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CHEMISTRY
PART-A
SECTION1
Single Correct Questions
Section 1 contains 30 Single Correct Questions out of which only one option is correct
1. In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti Markovnikov
addition to alkenes because
(A) both are highly ionic
(B) one is oxidising and the other is reducing
(C) one of the steps is endothermic in both the cases
(D) all the steps are exothermic in both the cases
(A) 2 > 1 > 3 > 4 (B) 1 > 3 > 2 > 4 (C) 3 > 1 > 2 > 4 (D) 1 > 2 > 3 > 4
3. The compound that will react most readily with NaOH to form methanol is:
+ - + -
(A) (CH3)4N I (B) CH3OH (C) (CH3)3S I (D) (CH3)3 CCl
4. The number of isomers for the compound with molecular formula C2BrClFl is:
(A) 3 (B) 4 (C) 5 (D) 6
6. In a solid AB having the NaCl structure, A atoms occupy the corners of the cubic unit cell. If all the
face-centered atoms along one of the axes are removed, then the resultant stoichiometry of the solid is-
(A) AB2 (B) A2B (C) A4B3 (D) A3B4
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7. The wavelength associated with a golf ball weighing 200 g and moving at a speed of 5 m/hr is of the
order.
-10 -20 -30 -40
(A) 10 m (B) 10 m (C) 10 m (D) 10 m
8. The quantum numbers +1/2 and -1/2 for the electron spin represent:
(A) rotation of the electron in clockwise and anticlockwise direction respectively
(B) rotation of the electron in anticlockwise and clockwise direction respectively
(C) magnetic moment of the electron pointing up and down respectively
(D) two quantum mechanical spin states which have no classical analogue
10. The root mean square velocity of an ideal gas at constant pressure varies with density (d)
(C) d (D) 1 / d
2
(A) d (B) d
The reaction 3ClO (aq) ClO3 (aq) + 2Cl (aq), is an example of:
- - -
11.
(A) oxidation reaction (B) reduction reaction
(C) disproportionation reaction (D) decomposition reaction
13. The aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH
required to completely neutralize 10 mL of this solution is
(A) 40 mL (B) 20 mL (C) 10 mL (D) 4 mL
14. The number of S-S bonds in sulphur trioxide trimer (S3O9) is:
(A) three (B) two (C) one (D) zero
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- +
16. The common features among the species CN , CO ad NO are:
(A) bond order three and isoelectronic (B) bond order three and weak field ligands
(C) bond order two and -acceptors (D) isoelectronic and weak field ligands
17. A mixture of benzaldehyde and formaldehyde on heating with aqueous NaOH solution gives
(A) benzyl alcohol and sodium formate (B) sodium benzoate and methyl alcohol
(C) sodium benzoate and sodium formate (D) benzyl alcohol and methyl alcohol
19.
Me H Me
C
C
H
C
Me H
Hydrogenation of the above compound in the presence of poisoned palladium catalyst gives
(A) an optically active compound (B) an optically inactive compound
(C) a racemic mixture (D) a diastereomeric mixture
20. The reaction of propene with HOCl process via the addition of
+ +
(A) H in the first step (B) Cl in the first step
- + -
(C) OH in the first step (D) Cl and OH in a single step
22. In the standardization of K2Cr2O7 by iodometry, the equivalent weight of K2Cr2O7 is-
(A) (molecular weight)/2 (B) (molecular weight)/6
(C) (molecular weight)/3 (D) same as molecular weight
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23. The complex ion which has no d electron in the central metal atom is-
- 3+ 3- 3+
(A) [MnO4] (B) [Co(NH3)] (C) [Fe(CN)6] (D) [Cr(H2O)6]
24. The set representing the correct order of first ionization potential is-
(A) K > Na > Li (B) Be > Mg > Ca (C) B > C > N (D) Ge > Si > C
2-
25. The correct order of hybridization of the central atom is the following species NH 3, [PtCl4] , PCl5 and
BCl3 is-
2 3 2 3 3 2 3 2
(A) dsp , dsp , sp and sp (B) sp , dsp , sp d and sp
2 2 3 3 2 3 2 3
(C) dsp , sp , sp and dsp (D) dsp , sp , sp and dsp
26. For a sparingly soluble salt ApBq, the relationship of its solubility product (Ls) with its solubility (S) is:
(A) Ls = S p q (B) Ls = S p q (C) Ls = S p q (D) Ls = S (pq)
p+q p q p+q q p pq p q pq p+q
28. The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and KCl is:
(A) LiCl > NaCl > KCl (B) KCl > NaCl > LiCl
(C) NaCl > KCl > LiCl (D) LiCl > KCl > NaCl
29. If I is intensity of absorbed light and C is the concentration of AB for the photochemical process AB +
hv AB, the rate of formation of AB is directly proportional to-
2
(A) C (B) I (C) I (D) C.I
30. At constant temperature, the equilibrium constant (Kp) for the decomposition reaction N2O4 2NO2
2 2
is expressed by Kp = (4x p)/(1 x ), where P = pressure, x = extent of decomposition. Which one
following statements is true?
(A) Kp increases with increase of P (B) Kp increases with increase of x
(C) Kp increases with increase of x (D) Kp remains constant with change in P and x
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PHYSICS
PART-A
SECTION2
Single Correct Questions
Section 1 contains 30 Single Correct Questions out of which only one option is correct
1. A particle located at x = 0 at time t = 0, starts moving along the positive, x-direction with a velocity v
that varies as v = x. The displacement of the particle varies with time as:
1/2 3 2
(A) t (B) t (C) t (D) t
3. The minimum force (along the plane) required to start pushing a body up a rough (frictional coefficient )
inclined plane is F1 while the minimum force (along the plane) needed to prevent it from sliding down is
F2. If the inclined plane makes an angle from the horizontal such that tan = 2, the ratio F1/F2 is:
(A) 2 (B) 3 (C) 4 (D) 1
4. The upper half of an incline plane with inclination is perfectly smooth while the lower half is rough. A
body starting from rest at the top will again come to rest at the bottom if the coefficient of friction for the
lower half is given by
(A) 2 tan (B) tan (C) 2 sin (D) 2 cos
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1
6. A bullet loses of its speed as it passes through a plank. Number of such planks required to stop the
n
bullet are
n2 n
(A) n (B) (C) (D) n n
2n 1 n 1
7. An object of mass m is projected with a velocity u at an angle 45 with the horizontal. When the object
is at maximum height, its angular momentum about the point of projection is
mu2 mu2 mu3 mu u
(A) (B) (C) (D)
g 2g 4 2g 2g
8. A solid sphere of mass M, radius R and having moment of inertia about an axis passing through the
centre of mass as I, is recast into a disc of thickness t, whose moment of inertia about an axis passing
through its edge and perpendicular to its plane remains I. Then, radius of the disc will be
2R 2 4R R
(A) (B) R (C) (D)
15 15 15 4
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10. The earth moves in an elliptical orbit with the sun S at one of foci D
as shown in figure. Its kinetic energy is maximum at the point:
(A) A (B) B
A C
(C) C (D) D Earth Sun
B
11. In YDSE value of , for which the phase difference at P is 1.57 radian, is
(A) sin1 (B) sin1 P
4d 2d
d
(C) sin1 (D) sin1 O
d 3d
12. The work done in moving an electron of charge e and mass m from A to B
B along the circular path of radius r shown by arrow in the vertical plane
in the field of charge Q is
(A) 2mgr (B) 2Qe/r
2Qe +Q
(C) 2mgr + (D) zero
r
13. The potential at a point x (measured in m) due to some charges situated on the x-axis is given by
2
V(x) = 20/(x 4) volts
The electric field E at x = 4 m is given by
(A) 160 volt/m and in the +ve x-direction
(B) 480 volt/m and in the -ve x-direction
(C) 480 volt/m and in the +ve x-direction
(D) 160 volt/m and in the -ve x-direction
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16. A wire is bent at a parabolic curve and kept in the xy-plane. The y(m)
2
curve can be described by the equation x = 6y. The wire carries
a current i = 25/12 A. If a uniform magnetic field B 2 103 k 6
tesla is applied, force experienced by the wire is nearly
i
(A) 1.5 jN (B) 1.5 jN
(C) 0.05 jN (D) 2.5 jN x(m)
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19. The kinetic energy of the most energetic photoelectrons emitted from a metal surface is doubled when
the wavelength of the incident radiation is reduced from 1 to 2. The work function of the metal is
hc hc
(A) (2 2 1 ) (B) (21 2 )
1 2 1 2
hc hc
(C) (1 2 ) (D) (1 2 )
1 2 1 2
nd
20. The ratio of the de-Broglie wavelength of the electron in the 2 excited state of hydrogen atom and the
st 2+
1 excited state of Li ion is
3 9 7 1
(A) (B) (C) (D)
2 2 2 2
21. The output current versus time curve of a rectifier is shown in figure.
The average value of output in this case is
Current
(A) 0
(B) I0 / 2
(C) 2I0 /
(D) I0
I0
Time
22. An observer moves towards a stationary source of sound, with a velocity one-fifth of the velocity of
sound. What is the percentage increase in the apparent frequency?
(A) zero (B) 0.5% (C) 5% (D) 20%
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23. A cylinder vessel filled with water upto the height H becomes empty in time t0 due to a small hole at the
bottom of the vessel. If water is filled in the same vessel to a height 4H it will flow out in time
(A) 8t0 (B) 4t0 (C) 2t0 (D) t0
24. Two spheres of the same material have radii 1 m and 4 m and temperatures 4000 K and 2000 K
respectively. The ratio of the energy radiated per second by the first sphere to that by the second is
(A) 1 : 1 (B) 16 : 1 (C) 4 : 1 (D) 1 : 9
T 4T
T
26. A 40kg slab rests on a frictionless floor. A 10kg block rests on top
of the slab. The static coefficient of friction between the block and 100N Block
10 kg
the slab is 0.70 while the kinetic coefficient is 0.50. The 10 kg block
is acted upon by a horizontal force of 100N, the resulting 40kg Slab
acceleration of the slab will be
2 2
(A) 1.00 m/s (B) 1.25 m/s
2 2
(C) 1.75 m/s (D) 2.00m/s
27. A sealed tank of length and height h completely filled by liquid of density moves with horizontal
accelerations a. The maximum difference in pressure between any two points is the liquids
(A) gh
(B) g
(C) (gh + a)
(D) all points in the liquid are at the same pressure
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28. Two rods of lengths L1 and L2 are made of materials whose coefficients of linear expansion are 1
and 2 . If the difference between their lengths is independent of temperature, then
L1 1 L1 2
(A) (B)
L2 2 L2 1
(C) L11 L2 2 (D) L11 L22
2 2 2 2
29. A block is resting over a smooth horizontal plane. A constant horizontal force starts acting on it at
t = 0. Which of the following graph is correct?
Power
KE KE KE
0 t 0 t 0 Displacement 0 Displacement
(A) (B) (C) (D)
30. A semi conducting device is connected in a series circuit with a battery and a resistance. A current is
found to pass through the circuit. If the polarity of the battery is reversed, the current drops to almost
zero. The device may
(A) a p-n junction (B) an intrinsic semiconductor
(C) a p-type semiconductor (D) an n-type semiconductor
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MATHEMATICS
PART-A
SECTION3
Single Correct Questions
Section 1 contains 30 Single Correct Questions out of which only one option is correct
2
4. A complex number z satisfies the equation z 2iz 2c (1 i ) 0 , where c is real. The values of c for
which the above equation has a solution is
(A) c ( 1 2) (B) c 1 2 1 2
(C) c ( 1 2 ) (D) c R
2
5. If the ratio of the roots of lx + nx + n = 0 is p : q, then
q p l p q n
(A) 0 (B) 0
p q n q p l
q p l p q n
(C) 1 (D) 1
p q n q p l
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1 2 1
A 1 1 2
6. If , then det. (adj (adj A)) is
2 1 1
4 3 2 1
(A) (14) (B) (14) (C) (14) (D) (14)
8. The sum of the digits in the unit place of all the numbers formed with the help of 3, 4, 5, 6 taken all at a
times is
(A) 432 (B) 108 (C) 36 (D) 18
9. The number of ways in which a committee of 5 can be chosen from 10 candidates so as to exclude the
youngest if it includes the oldest, is
(A) 196 (B) 178 (C) 202 (D) None of these
10
1
The 7 term in y 2 , when expanded in descending power of y, is
th
10.
y
210 y2 2
(A) (B) (C) 210y (D) None of these
y2 210
11. The sum of all natural numbers less than 200, that are divisible neither by 3 nor by 5, is
(A) 10730 (B) 10732 (C) 15375 (D) None of these
2
12. The sum to n terms of the sequence log a, log ar, log ar , ..... is
n 3n
(A) loga2r n1 (B) n log a2 r n1 (C) log a2 r n1 (D) None of these
2 2
13. Let Sn denotes the sum of n terms of an A.P. whose first term is a. If the common difference
d = Sn k Sn-1 + Sn-2 then k =
(A) 1 (B) 2 (C) 3 (D) None of these
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3
x 2 23 x 1
14. lim is equal to
x 1 (x 1)2
1 1 1
(A) (B) (C) (D) None of these
9 6 3
x(e1/ x e 1/ x )
,
15. The function f(x) = e1/ x e 1/ x x 0 is
0 , x0
(A) continuous everywhere but not differentiable at x = 0
(B) continuous and differentiable everywhere
(C) not continuous at x = 0
(D) none of these
du
16. If u = f(x3 ),v g(x 2 ),f '(x) cos x and g(x) = sin x, then
dv
1 3
(A) x cos x3 cosecx2 (B) x cos x3 cosecx2
2 2
3
(C) x sec x3 cosecx2 (D) None of these
2
2 e4
2
e dx a , the value of
x
18. Given ln(x) dx is
1 e
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20. Let P (2, 0) and Q(0, 2) be two points and O be the origin. If A (x, y) is a point such that xy > 0 and x + y
< 2, then
(A) A cannot be inside the OPQ
(B) A lies outside the OPQ
(C) A lies either inside OPQ or in the third quadrant
(D) none of these
21. If (, ) is a point on the chord PQ of the circle x2 y2 25 , where the coordinates of P and Q are (3, -
4) and (4, 3) respectively, then
(A) [3, 4], [-4, 3] (B) [-4, 3], [3, 4]
(C) [3, 3], [-4, 4] (D) None of these
22. Equation of the parabola whose vertex is (-3, -2), axis is horizontal and which passes through the point
(1, 2) is
(A) y2 4y 4x 8 0 (B) y2 4y 4x 8 0
(C) y2 4y 4x 8 0 (D) None of these
23. ABCD is parallelogram. If L and M are the middle points of BC and CD, then AL AM
1 3
(A) AC (B) AC (C) AC (D) None of these
2 2
24. If a b c 0 and | a | = 3, | b | = 5, | c | = 7, then the angle between a and b is:
(A) (B) (C) (D)
2 3 4 6
25. The direction ratios of a normal to the plane through (1, 0, 0), (0, 1, 0), which makes an angle of with
4
the plane x + y = 3 are
(A) 1, 2,1 (B) 1,1, 2 (C) 1, 1, 2 (D) 2, 1, 1
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26. The equation of the plane perpendicular to the yz-plane and passing through the points (1, -2, 4) and (3,
-4, 5) is
(A) y + 2z = 5 (B) 2y + z = 5 (C) y + 2z = 6 (D) 2y + z = 6
27. A man alternately tosses a coin and throws a dice beginning with the coin. The probability that he gets a
head before he gets 5 or 6 in the dice is
3 1 1
(A) (B) (C) (D) None of these
4 2 3
28. The probabilities of three events A, B and C are P(A) = 0.6, P(B) = 0.4 and P(C) = 0.5. If P(A B) = 0.8,
P(A C) = 0.3, P(A B C) = 0.2 and P(A B C) 0.85, then
(A) 0.2 P(B C) 0.35 (B) 0.5 P(B C) 0.85
(C) 0.1 P(B C) 0.35 (D) None of these
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CHEMISTRY
1 2 3 4 5 6 7 8 9 10
C B A D C D C D A D
11 12 13 14 15 16 17 18 19 20
C A A D B A A B B B
21 22 23 24 25 26 27 28 29 30
C B A B B A C B B D
PHYSICS
1 2 3 4 5 6 7 8 9 10
C A B A C B C A D A
11 12 13 14 15 16 17 18 19 20
A A D A C C C C A B
21 22 23 24 25 26 27 28 29 30
C D C A A B C B C A
MATHEMATICS
1 2 3 4 5 6 7 8 9 10
A C D B B A C B A C
11 12 13 14 15 16 17 18 19 20
B A B A A B B D A C
21 22 23 24 25 26 27 28 29 30
A C B B B C A A C D
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