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S GD T THI TH LN 1 THPT QUC GIA NM 2017

TNH VNH PHC Mn: KHOA HC T NHIN HA HC
Thi gian lm bi: 50 pht, khng k thi gian pht
( thi c 40 cu / 4 trang)
M : 135
Cho bit nguyn t khi ca cc nguyn t :
H =1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S =32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;

01
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.

oc
Cu 1: Khi ni v kim loi, pht biu no sau y sai ?
A. Kim loi c cng ln nht l Cr.

H
B. Kim loi dn in tt nht l Cu.

ai
C. Kim loi c nhit nng chy cao nht l W.

D
D. Kim loi c khi lng ring nh nht l Li.

hi
Cu 2: Vinyl axetat c cng thc cu to thu gn l:
A. CH3COOCH2-CH3 B. CH3COOCH3

nT
C. CH3COOCH=CH2 D. CH2=CH-COOCH3
Cu 3: Trong iu kin thng, X l cht rn, dng si mu trng. Phn t X c cu trc mch khng

uO
phn nhnh, khng xon. Thy phn X trong mi axit, thu c glucoz.Tn gi ca X l:
A. Fructoz B. Amilopectin C. Xenluloz D. Saccaroz

ie
Cu 4: Trong nhng nm 30 ca th k XX, cc nh ha hc ca hng Du Pont (M) thng bo
iL
pht minh ra mt loi vt liu mng hn t nhn, bn hn thp v p hn la. Theo thi gian, vt
liu ny c mt trong cuc sng hng ngy ca con ngi, ph bin trong cc sn phm nh lp
Ta
xe, d, qun o, tt, Hng Du Pont thu c hng t la mi nm bng sng ch v loi vt
liu ny. Mt trong s vt liu l t nilon-6. Cng thc mt on mch ca t nilon-6 l:
s/

A. (-CH2-CH=CH-CH2)n B. (-NH-[CH2]6-CO-)n
up

C. (-NH-[CH2]6-NH-CO-[CH2]4-CO-)n D. (-NH-[CH2]5-CO-)n
Cu 5: Khi thay nguyn t H trong phn t NH 3 bng gc hidrocacbon, thu c ?
ro

A. amino axit B. amin C. lipt D. este

Cu 6: Hp cht khng lm i mu giy qu tm m l:
/g

A. NH3 B. H2N-CH2-COOH C. CH3COOH D. CH3NH2

om

Cu 7: Glucoz ln men thnh ancol etylic theo phn ng sau:

men
C 6 H12O 6
30-350 C
2C 2 H 5OH + 2CO 2
.c

thu c 92 gam C 2H5OH cn dng m gam glucoz. Bit hiu sut ca qu trnh ln men l 60%.
ok

Gi tr m l:
A. 360 B. 108 C. 300 D. 270
bo

Cu 8: un nng 14,6 gam Gly-Ala vi lng d dung dch NaOH. Sau khi phn ng xy ra hon
ton, thu c dung dch cha m gam mui. Gi tr m l:
ce

A. 22,6 B. 18,6 C. 20,8 D. 16,8

Cu 9: Hp cht no di y thuc loi amino axit ?
.fa

A. CH3COOC2H5 B. HCOONH4 C. C2H5NH2 D. H2NCH2COOH

Cu 10: Thy phn 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy
w

ra hon ton, c cn dung dch, thu c m gam cht rn khan. Ga tr ca m l:

w

A. 8,20 B. 10,40 C. 8,56 D. 3,28

w

Cu 11: Cho m gam hn hp kim loi Zn, Cu vo dung dch HCl (d). Sau khi cc phn ng xy ra
hon ton, thu c 4,48 lt H 2 (ktc) v 2,0 gam kim loi khng tan. Ga tr ca m l:
A. 8,5 B. 18,0 C. 15,0 D. 16,0
Cu 12: X phng ha tristearin bng NaOH, thu c glixerol v cht X. Cht X l:
A. CH3[CH2]16(COOH)3 B. CH3[CH2]16COOH
C. CH3[CH2]16(COONa) 3 D. CH3[CH2]16COONa

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Cu 13: Cho dy cc kim loi: Na, Ca, Cu, Fe, K. S kim loi trong dy tc dng vi H 2O to dung
dch baz l:
A. 2 B. 4 C. 3 D. 1
Cu 14: Polime no sau y l polime thin nhin ?
A. Amiloz B. Nilon-6,6 C. Cao su isopren D. Cao su buna
Cu 15: ng fructoz c nhiu trong mt ong, ngoi ra cn c trong cc loi hoa qu v rau xanh
nh i, cam, xoi, rau dip xon, c chuart tt cho sc khe. Cng thc phn t ca fructoz l:
A. C12H22O11 B. C6H12O6 C. C6H10O5 D. CH3COOH
Cu 16: Polime no sau y c cu trc mch phn nhnh ?

01
A. Amilopectin B. Xenluloz C. Cao su isopren D. PVC

oc
Cu 17: iu kin thng, amin X l cht lng, d b oxi ha khi ngoi khng kh. Dung dch X
khng lm i mu qu tm nhng tc dng vi nc brom to kt ta trng. Amin X l:

H
A. anilin B. metylamin C. imetylamin D. benzylamin

ai
Cu 18: Cho 9,0 gam glucoz phn ng hon ton vi lng d dung dch AgNO 3 trong NH3 (un
nng), thu c m gam Ag.Ga tr ca m l :

D
A. 16,2 B. 21,6 C. 5,4 D. 10,8

hi
Cu 19: Hai cht no sau y u tham gia phn ng trng hp to ra polime ?

nT
A. Vinyl clorua v caprolactam B. Axit aminoaxetic v protein
C. Etan v propilen D. Butan-1,3-ien v alanin

uO
Cu 20: Tin hnh phn ng kh oxit X thnh kim loi bng kh CO (d) theo s hnh v:

ie
iL
Ta
s/

Oxit X l:
up

A. Al2O3 B. K2O C. CuO D. MgO

Cu 21: Mt on mch PVC c 1000 mt xch. Khi lng ca on mch l:
ro

A. 12500 vC B. 62500 vC C. 25000 vC D. 62550 vC

/g

Cu 22: Cho C2H4(OH)2 phn ng vi hn hp gm CH 3COOH v HCOOH trong mi trng axit

(H2SO4), thu c ti a s este thun chc l:
om

A. 3 B. 2 C. 4 D. 1
Cu 23: Ba dung dch: glucoz, saccaroz v fructoz c tnh cht chung no sau y ?
.c

A. un nng vi Cu(OH) 2 c kt ta gch.

ok

B. Ha tan Cu(OH)2 cho dung dch mu xanh lam.

C. u tc dng vi dung AgNO 3/NH3 to kt ta Ag.
bo

D. u tham gia phn ng thy phn.

Cu 24: Cht trng thi lng iu kin thng l:
ce

A. Natri axetat B. Tripanmetin C. Triolein D. Natri fomat

Cu 25: Hn hp X gm Fe2O3, FeO v Cu (trong st chim 52,5% v khi lng). Cho m gam X
.fa

tc dng vi 420 ml dung dch HCl 2M d, thu c dung dch Y v cn li 0,2 m gam cht rn
khng tan. Cho dung dch AgNO 3 d vo Y thu c kh NO v 141,6 gam kt ta. Bit cc phn
w

ng xy ra hon ton. Gi tr ca m l:
w

A. 20 B. 32 C. 36 D. 24
w

Cu 26: Hn hp M gm mt peptit X v mt peptit Y u mch h ( c cu to t 1 loi amino

axit, tng s nhm CO-NH- trong 2 phn t l 5 ) vi t l mol X : Y=1 : 3. Khi thy phn hon ton
m gam M thu c 81 gam glyxin v 42,72 gam alanin. Gi tr ca m l:
A. 116,28 B. 109,5 C. 104,28 D. 110,28
Cu 27: Cho 34 gam hn hp X gm 2 este n chc mch h u thuc hp cht thm (t khi hi
ca X so vi O 2 lun bng 4,25 vi mi t l mol ca 2 este). Cho X tc dng va vi 175 ml dung

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dch NaOH 2M. C cn dung dch sau phn ng thu c hn hp Y gm hai mui khan. Thnh phn
phn trm v khi lng ca 2 mui trong Y l:
A. 46,58% v 53,42% B. 56,67% v 43,33% C. 55,43% v 55,57% D. 35,6% v 64,4%
Cu 28: Cho cc pht biu sau:
(a) Thy phn hon ton vinyl axetat bng NaOH thu c natri axetat v andehit fomic.
(b) Polietilen c iu ch bng phn ng trng ngng.
(c) iu kin thng anilin l cht kh.
(d) Tinh bt thuc loi polisaccarit.
(e) iu kin thch hp triolein tham gia phn ng cng hp H 2.

01
S pht biu ng l:

oc
A. 2 B. 4 C. 5 D. 3
Cu 29: Cho 0,05 mol hn hp 2 este n chc X v Y phn ng va vi dung dch NaOH thu

H
c hn hp cc cht hu c Z. t chy hon ton Z thu c 0,12 mol CO 2 v 0,03 mol

ai
Na2CO3 .Nu lm bay hi hn hp Z thu c m gam cht rn khan .Gi tr ca m l:
A. 3,48 B. 2,34 C. 4,56 D. 5,64

D
Cu 30: Cho cc cht sau: amiloz, amilopectin, saccaroz, xenluloz, fructoz, glucoz. S cht

hi
trong dy b thy phn khi un nng vi dung dch axit v c l:

nT
A. 3 B. 5 C. 6 D. 4
Cu 31: Hn hp no sau y thuc loi ipeptit ?

uO
A. H 2 N - CH 2 - CO - NH - CH(CH 3 ) - COOH
B. H 2 N - CH 2 - CH 2 - CO - CH 2 - COOH

ie
C. H 2 N - CH 2 - CO - NH - CH 2 - CO - NH - CH 2 - COOH
D. H 2 N - CH 2 - CH 2 - CO - NH - CH 2 - CH 2 - COOH
iL
Cu 32: ha tan hon ton hn hp X gm 11,2 gam Fe v 4,8 gam Fe 2O3 cn dng ti thiu V
Ta
ml dung dch HCl 2M, thu c dung dch Y .Cho dung dch AgNO 3 vo d vo Y thu c m gam
kt ta . Gi tr ca V v m ln lt l:
s/

A. 290 v 83,23 B. 260 v 102,7 C. 290 v 104,83 D. 260 v 74,62

up

Cu 33: X phng ha hon ton m gam triglixerit X bng lng va NaOH thu c 0,5 mol
gilixerol v 459 gam mui khan. Gi tr ca m l:
ro

A. 444 B. 442 C. 443 D. 445

Cu 34: Cho hn hp X gm 0,56 gam Fe v Mg tc dng vi 250 ml dung dch CuSO 4. Sau khi cc
/g

phn ng xy ra hon ton, thu c 0,92 gam kim loi. Nng mol/l ca dung dch CuSO 4 l:
om

A. 0,02M B. 0,04M C. 0,05M D. 0,10M

Cu 35: Cho 20 gam hn hp gm 3 amin no, n chc, l ng ng lin tip ca nhau (c trn
.c

theo t l mol 1 : 10 : 5 v th t phn t khi tng dn) tc dng va vi dung dch HCl, thu c
31,68 gam hn hp mui. Cng thc phn t ca ba amin l :
ok

A. C2H7N, C3H9N, C4H11N B. C3H7N, C4H9N, C5H11N

C. CH5N, C2H7N, C3H9N D. C3H8N, C4H11N, C5H13N
bo

Cu 36: Cho 86,3 gam hn hp X gm Na, K, Ba v Al 2O3 (trong oxi chim 19,47% v khi
lng) tan ht vo nc, thu c dung dch Y v 13,44 lt kh H 2 (ktc). Cho 3,2 lt dung dch HCl
ce

0,75M vo dung dch Y. Sau khi cc phn ng xy ra hon ton, thu c m gam kt ta. Gi tr ca
.fa

m l:
A. 10,4 B. 27,3 C. 54,6 D. 23,4
w

Cu 37: X phng ha cht bo X, thu c glixerol v hn hp hai mui l natriolat, natri panmitat
c t l mol 1:2. Hy cho bit cht X c bao nhiu cng thc cu to ?
w

A. 3 B. 4 C. 1 D. 2
w

Cu 38: Nhn xt no sau y khng ng ?

A. Tripeptit Gly-Ala-Gly c phn ng mu biure.
B. Lin kt peptit l lin kt CO-NH- gia hai n v -amino axit.
C. Cc dung dch Glyxin, Alanin, Lysin u khng lm i mu qu tm.
D. Polipeptit b thy phn trong mi trng axit hoc kim.

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Cu 39: Hn hp E gm cht X (C3H10N2O4) v cht Y (C3H12N2O3). X l mui ca axit hu c a

chc, Y l mui ca mt axit v c. Cho 3,86 gam E tc dng vi dung dch NaOH d, un nng, thu
c 0,06 mol hai cht kh (c t l mol 1 : 5) v dung dch cha m gam mui. gi tr ca m l:
A. 5,92 B. 4,68 C. 2,26 D. 3,46
Cu 40: Thc hin phn ng chuyn ha PVC thnh t clorin bng cch cho Clo tc dng vi PVC.
Trong t clorin, Clo chim 66,67% v khi lng. S mc xch trung bnh ca PVC phn ng vi
1 phn t Clo l:
A. 2 B. 3 C. 4 D. 1

01
oc
----------HT----------

H
ai
D
hi
nT
uO
ie
iL
Ta
s/
up
ro
/g
om
.c
ok
bo
ce
.fa
w
w
w

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PHN TCH HNG DN GII

THI TH LN 1 S GD & T TNH VNH PHC M 135

Cu 1: Chn B.
A. ng, Kim loi cng nht l Cr, kim loi mm nht l Cs.
B. Sai, dn in gim dn theo dy: Ag > Cu > Au > Al > Fe.
C. ng, Kim loi c nhit nng chy cao nht l W, kim loi c nng chy thp nht l Hg.

01
D. ng, Kim loi c khi lng ring ln nht l Os, kim loi c khi lng ring nh nht l Li.
Cu 2: Chn C.

oc
Cng thc cu to CH3COOC2H5 CH3COOCH3 CH3COOCH=CH2 CH2=CH-COOCH3
Tn gi Etyl axetat Metyl axetat Vinyl axetat Metyl acrylat

H
Cu 3: Chn C.

ai
- Fructoz v saccaroz iu kin thng tn ti dng tinh th mu trng.

D
- Amilopectin l mt on mch ca tinh bt c mch phn nhnh, l cht rn v nh hnh khng tan
trong nc ngui, trong nc nng (khong 65 oC) to thnh dung dch keo (gi l h dn).

hi
- Xenluloz iu kin thng l cht rn, dng si mu trng, phn t c cu trc mch khng phn

nT
nhnh, khng xon v c cu to t cc mc xch glucoz nn khi thy phn trong mi trng
axit thu c glucoz.

uO
Vy cht rn X cn tm l xenluloz.
Cu 4: Chn D.

ie
- iu ch t nilon-6 bng phn ng trng ngng axit--aminocaproic:
xt,p,t o
iL
nH 2N - [CH 2 ]5 - COOH ( HN - [CH 2 ]5 - CO ) n + nH 2O
Ta
Cu 5: Chn B.
Cu 6: Chn B.
s/

Hp cht NH3 H2N-CH2-COOH CH3COOH CH3NH2

up

Mu qu m Xanh Khng mu Xanh

Cu 7: Chn C.
ro

- Ta c: n 5
n C6H12O 6 = C2H5OH = m C6H12O6 = 300 (g)
2.H% 3
/g

Cu 8: Chn C.
om

- Ta c: 14,6
nGlyNa = nAlaNa = nGly -Ala = = 0,1mol mmui = 97nGlyNa + 111nAlaNa = 20,8(g)
146
.c

Cu 9: Chn D.
- Amino axit l nhng hp cht hu c tp chc phn t cha ng thi nhm amino (-NH 2) v nhm
ok

cacboxyl (-COOH).
Cu 10: Chn D.
bo

- Phn ng : CH 3COOC 2 H 5 + NaOH t0

CH 3COONa + C 2 H 5OH

ce

0,1mol 0,04 mol 0,04 mol

m CH 3COONa = 3, 28(g)
.fa

Cu 11: Chn C.
BT:e
w

nZn = nH 2 = 0,2mol m = 65nZn + mCu(rn khng tan) = 15(g)
w

Cu 12: Chn D.
w

- Phn ng: (CH 3[CH2]16COO)3C3H5 + 3NaOH t0

3CH3[CH2]16COONa + C3H5(OH)3
Tristearin Natri sterat (X) Glixerol
Cu 13: Chn C.
- Cu khng tc dng vi H 2O trong khi Fe tc dng vi nc nhit cao to thnh cc oxit st
tng ng.

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Vy c 3 kim loi Na, Ca v K trong dy tc dng vi nc nhit thng to dung dch baz
ln lt l NaOH, Ca(OH) 2 v KOH.
Cu 14: Chn A.
Polime thin nhin Polime tng hp
amiloz Nilon-6,6, cao su isopren, cao su buna
Cu 15: Chn B.
Cng thc C12H22O11 C6H12O6 (C6H10O5)n CH3COOH
Tn gi Saccaroz Glucoz Tinh bt Axit axetic

01
Mantoz Fructoz Xenluloz
Cu 16: Chn A.

oc
- Cc polime mch phn nhnh thng gp l amilopectin v glicozen
- Cc polime mch khng gian thng gp l cao su lu ha v nha rezit.

H
- Cn li l cc polime mch phn nhnh.

ai
Cu 17: Chn A.

D
- Cht X l anilin (C6H5NH2) khi ngoi khng kh th b oxi trong khng kh oxi ha thnh mu

hi
nu en. Dung dch anilin khng lm i mu qu tm nhng tc dng vi nc brom to kt ta
trng theo phng trnh sau :

nT
uO
ie
iL
Cu 18: Chn D.
Ta

- Ta c : nAg = 2nC6H12O6 = 0,1.108 = 10,8(g)

s/

Cu 19: Chn A.
up

- Trng hp caprolactam to t capron

CH2 CH2 C O
n CH2 N (CH2)5 C
ro

to
CH2 CH2 C N n
/g

H O
- Trng hp vinyl clorua to t poli(vinyl clorua)
om

n CH2 to, p, xt
CH CH2 CH
.c

Cl Cl n
ok

Cu 20: Chn C.
- nhit cao, kh CO, H2 c th kh c cc oxit kim loi ng sau Al trong dy in ha.
bo

Vy oxit X l CuO.
Cu 21: Chn B.
ce

- Ta c n = 1000, vy M ( -CH 2 -CH(Cl )- )1000 = 1000M C2H 3Cl = 62500

.fa

Cu 22: Chn A.
- C 3 este thun cha thu c l: C 2H4(OOCCH3)2, C2H4(OOCH)2 v HCOOCH2CH2OOCCH3.
w

- Lu : Este thun chc l este m trong phn t ch cha chc este m khng cha cc nhm chc
w

khc.
w

Cu 23: Chn B.
A. Sai, Ch c glucoz v fructoz un nng vi Cu(OH) 2 c kt ta gch.
B. ng, Tt c cc cht trn u ha tan Cu(OH) 2 cho dung dch c mu xanh lam.
C. Sai, Ch c glucoz v fructoz tc dng vi dung dch AgNO3/NH3 to kt ta Ag.
D. ng, Ch c saccaroz tham gia phn ng thy phn.
Cu 24: Chn C.

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- Cc cht bo c to thnh t cc gc axt bo no thng trng thi rn cn cc cht bo c

to thnh t cc gc axt bo khng no thng trng thi lng.
Cu 25: Chn B.
Cu(d ) :0,2m(g)
6amol
78 } bmol
HCl(d )
- Qu trnh: Fe2O3 ,FeO,Cu Fe2+ ,Cu2+ ,Cl - ,H + (d )
AgNO3
Ag,AgCl + NO
1442 443 1444 42 4444 3 142 43 {
m(g) cmol
dung dch Y 141,6(g)

BT:Cl m - 143,5nAgCl
- Xt hn hp kt ta ta c : nAgCl = nHCl = 0,84mol nAg = = 0,195mol

01
108
- Khi cho X tc dng vi HCl v dung dch Y tc dng vi AgNO 3 th ta c h sau :

oc
160nFe2O3 + 72nFeO + 64nCu(p ) = m - m rn 160a + 72b + 64a = 0,8m
a = 0, 05
m 56.2a + 56b

H

Theo ta c Fe
= 0,525 b = 0,2

= 0,525
mX

ai
m
c = 0,035

BT:e b + 2a = 3c + 0,195

D
n FeO + 2n Cu(p ) = 3n NO + n Ag
m = 32
6a + 2b + 4c = 0,84

hi
nHCl = 6nFe2O3 + 2nFeO + 4nNO

nT
Cu 26: Chn C.
- Khi gp X v Y vi t l mol tng ng l 1 : 3 c X + 3Y
XY3 + 3H 2O

uO
n Gly 1, 08 9
+ T: = = XY3 l (Gly)9k (Ala) 4k .
n Ala 0, 48 4
s
ie
mc xch(min) < s mc xch4443
14442 ca XY3 < s
iLmc xch(max) 7.1 < 13k < 7.3 k = 1
m 1442 443 1442 443
(5+ 2).nX 9k + 4k (5+ 2).n Z
Ta
nGly nAla nX = nXY3 = 0,12mol
+ Vi k = 1 n(Gly)3 Ala = nXY3 = = = 0,12mol
s/

9 4 nY = 3nXY3 = 0,36mol
up

- Khi thy phn m gam M th : nH 2O = nM = nX + nY = 0,48mol v

- Quy i hn hp M thnh H2O, CH2 v C2H3ON.
ro

+ Ta c : nC2H3ON = nGly + nAla = 1,56mol v n-CH 2 = nAla = 0,48mol

/g

mM = 57nC2H 3ON + 14n- CH 2 + 18nH 2O = 104,28(g)

om

Cu 27: Chn A.
nNaOH
- Nhn thy rng 1 < < 2 , nn trong hn hp este c 1 este c to thnh t phenol (hoc
.c

neste
ng ng). Theo d kin bi ta c M X = 136 (C 8H8O2), mc khc dung dch Y ch cha hai mui
ok

khan nn hn hp X cha HCOOCH 2C6H 5(A) v HCOOC 6 H 4CH 3 (B) .

bo

nA + nB = n X nA + nB = 0,25 nA = 0,1mol
- Khi cho X tc dng vi NaOH th:
2nA + nB = nNaOH 2nA + nB = 0,35 nB = 0,15mol
ce

mmui = 68nHCOONa + 116nCH 3C6H 4ONa = 36,5(g) %mHCOONa = 46,58 v %mCH 3C6H 4ONa = 53,42
.fa

Cu 28: Chn A.
t0
(a) Sai, Phn ng: CH3COOCH=CH2 + NaOH CH3COONa + CH3CHO (andehit axetic)
w
w

o
xt,t ,p
(b) Sai, Polietilen c iu ch bng phn ng trng hp: CH 2 = CH 2 ( CH 2 - CH 2 ) .
w

(c) Sai, iu kin thng anilin l cht lng.

(d) ng, Tinh bt v xenluloz thuc loi polisaccarit.
Ni, t 0
(e) ng, Phn ng: (C17 H 33COO)3 C3H 5 + 3H 2 (C17 H 35COO) 3 C3H 5
triolein tristearin
Vy c 2 pht biu ng l (d) v (e)

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Cu 29: Chn C.
nNaOH
- Nhn thy rng 1 < < 2 , nn trong hn hp este c cha este c to thnh t phenol (hoc
neste
ng ng). Gi 2 este l A v B (vi CA 2 v CB 7)
nA + nB = 0,05 nA = 0,04mol
- Este tc dng vi NaOH th :
nA + 2nB = nNaOH = 0,06 nB = 0,01mol
- Khi t hn hp Z th :
CA = 2(HCOOCH 3 )

01
BT:C
nA .CA + nB.CB = nNa2CO3 + nCO2 0,04CA + 0,01CB = 0,15
CB = 7(HCOOC6 H 5)

oc
mmui = 68nHCOONa + 116nC6H 5ONa = 4,56(g)

H
Cu 30: Chn D.

ai
- C 4 cht trong dy khi thy phn khi un nng vi dung dch axit v c l: amiloz, amilopectin,

D
saccaroz v xenluloz.
Cu 31: Chn A.

hi
- ipeptit c to thnh t 2 n v - amino axit c s lin kt peptit l 1.

nT
- Lu : cu B, D cht ban u khng c to thnh t cc - amino axit nn khng c gi l
peptit.

uO
Cu 32: Chn B.
0,52
- Ho tan hon ton X th: nHCl(ti thiu) = 2nFeCl 2 = 2(nFe + 2nFe2O3 ) = 0,52mol VHCl = = 0,26(l)

ie
iL 2

BT:e
nAg = nFeCl 2 = 0,26mol
- Khi cho dung dch Y tc dng vi AgNO 3 th:
Ta
nAgCl = nHCl(ti thiu) = 0,52mol
s/

- Khi : m = 108nAg + 143,5nAgCl = 102,7(g)

up

Cu 33: Chn D.
- Ta c: nNaOH(p ) = 3nC3H 5(OH) 3 = 1,5mol
ro

BTKL
mx phng = mmui + 40nNaOH - 92nC3H 5(OH)3 = 445(g)
/g

Cu 34: Chn B.
om

TGKL
nMg.DM Cu-Mg + nFe(p ) .DM Cu-Fe = mrn - mFe,Mg(ban u) 0,005.40 + 8x = 0,24 x = 0,005
BT:e

nCuSO4 = nMg + nFe(p ) = 0,01mol CM(CuSO4 ) = 0,04M
.c

Cu 35: Chn A.
ok

- Gi X l cht c khi lng phn t nh nht trong 3 amin. Cho amin tc dng vi HCl th:
- mamin
bo

BTKL m
nHCl = mui = 0,32mol nX = 0,02mol; nY = 0,2mol v nZ = 0,1mol
36,5
ce

nX M X + nY (M X + 14) + n Z (M X + 28) = mamin = 2 M X = 45

Vy 3 amin c CTPT ln lt l : C2H 7N,C3H 9N v C4H11N
.fa

Cu 36: Chn D.
w

n O(trong X) 86,3.0,1947
- Theo ta c : n Al2O3 = = = 0,35mol
w

3 16.3
w

- Khi ha tan hn hp X bng nc. Xt dung dch Y ta c:

BTDT
+ n AlO2 - = 2n Al2O3 = 0, 7 mol n OH - = 2n H 2 - 2n AlO 2 - = 0,5 mol
- Khi cho dung dch Y tc dng vi 2,4 mol HCl, v: n AlO 2 - + n OH - < n H + < 4n AlO2 - + n OH -

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4n AlO 2 - - (n H + - n OH - )
n Al(OH)3 = = 0,3mol m Al(OH) 3 = 23, 4 (g)
3
Cu 37: Chn D.
- Gi A l gc C17H33COO- (oleat) v B l gc C15H31COO- (panmitat)
- X c hai cng thc cu to tha mn vi cc gc sau: A B B v B A B.
Cu 38: Chn C.
A. ng, Cc peptit c 2 lin kt CONH tr ln u tham gia phn ng mu biure.
B. ng, Lin kt peptit l lin kt CO-NH gia hai n v -amino axit.

01
C. Sai, Ch c lysin lm qu tm ha xanh, cn glyxin v alanin khng lm i mu qu tm.
D. ng, Tt c cc polipeptit b thy phn trong mi trng axit hoc kim.

oc
Cu 39: Chn D.
- Gi a v b ln lt l s mol ca X v Y. Khi cho E tc dng vi NaOH th :

H
t0
NH 4OOC - COONH 3CH 3 + NaOH (COONa)2 + NH 3 + CH 3NH 2 + H 2O

ai
amol amol amol amol

D
t0
(CH 3NH 3 )2 CO3 + NaOH 2CH 3NH 2 + Na2CO3 + H 2O

hi
bmol 2bmol bmol

nT
a + 2b = 0,05 a = 0,01mol
Ta c mmui = 134n(COONa)2 + 106nNa2CO3 = 3,46(g)
a = 0,01 b = 0,02mol

uO
Cu 40: Chn A.
- Phn ng: (C2H3Cl)n + Cl2 C2nH3n-1Cln+1 + HCl

ie
35,5(n + 1) iL
- Ta c: %Cl = = 0,6667 n = 2
12.2n + 3n - 1 + 35,5(n + 1)
Ta
s/
up
ro
/g
om
.c
ok
bo
ce
.fa
w
w
w

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