 Phng tin kim nh

Phng tin kim nh c ghi trong bng 2.
Bng 2
p dng cho
Tn phng tin
TT c trng k thut o lng c bn iu mc ca
kim nh
quy trnh
(1) (2) (3) (4)
1 Chun o lng
- Cc gi tr chun: (0 500) mS/cm
ti nhit (25 0,01) C;
Dung dch chun 7.3.2; 7.3.3;
dn in - khng m bo o khng ln 7.3.4
hn sai s ln nht cho php c a
phng tin o dn in.
2 Phng tin o khc

Phng tin o - Phm vi o: (0 20) S/cm;

2.1 6
dn in. - chnh c: 0,5 %.
- Phm vi o: (0 50) C;
2.2 B n nhit. 7.3
- chnh xc: 0,01 C.
- Phm vi o: (0 50) C;
2.3 Thit b o nhit . 7.3
- chnh c: 0,01 C.
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 LVN 274 : 2014

(1) (2) (3) (4)

- Nhit : (0 50) oC;
Phng tin o nhit Gi tr chia: 1 oC;
2.4 v m mi 5
trng. - m khng kh: (25 95) %RH;
Gi tr chia: 1 %RH.
3 Phng tin ph
- C gi tr in dn nh hn 2 S/cm
3.1 Nc ct. 7
ti (25 0,01) C.
3.2 Bnh t tia. 7
3.3 Giy thm. 7

5 iu kin kim nh
Khi tin hnh kim nh, phi m bo cc iu kin sau y:
- Nhit : (25 5) oC;
- m khng kh: 80 %RH (khng ng sng).

6 Chun b kim nh
Trc khi tin hnh kim nh phi th c hin cc cng vic chun b sau y.
- Chn cc im kim nh tng ng vi cc dung dch chun c gi tr danh nh
nh bng 3.
Bng 3
TT Phm vi o Dung dch chun la chn

Nc ct hoc dung dch chun

1 (0 20) S/cm.
c dn in 2 S/cm; 10 S/cm.

2 (0 200) S/cm. 10 S/cm; 84 S/cm; 147 S/cm.

3 (0 2000) S/cm. 147S/cm; 1000 S/cm; 1413 S/cm.

4 (0 20) mS/cm. 1,41 mS/cm; 8,00 mS/cm; 12,88 mS/cm.

5 (0 500) mS/cm. 1,41 mS/cm; 12,88 mS/cm; 111,3 mS/cm.

- Dung dch chun c gi n nhit ti (25 0,01) C bng b n nhit.

- Trc khi tin hnh kim nh, u o c a phng tin o dn in (sau y gi
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LVN 274 : 2014

tt l PT) phi c lm sch vi dung mi thch hp tu thuc vo vt liu ch to

u o, theo hng dn c a nh sn ut ghi trong ti liu k thut, sau r a li bng
nc ct.

7 Tin hnh kim nh

7.1 Kim tra bn ngoi
Phi kim tra bn ngoi theo cc yu cu sau y:
Kim tra bng mt c nh s ph hp c a PT vi cc yu cu quy nh trong ti
liu k thut v hnh dng, kch thc, hin th, ngun in s dng, nhn hiu v ph
kin km theo.
7.2 Kim tra k thut
Phi kim tra k thut theo cc yu cu sau y :
Kim tra trng thi hot ng bnh thng v c cu chnh c a PT theo ti liu k
thut.
7.3 Kim tra o lng
Phng tin o dn in c kim tra o lng theo trnh t ni dung, phng
php v yu cu sau y:
7.3.1 Phng php kim nh phng tin o dn in l so snh kt qu o tr c
tip gi tr dn in c a dung dch chun bng PT v gi tr dn in c
ch ng nhn c a dung dch chun ti nhit (25 0,01) C.
7.3.2 Kim tra sai s
- Ti m i im kim nh, u o c a PT phi c trng ti thiu 03 ln v
ngm 10 ph t trong dung dch chun tng ng.
- Ti m i im kim nh, o ti thiu 03 ln lin tip bng PT. Ghi kt qu o
c vo bin bn ph lc 1.
- Sai s c a m i php o c tnh theo cng th c sau:
C Cch
100
Cch

Tro :
- Sai s tng i, % ;
C - Gi tr c c a PT, S/cm hay mS/cm;
Cch - Gi tr dn in c ch ng nhn c a dung dch chun, S/cm hay
mS/cm.
- Sai s khng c ln hn sai s cho php c a PT.

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 LVN 274 : 2014

7.3.3 Kim tra lp li.

- Chn 01 dung dch chun nh trong mc 6 tin hnh kim tra lp li.
- Dng PT o ti thiu 05 ln lin tip c nh nng dung dch chun
chn. Ghi kt qu vo bin bn kim nh ph lc 1.
- lp li c tnh theo lch chun s theo cng th c sau:

Y
n
2
i Y
s i 1

n 1
Tro :
n s ln o;
Yi gi tr o th i;
Y- gi tr o trung bnh.
- lch chun s khng c ln hn 1/3 sai s cho php c a PT.
7.3.4 Kim tra n nh theo thi gian ( tri).
- Chn dung dch chun nh mc 7.3.3.
- Dng PT o 03 ln dung dch chun chn, m i ln cch nhau 02 gi. Ghi kt
qu vo bin bn kim nh ph lc 1.
- Sai lch gi a cc kt qu o so vi php o u tin khng c ln hn sai s cho
php c a PT.

8 X l chung
8.1 Phng tin o dn in sau khi kim nh nu t cc yu cu quy nh theo
quy trnh kim nh ny c nim phong c cu chnh v cp ch ng ch kim nh
(tem kim nh, du kim nh, giy ch ng nhn kim nh ...) theo quy nh.
8.2 Phng tin o dn in sau khi kim nh nu khng t mt trong cc yu cu
quy nh c a quy trnh kim nh ny th khng cp ch ng ch kim nh mi v a
du kim nh c (nu c).
8.3 Chu k kim nh c a phng tin o dn in: 12 thng.

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 Ph lc 1
Tn c quan kim nh
..
BIN BN KIM NH
S:

Tn phng tin o: .
Kiu: .S:..
C s sn sut: ..Nm sn ut:
c trng k thut:...
..
C s s dng:...
Phng php th c hin:.
Chun, thit b chnh c s dng:..
iu kin mi trng:...
Ngi th c hin: Ngy th c hin:.........
a im th c hin:...
KT QU
1. Kim tra bn ngoi: t Khng t

2. Kim tra k thut: t Khng t

3. Kim tra o lng:

- Kim tra sai s:

Dung dch chun Kt qu o Sai s Kt

TT Sai s
(............) (............) cho php lun

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 3

- Kim tra lp li:

Gi tr chun: . . . . . . . . . .
STT Kt qu o lch chun
lch chun
(.............) cho php
1
2
3
4
5
Kt lun:
- Kim tra n nh theo thi gian ( tri):

Gi tr chun: . . . . . . . . . .
STT Sai s vi php
Thi gian o Kt qu o Sai s cho php
o u tin
1
2
3
Kt lun:

4 Kt lun: .............................................................................................................
.............................................................................................................

Ngi sot li Kim nh vin

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 TI LIU THAM KHO

LU T O L NG nm 2011.

LVN 113 : 2003

Yu cu v ni dung v cch trnh by vn bn k thut o lng Vit Nam.

TCVN 6165 : 2009 (ISO/IEC GUIDE 99 : 2007)

T v ng quc t v o lng hc khi nim, thut ng chung v c bn (VIM).

OIML R 56 - 1981
Standard solutions reproducing the conductivity of electrolytes.

OIML R 68 - 1985
Calibration method for conductivity cells.

IUPAC TECHNICAL REPORT nm 2001

Molality-based primary standards of electrolytic conductivity.

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