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S GD T THI TH LN 1 THPT QUC GIA NM 2017

TNH VNH PHC Mn: KHOA HC T NHIN HA HC
Thi gian lm bi: 50 pht, khng k thi gian pht
( thi c 40 cu / 4 trang)
M : 303
Cho bit nguyn t khi ca cc nguyn t :
H =1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S =32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;

01
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.

oc
Cu 1: Khi thy phn hp cht hu c X (khng c phn ng trng bc) trong mi trng axit ri
trung ha axit th dung dch thu c c phn ng trng bc. X l:

H
A. Anehit axetic B. Ancol etylic C. Saccaroz D. Glixerol

ai
Cu 2: Cho kim loi Ba d vo dung dch Al 2(SO4)3, thu c sn phm c:

D
A. Mt cht kh v hai cht kt ta. B. Mt cht kh v khng cht kt ta.

hi
C. Mt cht kh v mt cht kt ta. D. Hn hp hai cht kh.
Cu 3: to thnh thy tinh hu c (plexiglat), ngi ta tin hnh trng hp:

nT
A. CH3-COO-C(CH3)=CH2 B. CH2=CH-CH=CH2
C. CH3-COO-CH=CH2 D. CH2=C(CH3)-COOCH3

uO
Cu 4: Hiu sut ca qu trnh iu ch anilin (C 6H5NH2) t benzen (C 6H6) t 30%. Khi lng
anilin thu c khi iu ch t 156 gam benzen l:

ie
A. 186,0 gam B. 111,6 gam C. 55,8 gam
iL D. 93,0 gam
Cu 5: Pht biu no sau y ng ?
Ta
A. Cc amino axit l cht rn iu kin thng.
B. Cc amin iu kin thng l cht kh hoc cht lng.
s/

C. Cc protein u dc tan trong nc.

up

D. Cc amin khng c.
Cu 6: phn bit cc dung dch: CaCl 2, HCl, Ca(OH)2 dng dung dch ?
ro

A. NaNO3 B. NaOH C. NaHCO3 D. NaCl

Cu 7: un nng tristearin trong dung dch NaOH thu c glixerol v ?
/g

A.C17H35COONa B. C17H33COONa C. C15H31COONa D. C17H31COONa

om

Cu 8: Nhng mt thanh st (d) vo 100ml dung dch CuSO 4 x mol/l. Sau khi cc phn ng xy ra
hon ton thy khi lng thanh st tng 0,4 gam. Bit tt c Cu sinh ra u bm vo thanh st. Gi
tr ca x l:
.c

A. 0,05 B. 0,5 C. 0,625 D. 0,0625

ok

Cu 9: ng phn ca glucoz l:
A. Xenluloz B. Fructoz C. Saccaroz D. Sobitol
bo

Cu 10: Cht no di y l etyl axetat ?

ce

A. CH3COOCH2CH3 B. CH3COOH
C. CH3COOCH3 D. CH3CH2COOCH3
.fa

Cu 11: un nng 5,18 gam metyl axetat vi 100ml dung dich NaOH 1M n phn ng hon ton.
C cn dung dch sau phn ng, thu c m gam cht rn khan. Gi tr ca m l:
w

A. 8,20 B. 6,94 C. 5,74 D. 6,28

w

Cu 12: Cht no sau y cn c gi l ng mt ong ?

w

A. Saccaroz B. Fructoz C. Glucoz D. Amilopectin

Cu 13: Ln men hon ton a gam glucoz, thu c C 2H5OH v CO2. Hp th ht CO 2 sinh ra vo
dung dch nc vi trong d, thu c 15 gam kt ta. Gi tr ca a l:
A. 30,6 B. 27,0 C. 15,3 D. 13,5
Cu 14: Mt phn t polieilen c khi lng phn t bng 56000u. H s polime ha ca phn t
polietylen ny l:

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A. 20000 B. 2000 C. 1500 D. 15000

Cu 15: Polime c cu trc mng li khng gian l:
A. Polietilen B. Poli(vinyl clorua) C. Amilopectin D. Nha bakelit
Cu 16: Cho dy cc dung dch sau: C 6H5NH2, NH2CH2COOH, HOOC[CH 2]2CH(NH2)COOH
C2H5NH2, NH2[CH2]2CH(NH2)COOH. S dung dch trong dy lm i mu qu tm ?
A. 4 B. 5 C. 2 D. 3
Cu 17: Cho cc cht sau: CH 3COOCH3, HCOOCH3, HCOOC6H5, CH3COOC2H5. Cht c nhit
si thp nht l:

01
A. HCOOC6H5 B. CH3COOC2H5 C. HCOOCH3 D. CH3COOCH3
Cu 18: Khng nh no sau y ng ?

oc
A. un nng tinh bt vi dung dch axit th xy ra phn ng khu mch polime.
B. Trng hp axit -amino caproic thu c nilon-6.

H
C. Polietilen l polime trng ngng.

ai
D. Cao su buna c phn ng cng.

D
Cu 19: Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c

hi
vi dung dch AgNO 3 ?
A. Fe, Ni, Sn B. Zn, Cu, Mg C. Hg, Na, Ca D. Al, Fe, CuO

nT
Cu 20: Pht biu no sau y ng ?

uO
A. Phn ng gia ancol vi axit cacboxylic c gi l phn ng x phng ha.
B. Phn ng x phng ha l phn ng thun nghch.
C. Trong cng thc ca este RCOOR, R c th l nguyn t H hoc gc hidrocacbon.

ie
D. Phn ng este ha l phn ng mt chiu. iL
Cu 21: Nhn xt no sau y ng ?
Ta
A. a s cc polime d ha tan trong cc dung mi thng thng.
B. a s cc polime khng c nhit nng chy xc nh.
s/

C. Cc polime u bn vng di tc ng ca axit, baz.

up

D. Cc polime d bay hi.

Cu 22: Trong cc cht di y, cht no l amin bc hai ?
ro

A. H2N(CH2)6NH2 B. CH3NHCH3
C. C6H5NH2 D. CH3CH(CH3)NH2
/g

Cu 23: Mt tripeptit X mch h c cu to t 3 amino axit l glyxin, alanin, valin. S cng thc
om

cu to ca X l:
A. 6 B. 3 C. 4 D. 8
.c

Cu 24: Cacbohidrat no sau y c dng lm nguyn liu sn xut t visco ?

A. Saccaroz B. Tinh bt C. Glucoz D. Xenluloz
ok

Cu 25: Ha tan hon ton 21,5 gam hn hp X gm Al, Zn, FeO, Cu(NO 3)2 cn dng ht 430 ml
dung dch H2SO4 1M thu c hn hp kh Y (ktc) gm 0,06 mol NO v 0,13 mol H 2, ng thi thu
bo

c dung dch Z ch cha cc mui sunfat trung ha. C cn dung dch Z thu c 56,9 gam mui
ce

khan. Thnh phn phn trm ca Al trong hn hp X c gi tr gn nht l:

A. 25,5% B. 18,5% C. 20,5% D. 22,5%
.fa

Cu 26: Ha tan m (g) hn hp X gm Al v Na c t l mol 1:2 vo nc d thu c 4,48 (l) kh

(ktc). G tr ca m l:
w

A. 7,3 B. 5,84 C. 6,15 D. 3,65

w

Cu 27 : Cho s chuyn ha sau :

w

0
t
(1) C4H6O2 (M) + NaOH (A) + (B)
0
t
(2) (B) + AgNO 3 + NH3 +H2O (F) + Ag + NH 4NO3
0
t
(3) (F) + NaOH (A) + NH3 + H 2O
Cht M l:

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A. HCOO(CH2)=CH2 B. CH3COOCH=CH2 C. HCOOCH=CHCH3 D. CH2=CHCOOCH3

Cu 28: Cho 2 hp cht hu c X, Y c cng cng thc phn t l C 3H7NO2 . Khi phn ng vi dung
dch NaOH, X to ra H 2NCH2COONa v cht hu c Z, cn Y to ra CH 2=CHCOONa v kh T. Cc
cht Z v T ln lt l:
A. CH3OH v NH3 B. CH3OH v CH3NH2
C. CH3NH2 v NH3 D. C2H3OH v N2
Cu 29: Cht hu c X c cng thc phn t C 3H9O2N. Cho 9,1 gam X tc dng vi dung dch
NaOH va . C cn dung dch sau phn ng thu c 6,8 gam cht rn khan. S cng thc cu to

01
ca X ph hp vi tnh cht trn l:
A. 1 B. 2 C. 3 D. 4

oc
Cu 30: Tin hnh cc th nghim sau:
(a) Cho Cu d vo dung dch Fe(NO 3)3.

H
(b) Sc kh CO 2 d vo dung dch NaOH.

ai
(c) Cho Na2CO3 d vo dung dch Ca(HCO 3)2.

D
(d) Cho bt Fe vo dung dch FeCl 3 d.

hi
S th nghim cui cng cn li dung dch cha 1 mui tan l:
A. 2 B. 1 C. 4 D. 3

nT
Cu 31: t chy hon ton 1 lng hn hp 2 este. Dn sn phm chy ln lt qua bnh (1) ng

uO
P2O5 d v bnh (2) ng dung dch Ca(OH) 2 d, thy khi lng bnh (1) tng 6,21 gam, cn bnh
(2) thi c 34,5 gam kt ta. Cc este trn thuc loi este no sau y ?
A. Este no, n chc, mch h B. Este khng no

ie
C. Este thm D. Este a chc
iL
Cu 32: t chy hon ton m gam hn hp X gm 2 este ng phn cn dng 4,704 lt kh O 2 , thu
Ta
c 4,032 lt CO 2 v 3,24 gam H2O. Nu cho m gam X tc dng ht vi 110 ml dung dch KOH 1M.
C cn dung dch sau ph ng th thu c 7,98 gam cht rn khan, trong c a mol mun Y v b
s/

mol mui Z (M Y > MZ ). Cc th tch kh u o iu kin chun. T l a : b l:

up

A. 2 : 3 B. 3 : 2 C. 2 : 1 D. 1 : 5
Cu 33: Thy phn m gam hn hp X gm 1 tetrapeptit A v 1 pentapeptit B (A v B u h cha
ro

ng thi Glyxin v Alanin trong phn t) bng 1 lng dung dch NaOH va . C cn dung dch
sn phm cho (m+ 15,8) gam hn hp mui. t chy ton b lng mui sinh ra bng 1 lng oxi
/g

va , thu c Na 2CO3 v hn hp hi Y gm CO2 , H2O v N2. Dn Y i qua bnh ng dung

om

dch NaOH c d, thy khi lng thy khi lng bnh tng thm 56,04 gam so vi ban u v c
4,928 lt kh duy nht (ktc) thot ra khi bnh. Xem nh N 2 khng b nc hp th , cc phn ng
.c

xy ra hon ton. Thnh phn phn trm khi lng ca B trong hn hp X l:

A.35,37% B. 58,92% C. 46,94% D. 50,92%
ok

Cu 34: Braikinin c tc dng lm gim huyt p, l mt nonapeptit c cng thc l:

Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Arg
bo

Khi thu phn khng hon ton peptit ny, thu c bao nhiu tripeptit m trong thnh phn c
ce

phenyl alanin (Phe) ?

A. 4 B. 3 C. 6 D. 5
.fa

Cu 35: Hn hp X gm metyl fomat, anehit acrylic v metyl acrylat. t chy hon ton m gam X
ri hp th ht sn phm chy vo dung dch Ca(OH) 2 d, thu c 9 gam kt ta v khi lng dung
w

dch gim 3,78 gam. Gi tr ca m l :

w

A. 1,95 B. 1,54 C. 1,22 D. 2,02

w

Cu 36: Poli(vinyl clorua) c iu ch t kh thin nhin (cha 95% metan v th tch) theo s
chuyn ho v hiu sut (H) nh sau :
H = 15% H = 95% H = 90%
Metan Axetilen Vinyl clorua Poli(vinyl clorua).
Th tch kh thin nhin (ktc) cn iu ch c 1 tn PVC l :
A. 5589,08 m3 B. 1470,81 m3 C. 5883,25 m3 D. 3883,24 m3

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Cu 37: Cho hn hp X gm hai cht hu c, no n chc, mch h (cha C, H, O) tc dng va

vi 20ml dung dch NaOH 2M thu c mt mui v mt ancol. un nng lng ancol thu c vi
axit H2SO4 c 170C thu c 0,015 mol anken (l cht kh iu kin thng). Nu t chy
lng X nh trn ri cho sn phm qua bnh ng CaO d th khi lng bnh tng 7,75 gam. Bit
cc phn ng xy ra hon ton. Pht biu no sau y ng ?
A. Khi lng ca cht c phn t khi ln hn trong X l 2,55 gam.
B. Tng phn t khi ca hai cht trong X l 164.
C. Thnh phn phn trm khi lng cc cht trong X l 49,5% v 50,5%.

01
D. Mt cht trong X c 3 cng thc cu to ph hp vi iu kin bi ton.
Cu 38: Sc 13,44 lt CO 2 (ktc) vo 200 ml dung dch X gm Ba(OH)2 1,5M v NaOH 1M. Sau

oc
phn ng thu c dung dch Y. Cho dung dch Y tc dng vi 200 ml dung dch hn hp BaCl 2
1,2M v KOH 1,5M thu c m gam kt ta. Gi tr ca m l:

H
A. 66,98 B. 39,4 C. 47,28 D. 59,1

ai
Cu 39: Cho cc pht biu sua :

D
(a) Hidro ho hon ton glucoz to ra axit gluconic

hi
(b) Phn ng thu phn xenluloz xy ra c trong d dy ca ng vt n c.
(c) Xenluloz trinitrat l nguyn liu sn xut t nhn to.

nT
(d) Saccaroz b ho en trong H 2SO4 c.

uO
(e) Trong cng nghip dc phm, saccaroz c dng pha ch thuc.
Trong cc pht biu trn, s pht biu ng l:
A. 3 B. 2 C. 4 D. 5

ie
Cu 40: Cht X c cng thc phn t C 2H7O3N. Khi cho X tc dng vi dung dch HCl hoc dung
iL
dch NaOH un nng nh u thy kh thot ra. Ly 0,1 mol X cho vo dung dch cha 0,25 mol
Ta
KOH. Sau phn ng c cn dung dch c cht rn Y, nung nng Y n khi lng khng i c
m gam cht rn. Gi tr ca m l:
s/

A. 16,6 B. 18,85 C. 17,25 D. 16,9

up
ro

----------HT----------
/g
om
.c
ok
bo
ce
.fa
w
w
w

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PHN TCH HNG DN GII CHI TIT

THI TH LN 1 S GD & T TNH VNH PHC M 303

Cu 1: Chn C.
- Thy phn saccaroz:
+H O
C12H22O11 C6H12O6 (glucoz) + C6H12O6 (fructoz)
2
H+

01
- Phn ng trng bc ca sn phm:
o
t
C6H12O6 + 2[Ag(NH3)2]OH CH2OH[CHOH]4COONH4 + 2Ag + 3NH3 + H2O

oc
Cu 2: Chn C.
- Th t phn ng xy ra nh sau:

H

Ba + 2H2O Ba(OH)2 + H2 (1)

ai
Ba(OH)2 + Al2(SO4)3
Al(OH)3 trng keo + BaSO4 trng (2)

D
hi
2Al(OH)3 + Ba(OH)2
Ba(AlO2)2 + 4H2O (3)
3BaSO4 + 2BaAlO2 + 4H 2
- Hay c th vit gn li: 5Bad + 4H 2O + Al 2 (SO4 )3

nT
Vy sn phm thu c c mt cht kh (H 2) v mt cht kt ta (BaSO 4).

uO
Cu 3: Chn D.
- Phng trnh phn ng:

ie
COOCH3

n CH2 C COOCH3 to, p, xt

iL CH2 C
Ta
n
CH3 CH3
s/

Cu 4: Chn C.
up

+ HNO +6H, t o
- Qu trnh phn ng: C 6 H 6
3
o C6 H 5 NO 2
Fe + HCl
C6 H 5 NH 2 , H = 30%
H 2SO 4 ,t
ro

156
- Ta c: nC6H 5NH 2 = nC6H 6 .H% = .0,3 = 0,6 mol mC6H6 = 55,8(g)
78
/g

Cu 5: Chn A.
om

A. ng, Cc amino axit u l cht rn iu kin thng.

B. Sai, Ch c -metyl, -imetyl, -trimetyl v etyl amin l cht kh iu kin thng.
C. Sai, Ch c cc dng protein hnh cu tan tt trong nc, cn protein dng si th hon ton khng
.c

tan trong nc.

ok

D. Sai, Hu ht cc amin u c.
Cu 6: Chn C.
bo

CaCl2 HCl Ca(OH)2

A. NaNO3 Khng phn ng Khng phn ng Khng phn ng
ce

B. NaOH Khng phn ng Khng hin tng Khng phn ng

C. NaHCO3 Khng phn ng Thot kh khng mu Kt ta trng
.fa

D. NaCl Khng phn ng Khng phn ng Khng phn ng

Cu 7: Chn A.
w

- Phn ng: (CH 3[CH2]16COO)3C3H5 + 3NaOH t0

3CH3[CH2]16COONa + C3H5(OH)3
w

Tristearin Natri sterat (X) Glixerol

w

Cu 8: Chn B.
TGKL Dm 0,4 0,05
nCu2+ = = = 0,05mol CM (CuSO4 ) = = 0,5M
DM Cu-Fe 8 0,1
Cu 9: Chn B.
Cu 10: Chn A.

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Cu 11: Chn B.
t0
- Phn ng: CH 3COOCH 3 + NaOH CH 3COONa+ CH 3OH
0,07mol 0,1mol 0,07mol

m rn khan = 40nNaOH(d ) + 82nCH 3COONa = 6,94(g)

Cu 12: Chn B.
- Saccaroz hay cn gi l ng ma, ng tht nt.
- Fructoz l thnh phn chnh ca mt ong (fructoz c ngt ln nht trong cc loi cacbohidrat).
- Glucoz hay cn gi l ng nho, ng tri cy.

01
- Amilopectin l mt on mch ca tinh bt.

oc
Cu 13: Chn D.
nCO2 nCaCO3
- Ta c: nglucoz = = = 0,075mol mglucoz = 0,075.180 = 13,5(g)

H
2 2

ai
Cu 14: Chn B.

D
56000
- Ta c: M ( -CH 2 -CH 2 )n = 56000 n = = 2000

hi
28
Cu 15: Chn D.

nT
- Cc polime mch phn nhnh thng gp l amilopectin v glicozen.
- Cc polime mch khng gian thng gp l cao su lu ha v nha rezit (nha bakelit).

uO
- Cc polime mch khng phn nhnh thng gp l cn li.
Cu 16: Chn D.

ie
- Cc amin c tnh baz nn c kh nng lm i mu qu tm chuyn thnh mu xanh tr anilin (v
iL
ng ng ca n) khng lm i mu qu tm do c tnh baz yu.
- i vi cc amino axit c dng (H 2N)x-R-(COOH)y th :
Ta
+ Nu x > y : qu tm chuyn sang mu xanh
+ Nu x = y : qu tm khng i mu.
s/

+ Nu x < y : qu tm chuyn sang mu .

up

Vy c 3 dung dch lm i mu qu tm l:
Dung dch HOOC[CH2]2CH(NH2)COOH C2H5NH2 NH2[CH2]2CH(NH2)COOH
ro

Mu qu tm Xanh Xanh
Cu 17: Chn C.
/g

Cc yu t nh hng n nhit si:

om

- Phn t khi: nu nh khng xt n nhng yu t khc, cht phn t khi cng ln th nhit si
cng cao.
.c

- Lin kt Hiro: nu hai cht c phn t khi xp x nhau th cht no c lin kt hiro s c nhit
si cao hn.
ok

- Cu to phn t: nu mch cng phn nhnh th nhit si cng thp.

Dy sp xp nhit si gim dn ca cc hp cht c nhm chc khc nhau v phn t khi xp x
bo

nhau:
ce

Axit > ancol > amin > este > xeton > anehit > dn xut halogen > ete > CxHy
Vy cht c nhit si thp nht l HCOOCH3.
.fa

Cu 18: Chn D.
A. Sai, un nng tinh bt vi dung dch axit th xy ra phn ng ct mch polime.
w

B. Sai, Trng hp axit -aminocaproic thu c nilon-6.

w

C. Sai, Polietilen l polime c iu ch t phn ng trng hp.

w

D. ng, Trong phn t cao su buna: ( CH 2 - CH = CH - CH 2 ) cn lin kt i C = C, nn c th

tham gia phn ng cng.
Cu 19: Chn A.
- Cc kim loi ng trc cp H +/H2 c th tc dng c vi HCl.
- Cc kim loi ng trc cp Ag +/Ag c th tc dng c vi AgNO 3.

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Vy cc kim loi va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO 3 l
Mg, Zn, Al, Fe, Ni v Sn.
Cu 20: Chn D.
A. Sai, Phn ng gia ancol vi axit cacboxylic c gi l phn ng este ha.
B. Sai, Phn ng x phng ha l phn ng mt chiu.
C. ng.
D. Sai, Phn ng este ha l phn ng thun nghch.
Cu 21: Chn B.
A. Sai, a s cc polime khng tan trong cc dung mi thng thng.

01
B. ng, Hu ht cc polime khng c nhit nng chy xc nh, nng chy nhit kh rng.

oc
C. Sai, Ly v d nh:

H
ai
D
hi
nT
uO
D. Sai, Cc polime khng bay hi.

ie
Cu 22: Chn B.
iL
- Bc ca amin c tnh bng s nguyn t H trong phn t aminoac b thay th bi gc
hidrocacbon do vy ch c CH 3NHCH3 l amin bc 2.
Ta
Cu 23: Chn A.
- C 6 cng thc cu to l:
s/

GlyAlaVal, GlyValAla, AlaGlyVal, AlaValGly, ValGlyAla, ValAlaGly.

up

Cu 24: Chn D.
- T visco c to thnh t phn ng gia xenluloz vi CS 2 v NaOH to thnh mt dung dch
ro

nht gi l visco. Bm dung dch ny qua nhng l rt nh ri ngm trong dung dch H 2SO4 to
/g

thnh t visco.
Cu 25: Chn C.
om

- Khi cho 21,5 gam X tc dng vi 0,43 mol H 2SO4 th :

BTKL m + 98n H 2SO 4 - 30n NO - 2n H 2 - m Z
n H 2O = X = 0, 26 mol
.c

18
ok

BT:H 2n - 2n H 2O - 2n H 2 n + + n NO
n NH 4+ = H 2SO 4 = 0,02 mol n Cu(NO3 ) 2 = NH 4 = 0, 04 mol
4 2
bo

2n H 2SO 4 - 10n NH 4 + - 4n NO - 2n H 2
- Ta c n O(trong X) = n FeO = = 0, 08 mol
ce

2
3n Al + 2n Zn = 3n NO + 2n H 2 + 8n NH 4 + = 0, 6 n Al = 0,16 mol

.fa

- Xt hn hp X ta c:
27n Al + 65n Zn = m X - 72n FeO - 188n Cu(NO3 ) 2 = 8, 22 n Zn = 0, 06 mol
w

27.0,16
%m Al = .100 = 20, 09
w

21,5
w

Cu 26: Chn B.
BT:e

3nAl + nNa = 2nH 2 3x + 2x = 0,4 x = 0,08 m = 27nAl + 23nNa = 5,84(g)
Cu 27: Chn B.
- Cc phn ng xy ra:
t0
(1) CH3COOCH=CH2 (M) + NaOH CH3COONa (A) + CH 3CHO (B)

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0
(2) CH3CHO (B) + AgNO 3 + NH3 t
CH3COONH4 (F) + Ag + NH 4NO3
0
(3) CH3COONH4 (F) + NaOH t
CH3COONa (A) + NH 3 + H2O
Cu 28: Chn A.
- X v Y ln lt l NH2CH2COOCH3 v CH2 = CH COONH4.
0
t
NH 2 CH 2 COOCH 3 (X) + NaOH NH 2CH 2COONa + CH 3OH(Z)
0
t
CH 2 = CH - COONH 4 (Y) + NaOH CH 2 = CH - COONa + NH 3 (T) + H 2O
Cu 29: Chn B.

01
- X c 2 ng phn cu to l HCOONH 3C2H5 v HCOONH(CH 3)2.

oc
0
t
HCOONH 3C 2 H 5 + NaOH HCOONa + C 2H 5 NH 2 + H 2O
0
t
HCOONH 2 (CH 3 ) 2 + NaOH HCOONa + CH 3 NHCH 3 + H 2 O

H
Cu 30: Chn A.

ai
(a) Cu(d) + 2Fe(NO3)3 Cu(NO3)2 + 2Fe(NO3)2

D
(b) CO2 (d) + NaOH NaHCO3

hi
(c) Na2CO3 (d) + Ca(HCO3)2 CaCO3 + 2NaHCO3 (ngoi ra cn Na2CO3 d)

nT
(d) Fe d + 2FeCl3 3FeCl2

uO
Vy c 2 th nghim dung dch thu c ch cha 1 mui tan l (b), (d).
Cu 31: Chn A.

ie
mbnh 1 t ng mbnh 2 t ng
- t chy hn hp este th: nH 2O = = 0,345mol v nCO2 = nCaCO3 =
iL = 0,345mol
18 100
- Nhn thy rng nH 2O = nCO2 , nn trong X ch cha cc este no, n chc, mch h.
Ta

Cu 32: Chn D.
s/

- Khi t chy m gam X ta nhn thy nCO2 = nH 2O X cha 2 este no, n chc mch h.
up

BT:O 2nCO2 + nH 2O - 2nO2 nCO2

n- COO = nX = = 0,06mol CX = = 3(C3H 6O2 )
2 nX
ro

- Khi cho m gam X trn tc dng vi 0,11 mol KOH th :

/g

68nHCOOK + 82nCH 3COOK = m rn khan - 56nKOH = 5,18 nHCOOK = 0,05mol n 0,01 1

CH 3COOK = =
nHCOOK + nCH 3COOK = nX = 0,06 nCH 3COOK = 0,01mol
om

nHCOOK 0,05 5
Cu 33 : Chn C.
- Quy i hn hp X thnh C2H3ON (a mol), -CH 2 (b mol) v H2O (c mol).
.c

- Khi cho X tc dng vi dung dch NaOH th c hn hp quy i gm C 2H4ONNa (a mol) v CH 2

ok

(b mol). Xt qu trnh t chy hn hp mui ta c h sau:

97n NH CH COONa + 14n CH - (57n C H ON + 14n CH + 18n H O ) = D m 40a - 18c = 15,8
bo

a = 0, 44


2 2 2 2 3 2 2

44n CO 2 + 18n H 2O = m bnh Z 102a + 62b = 56, 04 b = 0,18
ce

BT:N a = 0, 44
n C 2H 3ON = 2n N 2
c = 0,1
.fa

- Ta c: n Ala = n CH 2 = 0,18 mol n Gly = 2n N 2 - n Ala = 0, 26 mol

n A + n B = n H 2O n A + n B = 0,1 n A = 0, 06 mol
w

- Xt hn hp X ta c :
4n A + 5n B = 2n N 2 4n A + 5n B = 0, 44 n B = 0, 04 mol
w

- Gi peptit A v B ln lt l (Gly) x (Ala) 4-x v (Gly) y (Ala)5-y (v i x < 4 v y < 5) .

w

BT:Gly

nA .x + nB.y = nGly 0,06x + 0,04y = 0,26 x = 3 v y = 2 (tha)
0,04.M Gly 2Ala3 0,04.345
%mB = = .100% = 46,94
mX 57.0,44 + 14.0,18 + 18.0,1
Cu 34: Chn D.

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- Khi thu phn khng hon ton peptit trn th thu c 5 tripeptit m trong thnh phn c
phenylalanin (Phe) l: Pro-Gly-Phe, Gly-Phe-Ser, Phe-Ser-Pro, Ser-Pro-Phe v Pro-Phe-Arg.
Cu 35: Chn D.
- V dng 1 lng d Ca(OH) 2 nn n CO 2 = n CaCO3 = 0, 09 mol
vi mdd gim = mCaCO3 - (44nCO2 + 18nH 2O ) = 3,78 nH 2O = 0,07mol
- Xt hn hp cc cht trong X: HCOOCH3 (k=1); CH2=CH-CHO (k=2) v CH 2=CH-COOCH3 (k=2)
quan h

CO v H O
nC3H 4O + nC4H 6O2 = nCO2 - nH 2O = 0,02 mol

01
2 2

n CO 2 - 4n C4H 6O 2
- m X(min) th n C 2H 4O 2 min khi v ch khi: n C3H 4O = 0 n C 2H 4O 2 = = 0, 005 mol

oc
2
m X(min) = 60n C2H 4O2 + 86n C4 H6O2 = 2, 02 (g) (tha mn vi p n ca ).

H
0, 02

ai
- Lu : Nu ta cho n C3H 4O = n C 4H 6O 2 = = 0, 01 mol th lc ny ta s gii ra c chnh xc p
2

D
n ca bi cho.

hi
Cu 36: Chn C.
2nC2H 3Cl

nT
H1.H 2 .H 3
- Ta c : H = = 0,12825 nCH 4 = = 0,25.103 mol
100 H

uO
nCH 4
VCH 4 (trong t nhin) = .22,4 = 5883,25(m3)
0,95

ie
Cu 37: Chn C. iL
- Khi t chy X c nCO2 = nH 2O 44nCO2 + 18nH 2O = mbnh t ng 44a + 18a = 7,75 a = 0,125mol
Ta
- Xt qu trnh X tc dng vi NaOH :
+ Nhn thy rng, nNaOH > nanken , trong trong X cha 1 este v 1 axit. Khi dehirat ha ancol th :
s/

neste(A ) = nanken = 0,015mol naxit(B) = nX - neste = 0,025mol

up

- Gi CA v CB ln lt l s nguyn t C ca este A v axit B (vi C A 3, CB 1)

nA .CA + nB.CB = nCO2 0,015CA + 0,025CB = 0,125 CA = 5 v CB = 2(tha)
ro

Vy (A) l C5H10O2 v (B) l C2H 4O2

/g

A. Sai, chnh lch khi lng gia A v B l: Dm = 102nA - 60nB = 0,03(g)

om

B. Sai, Tng khi lng phn t khi ca A v B l 162.

102nA
C. ng, %mA =
.c

.100% = 50,5 %mB = 49,5

102nA + 60nB
ok

D. Sai, Este A c 7 ng phn tng ng l: CH 3COO-C3H7 (2 ng phn) ; HCOO-C4H9 (4 ng

phn) ; C2H5COOC2H5 (1 ng phn) v axit B ch c 1 ng phn l CH 3COOH.
bo

Cu 38: Chn D.
- Khi cho 0,6 mol CO 2 tc dng vi dung dch X gm 0,3 mol Ba(OH) 2 v 0,2 mol NaOH:
ce

n - BT: C
V OH < nCO2 < nOH - nCO32- = nOH - - nCO2 = 0,2mol nHCO3- = nCO2 - nCO32- = 0,4mol
.fa

2
- Khi cho dung dch Y tc dng vi dung dch cha 0,24 mol BaCl 2 v 0,3 mol KOH th:
w

HCO3- + OH - + Ba2+
BaCO3 + H 2O
w

0,4mol 0,3mol 0,54mol 0,3mol

w

mBaCO3 = 0,3.197 = 59,1(g)

Cu 39: Chn A.
(a) Sai, Hidro ha glucoz thu c soritol:
HOCH2[CHOH]4CHO + H2 Ni ,t 0
HOCH2[CHOH]4CH2OH

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(b) ng, Trong d dy ca cc ng vt nhai li nh tru, b c cha enzim xenlulaza c th lm

thy phn xenluloz.
(c) Sai, Xenluloz trinitrat l cht d chy v n mnh c dng lm thuc sng.
(d) ng, Do H2SO4 c c tnh ho nc nn khi cho H 2SO4 vo ng saccaroz th :
C12(H2O)11 + H2SO4(c) C(en) + H2SO4.11H2O
(e) ng, Trong cng nghip dc phm, saccaroz c dng pha ch thuc.
Vy c 3 pht biu ng l (b), (d) v (e)
Cu 40: Chn A.

01
t0
- Phng trnh phn ng : CH 3NH 3HCO3 + 2KOH K 2CO3 + CH 3NH 2 + H 2O

oc
0,1mol 0,25mol 0,1mol

m rn = 138nK 2CO3 + 56nKOH(d ) = 16,6(g)

H
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